t 492 t mg/l 30 mg/l BOD 95 OH = cm 3 / sec 25 8 OH /cm 3 12 = ph ph
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- かずし いちぬの
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1 CAS O H 3 C C O CH 2 CH 2 O CH 3 C 5 H 10 O , , o.c d = 1 30 Pa 0.23 mmhg log Pow m/z 43, , ppm = 4.91 mg/m 3, 20 1 mg/m 3 = ppm
2 t 492 t mg/l 30 mg/l BOD 95 OH = cm 3 / sec 25 8 OH /cm 3 12 = ph ph ppb ppm ppm B/A B/A B/A B/A 0/30 0/ B/A
3 2-3 4 LC 50 mg/l EC 50 mg/l : *11 Crassius auratus h * OECD 1,250 mg/kg 2, 13, LD 50 3,100 mg/kg 13 1,250-3,930 mg/kg 2, 13, 14 LC 50 LD 50 5,214 mg/kg mg ICR ,0002,000 mg/kg/day 5 / mg/kg/day 1,000 mg/kg/day 2,000 mg/kg/day 1/4 14, 15, 16, ,000 ppm 8 / 200 ppm 500 ppm 500 ppm 1,000 ppm 2, 14, 15
4 2-4 5 in vitro in vivo * S9 w CHO S9 D61.M/ CHO S9 1,333 mg/kg 19 / 3,200-32,000 ppm 4,200-42,000 ppm 500-5,000 ppm 20 3,200 ppm 4,200 ppm 500-5,000 ppm * w ,225 mg/kg/day L ME 22
5 2-5 23, 24, 25 3 EPA 1999 EU 1999 NTP 1999 IARC 1999 ACGIH , 25 4 ACGIH ppm , ME 2-ME MAA 17 2-ME 2-ME MAA 2-ME ME 2-ME ME 250 mg/kg 2-ME 2-MAA 2-MAA 20 2-MAA OECD * 11 4 * OECD OECD
6 ME 1 in vitro in vivo 2-ME in vivo
7 2-7 CAS
8 Hazardous Substances Data Bank HSDB, U.S. National Library of Medicine IPCS, International Chemical Safety Cards KowWin ver 1.66, Syracuse Research Corporation NIST Library of 54K Compounds , , AOPWIN ver1.86, Syracuse Research Corporation Hydrowin ver1.67, Syracuse Research Corporation , OECD, Harmonised Integrated Classification System for Human Health and Environmental Hazards of Chemical Substances and Mixtures. OECD Series on Testing and Assessment No AQUIRE US EPA, ECOTOX Database System. 13US NIOSH, Registry of Toxic Effects of Chemical Substances RTECS ACGIH, Documentation of the Threshold Limit Values and Biological Exposure Indices ,, ,,, 21, K. Nagano et al., Experimental Studies on Toxicity of Ethylene Glycol Alkyl Ethers in Japan. Environmental Health Perspectives, 57, F. K. Zimmermann et al., Acetone, Methyl Ethyl Ketone, Ethyl Acetate, Acetonitrile and other Polar Aprotic Solvents are Strong Inducers of Aneuploidy in Saccharomyces Cervisiae. Mutation Research, 149, IPCS, Environmental Health Criteria EHC, C. Osgood et al., Aneuploidy in Drosophila, II. Further Validation of the FIX and ZESTE Genetic Test Systems Employing Female Drosophila Melanogaster. Mutation Research, 259, NTIS, Screening of Priority Chemicals for Reproductive Hazards, PB H. M. Bolt et al., Maternal Exposure to Ethylene Glycol Monomethyl Ether Acetate and Hypospadia in Offspring : a Case Report, Br. J. Ind. Med., 47, JETOC,,, ACGIH, Booklet of the Threshold Limit Values and Biological Exposure Indices ,, 43,
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10 2-10 mg/l 1, h 10 LC AQUIRE US EPA, ECOTOX Database System.
11 2-11 5d/w 5w 8d mg/kg/day 10,000 1,000 2,000 1,000-2, ,000 1,225 :
CAS H 3 C C CH 2 C 9 H tert d = hpa
1 200140 35 CAS 98839 1335-2- H 3 C C CH 2 C 9 H 10 118.18 1 99 4-tert- 1. 2-23.2 2 163164 2 54 574 3 0.96.6 20 d 4 0.9082 2 4.07 = 1 2.5 hpa 1.9 mmhg20 2 4 log Pow3.48 3.44 m/z 118, 1.0 103 0.58 91 0.21
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1 200117 21512 CAS 111693 110 NC(CH 2 ) 4 CN 1,4- C 6 H 8 N 2 108.14 1 99 2-1. 2 1 295 159 c.c. 550 3 1.7-4.9 20 d 0.965 4 3.73 = 1 0.3 Pa 0.002 mmhg20 2 log Pow-0.32 m/z 41, 1.0 68 0.54 54 0.43 4 Koc9-16
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1 9924 2260 CAS 107186 H 2 C CH CH 2 OH 2- -1- C 3 H 6 O 58.08 1 99 1. 2, 3 3, 4, 5-129 96-97 2 21c.c. 24o.c. 2 6, 7 378 6, 7 2.5-18 d 20 4 0.8540 2, 5 2.00 = 1 2.7 kpa 20 mmhg204.3 kpa 32 mmhg30 4 log
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1 982 2207 CAS 67630 2- H 3 C H 3 C CH OH C 3 H 8 O 60.10 1 99.9 % n- 1. 2-88.5 3 82.5 3 11.7c.c. 455 4 212 d 20 4 0.78505 3 2.1 = 1 4 4.4 kpa 33 mmhg20 4 log Pow0.05 0.07 5 m/z45, 1.0 43 0.19 27 0.17
More information3, ,104 t mg/l 30 mg/l BOD mg 14 C 8, /kg 11 8, 1 11 OH = cm 3 / sec 11 OH /cm ppm
3, 3-1 200019 4800 CAS 91941 1138 3, 3-4, 4 - -3, 3 - H 2 N Cl Cl NH 2 C 12 H 10 C l2 N 2 253.13 1 95 1. 2 3, 4 132-133 402 5 >200 5 700kg/m 3 5 8.73 = 1 5.610-8 kpa 4.210-7 mmhg20 4 6 log Pow3.51 3.57
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1 200117 21512( ) CAS 111693 110( ) 1,4- NC(CH 2 ) 4 CN C 6 H 8 N 2 108.14 1) 99 2-1. 2) 1 2) 295 2) 159(c.c.) 3) 550 3) 1.7-4.9 vol % ( ) 3) d 20 0.965 2) 3.73 ( = 1) 4 0.3 Pa (0.002 mmhg) (20) 2) log
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1 97 7 3 1312 CAS 85 68 7 O BBP 1, 2- C 19 H 20 O 4 312.4 C C O O O (CH 2 ) 3 1 99.9 % 1. 2-35 3 2, 3 370 3, 4 199 d 25 4 1.117 2 10.8 = 1 5 1.15 10-3 Pa 8.6 10-6 mmhg 20 5 253 Pa 1.9 mmhg 200 5 log Pow
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1 961 31 CAS 71432 C 6 H 6 78.11 1) 99 % 1. 5.5 2) 80.1 2) -11 3) 293563 3) 1.48.0% 3) d 20 0.8786 4) 2.77 ( = 1) 4) 4 13.33 kpa (100 mmhg) (26.9) 2) log Pow2.13 ( ) 5) 2.14 ( ) 6) m/z78 ( 1.0 )77 ( 0.20
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