有機非線形光学材料
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1 Organic Nonlinear Optical Materils Osamu Watanabe E P P E P ε 0 E EE EEE ε 0 (n) n n NLO d (2) =2d (1) SI P E E F ζe P p ε 0 αf βff γfff α β γ α β γ π R&D Vol. 27 No. 1 ( )
2 NLO effects and the applications. ω ωω ω ω ω ω ω ω ω ω d d d R&D Vol. 27 No. 1 ( )
3 d n n π π π γ π P 2ω = 2µ 0 3/2 ε 1/2 0 ω 2 d 2 eff L 2 sin P 2 kl/2 ω P ω An 2ω n ω kl/2 2 ω ω µ ε ω eff ω ω ω ω ω ω ω ω π ω lc ω ω e o ω = ω Theoretical relationships between P 2ω and L. R&D Vol. 27 No. 1 ( )
4 Absorption edge and d coefficients of representative crystals. Angle phase matching for positive uniaxial crystal. o n ω : refractive index for ordinary ray of fundamental wave n e ω (θ): refractive index for extraordinary ray of fundamental wave o n 2ω : refractive index for ordinary ray of SHG wave e n 2ω (θ): refractive index for extraordinary ray of SHG wave β β β µ β = ge f 2 2 E g 2 E g hν 2 2 E g 4 hν 2 f µ ν f µge g β R&D Vol. 27 No. 1 ( )
5 β β d d d 11 d 11 d 12 d 11 d 11 d Chemical structures and SHG powder efficiency of low molecular weight compounds for second NLO materials. R&D Vol. 27 No. 1 ( )
6 d ii d β d d 33 β π d d 11 d 12 µ β R&D Vol. 27 No. 1 ( )
7 µ β µ Chemical structures of polymers and low molecular weight compounds for second NLO materials. R&D Vol. 27 No. 1 ( )
8 d d d µ Chemical structures of polymers and low molecular weight compounds for second NLO materials. R&D Vol. 27 No. 1 ( )
9 β π π β β d d R&D Vol. 27 No. 1 ( )
10 ε ε Chemical structures of low molecular weight compounds for third NLO materials. Chemical structures of polymers for third NLO materials. R&D Vol. 27 No. 1 ( )
11 α τ α τ π β γ β β α R&D Vol. 27 No. 1 ( )
12 π 1) Franken, P. A., Hill, A.E, Peters, C. W. and Weinreich, G. Phys. Rev. Lett., (1961), 118 2) Williams, D. J. ACS Symp. Ser., (1983) 3) Choy, M. M. and Byer, R. L. : Phys. Rev., (1976), 14 4) Levine, B. F., Betha, C. G., Thurmond, C. D., Lynch, R. T. and Bernstein, J. L. J. Appl. Phys., (1979), ) Heilmeir, G. H., Ockman, N., Brannstein, R. an Kramer, D. A. : Appl. Phys. Lett., (1964), 156 6) Hermann, J. P. and Ducuing, J. J. Appl. Phys., (1974), ) Rustagi, K. C. and Ducing, J. Opt. Commun., (1974), 258 8) (1982), 163, 9) Hattori, T. and Kobayashi, T. Chem. Phys. Lett., (1987), ) Yariv, A. (1988), 250, 11) (1985), 113, 12) (1990), 6, 13) Oudar, J. L. and Chemla, D. S. Opt. Commun., (1975), ) Levin, B. F. Chem. Phys. Lett., (1976), ) Oudar, J. L. and Chemla, D. S. J. Chem. Phys., (1977), ) Nicoud, J. F. and Twieg, R. J. Nonlinear Optical Properties of Organic Molecules and Crystal, (1987), 255, Acdemic Press 17) Zyss, J. and Oudar, J. L. Phys. Rev., (1982), ) Zyss, J. : J. Non-Cryst. Solid., (1982), ) Halbout, J. M., Blit, S., Donaldson, W. and Tang, C.L. IEEE, J. Quantum Electron., QE- (1979), ) Jain, K., Hewing, G. H., Cheng, Y. Y. and Crowley, J. I. : IEEE J. Quantum Electron., QE- (1981), ) (1990), ) Twieg, R. and Jain, K. ACS Symp. Ser., (1983), 57 23) Panunto, T. W., Urbanczyk, Z., Johnson, R. and Etter, M. C. : J. Am. Chem. Soc., (1987), ) Zhao, X., Chang, Y.-L., Fowler, F. W. and Lauher, J. W. : J. Am. Chem. Soc., (1990), ) R&D Vol. 27 No. 1 ( )
13 (1989), ) (1991), ) Wada, T., Yamada, A. and Sasabe, H. Preprints of Int. Workshop on Crystal Growth of Organic Mater., (1989), ) Tam, W., Guerin, B., Calabrese, J. C. and Stevenson, S. H. Chem. Phys. Lett., (1989), 93 29), (1990), ) Oudar, J. L. and Hierle, R. : J. Appl. Phys., (1977), ) Zyss, J., Chemla, D. S. and Nicoud, J. F. J. Chem. Phys., (1984), ) Zyss, J., Chemla, D. S. and Nicoud, J. F. J. Chem. Phys., (1981), ) Meredith, G. R. ACS Sym. Ser., (1983), 27 34) Tasaka, S., Abe, T., Matsushima, R, Suzuki, M., Chen, D. Y. and Okamoto, N. : Jpn. J. Appl. Phys., (1991), ) Twieg, R. J. and Jain, K. ACS Sym, Ser., (1983), 57 36) (1989), ) Microoptic News, (1991), 73 38) Singer, K. D., Kuzyk, M. G., Holland, W. R., Sohn, J. E. and Lalama, S. J. J. Opt. Soc. Am., (1987), ) Singer, K. D., Kuzyk, M. G., Holland, W. R., Sohn, J. E. and Lalama, S. J. Appl. Phys. Lett., (1988), ) McFee, J. H., Bergman, J. G. and Crane, G. R. IEEE Trans. Sonics and Ultrason., SU- (1972), ) Yoshimura, T. Phys. Rev., (1989), ) Meredith, G. R., Vandusen, J. G. and Williams, D. J. ACS Sym. Ser., (1983), ) Leslie, T. M., Martino, R. N., Chue, E. W., Kanarian, G., Haas, D., Nelson, G., Stamatoff, J. B., Suetz, D. E., Teng, C. C. and Yoon, H. N. Mol. Cryst. Liq. Cryst., (1987), ) Heckingbottom, R., Hill, J. R., Holdcroft, G. E., Dunn, P. L., Panteils, P. and Rush, J. D. Nonlinear Optics of Organics and Semiconductors, (1989), 284, Springer-Verlag 45) Jungbauer, D., Reck, B., Twieg, R., Yoon, D. Y., Willson, C. G. and Swalen, J. C. Appl. Phys. Lett., (1990), ) Yoon, H. N., Man, H. T. and Haus, D. Microoptic News, (1991), 67 47) Hampsch, H. L., Yang, J., Wong, G. K. and Torkelson, J. M. : Macromolecules, (1990), ) Miyazaki, T., Watanabe, T. and Miyata, S. Jpn. J. Appl. Phys., (1988), ) Yamada, S., Matsuoka, Y., Wada, T., Grossman, H., Hara, M. and Sasabe, H. Proc. Annu. Conf. IEEE Engineering in Medicine and Biology Society, (1988), ), 24(1989), ) Kaino, T., and Kurihara, T. : Microoptics News, (1991), 83 52) Huggard, P. G., Blau, W. and Schweitzer, D. Appl. Phys. Lett., (1987), ) (1991), ) (1991), ) Sauteret, C., Hermann, J. P., Frey, R., Pradere, F., Ducuing, J., Baughman, R. H. and Chance, R. R. Phys. Rev. Lett., (1976), ) Shand, M. L. and Chance, R. R. : J. Chem. Phys., (1978), ) Okada, S., Ohsugi, M., Masaki, A. and Kato, M. Mol. Cryst. Liq. Cryst., (1990), 81 58) Drury, M. R. Solid Stata Commun., (1988), ) Sinclair, M., Moses, D., Akagi, K. and Heeger, A. J. : Phys. Rev., (1988), ) Prasad, P. N., Swiatkiewicz, J. and Pfleger, J. Mol. Cryst. Liq. Cryst., (1988), 53 61) 61(1991), ) Jenekhe, S. A., Chen, W.-C., Lo, S. and Flom, S. R. : Appl. Phys. Lett., (1990), ) Kaino,T., Kubodera, K., Tomaru, S., Kurihara, T., Saito, S., Tsutsui, T. and Tokito, S. Electron. Lett. (1987), ) Kainou, T., Kubodera, K., Kobayashi, H., Kurihara, T., Saito, S., Tsutsui, T., Tokito, S. and Murata, H. : Appl. Phys. Lett., (1988), ) Kaino, T., Kobayashi, H., Kubodera, T., Saito, S., Tsutsui, T. and Tokito, S. : Appl. Phys. Lett., (1988), R&D Vol. 27 No. 1 ( )
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