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1 H2S ) 1
2 Map of Ishikari River 2
3 COD
4 4
5 5
6 Rice field along the Ishikari River 6
7 7
8 Snow melting in Ishikari river L-Q, 8
9 H. Tachibana, K. Yamamoto, K. Yoshizawa, and Y. Magara, Non Point Pollution of Ishikari River, Hokkaido, Japan Water Science & Tech. Vol.44 No.7,1-8 () 9
10 Flooding period Naie(St.6) Snow-melting Period Naie St.6) 10
11 11
12 12
13 Runoff characteristics of chemical water components Water quality is affected by the characteristics of the water's area of origin. We tried to clarify the runoff characteristics of chemical components from the relationship between specific water flux (Q/A) and specific runoff load of chemical components (L/A). L/A= C (Q/A) n L runoff load of chemical components in g/s, Q: flux in m 3 /s, A: watershed area in km 2, C, n: constant coefficient L = c Q, c: concentration of chemical component in mg/l When n>1 (increasing concentration of chemical component), the water component is of washout type. When n=1, the concentration is stable. When n<1, the concentration is decreasing and is of dilution type. Smith et al. (1977) Wat. Res. Stevens et al. (1978) Wat. Res. -6C-Q L-QL=kQ n -DN PP n>1 -DP n<1 (1978) BOD, COD, TN, TP, SS L=aQ+b -SS - - k, n 2007/3/15 13
14 (1980) (1983) (1986) ( ) (1991) L-Q, C-Q k,n L=f(Q) n>1 L = f (Q, S) n<1 2007/3/15 14
15 n: C n L=c.Q L/A=CQ/A n c = C (Q/A) n-1 C R R Osamunai (St. 3) Naie (St. 6) N R n C N R n C Snow melting SS Flooding Annual Snow melting BOD Flooding Annual Snow melting TOCT Flooding Annual Snow melting TOCF Flooding Annual Snow melting TOCss Flooding Annual Snow melting Cl- Flooding Annual Snow melting SO4 2- Flooding Annual Snow melting Bx Flooding Annual Snow melting SiO2 Flooding Annual Snow melting NH4 + -N Flooding Annual Snow melting NO3- -N Flooding Annual Snow melting TIN Flooding Annual
16 Osamunai (St. 3) Naie (St. 6) N R n C N R n C Snow melting SS Flooding Annual Snow melting BOD Flooding Annual Snow melting TOC T Flooding Annual Snow melting TOC F Flooding Annual Snow melting TOCss Flooding Annual Snow melting Cl- Flooding Annual SO 4 2- Snow melting Flooding Annual Snow melting g TOC F Flooding Annual Snow melting TOCss Flooding Annual Snow melting Cl- Flooding Annual SO 4 2- Snow melting Flooding Annual Snow melting Bx Flooding Annual Snow melting SiO2 Flooding Annual Snow melting NH + 4 -N Flooding Annual Snow melting NO - 3 -N Flooding Annual Snow melting TIN Flooding Annual
17 Table 3. Daily runoff loads of chemical components during three periods (snow melting period, flooding period and annual period). Snow melting Period kg/km 2 /day Osamunai (St. 3) Naie (St. 6) Flooding period kg/km 2 /day Annual period kg/km 2 /day Snow melting Period kg/km 2 /day Flooding period kg/km 2 /day Annual period kg/km 2 /day Q (x10 3 m 3 /km 2 /day) SS BOD TOCT * TOCF* TOCSS* NH4 + -N NO3- -N TIN DN TN PN DRP DP PRP TP PP Cl SO Bx** SiO *TOC = COD(Cr); Flooding period and period. **10 3 eq/km 2 /day 17
18 Table 4. Average concentration of loads of chemical components during three periods (snow melting period, flooding period and annual period) The values in that table are calculated by flow weighted method. Snow Flooding melting period Period Osamunai (St. 3) Naie (St. 6) Snow Annual Flooding melting period period Period Annual period mg/l mg/l mg/l mg/l mg/l mg/l Q (m 3 /s) SS BOD TOC T * TOC F * TOC SS * NH + 4 -N NO - 3 -N TIN Cl SO Bx** SiO *TOC = COD(Cr); Flooding period and Yearly **meq/l CONCLUSIONS We studied how non-point pollution relates to the characteristics of runoff loads of chemical components of the Ishikari River. Non-point pollution greatly influences the water quality of the Ishikari River. In other words, chemical components are present in great quantities as non-point pollutants on the ground surface and in soil. Because of the land area used by people expands, pollutant loads rise when the river rises. For the Ishikari river basin, preservation measures are necessary to control non-point pollutants, so as to maintain the environment of the basin in its natural state, and improved agricultural production methods are necessary to decrease non-point pollution. We must rethink our approach to water if we are to preserve it successfully. 18
19 1993 n n n 1 n 19
20 1998. L/A= C (Q/A) n C 20
21 21
22 22
23
24 e 0.23 K NO3 =e
25 L= Q/Q 0 k 0 e Q/Q 0 L Q
26 Methods-Data processing Quantification of the magnitude of the hysteresis Clockwise rotation type Anticlockwise rotation type L S 1 L S 1 S 2 S 2 Q Q S 1 /(S 1 +S 2 )represents magnitude of the hysteresis. S 1 /(S 1 +S 2 )=Nutrient Load Hysteresis Coefficient (NLHC) 9 Methods-Data processing Classification of the characteristics of nutrients load L by modeling with power number n in the L = CQ n and H n < n < n 0.25<H D ++ C ++ I <H 0.25 D + C + I H 0.1 D C I 0.25< H 0.1 D - C - I - H < 0.25 D -- C -- I -- H: Nutrient Load Hysteresis Coefficient, n: Power of the flow rate D: Dilution type, C: Constant type, I: Increasing type ++ to +: clockwise rotation type, none: little hysteresis, - to --: anticlockwise rotation type 26
27 Results- Classification of the characteristics of nutrients load L by modeling with power number n in the L = CQ n and H Components n H Classification Max. Av. Min. S.D. Max. Av. Min. S.D. Turbidity I ++ SS I ++ NH + 4 -N C NO - 2 -N I NO - 3 -N C - DN C TN I + PN I ++ DRP D + DP C ++ TP I ++ PP I ++ TOC I ++ DOC I POC I ++ Hinuma R And Shirakawa R. L-Q L-Q C=K Q -1 27
28 Sebangau R. 28
29 H. Tachibana, R. Iqbal, S. Akimoto, M. Kobayashi, K. Ohno, A. Mori, T. Itakura, H. Takahashi, K. Utosawa, N. Sumawijaya, S. Dohong, U. Darung and S. Limin Chemical characteristics of water at the upper reaches of the sebangau river, central kalimantan, indonesia TROPICS 15(4), ,
30 30
31 L-Q C, 31
32 Brisbane R. 32
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