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1 201210

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4 BP2011 BP2011

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12 J-POWER C

13 Coal ship Coal silo / yard Coal bunking Coal conveyer Coal bunker Coal stack /storage Transporting Unloading Coal feeder boiler Mill (pulverizer) Drying and milling

14 Unloader Mill Coal silo J-POWER C

15 De-NOx AH EP De-SOx IDF FDF GRF Coal Bunker Mill GRF: FDF: IDF: De-NOx: AH: EP: De-Sox:

16 De-NOx De-SOx EP J-POWER C

17 Governor valve boiler HPT : high-pressure turbine IPT : intermediate-pressure turbine LPT : low-pressure turbine HPT IPT LPT G generator Fuel Super heater Reheater condenser See water for cooling Air evaporator Dearator P Condensate pump P Heat exchanger Boiler feed pump Heat exchanger

18 or Burner J-POWER C

19 Generator LPT LPT IPT HPT J-POWER C

20 Load demand Boiler/Turbine cooperative Fx Fx Turbine governor control Boiler feed water control Fuel control Air control Load G Governor valve Steam pressure Steam temperature O 2 concentration in flue gas generator boiler Flue gas condenser Condensate pump P Heat exchanger Dearator Reheater evaporator Boiler feed pump Super heater Air Fuel P Heat exchanger

21

22 11% CO 2 (SC) (USC) USC (A-USC) 38% (Sub-C) 34 ~ 36% 17% CO 2 41% 13% CO 2 25% CO 2 : :LNG 1300 GT 1500 GT 1700 GT 1300 IGCC 43 ~ 44% MCFC SOFC 1500 IGCC 46 ~ 48% 1700 IGCC 50%~ IGFC 55%

23 G P Turbine Condenser Pump Boiler Wturbine qout Wpump qin G P G P Turbine Condenser Pump Boiler Wturbine qout Wpump qin s T Evaporate Super heat q in q out W turbine p1 (Constant pressure) p2 s T W pump p1 p2 (Constant pressure) entropy temperature

24 T Increase of steam pressure 1 p1 (Constant pressure) q in Super heat Increase of steam temperature Evaporate W pump 4 W turbine p2 (Constant pressure) 3 q out 2 Reduce condensate temperature s

25 SC USC Sub-Critical 22.1MPa SC:Super Critical 22.1MPa566 USC:Ultra Super Critical SC 593USC

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27 Ceramic Tube Filter Steam Turbine Expander 14.8MW Intercooler Air Coal Limestone Water Ash Air Dea. CP 56.2MW Paste Pumps M-BFP Heaters Stack

28 + Coal CO2 + H2O + Heat Coal CH4 + H2 + Char Char + CO2 2CO Char + H2O CO + H2 CO + H2O CO2 + H2 Char

29 CO2 180m 100m 60m(H) 18,000m 2

30 ST G EAGLE

31 1 2EAGLE CH 4 /H 2 CO/H 2

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33

34 1. USC 2. GT/ST (1) PFBC (2) Advanced PFBC (3) IGCC / IGFC CCS CO 2 Capture & Storage 1. CO 2 (1) (2) (3) Increasing renewable utilization 1. CDM 2. JI 3. Best practice by applying BAT

35 CCS: Carbon dioxide Capture and Storage CCS (Generation) (Capture) (Transportation) (Storage) : Solutions for the 21 st Century, Zero emissions technologies for Fossil Fuels, International Energy Agency 2002

36 CO/H 2 H 2 /CO 2 ( 40%) N 2 /H 2 O/O 2 CO 2 H 2 CO 2 CO 2 (12-15%) N 2 /H 2 O/O 2 CO 2 CO 2 CO 2 CO 2 CO 2 (70-80%) CO+H 2 O CO 2 +H 2 CO 2

37 CO2 H2 MDEA CO2 H2S HTS HTS LTS

38 Selexol H2 CO2 CO2 H2S CO2 H2S CH3-O-(CH2-CH2-O)n-CH3

39 60 CO 2 Recovery [%] DOE/NETL report 55 Net efficiency (HHV) [%] IGCC DOE/Shell IGCC 41.1, 0.79 SC/USC (PC) 1.0 DOE/PCF SC:593/ , CO 2 emission intensity [kg-co 2 /kwh] DOE/Shell IGCC 32.0, 0.10 DOE/PCF SC:593/ , 0.12

40

41 IGFC IGFC CO 2 Gas Clean Up FC AC GT HRSG ST IGCC IGFC GTL DME CO2 CO2 CO H2O CO2 H2 CO2

42 CO 2 CDM

26 5 9 4 48% 11% 10% 3% 3% 2% 2% 2% 2% 2% 15% 76 9690 (2012 ) 63.6% 19.1% 6.4% 5.2% 3.5% 1.1% 1.1% 1 9,154 2013 23% 14% 12% 10% 5% 4% 4% 2% 2% 1% 23% 12 7603 (2012 ) 383 30% 302 24% 134 11% 114 9% 82,

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