Transcription

1 Positive list system simultaneous test method compliant Pesticides Standard Solution

2

3 Positive lis system simultaneous test method compliant Pesticides standard solution -CONTENTS- Simultaneous test method for agrochemical etc. by GC/MS Farm products Pesticides standard solution61 (49 kinds mixture)...4 Pesticides standard solution63 (44 kinds mixture)...6 Pesticides standard solution7 (83kinds mixture)...8 Pesticides standard solution48 (61 kinds mixture)...12 Pesticides standard solution51 (26 kinds mixture)...16 Livestock and Marine products Pesticides standard solution71 (52 kinds mixture)...18 Pesticides standard solution49 (71 kinds mixture)...22 Pesticides standard solution52 (47 kinds mixture)...26 Simultaneous test method for agrochemical etc. by LC/MS Farm products I Pesticides standard solution58 (35 kinds mixture)...28 Pesticides standard solution53 (29 kinds mixture)...3 Pesticides standard solution54 (28 kinds mixture)...32 Farm products II Pesticides standard solution45 (19 kinds mixture)...34 Pesticides standard solution55 (34 kinds mixture)...36 Livestock and Marine products I Appended table 1 Pesticides standard solution53 (29 kinds mixture)...3 Pesticides standard solution56 (24 kinds mixture)...38 Livestock and Marine products I Appended table 2 Pesticides standard solution53 (29 kinds mixture)...3 Pesticides standard solution56 (24 kinds mixture)...38 Pesticides standard solution57 (11 kinds mixture)...4 3

4 Pesticides standard solution 61 4 Example of analysis of Pesticides standard solution ZOOM(No.9 36) Column HP-5MS.25mmID 3m.25µm Oven 5 (1min) 25 /min /min 3 (6.5min) Flow He Injector 25 Split Splitless 1µL 33 Detection MSD Conc. 1ppm 9 1 2, ,18 2, ,

5 Peak No. Product name RT(min) Monitor Ion(m/z) Catalog No. packing 1 Methamidophos mg 2 EPTC mg 3 Acephate mg 4 Fenobucarb(BPMC) mg 5 Chlorpropham mg 6 Cadusafos mg 7 Thiometon mg 8 Dimethipin mg 9 Diazinon mg 1 Etrimfos mg 11 Pirimicarb mg 12 Benfuresate mg 13 Parathion-methyl mg 14 Carbaryl mg 15 Fenitrothion mg 16 Esprocarb mg 17 Dichlofluanid mg 18 Thiobencarb mg 19 Fenthion mg 2 Chlorpyrifos mg 21 Parathionl mg 22-1 Fosthiazate mg 22-2 Fosthiazate mg 23 Pendimethalin mg 24 Z -Pyrifenox mg 25 Captan mg 26 Phenthoate mg 27 E -Pyrifenox ppm/1 ml IO* 28 Prothiophos mg 29 Tricyclazole mg 3 Myclobutanil mg 31 Cyproconazole mg 32 Chlorobenzilate mg 33 p, p '-DDD mg 34 Mepronil mg 35 Edifenphos mg 36 Tebuconazole mg 37 Iprodione mg 38 EPN mg 39 Tebufenpyrad mg 4 Pyriproxyfen mg 41 Acrinathrin mg 42 Pyraclofos mg 43-1 Permethrin mg 43-2 Permethrin mg 44-1 Cyfluthrin mg 44-2 Cyfluthrin mg 44-3 Cyfluthrin mg 44-4 Cyfluthrin mg 45 Halfenprox mg 46 Silafluofen mg 47-1 Fenvalerate mg 47-2 Fenvalerate mg 48-1 Difenoconazole mg 48-2 Difenoconazole mg 49 Imibenconazole mg * IO:Isooctane solution Catalog No. Product Name Number of ingredient Pesticides standard solution Grade For pesticide residue analysis Packing 5 ml 5 5 ml 1 ( 5mg/L of acephate and methamidophos and 1mg/L of each other chemicals contained in acetone solution, Freeze storage) 5

6 Pesticides standard solution 63 Example of analysis of Pesticides standard solution Column HP-5MS.25mmID 3m.25µm Oven 5 (1min) 25 /min /min 3 (6.5min) Flow He Injector 25 Split Splitless 1µL Detection MSD Conc. 1ppm 25, ZOOM(No.6 28) , ZOOM(No.29 44)

7 Peak No. Product name RT(min) Monitor Ion(m/z) Catalog No. Packing Dichlorvos mg 2 Butylate mg 3 Isoprocarb mg 4 Ethoprophos mg 5 Bendiocarb mg 6 Terbufos mg 7 δ -HCH mg 8 Tefluthrin mg 9 Ethiofencarb mg 1 Tolclofos-methyl mg 11 Methiocarb mg 12 Pirimiphos-methyl mg 13 Malathion mg 14 Diethofencarb mg 15 Metolachlor mg 16 Z -Dimethylvinphos mg 17 Isofenphos-oxon mg 18-1 Chlorfenvinphos mg 18-2 Chlorfenvinphos mg 19 Isofenphos mg 2 Quinalphos mg 21-1 Triadimenol mg 21-2 Triadimenol mg 22 Chinomethionat mg 23 Paclobutrazol mg 24 Flutolanil mg 25 Pretilachlor mg 26 p, p '-DDE mg 27 Flusilazole mg 28 Fensulfothion mg 29-1 Propiconazole mg 3 Lenacil mg 29-2 Propiconazole mg 31 Thenylchlor mg 32 Captafol mg 33 Acetamiprid mg 34 Phosalone mg 35-1 Cyhalothrin mg 36 Mefenacet mg 35-2 Cyhalothrin mg 37 Fenarimol mg 38-1 Bitertanol mg 38-2 Bitertanol mg 39 Pyridaben mg 4-1 Cypermethrin mg 4-2 Cypermethrin mg 4-3 Cypermethrin mg 4-4 Cypermethrin mg 41-1 Flucythrinate mg 41-2 Flucythrinate mg 42 Pyrimidifen mg 43-1 Fluvalinate mg 43-2 Fluvalinate mg 44 Deltamethrin mg Catalog No. Product name Number of ingredient Grade Pesticides standard solution For pesticide residue analysis Packing 5 ml 5 5 ml 1 (5mg/L of acetamiprid and 1mg/L of each other chemicals contained in acetone solution, Freeze storage) 7

8 Pesticides standard solution 7 Example of analysis of Pesticides standard solution 7(No.1~37) Column ENV-5 MS.25 mmid 3m.25µm Oven 7 (2min) 25 /min 15 3 /min 2 8 /min 28 (1min) Flow He, 1.2ml/min Injector 28 Split Splitless 2µl Detection MSD 1 2 3, ,11, , , , ZOOM(No.7 37) ,11,12 2,21 31, ,

9 Peak No. Product name RT(min) Monitor Ion(m/z) Catalog No. Packing XMC mg 2 Tecnazene mg 3 Propachlor mg 4 Propoxur mg 5 Benfluralin mg 6 Monocrotophos mg 7 Dicloran mg 8 Carbofuran mg 9 Simazine mg 1 Quintozene mg 11 Clomazone mg 12 Atrazine mg 13 Cyanophos mg 14 Propyzamide mg 15 Isazofos mg 16 Triallate mg 17 Iprobenfos mg 18 Benoxacor mg 19 Phosphamidon mg 2 Bromobutide mg 21 Acetochlor mg 22 Chlorpyrifos-methyl mg 23 Propanil mg 24 Vinclozolin mg 25 Metalaxyl mg 26 Ametryn mg 27 Prometryn mg 28 Ethofumesate mg 29 Bromacil mg 3 Quinoclamine mg 31 Fenpropimorph mg 32 Chlorthal-dimethyl mg 33 Triadimefon mg 34 Nitrothal-isopropyl mg 35 Bromophos-methyl mg 36 Fthalide mg 37 Diphenamid mg 9

10 Example of analysis of Pesticides standard solution 7(No.38~83) Column ENV-5 MS.25 mmid 3m.25µm Oven 7 (2min) 25 /min 15 3 /min 2 8 /min 28 (1min) Flow He, 1.2ml/min Injector 28 73,74,75 Split Splitless 2µl Detection MSD ,5 67,68 57,58, , , ZOOM(No.38 78) 14 73,74, ,45 49, , ,58, ,

11 Peak No. Product name RT(min) Monitor Ion(m/z) Catalog No. Packing Dimethametryn mg 39-1 Allethrin mg 39-2 Allethrin mg 39-3 Allethrin mg 39-4 Allethrin mg 4 Dimepiperate mg 41 Methidathion mg 42 Tetrachlorvinphos mg 43 Fenothiocarb mg 44 Flutriafol mg 45 Napropamide mg 46 Fenamiphos mg 47 E -Metominostrobin ppm/1 ml AL* 48 Profenofos mg 49 Isoprothiolane mg 5 Isoxathion oxon mg 51 Oxadiazon mg 52 Tribufo(s DEF) mg 53 Flamprop-methyl mg 54 Buprofezin mg 55 Bupirimate mg 56 Oxyfluorfen mg 57 Z -Metominostrobin ppm/1 ml AL* 58 Azaconazole mg 59 Imazamethabenz-methyl mg 6 Isoxathion mg 61 Ethion mg 62 Oxadixyl mg 63 Fluacrypyrim mg 64 Benalaxyl mg 65 Carfentrazone-ethyl mg 66 Trifloxystrobin mg 67 Quinoxyfen mg 68 Norflurazon mg 69 Hexazinone mg 7-1 Propargite(BPPS) mg 7-2 Propargite(BPPS) mg 71 Diclofop methyl mg 72 Pyridaphenthion mg 73 Bromopropylate mg 74 Piperophos mg 75 Phosmet mg 76 Methoxychlor mg 77-1 Phenothrin-1 楈尀 mg 77-2 Phenothrin mg 78 Tetradifon mg 79 Pyrazophos mg 8 Fenbuconazole mg 81 Flumioxazin mg 82 Flumiclorac-pentyl mg 83 Tolfenpyrad mg *AL:Acetonitrile solution Catalog No. Product name Number of ingredient Grade Packing Pesticides standard solution 7 83 For pesticide residue analysis 2 ml 5 ( 1 mg/l of each chemicals contained in acetone-hexane solution(1:1), Freeze storage) 11

12 Pesticides standard solution 48 Example of analysis of Pesticides standard solution 48(No.1~39) Column ENV-5MS.25mmID 3m.25µm Oven 5 (1min) 25 /min /min 2 1 /min 3 (7min) Injector 28 Split Splitless 1µL Flow He 1.mL/min 29,3,31 Detection MSD 33 Conc. 1ppm 34,35, ,1 13, , ZOOM(No.9 39) ,3, , ,

13 Peak No. Product name RT(min) Monitor Ion(m/z) Catalog No. Packing 1 Mevinphos mg 2 Demeton-S-methyl mg 3 Ethalfluralin mg 4 Trifluralin mg 5 Phorate ppm/1 ml CY* 6 Dimethoate mg 7 Chlorbufam mg 8 Propazine mg 9 Pyroquilon mg 1 Pyrimethanil mg 11-1 Prohydrojasmon ppm/1.1 ml CY* 12 Terbacil mg 11-2 Prohydrojasmon ppm/1.1 ml CY* 13 Dichlofenthion mg 14 Dimethenamid mg 15-1 Spiroxamin mg 16 Alachlor mg 15-2 Spiroxamin mg 17 Simetryn mg 18 Terbutryn mg 19 Cyanazine mg 2 4,4 '-Dichlorobenzophenone mg 21-1 Methoprene mg 22 Fipronil mg 23 Penconazole mg 24-1 Diclocymet mg 21-2 Methoprene mg 25 Procymidone mg 24-2 Diclocymet mg 26 Butachlor mg 27 Butamifos mg 28 Hexaconazole mg 29 TCMTB mg 3 Thifluzamide mg 31 Fludioxonil mg 32 Uniconazole-P ppm/1 ml CY* 33 Kresoxim-methyl mg 34 Chlorfenapyr mg 35 Carboxin mg 36 Imibenconazole-desbenzyl mg 37 Fenoxanil mg 38 Z -Pyriminobac-methyl ppm/1 ml CY* 39 Triazophos mg * CY:cyclohexane solution 13

14 Example of analysis of Pesticides standard solution 48(No.4~61) Column ENV-5MS.25mmID 3m.25µm Oven 5 (1min) 25 /min /min 2 1 /min 3 (7min) Injector 28 Split Splitless 1µL 46 Flow He 1.mL/min 43,44,45 47,48,49 Detection MSD Conc. 1ppm 5,51,52 4,41 55, ZOOM(No.4 6) ,

15 Peak No. Product Name RT(min) Monitor Ion(m/z) Catalog No. Packing 4 E -Pyriminobac-methyl ppm/1 ml CY* 41 Pyraflufen-ethyl mg 42 Diflufenican mg 43 Mefenpyr-diethyl mg 44 Zoxamide mg 45 Pyributycarb mg 46 Bifenthrin mg 47 Picolinafen mg 48 Etoxazole mg 49 Fenpropathrin mg 5 Fenamidone mg 51 Anilofos mg 52 Bifenox mg 53 Cyhalofop-butyl mg 54 Azinphos-methyl mg 55 Spirodiclofen mg 56 Oryzalin mg 57 Fluquinconazole mg 58 Cafenstrole mg 59 Etofenprox mg 6 Fluridone mg 61 Fluthiacet methyl mg * CY:Cyclohexane solution Catalog No. Product name Number of ingredient Grade Pesticides standard solution For pesticide residue analysis ( 1 mg/l of each chemicals contained in acetone-hecane solution(1:1) Freeze storage) Packing 2 ml 5 2 ml 1 15

16 Pesticides standard solution 51 Example of analysis of Pesticides standard solution Column ENV-5MS.25mmID 3m.25µm Oven 5 (1min) 25 /min /min 2 1 /min 3 (1min) Injector 25 Split Splitless 1µL Flow He 1.mL/min 2 MS Full Scan Conc. 1ppm , ZOOM(No.1 25)

17 Peak No. Product name RT(min) Monitor Ion Catalog No. Packing 8 '* Carbofuran-3 -hydroxy mg 1 Chloroneb mg 2 Chlorethoxyfos mg 3 Dicrotophos mg 4-1 Diallate mg 4-2 Diallate mg 5 Dioxathion mg 6 Disulfoton mg 7 Formothion mg 8 Carbofuran-3 -hydroxy mg 9 Fenchlorphos mg 1 1 -Naphthyl acetamide mg 11 Tetraconazole mg 12 Chlozolinate mg 13 Mecarbam mg 14 Bromophos-ethyl mg 15 Propaphos mg 16 Chlorbenside mg 17 Disulfoton sulfone mg 18 Chlorfenson mg 19-1 Aramite mg 19-2 Aramite mg 19-3 Aramite mg 19-4 Aramite mg 2 Perthane mg 21 Flufenpyr-ethyl mg 22 Endosulfan-sulphate mg 23-1 Resmethrin mg 24 Piperonyl butoxide mg 23-2 Resmethrin mg 25 Epoxiconazole mg 26 Cinidon-ethyl mg * Carbofuran -3 - Degradation of Hydroxy Catalog No. Product name Number of ingredient Grade Pesticides standard solution For pesticide residue analysis Packing 2 ml 5 2 ml 1 ( 1 mg/l of each chemicals contained in acetone-hexane solution(1:1) Freeze storage) 17

18 Pesticides standard solution 71 Example of analysis of Pesticides standard solution 71(No.1~33) Column ENV-5MS.25mmID 3m.25µm Oven 5 (1min) 25 /min /min 3 (6.5min) Flow He 27 Injector 25 Split Splitless 1µL 3 Detection MSD 17 6,7 19 Conc. 1ppm 15, , ZOOM(No.3 33) , , ,

19 Peak No. Product name RT( mi n) Monitor Ion(m/z) Catalog No. Packing Methamidophos mg 2 Acephate mg 3 Dimethoate mg 4 Quintozene mg 5 Terbufos mg 6 Dimethipin mg 7 Diazinon mg 8 Tefluthrin mg 9 Pirimicarb mg 1 δ -HCH mg 11 Carbary(l NAC) mg 12 Pirimiphos-methyl mg 13 Fenitrothion mg 14 Malathion mg 15 Metolachlor mg 16 Chlorpyrifos mg 17 Thiobencarb mg 18 Fenthion mg 19-1 Chlorfenvinphos mg 2 Isofenphos mg 19-2 Chlorfenvinphos mg 21-1 Triadimenol mg 21-2 Triadimenol mg 22 Thiabendazole mg 23 Methidathion mg 24 Flutolanil mg 25 Imazalil mg 26 Fludioxonil mg 27 p,p '-DDE mg 28 Flusilazole mg 29 Myclobutanil mg 3 p,p '-DDD mg 31-1 Propiconazole mg 31-2 Propiconazole mg 32 Endosulfan-sulphate mg 33 Tebuconazole mg 19

20 Example of analysis of Pesticides standard solution 71(No.33~52) 5 4 Column ENV-5MS.25mmID 3m.25µm Oven 5 (1min) 25 /min /min 3 (6.5min) Flow He Injector 25 Split Splitless 1µL Detection MSD Conc. 1ppm 36,37 34, ZOOM(No.33 52) 5 34,35 36,

21 Peak No. Product name RT( mi n) Monitor Ion(m/z) Catalog No. Packing 34 Bifenthrin mg 35 Iprodione mg 36 Acetamiprid mg 37 Fenpropathrin mg 38 Methoxychlor mg 39-1 Cyhalothrin mg 39-2 Cyhalothrin mg 4 Pyriproxyfen mg 41 Azinphos-methyl mg 42 Fenarimol mg 43 Bitertanol mg 44-1 Permethrin mg 44-2 Permethrin mg 45 Pyridaben mg 46-1 Cyfluthrin mg 46-2 Cyfluthrin mg 46-3 Cyfluthrin mg 46-4 Cyfluthrin mg 47-1 Cypermethrin mg 47-2 Cypermethrin mg 48-1 Flucythrinate mg 47-3 Cypermethrin mg 47-4 Cypermethrin mg 48-2 Flucythrinate mg 49-1 Fluvalinate mg 5-1 Fenvalerate mg 49-2 Fluvalinate mg 5-2 Fenvalerate mg 51-1 Difenoconazole mg 51-2 Difenoconazole mg 52 Deltamethrin mg Catalog No. Product name Number of ingredient Grade Packing Pesticides standard solution For pesticide residue analysis ( 1 mg/l of each chemicals contained in acetone-hexane solution(1:1) Freeze storage) 2 ml 5 21

22 Pesticides standard solution 49 Example of analysis of Pesticides standard solution 49(No.1~26) Column ENV-5MS.25mmID 3m.25µm Oven 5 (1min) 25 /min /min 3 (6.5min) Flow He 1.mL/min Injector 25 Split Splitless 2µL Detection MSD Conc. 1ppm 6, , ZOOM(No.4 26) , ,

23 Peak No. Product name RT( mi n) Monitor Ion(m/z) Catalog No. Packing 1st 2nd 3nd 4th 5th 1 EPTC mg 2 Etridiazole mg 3 Chloroneb mg 4 Fenobucarb(BPMC) mg 5 Propoxur mg 6 Ethoprophos mg 7 Diphenylamine ppm/ 5 2 ml EA* 8 Trifluralin mg 9 Bendiocarb mg 1 Phorate ppm/1 ml CY* 2 11 Thiometon mg 12 Carbofuran mg 13 Simazine mg 14 Atrazine mg 15 Propetamphos mg 16 Propyzamide mg 17 Disulfoton mg 18 Triallate mg 19 Chlorpyriphos-methyl mg 2-1 Spiroxamin mg 21 Propani(l DCPA) mg 22 Vinclozolin mg 23 Metribuzin mg 24 Alachlor mg 25 Parathion-methyl mg 26 Metalaxyl mg 2-2 Spiroxamin mg * EA:Ethyl acetate solution *2 CY:Cyclohexane solution 23

24 Example of analysis of Pesticides standard solution 49(No.27~71) Column ENV-5MS.25mmID 3m.25µm Oven 5 (1min) 25 /min /min 3 (6.5min) 62,63 Flow He 1.mL/min 56,57 43,44,45 Injector Split Splitless 2µL 3,31,32 58,59,6 Detection MSD 49,5 Conc. 1ppm 37 67,68 41,42 46,47, , , ZOOM(No.27 64) 4 62, ,44, , , ,42 46, ,

25 Peak No. Product name RT(min) Monitor Ion(m/z) Catalog No. Packing 1st 2nd 3nd 4th 5th 27 Terbutryn mg 28 Ethofumesate mg 29 Fenpropimorph mg 3 Isofenphos-oxon mg 31 Parathion(-ethyl) mg 32 Triadimefon mg 33 4,4 '-Dichlorobenzophenone mg 34-1 Methoprene mg 35 Pendimethalin mg 36 Fipronil mg 38-1 Allethrin mg 37 Penconazole mg 38-2 Allethrin mg 38-3 Allethrin mg 38-4 Allethrin mg 34-2 Methoprene mg 39 Procymidone mg 4 Tetrachlorvinphos mg 41 Fenamiphos mg 42 Flutriafol mg 43 Profenofos mg 44 Isoprothiolane mg 45 Oxadiazon mg 46 Oxyfluorfen mg 47 Buprofezin mg 48 Kresoxim-methyl mg 49 Chlorfenapyr mg 5 Carboxin mg 51-1 Cyproconazole mg 51-2 Cyproconazole mg 52 Chlorobenzilate mg 53 Ethion mg 54 Triazophos mg 55 Famphur mg 56 Norflurazon mg 57 Quinoxyfen mg 58 Hexazinone mg 59 Propargite(BPPS) mg 6 Diflufenican mg 61 Piperonyl butoxide mg 62 Picolinafen mg 63 Bromopropylate ppm/1 ml AL* 64 Phosmet mg 65 Pyraclofos mg 66 Fenoxaprop-ethyl mg 67 Prochloraz mg 68 Fluquinconazole mg 69 Fenbuconazole mg 7 Fluridone mg 71 Azoxystrobin mg * AL:Acetonitrile solution Catalog No. Product name Number of ingredient Pesticides standard solution ( 1 mg/l of each chemicals contained in acetone-hexane solution(1:1) Freeze storage) Grade For pesticide residue analysis Packing 2 ml 5 25

26 Pesticides standard solution 52 Example of analysis of Pesticides standard solution Column ENV-5MS.25mmID 3m.25µm Oven 5 (1min) 15 /min 1 3 /min 14 1 /min 3 (6.33min) Flow He 1.mL/min Injector 25 2,21 19 Split Splitless 1µL Detection MSD Conc. 1ppm , , ZOOM(No.1 39) , , , Peak No. Product name RT( mi n) Monitor Ion(m/z) Catalog No. Packing 1st 2nd 3nd 4th 5th 1 Z -Mevinphos mg 2 E -Mevinphos mg 3 Nitrapyrin mg 4 Methacrifos mg 5 Tebuthiuron mg 6 Tecnazene mg 7-1 Diallate mg 7-2 Diallate mg 8 Chlorbufam(BIPC) mg 9 Pyrimethanil mg 1 Oxabetrinil mg 11 Ametryn mg 26

27 Peak No. Product name RT( mi n) Monitor Ion(m/z) Catalog No. Packing 1st 2nd 3nd 4th 5th 12 Prometryn mg 13 Bromacil mg 14 Chlorthal-dimethyl (Dacthal mg 15 Triflumizole mg 16 Chlorbenside mg 17 Disulfoton sulfone mg 18 Chlorfenson mg 19-1 Aramite mg 19-2 Aramite mg 2 Tribufo(s DEF) mg 21 Flamprop-methyl mg 22 Barban mg 19-3 Aramite mg 19-4 Aramite mg 23 Perthane mg 24 Carfentrazoneethyl mg 25 Trifloxystrobin mg 26 Benalaxyl mg 27 Azamethiphos mg 28-1 Resmethrin mg 29 Diclofop methyl mg 28-2 Resmethrin mg 3 Mefenpyr-diethyl mg 31 Carbosulfan mg 32 Epoxiconazole mg 33 Etoxazole mg 34 Fenamidone mg 35-1 Phenothrin mg 36 Furathiocarb mg 35-2 Phenothrin mg 37 Triticonazole mg 38 Pyrazophos mg 39 Benfuracarb mg 4 Boscalid mg 41 Flumioxazin mg 42 Thiacloprid mg 43 Pyraclostrobin mg 44 Flumiclorac-pentyl mg 45-1 Dimethomorph mg 46 Famoxadone mg 45-2 Dimethomorph mg 47 Propaquizafop mg Catalog No. Product name Number of ingredient Grade Packing Pesticides standard solution For pesticide residue analysis 2 ml 5 ( 1 mg/l of each chemicals contained in acetone-hexane solution(1:1) Freeze storage) 27

28 Pesticides standard solution 58 Example of analysis of pesticides standard solution 58 by Mightysil MS Columun : Mightysil RP-18 MS 15-2.(5µm) Eluent : Solution A 5mmol/L Ammonium acetate solution Solution B 5mmol/L Ammonium acetate methanol solution Flow :.2mL/min Detection : ESI(TIC : Positive & Negative) Temperature : 4 Injection volume: 5µL , , ,31,32,33 18,19,2 21, Gradient condition min A(%) B(%) Thiamethoxam m/z Imidacloprid m/z Clothianidin m/z Chloridazon m/z Oxycarboxin m/z Thiacloprid m/z Thiabendazole m/z Azamethiphos m/z Dimethirimol m/z Tralkoxydim m/z Isoxaflutole m/z Azinphos-methyl m/z Phenmedipham m/z Pyriftalid m/z E-Ferimzone m/z Z-Ferimzone m/z Methoxyfenozide m/z Chromafenozide m/z Butafenacil m/z Iprovalicarb m/z Simeconazole m/z Oryzalin m/z Naproanilide m/z Fenoxycarb m/z Anilofos m/z Cyflufenamid m/z Pyrazolate m/z Indoxacarb m/z Benzofenap m/z Quizalofop-ethyl m/z Lactofen m/z Furathiocarb m/z Clomeprop m/z Cloquintocet-1-methylhexyl m/z Abamectin m/z

29 No. Chemical compound RT (min) Ion measuring by LC/MS(m/z) Ion measuring by LC/MS(m/z) Positive Negative Positive Negative Quantity Quality Quan tity Quality Precursor Product Product (Quantity) (Quality) 1 Thiamethoxam Imidacloprid Clothianidin Chloridazon Oxycarboxin Thiacloprid Thiabendazole Azamethiphos Dimethirimol Precurs Product Product or (Quantity) 性 1-1 Tralkoxydim Isoxaflutole Azinphos-methyl Phenmedipham Pyriftalid E -Ferimzone Z -Ferimzone Tralkoxydim Methoxyfenozide Chromafenozide Butafenacil Iprovalicarb Simeconazole Oryzalin Naproanilide Fenoxycarb Anilofos Cyflufenamid Pyrazolate Indoxacarb Benzofenap Quizalofop-ethyl Lactofen Furathiocarb Clomeprop Cloquintocet- 1-methyl-hexyl ester Abamectin Catalog No. Product name Number of ingredient Grage Packing Pesticides standard solution For pesticide residue analysis 2 ml 5 2 ml 1 (1/L of each chemicals contained in methanol solution Freeze storage) 29

30 Pesticides standard solution 53 Example of analysis of pesticides standard solution 53 by Mightysil MS Columun : Mightysil RP-18 MS 15-2.(5µm) Eluent : Solution A 5mmol/L Ammonium acetate solution Solution B 5mmol/L Ammonium acetate methanol solution Flow :.2mL/min Detection : ESI(TIC : Positive & Negative) Temperature : 4 Injection volume: 5µL ,17 1,12 24,25,26,27 14, , Gradient condition min A(%) B(%) Aldicarb-sulfone m/z Oxamyl m/z Aldicarb m/z Carbofuran m/z Tebuthiuron m/z Carbaryl m/z Monolinuron m/z Diuron m/z Fluridone m/z Linuron m/z Dimethomorph m/z Fenamidone m/z Boscalid m/z Flufenacet m/z Epoxiconazole m/z Tebufenozide m/z Diflubenzuron m/z Cyprodinil m/z Pyraclostrobin m/z Triflumuron m/z Clofentezine m/z Novaluron m/z Diallate m/z Propaquizafop m/z Aramite m/z Lufenuron m/z Teflubenzuron m/z Hexythiazox m/z Fenpyroximate m/z

31 No. Chemical compound RT (min) Ion measuring by LC/MS(m/z) Ion measuring by LC/MS/MS(m/z) Positive Negative Positive Negative Quantity Quality Quan tity Quality Precursor Product Product Precursor Product (Quantity) (Quality) (Quantity) 性 1 Aldicarb-sulfone Oxamyl Aldicarb Carbofuran Tebuthiuron Carbaryl Monolinuron Diuron Fluridone Linuron Dimethomorph Fenamidone Boscalid Dimethomorph Flufenacet Epoxiconazole Tebufenozide Diflubenzuron Cyprodinil Pyraclostrobin Triflumuron Clofentezine Novaluron Diallate Propaquizafop Aramite Lufenuron Teflubenzuron Hexythiazox Fenpyroximate Product Catalog No. Product name Number of ingredient Grade Packing Pesticides standard solution For pesticide residue analysis 2 ml 5 2 ml 1 (1/L of each chemicals contained in methanol solution Freeze storage) 31

32 Pesticides standard solution 54 Example of analysis of pesticides standard solution 54 by Mightysil MS Columun : Mightysil RP-18 MS 15-2.(5µm) Eluent : Solution A 5mmol/L Ammonium acetate solution Solution B 5mmol/L Ammonium acetate methanol solution Flow :.2mL/min Detection : ESI(TIC : Positive & Negative) Temperature : 4 Injection volume: 5µL ,6 13,14 9,1 21,22 7, , , , Gradient condition min A(%) B(%) Methomyl m/z Bendiocarb m/z Thiodicarb m/z Pirimicarb m/z Furametpyr m/z Methabenzthiazuron m/z Azoxystrobin m/z Fenobucarb m/z Acibenzolar-S-methyl m/z Methiocarb m/z Daimuron m/z Cumyluron m/z Chloroxuron m/z Mepanipyrim m/z Triticonazole m/z Indanofan m/z Tetrachlorvinphos m/z Carpropamid m/z Imazalil m/z Pencycuron m/z Hexaflumuron m/z Cycloate m/z Oxaziclomefone m/z Fenoxaprop-ethyl m/z Flufenoxuron m/z Spinosad Spinosyn A m/z Spinosad Spinosyn D m/z Tridemorph m/z Silafluofen m/z

33 Ion measuring by LC/MS(m/z) Ion measuring by LC/MS/MS(m/z) RT No. Chemical Positive Negative Positive Negative (min) compound Quantity Quality Quan Quality Precursor Product Product Precursor Product Product tity (Quantity )(Quality ) (Quantity) 1 Methomyl 性 2 Bendiocarb Thiodicarb Pirimicarb Furametpyr Methabenzthiazuron Azoxystrobin Fenobucarb Acibenzolar-S-methyl Methiocarb Daimuron Cumyluron Chloroxuron Mepanipyrim Triticonazole Indanofan Tetrachlorvinphos Carpropamid Imazalil Pencycuron Hexaflumuron Cycloate Oxaziclomefone Fenoxaprop-ethyl Flufenoxuron Spinosad-1 (Spinosyn A) Spinosad-2 (Spinosyn D) Tridemorph Silafluofen Tridemorph Catalog No. Product name Number of ingredient Grade Pesticides standard solution For pesticide residue analysis Packing 2 ml 5 2 ml 1 (1/L of each chemicals contained in methanol solution Freeze storage) 33

34 Pesticides standard solution Example of analysis of pesticides standard solution 45 by Mightysil PA , ,11 12,13,14 15, ,18 Columun : Mightysil RP-18 PA 15-2.(3µm) Eluent : Solution A 5mmol/L Ammonium acetate solution Solution B 5mmol/L Ammonium acetate methanol solution Flow :.2mL/min Detection : ESI(TIC : Positive & Negative) Temperature : 4 Injection volume: 5µL Gradient condition min A(%) B(%) Flumetsulam m/z Fluroxypyr m/z Imazaquine m/z CPA m/z Bromoxynil m/z Naphthylacetic acid m/z Cloprop m/z Ioxynil m/z Cloransulam-methyl m/z Thidiazuron m/z Diclosulam m/z Mecoprop m/z Triclopyl m/z Dichlorprop m/z Forchlorfenuron m/z MCPB m/z Fomesafen m/z Acifluorfen m/z Haloxyfop m/z

35 No. Chemical compound RT (min) Ion measuring by LC/MS Ion measuring by LC/MS/MS(m/z) Positive Negative Positive Negative Quantity Quality Quantity Quality Precursor Product (Quantity) Product (Quality) 1 Flumetsulam Precursor Product (Quantity) 2 Fluroxypyr Imazaquine CPA Bromoxynil Naphthylacetic acid Cloprop Ioxynil Cloransulam-methyl Thidiazuron Diclosulam Mecoprop Triclopyl Dichlorprop Forchlorfenuron MCPB Product (Quality) 17 Fomesafen Acifluorfen Haloxyfop Catalog No. Product name Number of ingredient Grade Pesticides standard solution For pesticide residue analysis Packing 2 ml 5 2 ml 1 (1/L of each chemicals contained in methanol solution Freeze storage) 35

36 Pesticides standard solution 55 Example of analysis of pesticides standard solution 55 by Mightysil MS Columun : Mightysil RP-18 MS 15-2.(5µm) Eluent : Solution A 5mmol/L Ammonium acetate solution Solution B 5mmol/L Ammonium acetate methanol solution Flow :.2mL/min 28,29,3,31 Detection : ESI(TIC : Positive & Negative) Temperature : 4 Injection volume: 5µL 14 9,1,11 18,19, ,22,23 1 2,3 12,13 16,17 5,6, Gradient condition min A(%) B(%) Gibberellic acid m/z Metsulfuron methyl m/z Thifensulfuron methyl m/z Azimsulfuron m/z Chlorsulfuron m/z Florasulam m/z Cinosulfuron m/z Foramsulfuron m/z Sulfosulfuron m/z Flazasulfuron m/z Propoxycarbazone sodium m/z Triasulfuron m/z Clofencet m/z Mesosulfuron methyl m/z Ethametsulfuron methyl m/z Pyrazosulfuron ethyl m/z Naptalam m/z Iodosulfuron methyl sodium m/z Trifloxysulfuron sodium m/z Halosulfuron methyl m/z ,4-D m/z MCPA m/z Metosulam m/z Penoxsulam m/z Chlorimuron m/z Ethoxysulfuron m/z Sulfentrazone m/z Clodinafop free acid m/z Bensulfuron methyl m/z Fluazifop free acid m/z Cyclanilide m/z Cyclosulfamuron m/z Fenhexamid m/z Diclomezine m/z

37 No. 農薬混合標準液 RT Chemical compound Ion measuring by LC/MS Ion measuring by LC/MS/MS(m/z) Positive Negative Positive Negative (min) Quantity Quality Quantity Quality Precursor Product Product Precursor Product Product (Quantity) (Quality) (Quantity )(Quality) 1-1 Gibberellic acid Gibberellic acid Metsulfuron methyl Thifensulfuron methyl Azimsulfuron Chlorsulfuron Florasulam Cinosulfuron Foramsulfuron Sulfosulfuron Flazasulfuron Propoxycarbazone sodium Triasulfuron Clofencet Mesosulfuron methyl 15 Ethametsulfuron methyl Pyrazosulfuron ethyl Naptalam Iodosulfuron methyl sodium 19 Trifloxysulfuron sodium Halosulfuron methyl ,4-D MCPA Metosulam Penoxsulam Chlorimuron ethyl Ethoxysulfuron Sulfentrazone Clodinafop free acid Bensulfuron methyl Fluazifop(free acid) Cyclanilide Cyclosulfamuron Fenhexamid Diclomezine Catalog No. Product name Number of ingredient Grade Packing Pesticides standard solution For pesticide residue analysis 2 ml 5 2 ml 1 (1/L of each chemicals contained in methanol solution Freeze storage) 37

38 Pesticides standard solution 56 Example of analysis of pesticides standard solution 56 by Mightysil MS Columun : Mightysil RP-18 MS 15-2.(5µm) Eluent : Solution A 5mmol/L Ammonium acetate solution Solution B 5mmol/L Ammonium acetate methanol solution Flow :.2mL/min Detection : ESI(TIC : Positive & Negative) Temperature : 4 Injection volume: 5µL 1 6 3,4 5 13, ,11 18, , Gradient condition min A(%) B(%) Sethoxydim m/z Oxabetrinil m/z Ametryn m/z Pyrimethanil m/z 2 5. Methoxyfenozide m/z Flamprop-methyl m/z Butafenacil m/z Prometryn m/z Triflumizole metabolite m/z Clodinafop-propargyl ester m/z Carfentrazone-ethyl m/z Benalaxyl m/z Mefenpyr-diethyl m/z Phoxim m/z Pyrazophos m/z Trifloxystrobin m/z Triflumizole m/z Benfuracarb m/z Quizalofop-ethyl m/z Cloquintocet-1-methylhexyl ester m/z Fluazuron m/z Etoxazole m/z Chlorfluazuron m/z Fenpropimorph m/z 34 38

39 No. 農薬混合標準液 RT Chemical compound Ion measuring by LC/MS(m/z) Ion measuring by LC/MS/MS(m/z) Positive Negative Positive (min) Quantity Quality Quantity Quality Precursor Product(Quantity) Product(Quality ) 1-1 Sethoxydim Oxabetrinil Ametryn Pyrimethanil Sethoxydim Methoxyfenozide Flamprop-methyl Butafenacil Prometryn Triflumizole metabolite Clodinafop-propargyl ester Carfentrazone-ethyl Benalaxyl Mefenpyr-diethyl Phoxim Pyrazophos Trifloxystrobin Triflumizole Benfuracarb Quizalofop-ethyl Cloquintocet-1- methylhexyl ester Fluazuron Etoxazole Chlorfluazuron Fenpropimorph Catalog No. Product name Number of ingredient Grade Packing Pesticides standard solution For pesticide residue analysis 2 ml 5 (1/L of each chemicals contained in methanol solution Freeze storage) 39

40 Pesticides standard solution 57 Example of analysis of pesticides standard solution 57 by Mightysil MS Columun : Mightysil RP-18 MS 15-2.(5µm) Eluent : Solution A 5mmol/L Ammonium acetate solution Solution B 5mmol/L Ammonium acetate methanol solution Flow :.2mL/min Detection : ESI(TIC : Positive & Negative) Temperature : 4 Injection volume: 5µL Gradient condition min A(%) B(%) Demeton-S-methyl sulfoxide m/z Thiamethoxam m/z Carbofuran-3-hydroxy m/z Tepraloxydim m/z Cymoxanil m/z Carbendazim m/z Thiabendazole m/z Carbetamide m/z Bromacil m/z Triforine m/z Carbosulfan m/z 381 4

41 No. 農薬混合標準液 RT Chemical compound (min) Ion measuring by LC/MS Ion measuring by LC/MS/MS(m/z) Positive Positive Quantity Quality Precursor Product(Quantity) Product(Quality ) 1 Demeton-S-methyl sulfoxide Thiamethoxam Carbofuran-3-hydroxy Tepraloxydim Cymoxanil Carbendazim Thiabendazole Carbetamide Tepraloxydim Bromacil Triforine Triforine Carbosulfan Catalog No. Product name Number of ingredient Grade Packing Pesticides standard solution For pesticide residue analysis 2 ml 5 (1/L of each chemicals contained in methanol solution Freeze storage) 41

42 Supporting residue standard of pharmaceutical products for animals Food analysis mixed standard solution Product range Catalog No. Product name Standards Packing Food analysis mixed standard solution 1 (Sulfa drug LC covered 9types) <Composition> Sulfadiazine Sulfamethoxypyridazine Sulfisoxazole Sulfamerazine Sulfamonomethoxine Sulfadimethoxine Sulfadimidine Sulfamethoxazole Sulfaquinoxaline sodium salt For food analyses 5mL 5 (Each 1mg/L Methanol solution) Catalog No. Product name Standards Packing Food analysis mixed standard solution 2 (Quinolone LC covered 7types) <Composition> Oxolinic acid Flumequine Danofloxacin mesylate Nalidixic acid Enrofloxacin Ofloxacin Piromidic acid For food analyses 5mL 5 (Each 1mg/L.1mol/L NaOH:Methanol solution(4:96)) Example of analysis of Food analysis mixed standard solution 1 by Mightysil RP-18 PA Column : Mightysil RP-18 PA mm(5μm) Gradient condition Eluent : Solution A Acetonitrile :Water: Acetic acid =1:9:.3 min A(%) B(%) Solution B Acetonitrile :Water: Acetic acid =6:4:.3 1 Flow : 1.mL/min Temperature : 4 Detection : 265nm Injection volume : 5μl Sulfadiazine 2 Sulfamerazine 3 Sulfadimidine 4 Sulfamethoxypyridazine 5 Sulfamonomethoxine.1 6 Sulfamethoxazole 7 Sulfisoxazole 8 Sulfadimethoxine. 9 Sulfaquinoxaline sodium salt

43 Example of analysis of Food analysis mixed standard solution 2 by Mightysil RP-18 PA 4 Column: Mightysil RP-18 PA mm(5μm) Eluent : Acetonitrile :.5mol/L Phosphoric acid Na buffer solution(ph2.5)= 3:7 (Contain.35mol/L sodium dodecyl sulfate) Flow : 1.2mL/min 1 Temperature : 4 Detection : 282nm Injection volume : 5μl Oxolinic acid 2 Nalidixic acid 3 Flumequine 4 Piromidic acid 5 Ofloxacin 6 Danofloxacin mesylate 7 Enrofloxacin Related products (Standard products ) Catalog No. Product name Standard Size Sulfadiazine For food analyses 5mg Sulfamerazine For food analyses 5mg Sulfadimidine For food analyses 5mg Sulfamethoxypyridazine For food analyses 5mg Sulfamonomethoxine For food analyses 5mg Sulfamethoxazole For food analyses 5mg Sulfisoxazole For food analyses 25mg Sulfadimethoxine For food analyses 5mg Sulfaquinoxaline sodium salt For food analyses 5mg Oxolinic acid For food analyses 5mg Nalidixic acid For food analyses 5mg Piromidic acid For food analyses 5mg Flumequine For food analyses 5mg Enrofloxacin For food analyses 5mg Danofloxacin mesylate For food analyses 5mg Ofloxacin For food analyses 5mg Related products(column) Catalog No. Product name Size Mightysil RP-18 PA 25mm-4.6mm(5μm) 1pk Mightysil RP-18 PA 15mm-4.6mm(5μm) 1pk Mightysil RP-18 PA 5mm-4.6mm(5μm) 1pk (1PCS) 214 年 4 月 43

44 44