CoPt 17

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1 CoPt 17

2 CoPt X CoPt ( ) CoPt i-

3 CoPt Co:Pt=8: EPMA X Co:Pt=4: T T X ii-

4 1 1.1 (HDD MD ) ( )

5 ( ) ( ) ( ) ) 1.2 (1) (2) (3) / -2-

6 2) 3) 4) 1.3 (anodized aluminum) 20 (Al 2 O 3 ) ( ) 1.3 ( ) CoPt 5) Co Pt (solid solution) 2 ( ) (substitutional solid solution) (interstitial solid solution) CoPt Co -3-

7 (hcp:hexagonal close packed) (fcc:face centered cubic) Pt fcc CoPt 1.4 CoPt Co:Pt 4:1 CoPt Cu 3 Au 1.5(a) fcc Co Pt Co:Pt 1:1 CoPt 825 CuAuI (fct:face centered tetragonal) 1.5(b) Co Pt fct (001) c/a fcc CoPt fct CoPt c 1.4 CoPt (a)copt 3 Cu 3 Au (b)copt CuAuI 1.5 CoPt

8 Co Fe Ni Co Fe 1.4 Co Pt 1:1 CoPt CoPt CoPt CoPt CoPt -5-

9 2 2.1 (VSM:Vibrating Sample Magnetometer) M x z a A(x,y,z) x-y S N E =2 f E = KafM j t + exp ω π (2.1) 2 K NSx K = 3 (2.2) 5 2r r N S (2.1) a f M E M VSM ( ) VSM-5 (1) z (2) a -6-

10 (3) E 80Hz 10kOe 2.2 X X 6) 7) X 2.2 X X Bragg X X X X (Cu) CuK 2.2 X X 2.2 Bragg λ = 2dsinθ (2.3) d a,b,c, (h k l) a=b=c h + k + l 2 = 2 (2.4) d a (2.3) (2.4) λ + + 2θ = 2sin -1 h k l 2 2 (2.5) a a=b h + k l 2 = (2.6) d a c -7-

11 (2.3) (2.5) λ + h k l 2θ = 2sin (2.7) a c a=b h + hk + k l 2 = (2.8) d a c (2.3) (2.8) λ θ = 2sin - h k l l (2.9) a c X CuK (40kV 40mA) λ = ( ) (2.10) (2.5) (2.7) (2.9) (2.10) (EPMA:Electron Probe(X-ray) Micro Analyzer) CoPt EPMA

12 ( ) X ( ) X X ( ) ( ) ) 2.3 CoPt ( ) Co:Pt=1:

13 3 CoPt mm (Al) 15mm 25mm mol/l (C 2 O 4 H 2 ) (C) 10mA/cm ( ) mol/l (H 3 PO 4 ) 5V -10-

14 3.3 CoPt 3.2 CoPt Co:Pt=8:1,4:1 (Pt) ( 3.3 ) 10V ON (T on ) 30ms T(T no T off ) 150ms 450ms mm 10mm ) CoPt Co Pt 1:1 (fct ) c -11-

15 CoPt

16 4 CoPt 4.1 Co Pt 50:50 fcc CoPt fct CoPt CoPt 50:50 Co Pt 4:1 8:1 CoPt 4.2 Co:Pt=8:1 Co:Pt=8:1 CoPt T on =30ms T=230ms N= EPMA CoPt 4.1 Co 50% 4.1 Co (8:1) (a) (i) -13-

17 (a) 100 (b) 200 (c) 300 (d) 400 (e) 500 (f)

18 (g) 700 (h) 800 (i) m s H c

19 4.3 m s H c kOe

20 4.2.3 X X 4.5(a) (i) (a) 100 (b) 200 (c) 300 (d) 400 (e) 500 (f)

21 (g) 700 (h) 800 (i) X =21.6(deg) Al 2 O 3 (113) =39.8(deg) Pt(111) 2 =44.7(deg) Al{200} Co CoPt EPMA Co:Pt=1:1 T on =30ms T=230ms N=

22 4.6 (8:1) Co:Pt=1:1 Co 4.3 Co:Pt=4:1 4.2 EPMA Co:Pt=1:1 600 Co EPMA Pt Co:Pt=4:1 T on =30ms T=150ms N= EPMA

23 Co (4:1) EPMA Co 12.5 Co:Pt=4:1 T on =30ms T=150ms N= (4:1,T=150ms) Co -20-

24 T Pt T T on =30ms T= ms N= (a) (d) (a) T=300ms (b) T=400ms (c) T=450ms (d) T=500ms 4.9 T 4.9 T=300,400ms Co T=450,500ms CoPt T (a) (e) T on =30ms T= ms N=

25 (a) T=150ms (b) T=300ms (c) T=400ms (d) T=450ms (e) T=500ms 4.10 T T m s H c

26 4.11 T m s 4.11 T T=400ms T=150ms 4.12 T H c 4.12 T T=150ms kOe -23-

27 4.3.3 T X X 4.13(a) (e) T on =30ms T= ms N=600 (a) T=150ms (b) T=300ms (c) T=400ms (d) T=450ms (e) T=500ms 4.13 T X =21.6(deg) Al 2 O 3 (113) 2 =39.8(deg) Pt(111) 2 =44.7(deg) Al{200} -24-

28 2 =46.2(deg) Pt{200} Co CoPt N=500 N= N= T T off CoPt Co:Pt=8:1 Co Co:Pt=4:1 Co Pt 1:1 Co -25-

29 5 ( ) Fe Co 2kOe CoPt EPMA EPMA EPMA Co:Pt=8:1,4:1 600 Co CoPt kOe Co:Pt 1:1 CoPt CoPt CoPt -26-

30 -27-

31 1) 1998 p56 p59 2) 1998 p74 p75 3) ) p17 5) 1993 p45,46,516 6) X ) 1993 p37 p39 8) 1997 p80,81 9) ( ) -28-

15

15 15 1...1 1-1...1 1-1-1...1 1-1-2...3 1-1-3...4 1-1-4...5 1-2...5 1-2-1...5 1-2-2...6 1-3...6 1-3-1...6 1-3-2...7 1-3-3...8 1-3-4...8 1.4 Co-Pt...9 1.5...9 2...10 2-1...10 2-1-1...10 2-1-2...10 2-2...11

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