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2 D nucleation 3 3D nucleation

6 Glucose isomerase 10 V / nm s C - C e / mg ml -1

8 kinetics

9 µ R K kt

10 kinetics

11 kinetics

12 kinetics r β π µ π r a r s + a s : β: µ πβ µ β s c s c a a r, & exp exp 0, 0 kt a J kt J J S C s µ πβ

13 r a r N a r N S S δ π δ π kinetics β π µ π r a r s + r a N a N N a N s s s β µ β π µ β π µ / 1/ & µ β µ kt K r r r a kt K N kt K s c s s s Q r µ kt K s 0

14 kinetics a τ 1 J s 1A R a τ 1 aj s A τ N n J s Aτ A n? A n N n τ J τ s 1 / 3 A aj a R τ 1/ 3 0 : a J / 3 s 1/ 3 exp πβ as 3 µ kt

15 kinetics

16 kinetics

17 3 c c r r r λ µ kt K s 0 kinetics λ / µ β λ kt a aks r a a R s c µ β s c a r

18 kinetics

19 T T h M L µ µ µ L µ S M S L S L S L M S S M S L M L L T h T P T T P T h h h s s T s T h s T h,, µ µ µ µ 1

20 R R C C R R S π γ π µ µ γ π S S C 3 16 exp exp kt J kt J J S C µ γ π

21 3 R K R R R a aν a P Pe S P P πmkt πmkt S exp E aν exp kt µ kt E kt desol C S exp k C 1 exp kt d µ e e

22 4 a τ 1 J s 1A R a τ 1 aj s A τ N n J s Aτ A n? A n N n τ J τ s 1 / 3 R A aj a τ 1/ 3 0 : a J / 3 s 1/ 3 exp πβ as 3 µ kt

23 c c r r r λ µ kt K s 0 λ / µ β λ kt a aks r a a R s c µ β s c a r 5

24 Hard copies 514 A4 3 5 Intro Experimental Results&Discussion or

25 H0 energy E E d µ

26 H0 R C µ S T γ, P l T e S γ T e T

27 H0

28 H0

29 H0

30 H0 R V V V V V V

31 H0 Thermal roughening Kinetic roughening

32 H18

33 H18 1, d sinθ nλ /nano_tech/yamashita/

34 H18

35 H18 Pectin Esterase Google Scholar

36 H18 Silicon GaN Photonic Crystal, Protein Crystal

37 H18 X X Integrated Circuit, IC

38 H18 DNA 3

39 H18 h k l1/x 1/y 1/z 111

40 H18 DNA Si 1. Photonic. DNA 4. 3.

41 H

42 H18 µ Si

43 H18 DNA DNA

44 H18 %

45 H18

46 H18 Silicon Silicon

47 H18

48 H18 P 0 Zn-Mg-Ho p-zn-mg-ho 6 6 P 0 Zn-Mg-Ho p-zn-mg-ho

49 H18

50 H18

51 H18 lnc/c e 0.01 lnc/c e 1~

52 H18 0 I ln K RT V p Si Si

53 H18 DNA nm/s mm 10

54 H18 kt

55 H18 critical nucleous embryo, crystal

56 H nm 10 But!

57 H18 µ 3 C 16π S γ J J 0 exp J 0 exp kt 3 µ kt µ

58 H18 VI

59 H18

60 H18 ρgh h γ cosθ r

61 H mg

62 H18 Hen egg-white lysozyme s.964x10-6 m 3 γ 1.1X10-3 Jm - µ 1.381X10-3 X93.15X c.99x10-19 J C 16 π 3 S µ γ 3

63 H18

64 H18 Epitaxial

65 H18 G α 5 Jackson s α parameter α 3 α α X Z α ' Z s R

66 H18 Volmer-Weber rank an der Merwe M VW

67 H18 A : µ < 0 C e B C B A B, B': µ > 0 C : µ > µ c > 0 µ kt ln C / Ce T

68 H18 γ SL γ WL > γ WS + γ SL rank an der Merwe Rsinθ O θ R θ γ WL γ WS γ WL + γ SL > γ WS > γ WL - γ SL Volmer Weber γ WS > γ WL + γ SL

69 H18

70 H18 Zone refining M

71 H18

72 H18 Maxwell-Boltzmann d kt m kt m d exp Pr / 3 π,,,, z z y y x x z y x d d d N z y x z y x d d d,,,, z y x z y x f f f

73 H18 1,, 0 6 z y x x z z y y x x a f a f a f a a f ζ η ξ ζ η ξ + +,, z y x 1 6 ζ η ξ ζ η ξ a + +

74 H ζ η ξ ζ η ξ a ζ η η ξ ζ η ξ ζ η ξ η ζ η ξ a η η, ξ '0 0 '0 1 ' a a a f a a Q ξ ξ ξ

75 H18 N exp '0 ' 3 αξ ξ ξ α ξ ξ A a z y x z y x z y x z y x z y x z y x d d d A N d d d A d d d exp exp,, α α z y x z y x z y x z y x d d d N d d d N A d exp,, 1 exp 3 / 3 / + + α π α π α α π ξ αξ

76 H18 z y x z y x z y x z y x d d d N d d d exp,, 3/ + + α π α E α z y x z y x z y x d d d m N E exp 3 / α π α 5 / / / 3 / 0 3 / 8 3 exp 4 1 exp 1 exp exp exp α π η αη η α π η αη η α π η αη π ξ ξ α α π π α π π α π α d d d d N m N m d m N E Q

77 H18 E RT 3 kt m α N m E 4α 3 N N A z y x z y x z y x z y x d d d kt m kt m N d d d exp,, 3/ + + π

1 (Berry,1975) 2-6 p (S πr 2 )p πr 2 p 2πRγ p p = 2γ R (2.5).1-1 : : : : ( ).2 α, β α, β () X S = X X α X β (.1) 1 2

1 (Berry,1975) 2-6 p (S πr 2 )p πr 2 p 2πRγ p p = 2γ R (2.5).1-1 : : : : ( ).2 α, β α, β () X S = X X α X β (.1) 1 2 2005 9/8-11 2 2.2 ( 2-5) γ ( ) γ cos θ 2πr πρhr 2 g h = 2γ cos θ ρgr (2.1) γ = ρgrh (2.2) 2 cos θ θ cos θ = 1 (2.2) γ = 1 ρgrh (2.) 2 2. p p ρgh p ( ) p p = p ρgh (2.) h p p = 2γ r 1 1 (Berry,1975) 2-6