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21 Coarsening and Microstructure Development in Nanocrystalline Materials Minerals with nanometer-scale dimensions (nanocrystalline materials) are extremely common constituents of the Earth's surface (e.g., clays, oxyhydroxides of Fe, Mn, Ti, A1, etc.). These finely crystalline particles are highly reactive and their behavior directly controls the geochemical cycles of many elements. In addition to crystallization as products of chemical weathering, nanocrystals are almost ubiquitous products of biomineralization reactions. A key question stimulated by reports of possible evidence for life on Mars centers on how biologically produced nanocrystals can be distinguished from abiotic phases in extraterrestrial and in ancient Earth materials. This challenge raises issues related to preservation of primary nanocrystalline characteristics (especially morphology and defect mic- Atomic-resolution transmission electron microscope image (inset) of the brookite (TiOz) polytype formed at a twin interface in anatase (TiOz). Arrows indicate displacement required for polytypic interconversion. Penn and Banfield. Am. Min. submitted.
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