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QMI_10.dvi

25 3 19 Erwin Schrödinger 1925 3.1 3.1.1 σ τ x u u x t ux, t) u 3.1 t x P ux, t) Q θ P Q Δx x + Δx Q P ux + Δx, t) Q θ P u+δu x u x σ τ P x) Q x+δx) P Q x 3.1: θ P θ Q P Q equation of motion P τ Q τ σδx

V(x) m e V 0 cos x π x π V(x) = x < π, x > π V 0 (i) x = 0 (V(x) V 0 (1 x 2 /2)) n n d 2 f dξ 2ξ d f 2 dξ + 2n f = 0 H n (ξ) (ii) H

199 1 1 199 1 1. Vx) m e V cos x π x π Vx) = x < π, x > π V i) x = Vx) V 1 x /)) n n d f dξ ξ d f dξ + n f = H n ξ) ii) H n ξ) = 1) n expξ ) dn dξ n exp ξ )) H n ξ)h m ξ) exp ξ )dξ = π n n!δ n,m x = Vx)

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高知工科大学電子 光システム工学科

卒業研究報告 題 目 量子力学に基づいた水素分子の分子軌道法的取り扱いと Hamiltonian 近似法 指導教員 山本哲也 報告者 山中昭徳 平成 14 年 月 5 日 高知工科大学電子 光システム工学科. 3. 4.1 4. 4.3 4.5 6.6 8.7 10.8 11.9 1.10 1 3. 13 3.113 3. 13 3.3 13 3.4 14 3.5 15 3.6 15 3.7 17

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January 23, 2013 I Ryuichiro Kitano Department of Physics, Tohoku University, Sendai 980-8578, Japan Abstract I Griffiths Contents 0 5 1 6 1.1....................... 7 1.2..............................

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