Hideki MATSUOKA: An Introduction to Small-angle Scattering Fundamental aspects of small-angle scattering technique are duly explained from the very ba

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1 Hideki MATSUOKA: An Introduction to Small-angle Scattering Fundamental aspects of small-angle scattering technique are duly explained from the very basic points for the beginners and newcommers of this useful technique to study the strucuture of g Vernachlasisgten Dimensionen h.

2 (Dimension studied by scattering techniques.) from small, large and anisotropic particles.)

3 (Three scattering regions and information obtained.) small-angle scattering from isolated particle.)

4

5 (Calculation of scattering from core-shell sphere.) small-angle scattering from multi-particle system.)

6 (Radius of gyration (Rg) of particles.)

7 (Maximum position for scattering from sphere with radius R.) from polydisperse sphere.)

8

9

10

11

12 (Schematic representation of internal and external contrast variation techniques.)

13 1) O. Kratly, O. Glatter, ed.: gsmall-angle X-ray Scattering h, Academic (1982). 3) A. Guinier and G. Fournet: gsmall-angle Scattering of X-rays h, Wiely (1955). 4) A. Guinier: gx-ray Diffraction in Crystals, Imperfect Crystals, and Amorphous Bodies h, Freeman 1963, Dover Edition (1994). 5) H. Brumberger ed.: gsmall-angle X-ray Scattering h, Gordon & Breach (1967). 6) P. Lindner and Th. Zemb: gneutron, X-ray and Light Scattering: An Introduction to an investigative tool for colloidal and polymeric systems. hnorth Holland (1991). 7) J. S. Higgins and H. G. Benoit: gpolymers and Neutron Scattering h, Oxford (1994). 13) J. B. Hayter, J. Penfold: Coll. Polym. Sci (1983). 14) I. Fankuchen et al.: Ind. Eng. Chem (1945). 15) T. Hashimoto, M. Fujimura, and H. Kawai: Macromolecules (1980). 16) P. Mittelbach: Acta Physica Austriaca (1964). 18) P. W. Schmidt: gthe fractal approach to Heterogeneous Chemistry, Surface, Colloids, Polymers h, Ed. D. Avnir, Chap. 2, Weily (1989). 19) D. W. Schaefer and K. D. Keefer et al.: in gscience of Ceramic Chemical Processing h, LL. Hench, D. R. Ulrich eds., Weily, (1986). 21) K. Nakanishi et al.: J. Amer. Ceram. Soc (1992). 22) P. Debye: Phys. Z (1927), ibid (1930). 23) G. Fournet: Handbuch der Physik XXXII Springer (1957). 25) F. Zernike and J. A. Prins: Z. Physik (1927). 26) P. Debye and H. Menke: Phys. Z (1930). 27) J. P. Hansen and J. B. Hayter: Mol. Phys (1982). 28) R. Hosemann and S. N. Baguchi: gdirect Analysis of Diffraction by Matter h, North Holland (1966).

14 29) H. Matsuoka et al.: PhYs. Rev. B (1990). 30) P. Debye and A. M. Bueche: J. Appl. Ctvst (1949). 31) L. S. Ornstein and F. Zernike: Physik. Z (1918). 32) L. S. Ornstein and F. Zernike: Physik. Z (1926). 34) G. Porod: Kollid-Z (1951). 35) T. Hashimoto et al.: Macromolecules (1980). 36) M. Nakano, H. Matsuoka, H. Yamaoka, A. Poppe, and D. Richter: Macromolecules (1999). 37) M. Nierlich et al.: J. Physique (1985). 38) K. Sumaru, H. Matsuoka, H. Yamaoka, and G. D. Wignall: Phys. Rev. E (1996). Department of Polymer Chemistry, Kyoto University, Kyoto , Japan TEL FAX

A. Guinier and G. Fournet, "Small-Angle Scattering of X-rays" John Wiley & Sons, New York (1955). "Small Angle X-ray Scattering" eds. O. Glatter and O. Kratky Academic Press, London (198). R.-J. Roe, "Method

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