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1 1327ｨｰｨｨｨｺｨ ｨ ｨｰｨｬ69284 ｨｨ 6ｨｺ2ｨ ｨｪｨ 3, 26, 1 9 (213) ｨｰ61 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ 157 ｨｨ4ｨｬ282ｨｪｨｨｨｦ 1ｨｨ6ｨｺ9ｨｨ1ｨ ｨ 46ｨｰｨ 9 ｨ ｨｰｨｬ6928ｨｪ6ｨｬ 9641ｨｮ ｨｮｨ ｨｪ4ｨｦ, ｨｺ2ｨｰ69ｨ 6ｨｪ9ｨｰｨｨｨｰｨｮｨｰ 786ｨｬ4352ｨｪｨｪ6ｨｦ 5ｨｺ656ｨｨｨｨ ,. 3ｨｺｨ ｨｰ28ｨｨｨｪｨ ｨｮ8, , ｨｮ5. 56ｨｹｨｨ 869ｨ 5299ｨｺ6ｨｦ, 2ｨ 369ｨｰｨｮ7ｨｨ5ｨ 9 821ｨ ｨｺ2ｨｨ ｨｰ61 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ 79572ｨｰ ｨｰ4ｨｬ ｨｬｨ 564ｨ ｨｰ8ｨ ｨｰｨｪ4ｨｬ ｨｬ2ｨｰ616ｨｬ ｨｪｨｺｨｨ ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｦ ｨ 466ｨ 8ｨ 4ｨｪ41 92ｨｴ29ｨｰ ｨｮ ｨ 9ｨｪ2ｨｪｨｨ6 96 9ｨｰｨ ｨｪ1ｨ 8ｨｰｨｪ4ｨｬｨｨ ｨｬ2ｨｰ61ｨ ｨｬｨｨ ｨｬ6ｨｪｨｨｨｰ68ｨｨｨｪｨ ｨｪｨ ｨｰ6 ﾂｨｪ69ｨｰｨｹ ｨｨ4ｨｬ282ｨｪｨｨｨｦ ｨｬ2ｨｰ616ｨｬ 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ 9 4ｨｪｨ ﾂｨｨｨｰ25ｨｹｨｪ6 ｨ 65ｨｹ32ｨｦ 9ｨｰ272ｨｪｨｨ 95ｨｨ76ｨｰ ｨｬ2ｨｰ268656ｨｨ ﾂ29ｨｺｨｨ2 ｨｨ ｨｬ2ｨｰ61ｨｨ ﾂ29ｨｺｨｨ2 ｨ ｨｺｨｰ684. 9ｨｰｨ ｨｰｨｹ ｨｰｨ 952ｨｪ4 1ｨ ｨｪｨｪ42 ｨｰ2682ｨｰｨｨ ﾂ29ｨｺｨｨ1 ｨｨ 5ｨｺ9728ｨｨｨｬ2ｨｪｨｰｨ 5ｨｹｨｪ41 ｨｨ ｨ ｨｪｨｨｨｦ 871ｨ ｨ ｨｺｨｰ6869, 95ｨｨ76ｨｴｨｨ1 ｨｪｨ ｨｰ6 ﾂｨｪ69ｨｰｨｹ 824ｨｮ5ｨｹｨｰｨ ｨｰ69 ｨｨ4ｨｬ282ｨｪｨｨｨｦ ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｦ NO 2 9 ｨ ｨｰｨｬ6928ｨｪ6ｨｬ 9641ｨｮ12. 58ｨ 9ｨｪ2ｨｪｨｨ2 ｨｬ2ｨｰ61ｨ 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ ｨｨ ｨｺ6ｨｪｨｰ865ｨｹｨｪ41 ｨｬ2ｨｰ6169 (968ｨ 2ｨｨ6ｨｪｨｪ42 ｨｰ8ｨｮｨ ｨｺｨｨ, 12ｨｬ656ｨｬｨｨｨｪ2922ｨｪｨｰｨｪ4ｨｦ ｨ 46ｨ ｨｪｨ 5ｨｨ4ｨ ｨｰ68) 9 ｨｮ9569ｨｨ71 ｨｮｨｬ282ｨｪｨｪ6-ｨｺ6ｨｪｨｰｨｨｨｪ2ｨｪｨｰｨ 5ｨｹｨｪ66 ｨｺ5ｨｨｨｬｨ ｨｰｨ 9479ｨｨ56 9ｨｨ9ｨｰ2ｨｬｨ ｨｰｨｨ ﾂ29ｨｺ62 9ｨｰｨ ｨｰｨｨ9ｨｰｨｨ ﾂ29ｨｺｨｨ 4ｨｪｨ ﾂｨｨｨｬ62 4ｨ ｨｪｨｨ32ｨｪｨｨ2 ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｦ NO 2, ｨｪｨ ｨｦ12ｨｪｨｪ ｨｬ6ｨｴｨｹ6 ｨｬ2ｨｰ61ｨ 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ. 36ｨｺｨ 4ｨ ｨｪ6, ﾂｨｰ6 6ｨ ｨｪｨ 8ｨｮ32ｨｪｨｪ62 4ｨ ｨｪｨｨ32ｨｪｨｨ2 9974ｨ ｨｪ6 9 ｨｰ2ｨｬ, ﾂｨｰ6 6ｨ ｨｴ278ｨｨｨｪ7ｨｰｨ 7 ｨｬ6125ｨｹ 6ｨ 8ｨ ｨ 6ｨｰｨｺｨｨ 1ｨ ｨｪｨｪ41 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ ｨｪ2 ｨｮ ﾂｨｨｨｰ49ｨ 2ｨｰ 696ｨ 2ｨｪｨｪ69ｨｰｨｨ ｨｨ4ｨｨｨｺ6-1ｨｨｨｬｨｨ ﾂ29ｨｺ66 94ｨ ｨｨｨｬ612ｨｦ9ｨｰ9ｨｨ7 1ｨｨ6ｨｺ9ｨｨ1ｨ ｨ 46ｨｰｨ 9 8ｨ 9ｨｰ9686ｨｬ 968ｨ 2ｨｪｨｰｨ, 9974ｨ ｨｪｨｪ ｨｨ7ｨｪｨｨ2ｨｬ 95ｨ 3ｨｪ69ｨｰｨｨ 9641ｨｮ1ｨ. 4ｨ 48ｨ ｨ 6ｨｰｨ ｨｪｨ ｨｪ69ｨ 7 ｨｨ4ｨｨｨｺ6-1ｨｨｨｬｨｨ ﾂ29ｨｺｨ 7 ｨｬ6125ｨｹ 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ 1ｨｨ6ｨｺ9ｨｨ1ｨ ｨ 46ｨｰｨ, 69ｨｪ69ｨ ｨｪｨｪｨ 7 ｨｪｨ ｨｨ4929ｨｰｨｪ41 1ｨ ｨｪｨｪ ｨ ｨｨｨｬ612ｨｦ9ｨｰ9ｨｨｨｨ NO 2 9 8ｨ 9ｨｰ9686ｨｬ 968ｨ 2ｨｪｨｰｨ. 38ｨｨｨｬ2ｨｪ2ｨｪｨｨ2 ｨｬ6125ｨｨ ｨｨ56 9ｨｮｨｴ29ｨｰ92ｨｪｨｪ6 ｨｮ5ｨｮ ﾂ3ｨｨｨｰｨｹ 965ｨ 9ｨｨ2 ｨｬ231ｨｮ ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨ7ｨｬｨｨ NO 2, 8ｨ 99 ﾂｨｨｨｰｨ ｨｪｨｪ4ｨｬｨｨ 76 1ｨ ｨｪｨｪ4ｨｬ 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ, ｨｨ ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨ7ｨｬｨｨ, ｨｨ4ｨｬ282ｨｪｨｪ4ｨｬｨｨ ｨｺ6ｨｪｨｰ865ｨｹｨｪ4ｨｬｨｨ ｨｬ2ｨｰ61ｨ ｨｬｨｨ, ｨｮ9ｨｰ8ｨ ｨｪｨｨｨｰｨｹ 9ｨｨ9ｨｰ2ｨｬｨ ｨｰｨｨ ﾂ29ｨｺ62 ｨｨ 9ｨｰｨ ｨｰｨｨ9ｨｰｨｨ ﾂ29ｨｺｨｨ 4ｨｪｨ ﾂｨｨｨｬ62 8ｨ 45ｨｨ ﾂｨｨ2 ｨｬ231ｨｮ ｨｪｨｨｨｬｨｨ. 856 ﾂ ｨ : 1ｨｨ6ｨｺ9ｨｨ1 ｨ 46ｨｰｨ, ｨｬ6ｨｪｨｨｨｰ68ｨｨｨｪ 4ｨ 874ｨｪ2ｨｪｨｨ7 9641ｨｮ1ｨ, ｨｬｨ 564ｨ ｨｰ8ｨ ｨｰｨｪ42 ｨｬ2ｨｰ614 ｨｬ6ｨｪｨｨｨｰ68ｨｨｨｪｨ, 7ｨ 99ｨｨ9ｨｪ4ｨｦ 786ｨ 66ｨｰｨ 68, ｨｨ4ｨｨｨｺ6-1ｨｨｨｬｨｨ ﾂ29ｨｺｨ 7 ｨｬ6125ｨｹ; nitrogen dioxide, air pollution monitoring, low cost monitoring methods, passive sampling, physico-chemical model. 9212ｨｪｨｨ2 5ｨ 874ｨｪ2ｨｪｨｨ2 ｨ ｨｰｨｬ6928ｨｪ ｨｮ1ｨ 79572ｨｰ97 61ｨｪ6ｨｦ ｨｨ4 ｨ ｨｺｨｰｨｮｨ 5ｨｹｨｪ ｨｬ2ｨｪｨｪ41 786ｨ 52ｨｬ ｨｰ686ｨｪｨｪ26 ｨｨ4ｨｮ ﾂ2ｨｪｨｨ , 786ｨｰ2ｨｺｨ 6ｨｴｨｨ1 9 6ｨｺ8ｨｮ3ｨ 6ｨｴ2ｨｦ 98212, ｨｨ 622ｨｪｨｺｨｨ ｨｰ9ｨｨｨｦ 4ｨ 874ｨｪ2ｨｪｨｨ7 ｨｪ26ｨ 161ｨｨｨｬ4 8ｨ 4ｨｪ66ｨ 8ｨ 4ｨｪ42 ｨｨｨｪ9ｨｰ8ｨｮｨｬ2ｨｪｨｰ4 ｨｨ ｨｬ2ｨｰ614 5ｨｺ656ｨｨ ﾂ29ｨｺ66 ｨｬ6ｨｪｨｨｨｰ68ｨｨｨｪｨ. 21ｨｪｨｨｨｬ ｨｨ ｨｬ2ｨｪｨｪ ｨｺｨｰｨｨ9ｨｪ41 ｨｬ2ｨｰ6169, ｨｺ6ｨｰ684ｨｦ ｨｨ9765ｨｹ4ｨｮ2ｨｰ97 78ｨｨ 622ｨｪｨｺ2 4ｨ 874ｨｪ2ｨｪｨｨ7 ｨ ｨｰｨｬ6928ｨｪ ｨｮ1ｨ, 79572ｨｰ97 ｨｬ2ｨｰ61 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ [1]. 38ｨｨｨｪ2ｨｨ7 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ 69ｨｪ69ｨ ｨｪ ｨｪｨ ｨｬ652ｨｺｨｮ578ｨｪ6ｨｦ 1ｨｨｨｮ4ｨｨｨｨ 4ｨ 874ｨｪ76ｨｴ26 92ｨｴ29ｨｰ9ｨ ｨｨ4 6ｨｺ8ｨｮ3ｨ 6ｨｴ ｨｮ1ｨ ｨｺ 968ｨ 2ｨｪｨｰｨｮ (ｨ ｨｺｨ ﾂｨｺｨｨ 9641ｨｮ1ｨ ) ｨｮ6ｨｴｨｨｨｬ ｨｴ2ｨｪｨｨ2ｨｬ ｨｨ ｨｪｨ ｨｺ6752ｨｪｨｨ2ｨｬ 9 8ｨ 9ｨｰ ｨ 2ｨｪｨｰｨ 4ｨ 9 ﾂ2ｨｰ ｨｨ4ｨｨ ﾂ29ｨｺ6ｨｦ ｨｨ5ｨｨ 1ｨｨｨｬｨｨ ﾂ29ｨｺ6ｨｦ 968ｨ 2ｨｨｨｨ ｨｨｨｰ25ｨｹｨｪ69ｨｰｨｹ 6ｨｰｨ 68ｨ 21ｨｨｨｪｨｨ ﾂｨｪ6ｨｦ 786ｨ 4 969ｨｰｨ 9572ｨｰ 6ｨｰ ｨｪ29ｨｺ65ｨｹｨｺｨｨ1 1ｨｪ2ｨｦ 16 ｨｪ29ｨｺ65ｨｹｨｺｨｨ1 ｨｪ2125ｨｹ, ﾂｨｰ ｨｰ 622ｨｪｨｨ9ｨ ｨｰｨｹ 9821ｨｪｨｨ2 ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｨ 4ｨ 874ｨｪ76ｨｴｨｨ1 92ｨｴ29ｨｰ9 4ｨ 728ｨｨ61 786ｨ 66ｨｰｨ 68ｨ. 269ｨｰ6ｨｨｨｪ9ｨｰ9ｨ ｨｬｨｨ ｨｬ2ｨｰ61ｨ 79576ｨｰ ｨｰ6ｨｰｨ ｨｨ9765ｨｹ469ｨ ｨｪｨｨ7, 6ｨｰｨｪ69ｨｨｨｰ25ｨｹｨｪｨ ｨｨ4ｨｪｨ, ｨｺ6ｨｬ7ｨ ｨｺｨｰｨｪ69ｨｰｨｹ 786ｨ 66ｨｰｨ 68ｨｪ41 ｨｮ9ｨｰ86ｨｦ9ｨｰ9, ｨｪ24ｨ 9ｨｨ9ｨｨｨｬ69ｨｰｨｹ 6ｨｰ ｨｨ9ｨｰ6 ﾂｨｪｨｨｨｺ69 ｨ 9ｨｨ5ｨｨｨｦ 852ｨｺ9229ｨｨ ﾂ 3611ｨｮｨ ｨｪ4ｨｦ (Basil@ecko.uran.ru); 1ｨ ｨｰｨ 5ｨｹ7 852ｨｺ9ｨ ｨｪ1869ｨｪｨ 73ｨｺ2ｨｰ69ｨ. 552ｨｺｨｰ865ｨｪ28ｨｨｨｨ. 6ｨｰｨｨ 1ｨ 8ｨ ｨｺｨｰ28ｨｨ9ｨｰｨｨｨｺｨｨ ｨｰ ｨｨ9765ｨｹ469ｨ ｨｰｨｹ 7ｨ 99ｨｨ9ｨｪ4ｨｦ 786ｨ 66ｨｰｨ ｨｪｨｨ7 ｨｰｨ ｨｺｨｨ1 4ｨ 1ｨ ﾂ, ｨｺｨ ｨｺ 622ｨｪｨｺｨ ｨｮ869ｨｪ7 4ｨ 874ｨｪ2ｨｪｨｨ7 9 6ｨｰ1ｨ 52ｨｪｨｪ41 8ｨ ｨｦ6ｨｪｨ 1, 12 ｨｨ4ｨｬ282ｨｪｨｨ7 18ｨｮｨｨｨｬｨｨ (9ｨｰｨ ｨｪ1ｨ 8ｨｰｨｪ4ｨｬｨｨ) ｨｬ2ｨｰ61ｨ ｨｬｨｨ 4ｨ ｨｰ8ｨｮ1ｨｪ2ｨｪ4 ｨｨ5ｨｨ 8ｨ ｨｪ22 ｨｪ ｨｨ5ｨｨ9ｨｹ, ｨｺｨ 8ｨｰｨｨ869ｨ ｨｪｨｨ2 4ｨ 874ｨｪ2ｨｪｨｨ7, 622ｨｪｨｺｨ 72896ｨｪｨ 5ｨｹｨｪ ｨｨｨｬｨｨ ﾂ29ｨｺ ｨｦ9ｨｰ9ｨｨ7 ｨｨ ｨｰ.1. [2]. 5 76ｨｬ6ｨｴｨｹ6 ｨｬ2ｨｰ61ｨ 7ｨ 99ｨｨ9ｨｪ66 786ｨ 66ｨｰｨ 68ｨ ｨｬ63ｨｪ ｨｰｨｹ ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｨ ｨｪ268ｨ ｨｪｨｨ ﾂ29ｨｺｨｨ1 ｨ 469 (NO 2, SO 2, NH 3, O 3 ｨｨ ｨｰ.1.), 52ｨｰｨｮ ﾂｨｨ1 68ｨ ｨｪｨｨ ﾂ29ｨｺｨｨ1 9621ｨｨｨｪ2ｨｪｨｨｨｦ, 9ｨｰ6ｨｦｨｺｨｨ1 68ｨ ｨｪｨｨ ﾂ29ｨｺｨｨ1 9621ｨｨｨｪ2ｨｪｨｨｨｦ, ｨｪｨｪ41 ﾂｨ 9ｨｰｨｨ2 [2]. 2ｨｰ61 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ 3ｨｨ86ｨｺ6 78ｨｨｨｬ2ｨｪ72ｨｰ97 4ｨ 8ｨｮｨ 236ｨｬ (5ｨ 7ｨ 1ｨｪｨ ｨ [1], 518 [3]), 61ｨｪｨ ｨｺ6 9 ｨｪｨ 32ｨｦ 9ｨｰ8ｨ ｨｪ2 ｨｨ4929ｨｰ2ｨｪ 98ｨ 9ｨｪｨｨｨｰ25ｨｹｨｪ6 ｨｬｨ ｨｹ 1ｨ ｨｪｨｪ6ｨｦ 8ｨ ｨ 6ｨｰ4 4ｨ ｨｺ56 ﾂｨ 5ｨ 9ｨｹ 9 ｨｰ6ｨｬ, ﾂｨｰ6ｨ 4 9 ｨｨ9765ｨｹ469ｨ ｨｪｨｨ2ｨｬ 98219ｨｰ9 ｨｬｨ ｨｰ2ｨｬｨ ｨｰｨｨ ﾂ29ｨｺ66 ｨｬ6125ｨｨ869ｨ ｨｪｨｨ7 ｨｨ ｨｪｨ ｨｰｨｮ8ｨｪ41 ｨｨ4ｨｬ282ｨｪｨｨｨｦ 9 ｨｮ9569ｨｨ71 ｨｮｨｬ282ｨｪｨｪ6ｨｺ6ｨｪｨｰｨｨｨｪ2ｨｪｨｰｨ 5ｨｹｨｪ66 ｨｺ5ｨｨｨｬｨ ｨｰｨ ｨｨ ｨ ｨｰｨｹ 95ｨｨ7ｨｪｨｨ2 8ｨ 45ｨｨ ﾂｨｪ41 ｨｬ2ｨｰ268656ｨｨ ﾂ29ｨｺｨｨ1 ｨｨ ｨｬ2ｨｰ61ｨｨ ﾂ29ｨｺｨｨ1 ｨ ｨｺｨｰ6869 ｨｪｨ ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ NO 2 ｨｨ4 ｨ ｨｰｨｬ6928ｨｪ ｨｮ1ｨ. ｨｪｨ 9ｨｰ67ｨｴ2ｨｦ 9ｨｰｨ ｨｰｨｹ2 8ｨ 99ｨｬ6ｨｰ82ｨｪ4 9521ｨｮ6ｨｴｨｨ2 ｨ ｨｺｨｰ684: 26ｨｬ2ｨｰ8ｨｨ7 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺｨ, ｨｺ652ｨ ｨ ｨｪｨｨ2 ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｨ 6ｨｰｨ ｨｨ8ｨ 2ｨｬ66 92ｨｴ29ｨｰ9ｨ, ｨｺ652ｨ ｨ ｨｪｨｨ2 ｨｰ2ｨｬ728ｨ ｨｰｨｮ84 ｨｨ 95ｨ 3ｨｪ69ｨｰｨｨ 9641ｨｮ1ｨ, 92ｨｰ28, ｨｪｨ 94ｨｴ2ｨｪｨｨ2 968ｨ 2ｨｪｨｰｨ, 52ｨｺｨｰｨｨ9ｨｪ69ｨｰｨｹ 968ｨ 2ｨｪｨｰｨ ｨｮｨ ｨｪ4ｨｦ.8., 73ｨｺ2ｨｰ69ｨ 1.8.,

2 136125ｨｹ 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ 2ｨｰ61 7ｨ 99ｨｨ9ｨｪ66 786ｨ 66ｨｰｨ 68ｨ ｨ 45 ｨｨ9765ｨｹ469ｨ ｨｪ 157 ｨｨ4ｨｬ282ｨｪｨｨｨｦ ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｦ NO 2. 6ｨｪｨｰ2829 ｨｺ ｨｨ4ｨｬ282ｨｪｨｨ7ｨｬ NO ｨ ｨｪ 9 ｨｰ2ｨｬ, ﾂｨｰ6 1ｨｨ6ｨｺ9ｨｨ1 ｨ 46ｨｰｨ 6ｨｰｨｪ69ｨｨｨｰ97 ｨｺ 78ｨｨ68ｨｨｨｰ2ｨｰｨｪ4ｨｬ 4ｨ 874ｨｪｨｨｨｰ257ｨｬ 68619ｨｺ ｨｮ1ｨ, 94449ｨ 2ｨｰ ｨｪ2ｨ ｨｰｨｨ9ｨｪ ｨｰ9ｨｨ ｨｹ7 5612ｨｦ, 8ｨ 9ｨｰｨｨｨｰ25ｨｹｨｪ69ｨｰｨｨ, 9ｨｰ86ｨｨｨｰ25ｨｹｨｪ41 ｨｬｨ ｨｰ28ｨｨｨ ｨ ｨｨｨ ｨ 97869ｨｰ8ｨ ｨｪ2ｨｪｨｪ4ｨｬ 78ｨｨ 7ｨ 99ｨｨ9ｨｪ6ｨｬ 6ｨｰｨ ｨ NO ｨｰ97 ｨｨ9765ｨｹ469ｨ ｨｪｨｨ2 7ｨ 99ｨｨ9ｨｪ41 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺ69 ｨｰ8ｨｮｨ ﾂｨ ｨｰ66 ｨｰｨｨ7ｨ (1ｨｨｨｮ4ｨｨ6ｨｪｨｪｨ 7 ｨｰ8ｨｮｨ ｨｺｨ ) [1]. 865ｨｨ ﾂ29ｨｰ96 ｨｪｨ ｨｺ6752ｨｪｨｪ66 1ｨｨ6ｨｺ9ｨｨ1ｨ ｨ 46ｨｰｨ ｨｰ97 9 9ｨｨ12 ｨｪｨｨｨｰ8ｨｨｨｰ-ｨｨ6ｨｪ69 (NO 2 ｨC ) ｨｮ5ｨｹｨｰｨ ｨｰｨ ｨｬ 1ｨｨｨｬｨｨ ﾂ29ｨｺ66 ｨ ｨｪｨ 5ｨｨ4ｨ 786ｨ ｨｬｨ ｨ 7ｨ 99ｨｨ9ｨｪ66 786ｨ 66ｨｰｨ 68ｨ 78ｨｨ9212ｨｪｨ ｨｪｨ 8ｨｨ ｨ 2ｨｪｨｰ L 4ｨｨ ｨｬｨ ｨ 7ｨ 99ｨｨ9ｨｪ66 786ｨ 66ｨｰｨ 68ｨ : 5 ｨC ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨ7 4ｨ 874ｨｪ76ｨｴ26 92ｨｴ29ｨｰ9ｨ ｨｮ12; S ｨC 756ｨｴｨ 1ｨｹ ﾂｨｪ66 92 ﾂ2ｨｪｨｨ7 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺｨ ; L ｨC 15ｨｨｨｪｨ 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺｨ 2ｨ ｨｴ278ｨｨｨｪ7ｨｰｨ 7 ｨｬ6125ｨｹ 67ｨｨ9ｨ ｨｪｨｨ ｨ 7ｨ 99ｨｨ9ｨｪ66 786ｨ 66ｨｰｨ 68ｨ, ｨｪｨ 449ｨ 2ｨｬｨ 7 9 1ｨ 5ｨｹｨｪ2ｨｦ32ｨｬ ｨｪｨｮ529ｨ 73 ｨｬ6125ｨｹ, 69ｨｪ69ｨ ｨｪｨ ｨｪｨ 9521ｨｮ6ｨｴｨｨ ｨｪｨｨ71: 1) ｨｪｨ ｨｺ6752ｨｪｨｨ7 92ｨｴ29ｨｰ9ｨ 9 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺ2 5ｨｨｨｬｨｨｨｰｨｨ8ｨｮ2ｨｰ97 ｨｬ652ｨｺｨｮ578ｨｪ6ｨｦ 1ｨｨｨｮ4ｨｨ2ｨｦ 4ｨ 874ｨｪ76ｨｴ26 92ｨｴ29ｨｰ9ｨ ｨｨ4 9641ｨｮ1ｨ ｨｺ 968ｨ 2ｨｪｨｰｨｮ; 2) 7282ｨｪ69 92ｨｴ29ｨｰ9ｨ ｨｨ4 6ｨｺ8ｨｮ3ｨ 6ｨｴ2ｨｦ ｨｺ 968ｨ 2ｨｪｨｰｨｮ 79572ｨｰ97 9ｨｰｨ 2ｨｨ6ｨｪｨ 8ｨｪ4ｨｬ; 3) 968ｨ 2ｨｪｨｰ 79572ｨｰ97 ｨｨ12ｨ 5ｨｹｨｪ4ｨｬ, ｨｰ ｨｴｨ 2ｨｰ ｨｰｨｮ7ｨ 6ｨｴｨｨ2 ｨｺ ｨｪ69ｨｰｨｨ ｨｬ652ｨｺｨｮ54 ｨ 4ｨ ; 4) ｨｺ65ｨｨ2ｨｨ2ｨｪｨｰ ｨ NO 2 9 NO 2 ｨC 78ｨｨ 7656ｨｴ2ｨｪｨｨｨｨ 8ｨ 9ｨｰ9686ｨｬ 968ｨ 2ｨｪｨｰｨ 8ｨ 92ｨｪ 21ｨｨｨｪｨｨ ｨｰ8ｨｮｨ ﾂｨ ｨｰ66 786ｨ 66ｨｰｨ 68ｨｪ66 ｨｮ9ｨｰ86ｨｦ9ｨｰ9ｨ 9 ｨｮ ﾂ2ｨｰ6ｨｬ ｨｮｨｺｨ 4ｨ ｨｪｨｪ41 167ｨｮｨｴ2ｨｪｨｨｨｦ 9821ｨｪ77 ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨ7 4ｨ 874ｨｪ76ｨｴ26 92ｨｴ29ｨｰ9ｨ (NO 2 ) C, /ｨｬ 3, 4ｨ 728ｨｨ61 786ｨ 66ｨｰｨ 68ｨ ｦ ｦﾓ, c, 9 966ｨｰ92ｨｰ9ｨｰ9ｨｨｨｨ 9 ｨｪｨｮ5296ｨｦ3 ｨｬ6125ｨｹ6, 8ｨ 99 ﾂｨｨｨｰ49ｨ 2ｨｰ ｨｬｨｮ52 ｦ m L C =, ｦ ｦﾓ DS (1) 12 ｦ m ｨC ｨｬｨ 99ｨ 92ｨｴ29ｨｰ9ｨ, ｨｪｨ ｨｺ6752ｨｪｨｪｨ ｨ 2ｨｪｨｰ2 (ｨｬｨ 99ｨ ｨｨ6ｨｪ69 NO 2 ｨC ), ; L ｨC 15ｨｨｨｪｨ 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺｨ, ｨｬ; D ｨC ｨｺ65ｨｨ2ｨｨ2ｨｪｨｰ 1ｨｨｨｮ4ｨｨｨｨ NO 2, ｨｬ 2 /9; S ｨC 756ｨｴｨ 1ｨｹ ﾂｨｪ66 92 ﾂ2ｨｪｨｨ7 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺｨ, ｨｬ ｨｰ9ｨｨ2 9ｨ ｨｬ66 78ｨｨｨｪ2ｨｨ7ｨ ｨｬ2ｨｰ61ｨ ｨC 15ｨｨｨｰ25ｨｹｨｪ4ｨｦ 6ｨｰｨ ｨ ｨ 24 78ｨｨｨｪｨｮ1ｨｨｨｰ25ｨｹｨｪ6ｨｦ 786ｨｺｨ ﾂｨｺｨｨ 9641ｨｮ1ｨ, 76 98ｨ 9ｨｪ2ｨｪｨｨ6 9 18ｨｮｨｨｨｬｨｨ ｨｬ2ｨｰ61ｨ ｨｬｨｨ ｨ 99ｨｨ9ｨｪ66 786ｨ 66ｨｰｨ 68ｨ 9 4ｨｪｨ ﾂｨｨｨｰ25ｨｹｨｪ6 ｨ 65ｨｹ32ｨｦ 9ｨｰ272ｨｪｨｨ ｨｪ 95ｨｨ7ｨｪｨｨ6 ｨｬ2ｨｰ268656ｨｨ ﾂ29ｨｺｨｨ1 ｨｨ 871ｨ 18ｨｮｨｨ1 ｨ ｨｺｨｰ ﾂｨｪ69ｨｰｨｹ 824ｨｮ5ｨｹｨｰｨ ｨｰ69 ｨｨ4ｨｬ282ｨｪｨｨｨｦ ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｦ NO 2 ｨｬ2ｨｰ616ｨｬ 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ 622ｨｪｨｨ9ｨ 5ｨ 9ｨｹ 9 5ｨ ｨ 68ｨ ｨｰ68ｨｪ41 [4ｨC6] ｨｨ ｨｪｨ ｨｰｨｮ8ｨｪ41 ｨｮ9569ｨｨ71 [4ｨC9]. S C 1ｨｮ529ｨ 73 ｨｬ6125ｨｹ 69ｨｪ69ｨ ｨｪｨ ｨｪｨ 2256ｨｬ ｨｮｨｴ2ｨｪｨｨｨｦ ｨｨ ｨｪ2 ｨｮ ﾂｨｨｨｰ49ｨ 2ｨｰ ｨ ｨｺｨｰ684, ｨｺ6ｨｰ ｨｦ9ｨｰ9ｨｮ6ｨｰ 9 82ｨ 5ｨｹｨｪ41 ｨｮ9569ｨｨ ｨｪｨｨ7 ｨｨ4ｨｬ282ｨｪｨｨｨｦ 4ｨ 874ｨｪ2ｨｪｨｨ7 9641ｨｮ1ｨ ｨｨ ｨｬ6ｨｮｨｰ 6ｨｺｨ 4ｨ ｨｰｨｹ 4ｨｪｨ ﾂｨｨｨｰ25ｨｹｨｪ62 95ｨｨ7ｨｪｨｨ2 ｨｪｨ 786ｨｰ2ｨｺｨ ｨｪｨｨ ｨ ｨｨ ｨｰ6 ﾂｨｪ69ｨｰｨｹ 824ｨｮ5ｨｹｨｰｨ ｨｰｨ ｨｨ4ｨｬ282ｨｪｨｨｨｦ ｨｰｨｨ ﾂ29ｨｺｨｨ2 622ｨｪｨｺｨｨ 95ｨｨ7ｨｪｨｨ7 ｨ ｨｺｨｰ ｨｮ ﾂ2ｨｪｨｨ7 8ｨ 9 ﾂ2ｨｰｨｪ41 622ｨｪ6ｨｺ 95ｨｨ7ｨｪｨｨ7 ｨ ｨｺｨｰ6869 ｨ ｨｪ6 ｨｬｨ ｨｰ2ｨｬｨ ｨｰｨｨ ﾂ29ｨｺ62 ｨｬ6125ｨｨ869ｨ ｨｪｨｨ2 1ｨｨｨｮ4ｨｨ6ｨｪｨｪ41 ｨｨ ｨｨ1861ｨｨｨｪｨ ｨｬｨｨ ﾂ29ｨｺｨｨ ｨｪｨｺｨｨ 95ｨｨ7ｨｪｨｨ7 26ｨｬ2ｨｰ8ｨｨｨｨ 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺｨ ﾂｨｨ952ｨｪｨｪ6 8232ｨｪ4 928ｨｨｨｨ 7869ｨｰ41 1ｨｨｨｮ4ｨｨ6ｨｪｨｪ ｨｨｨｬｨｬ2ｨｰ8ｨｨ ﾂｨｪ41 4ｨ 1ｨ ﾂ 9 9ｨｰｨ 2ｨｨ6ｨｪｨ 8ｨｪ6ｨｬ 78ｨｨｨ 5ｨｨ32ｨｪｨｨｨｨ 78ｨｨ 786ｨｨ4965ｨｹｨｪ41 8ｨ 4ｨｬ28ｨ 1 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺｨ (6ｨｰｨｪ632ｨｪｨｨ71 15ｨｨｨｪｨ /8ｨ 1ｨｨｨｮ9 (L/r)) ｨｨ 786ｨｨ4965ｨｹｨｪ41 4ｨｪｨ ﾂ2ｨｪｨｨ71 ｨｰ2ｨｬ728ｨ ｨｰｨｮ ｨｮ1ｨ ｨｨ ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｨ 6ｨｰｨ ｨｨ8ｨ 2ｨｬ66 92ｨｴ29ｨｰ9ｨ. 365ｨｮ ﾂ2ｨｪ6, ﾂｨｰ ｨｪ69ｨｰｨｹ ｨｪｨｨ7 ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｨ, 6ｨ ｨｮ956952ｨｪｨｪｨ 7 4ｨ 1ｨ ｨｪｨｨ2ｨｬ ｨｺ6ｨｪ2 ﾂｨｪ6ｨｦ 15ｨｨｨｪ4 7ｨｮｨｰｨｨ 1ｨｨｨｮ4ｨｨｨｨ, 9ｨ 8ｨｹｨｨ8ｨｮ2ｨｰ97 6ｨｰ % 157 L/r 6ｨｰ, ｨｰ92ｨｰ9ｨｰ92ｨｪｨｪ ｨｰ8ｨｮｨ ﾂｨ ｨｰ66 1ｨｨｨｮ4ｨｨ6ｨｪｨｪ66 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺｨ (L/r = 12,9) 76823ｨｪ69ｨｰｨｹ ｨｪ ｨ 2ｨｰ 4%. 6125ｨｨ869ｨ ｨｪｨｨ2 ｨｪ29ｨｰｨ 2ｨｨ6ｨｪｨ 8ｨｪ41 1ｨｨｨｮ4ｨｨ6ｨｪｨｪ ｨｪｨｺｨｨ 95ｨｨ7ｨｪｨｨ7 ｨｺ652ｨ ｨ ｨｪｨｨ7 ｨｨ4ｨｬ2872ｨｬ6ｨｦ ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｨ ｨｨ ｨｰ2ｨｬ728ｨ ｨｰｨｮ ｨｮ1ｨ 76ｨｺｨ 4ｨ 56, ﾂｨｰ6 78ｨｨ ｨｨｨｰ25ｨｹｨｪ69ｨｰｨｨ 786ｨ 66ｨｰｨ 68ｨ, ｨ 6ｨｴ2ｨｦ 1ｨ 8ｨ ｨｺｨｰ28ｨｪ4ｨｦ 728ｨｨ61 ｨｨ4ｨｬ2ｨｪ2ｨｪｨｨｨｦ 9ｨｪ23ｨｪ2ｨｦ ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｨ, 76823ｨｪ69ｨｰｨｹ 4ｨｪｨ ﾂ2ｨｪｨｨ ｨｪ2ｨｪｨｪ6ｨｦ ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｨ, 765ｨｮ ﾂ2ｨｪｨｪ6ｨｦ 7ｨ 99ｨｨ9ｨｪ4ｨｬ 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺ6ｨｬ, 969ｨｰｨ 9572ｨｰ ｨｬ2ｨｪ22 1% 76 98ｨ 9ｨｪ2ｨｪｨｨ6 9 ｨｨ9ｨｰｨｨｨｪｨｪ4ｨｬ 9821ｨｪｨｨｨｬ 4ｨｪｨ ﾂ2ｨｪｨｨ2ｨｬ ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｨ 4ｨ 874ｨｪ76ｨｴ26 92ｨｴ29ｨｰ9ｨ. 8652ｨ ｨ ｨｪｨｨ7 ｨｰ2ｨｬ728ｨ ｨｰｨｮ84, ｨｺ6ｨｰ6842 6ｨｰ8ｨ 3ｨ 6ｨｰ97 ｨｪｨ 4ｨｪｨ - ﾂ2ｨｪｨｨｨｨ ｨｺ65ｨｨ2ｨｨ2ｨｪｨｰｨ 1ｨｨｨｮ4ｨｨｨｨ, ｨｰｨ ｨｺ32 ｨｪ2 ｨｨｨｬ26ｨｰ 4ｨｪｨ ﾂｨｨｨｰ25ｨｹｨｪ66 95ｨｨ7ｨｪｨｨ ｨｪｨｺｨｨ 95ｨｨ7ｨｪｨｨ7 92ｨｰ8ｨ ｨｪｨ ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ 94765ｨｪ2ｨｪ6 ｨｬ6125ｨｨ869ｨ ｨｪｨｨ2 19ｨｨ32ｨｪｨｨ7 ｨ 4ｨ 9 6ｨｺ829ｨｰｨｪ69ｨｰ ｨ 9 786ｨ 66ｨｰｨ 68ｨｪ62 ｨｮ9ｨｰ86ｨｦ9ｨｰ96 ｨｨ 9ｨｪｨｮｨｰ8ｨｨ 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺｨ 9 76ｨｬ6ｨｴｨｹ6 ﾂｨｨ952ｨｪｨｪ ｨｪｨｨ7 ｨｮ8ｨ 9ｨｪ2ｨｪｨｨｨｦ 1ｨ 9ｨｹ2ｨC5ｨｰ6ｨｺ9ｨ 157 ｨｪ293ｨｨｨｬｨ 2ｨｬ6ｨｦ 3ｨｨ1ｨｺ69ｨｰｨｨ. 4ｨ 9 ﾂ2ｨｰ ｨｪ2ｨｪ ｨ 66ｨｰｨ 68ｨｪｨｨｨｺ69 8ｨ 4ｨｪ41 26ｨｬ2ｨｰ8ｨｨ ﾂ29ｨｺｨｨ1 8ｨ 4ｨｬ2869 ｨｨ 157 ｨｪ29ｨｺ65ｨｹｨｺｨｨ1 9ｨｺ6869ｨｰ2ｨｦ 9ｨｪ23ｨｪ26 76ｨｰ6ｨｺｨ 9641ｨｮ1ｨ ｨ 9 ﾂ2ｨｰ69 ｨｨ9765ｨｹ469ｨ ｨｪ4 4ｨｪｨ ﾂ2ｨｪｨｨ7 756ｨｰｨｪ69ｨｰｨｨ ｨｨ 974ｨｺ69ｨｰｨｨ 9641ｨｮ1ｨ 78ｨｨ ｨｰ2ｨｬ728ｨ ｨｰｨｮ82 2 縺5 [1] ｨｮ5ｨｹｨｰｨ ｨｰｨ ｨｬ ｨｬ6125ｨｨ869ｨ ｨｪｨｨ7 765ｨｮ ﾂ2ｨｪ6, ﾂｨｰ6 78ｨｨ 6ｨ ｨｰ2ｨｺｨ ｨｪｨｨｨｨ 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺｨ 68ｨｨ46ｨｪｨｰｨ 5ｨｹｨｪ4ｨｬ 76ｨｰ6ｨｺ6ｨｬ 9641ｨｮ1ｨ 9ｨｪｨｮｨｰ8ｨｨ 786ｨ 66ｨｰｨ 68ｨｪ66 ｨｮ9ｨｰ86ｨｦ9ｨｰ9ｨ ｨｦ 26 15ｨｨｨｪ2 6ｨ 8ｨ 4ｨｮ6ｨｰ97 9ｨｨ18ｨｨ (8ｨｨ9. 2, ｨ ). 824ｨｮ5ｨｹｨｰｨ ｨｰ2 964ｨｪｨｨｨｺｨ 6ｨｴｨｨ1 ｨｨ1861ｨｨｨｪｨ ｨｬｨｨ ﾂ29ｨｺｨｨ1 ｨｰ2 ﾂ2ｨｪｨｨｨｦ 9 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺ2 69ｨｮｨｴ29ｨｰ9572ｨｰ97 ｨ 6522 ｨ 49ｨｰ84ｨｦ 76 98ｨ 9ｨｪ2ｨｪｨｨ6 9 ｨｬ652ｨｺｨｮ578ｨｪ6ｨｦ 1ｨｨｨｮ4ｨｨ2ｨｦ 7282ｨｪ69 92ｨｴ29ｨｰ9ｨ. 6ｨｰ6 78ｨｨ961ｨｨｨｰ ｨｺ 96ｨｺ8ｨ ｨｴ2ｨｪｨｨ6 52ｨｺｨｰｨｨ9ｨｪ6ｨｦ 15ｨｨｨｪ4 7ｨｮｨｰｨｨ 1ｨｨｨｮ4ｨｨｨｨ, ｨｺ6ｨｰ68ｨ 7 9 ｨｪｨｮ5296ｨｦ3 ｨｬ6125ｨｨ 78ｨｨｨｪｨｨｨｬｨ 2ｨｰ97 8ｨ 9ｨｪ6ｨｦ 26ｨｬ2ｨｰ8ｨｨ ﾂ29ｨｺ6ｨｦ 15ｨｨｨｪ2 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺｨ ｨｮ5ｨｹｨｰｨ ｨｰｨ ｨｬ ｨｬ6125ｨｹｨｪ41 8ｨ 9 ﾂ2ｨｰ69 ｨ 45ｨｨ 9125ｨ ｨｪ4 622ｨｪｨｺｨｨ 9ｨｺ6869ｨｰｨｨ 19ｨｨ32ｨｪｨｨ7 9641ｨｮ1ｨ 9 9ｨｨ1871 ｨｨ 622ｨｪｨｺｨｨ 52ｨｺｨｰｨｨ9ｨｪ6ｨｦ 15ｨｨｨｪ4 7ｨｮｨｰｨｨ 1ｨｨｨｮ4ｨｨｨｨ, ｨｰ.2. 8ｨ 99ｨｰ67ｨｪｨｨ7, ｨｪｨ ｨｺ6ｨｰ686ｨｬ 9ｨｺ6869ｨｰｨｹ ｨｮｨ ｨｪ4ｨｦ.8., 73ｨｺ2ｨｰ69ｨ 1.8.

3 13L/r = 3,6 62ｨｺｨｰｨｨ9ｨｪｨ 7 15ｨｨｨｪｨ 7ｨｮｨｰｨｨ 1ｨｨｨｮ4ｨｨｨｨ, % L/r = 7,3 v = 2 ｨｬ/9 L/r = 1,9 L/r = 12,9 L/r = 14,5 ｨ L/r = 3,6 L/r = 7,3 L/r = 12,9 L/r = 12,9 (5ｨｺ9728ｨｨｨｬ2ｨｪｨｰｨ 5ｨｹｨｪ42 1ｨ ｨｪｨｪ42 [5]) ｨｺ6869ｨｰｨｹ 9ｨｪ23ｨｪ26 76ｨｰ6ｨｺｨ 9641ｨｮ1ｨ, ｨｬ/9 ｨ 4ｨｨ ｨｮ5ｨｹｨｰｨ ｨｰ4 ｨｬ6125ｨｨ869ｨ ｨｪｨｨ7 95ｨｨ7ｨｪｨｨ7 92ｨｰ8ｨ : ｨ ｨC 9ｨｰ8ｨｮｨｺｨｰｨｮ8ｨ 19ｨｨ32ｨｪｨｨ7 9641ｨｮ1ｨ 9ｨｪｨｮｨｰ8ｨｨ 786ｨ 66ｨｰｨ 68ｨｪ66 ｨｮ9ｨｰ86ｨｦ9ｨｰ9ｨ ; ｨ ｨC 4ｨ 9ｨｨ9ｨｨｨｬ69ｨｰｨｹ 52ｨｺｨｰｨｨ9ｨｪ6ｨｦ 15ｨｨｨｪ4 7ｨｮｨｰｨｨ 1ｨｨｨｮ4ｨｨｨｨ 6ｨｰ 8ｨ 4ｨｬ ｨ 66ｨｰｨ 68ｨｪｨｨｨｺｨ ｨｨ 9ｨｺ6869ｨｰｨｨ 9ｨｪ23ｨｪ26 76ｨｰ6ｨｺｨ 9641ｨｮ1ｨ, 9 98ｨ 9ｨｪ2ｨｪｨｨｨｨ 9 5ｨｺ9728ｨｨｨｬ2ｨｪｨｰｨ 5ｨｹｨｪ4ｨｬｨｨ 1ｨ ｨｪｨｪ4ｨｬｨｨ ｨｨ1861ｨｨｨｪｨ ｨｬｨｨ ﾂ29ｨｺ ｨｪ69ｨ 92ｨｴ29ｨｰ9ｨ 9ｨｪｨｮｨｰ8ｨｨ 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺｨ ｨｬ2ｨｪｨｹ32 9ｨｺ6869ｨｰｨｨ ｨｬ652ｨｺｨｮ578ｨｪ6ｨｦ 1ｨｨｨｮ4ｨｨｨｨ. 1ｨ 8ｨｨ9. 2, ｨ 78219ｨｰｨ 952ｨｪ4 4ｨ 9ｨｨ9ｨｨｨｬ69ｨｰｨｨ 52ｨｺｨｰｨｨ9ｨｪ6ｨｦ 15ｨｨｨｪ4 7ｨｮｨｰｨｨ 1ｨｨｨｮ4ｨｨｨｨ ( ｨｪｨｰｨ 1 6ｨｰ 26ｨｬ2ｨｰ8ｨｨ ﾂ29ｨｺ6ｨｦ 15ｨｨｨｪ4) 6ｨｰ 9ｨｺ6869ｨｰｨｨ 9ｨｪ23ｨｪ26 76ｨｰ6ｨｺｨ 9641ｨｮ1ｨ 157 8ｨ 4ｨｪ41 8ｨ 4ｨｬ ｨ 66ｨｰｨ 68ｨｪｨｨｨｺｨ. 257 ｨｰ8ｨｮｨ ﾂｨ ｨｰ66 1ｨｨｨｮ4ｨｨ6ｨｪｨｪ66 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺｨ 9 1ｨｨｨ 7ｨ 46ｨｪ2 9ｨｺ6869ｨｰ2ｨｦ,8ｨC6 ｨｬ/9 96ｨｺ8ｨ ｨｴ2ｨｪｨｨ2 52ｨｺｨｰｨｨ9ｨｪ6ｨｦ 15ｨｨｨｪ4 7ｨｮｨｰｨｨ 1ｨｨｨｮ4ｨｨｨｨ 969ｨｰｨ 9572ｨｰ 6ｨｰ % ｨ 9ｨｪ2ｨｪｨｨ7 76ｨｺｨ 4ｨ ｨｪｨ ｨ ｨｪｨ 56ｨｨ ﾂｨｪｨ 7 4ｨ 9ｨｨ9ｨｨｨｬ69ｨｰｨｹ, 765ｨｮ ﾂ2ｨｪｨｪｨ ｨ ｨｪｨｪ6ｨｦ ｨｬ6125ｨｨ 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺｨ 9 5ｨ ｨ 68ｨ ｨｰ68ｨｪ6ｨｬ 5ｨｺ9728ｨｨｨｬ2ｨｪｨｰ2 [5]. 1ｨｨｨ 7ｨ 46ｨｪ2 9ｨｺ6869ｨｰ2ｨｦ,5ｨC2,3 ｨｬ/9 824ｨｮ5ｨｹｨｰｨ ｨｰ4 ﾂｨｨ952ｨｪｨｪ41 8ｨ 9 ﾂ2ｨｰ69 ｨｺｨ ﾂ29ｨｰ92ｨｪｨｪ6 ｨｨ ｨｺ65ｨｨ ﾂ29ｨｰ92ｨｪｨｪ6 965ｨ 9ｨｮ6ｨｰ97 9 5ｨｺ9728ｨｨｨｬ2ｨｪｨｰｨ 5ｨｹｨｪ4ｨｬｨｨ 1ｨ ｨｪｨｪ4ｨｬｨｨ. 5ｨｰｨｮ72ｨｪ ﾂｨ ｨｰ4ｨｦ 1ｨ 8ｨ ｨｺｨｰ28 8ｨ ｨｨｨｺ ｨ ｨｪ 96 9ｨｺｨ ﾂｨｺ66ｨ 8ｨ 4ｨｪ4ｨｬ ｨｨ4ｨｬ2ｨｪ2ｨｪｨｨ2ｨｬ 8ｨ ｨｪｨｨ24 8ｨ 92ｨｪ9ｨｰ9ｨ ｨｨ1861ｨｨｨｪｨ ｨｬｨｨ ﾂ29ｨｺ6ｨｦ 9ｨｺ6869ｨｰｨｨ ｨｨ 9ｨｺ6869ｨｰｨｨ ｨｬ652ｨｺｨｮ578ｨｪ6ｨｦ 1ｨｨｨｮ4ｨｨｨｨ 78ｨｨ ｨｪ66 9ｨｨ187 ｨｪｨ 18ｨｮ6ｨｦ. 4ｨ 99 ﾂｨｨｨｰｨ ｨｪｨｪ42 4ｨ 9ｨｨ9ｨｨｨｬ69ｨｰｨｨ ｨｬ6ｨｮｨｰ ｨ 4ｨｰｨｹ ｨｨ9765ｨｹ469ｨ ｨｪ4 157 ｨｺ6882ｨｺｨｰｨｨ869ｨｺｨｨ 824ｨｮ5ｨｹｨｰｨ ｨｰ69 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ 78ｨｨ ｨｪｨｨｨｨ ｨｨ4ｨｬ282ｨｪｨｨｨｦ 9 ｨｪｨ ｨｰｨｮ8ｨｪ41 ｨｮ9569ｨｨ71 ｨ 24 ｨｨ9765ｨｹ469ｨ ｨｪｨｨ7 92ｨｰ8696ｨｦ 4ｨ ｨｴｨｨｨｰ4. 6ｨｺ9728ｨｨｨｬ2ｨｪｨｰｨ 5ｨｹｨｪ42 622ｨｪｨｺｨｨ 95ｨｨ7ｨｪｨｨ7 ｨ ｨｺｨｰ ｨｪｨｨ7 ｨｨ4ｨｬ282ｨｪｨｨｨｦ ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｦ NO 2 9 ｨ ｨｰｨｬ6928ｨｪ6ｨｬ 9641ｨｮ12 ｨｨ9765ｨｹ469ｨ 5ｨｨ9ｨｹ ｨｰ8ｨｮｨ ﾂｨ ｨｰ42 1ｨｨｨｮ4ｨｨ6ｨｪｨｪ42 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺｨｨ 15ｨｨｨｪ6ｨｦ,71 ｨｬ 9 9ｨｪｨｮｨｰ82ｨｪｨｪｨｨｨｬ 1ｨｨｨ ｨｬ2ｨｰ86ｨｬ,11 ｨｬ (Gradko International Ltd, 25ｨｨｨｺ6ｨ 8ｨｨｨｰｨ ｨｪｨｨ7). ｨｺｨ ﾂ29ｨｰ92 968ｨ 2ｨｪｨｰｨ ｨ 45 ｨｨ9765ｨｹ469ｨ ｨｪ 2%-ｨｦ 961ｨｪ4ｨｦ 8ｨ 9ｨｰ968 ｨｰ8ｨｨ5ｨｰｨ ｨｪ65ｨ ｨｬｨｨｨｪｨ (668). 865ｨｨ ﾂ29ｨｰ96 ｨｪｨｨｨｰ8ｨｨｨｰ-ｨｨ6ｨｪ69 9 6ｨｰ6ｨ 8ｨ ｨｪｨｪ6ｨｦ 786ｨ ｨｹ 972ｨｺｨｰ866ｨｰ6ｨｬ2ｨｰ8ｨｨ ﾂ29ｨｺｨｨｨｬ ｨｬ2ｨｰ616ｨｬ ｨ ｨｪｨ 5ｨｨ4ｨ. 3616ｨｰ69ｨｺｨ 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺ69 ｨｨ 1ｨｨｨｬｨｨ ﾂ29ｨｺｨｨｨｦ ｨ ｨｪｨ 5ｨｨ4 786ｨ 69ｨｮｨｴ29ｨｰ9575ｨｨ9ｨｹ 9 966ｨｰ92ｨｰ9ｨｰ9ｨｨｨｨ 9 82ｨｺ6ｨｬ2ｨｪ1ｨ 2ｨｨ7ｨｬｨｨ [11] ｨ ｨｴｨｨｨｰ4 6ｨｰ 92ｨｰ8ｨ ｨｨ9765ｨｹ469ｨ 5ｨｨ9ｨｹ 9722ｨｨｨ 5ｨｹｨｪ42 75ｨ 9ｨｰｨｨｨｺ6942 ｨｺ6ｨｪｨｰ2ｨｦｨｪ284 (Gradko International Ltd, 25ｨｨｨｺ6ｨ 8ｨｨｨｰｨ ｨｪｨｨ7) 2ｨｨ5ｨｨｨｪ18ｨｨ ﾂ29ｨｺ6ｨｦ 68ｨｬ4 1ｨｨｨ ｨｬ2ｨｰ86ｨｬ,8 ｨｬ, 9496ｨｰ6ｨｦ,13 ｨｬ). 8ｨ 314ｨｦ ｨｺ6ｨｪｨｰ2ｨｦｨｪ ｨｪｨ 4ｨｪｨ ﾂ2ｨｪ 157 8ｨ 4ｨｬ2ｨｴ2ｨｪｨｨ7 1ｨC3 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺ69 61ｨｪ6982ｨｬ2ｨｪｨｪ6. 4ｨ 9 ﾂ2ｨｰ 9821ｨｪｨｨ1 ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｦ NO ｨｨ ｨｰ92ｨｰ9ｨｰ9ｨｨｨｨ 9 ｨｪｨｮ5296ｨｦ3 ｨｬ6125ｨｹ ｨｬｨｮ52 (1). 528ｨｨｨｨ ｨｪｨ ｨｰｨｮ8ｨｪ41 ｨｨ4ｨｬ282ｨｪｨｨｨｦ ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｦ NO ｨｨ5ｨｨ9ｨｹ ｨｪｨｪ2-692ｨｪｨｪｨｨ2 9246ｨｪ ｨｨ ｨ ｨｪ26 78ｨ 5ｨ : 3ｨｺｨ ｨｰ28ｨｨｨｪｨ ｨｮ8, 32896ｨｮ8ｨ 5ｨｹ9ｨｺ ｨｨ 281ｨｪ77 343ｨｬｨ. 66 ﾂｨｺｨｨ 6ｨｰｨ 68ｨ 786ｨ (12 ｨｰ6 ﾂ2ｨｺ 9 3ｨｺｨ ｨｰ28ｨｨｨｪｨ ｨｮ82, 61ｨｪｨ ｨｮ8ｨ 5ｨｹ9ｨｺ2, 61ｨｪｨ 9 281ｨｪ2ｨｦ 343ｨｬ2) 78219ｨｰｨ 9575ｨｨ 96ｨ 6ｨｦ ｨｬ29ｨｰｨ 9 8ｨ 45ｨｨ ﾂｨｪ4ｨｬｨｨ 1ｨ 8ｨ ｨｺｨｰ28ｨｪ4ｨｬｨｨ ｨｮ869ｨｪ7ｨｬｨｨ ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｦ NO 2 : 7282ｨｺ829ｨｰｨｺｨｨ 1686, ｨｮ ﾂｨ 9ｨｰ6ｨｺ 1686ｨｨ ｨｪ2ｨｦ ｨｨｨｪｨｰ2ｨｪ9ｨｨ9ｨｪ69ｨｰｨｹ6 19ｨｨ32ｨｪｨｨ7 ｨｰ8ｨ ｨｪ9768ｨｰｨ, 3ｨｨ542 46ｨｪ4, 12ｨｪ18656ｨｨ ﾂ29ｨｺｨｨｨｦ 7ｨ 8ｨｺ. 19ｨｮ1 ｨｰ6 ﾂｨｺｨ 1 ｨｨ4ｨｬ282ｨｪｨｨｨｦ 9 3ｨｺｨ ｨｰ28ｨｨｨｪｨ ｨｮ82 (7282ｨｺ829ｨｰ6ｨｺ ｨｨ 3ｨｨ5ｨ 7 46ｨｪｨ ) 7ｨ 99ｨｨ9ｨｪ4ｨｦ 6ｨｰｨ ｨ ｨｨ597 7ｨ 8ｨ 5525ｨｹｨｪ6 9 ｨｺ6ｨｪｨｰ865ｨｹｨｪ4ｨｬｨｨ ｨｨ4ｨｬ282ｨｪｨｨ7ｨｬｨｨ ｨｪｨ 769ｨｰｨ 1 1ｨｨ186ｨｬ2ｨｰ2695ｨｮ3ｨ 4. 1ｨ 769ｨｰｨ 1 69ｨｮｨｴ29ｨｰ9572ｨｰ97 82ｨｮ578ｨｪ4ｨｦ 6ｨｰｨ 68 8ｨ ｨ NO ｨｬ6ｨｴｨｹ6 968ｨ 2ｨｨ6ｨｪｨｪ41 ｨｰ8ｨｮｨ 6ｨｺ 9 ｨｨ9765ｨｹ469ｨ ｨｪｨｨ2ｨｬ 8ｨ 9ｨｰ968ｨ ｨｨ61ｨｨ1ｨ ｨｺｨ 5ｨｨ7 9 ｨｺｨ ﾂ29ｨｰ92 968ｨ 2ｨｪｨｰｨ [12] ｨｮ8ｨ 5ｨｹ9ｨｺ2 ｨｨ 281ｨｪ2ｨｦ 343ｨｬ2 7ｨ 99ｨｨ9ｨｪ4ｨｦ 6ｨｰｨ ｨ ｨｨ597 61ｨｪ6982ｨｬ2ｨｪｨｪ6 9 ｨｪ ｨｪ4ｨｬｨｨ ｨｨ4ｨｬ282ｨｪｨｨ7ｨｬｨｨ ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｦ NO ｨｬ6ｨｴｨｹ6 12ｨｬ656ｨｬｨｨｨｪ2922ｨｪｨｰｨｪ41 ｨ 46ｨ ｨｪｨ 5ｨｨ4ｨ ｨｰ6869 ( , 5ｨ ｨｪｨｺｨｰ-32ｨｰ28ｨ ｨｮ8). 5ｨ ｨｰ82152ｨｰｨｪｨｨｨｦ 728ｨｨ ｨｪｨｨ7 ｨｨ4ｨｬ282ｨｪｨｨｨｦ ｨ 456 6ｨｰ6ｨ 8ｨ ｨｪ ｨ, ｨｨ4 ｨｪｨｨ ｨ ｨC 7ｨ 8ｨ 5525ｨｹｨｪ6 9 ｨｺ6ｨｪｨｰ865ｨｹｨｪ4ｨｬｨｨ ｨｨ4ｨｬ282ｨｪｨｨ7ｨｬｨｨ ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｦ NO ｨｪｨｺｨ 15ｨｨｨｰ25ｨｹｨｪ69ｨｰｨｨ 786ｨ 66ｨｰｨ 68ｨ ｨｪｨ ｨｪｨ ｨｺ6752ｨｪｨｨ2 1ｨｨ6ｨｺ9ｨｨ1ｨ ｨ 46ｨｰｨ 8ｨ ｨ 6ｨｰ2 [8] 949ｨｺｨ 4ｨ ｨｪ ｨｪｨｨ ｨｬ63ｨｪ6ｨｬ ｨｬ2ｨｪｨｪ6ｨｬ ｨｪｨ 94ｨｴ2ｨｪｨｨｨｨ 968ｨ 2ｨｪｨｰｨ ｨｨ5ｨｨ 76ｨｰ282 ﾂｨ 9ｨｰｨｨ ｨｪｨ ｨｺ6752ｨｪｨｪ6ｨｦ ｨｬｨ 994 NO ｨｬ7 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ ｨｪｨｺｨｨ 5ｨｰ6ｨｦ ｨｨ76ｨｰ ｨｪ4 928ｨｨｨｨ 7ｨ 8ｨ 5525ｨｹｨｪ41 ｨｨ4ｨｬ282ｨｪｨｨｨｦ 9 728ｨｨ61ｨ ｨｬｨｨ 6ｨｰｨ 68ｨ 786ｨ 3, 4 ｨｨ 7 1ｨｪ2ｨｦ, 2 ｨｨ 4 ｨｪ ｨｮ ﾂ2ｨｪ6, ﾂｨｰ6 9ｨｮｨｬｨｬｨ 8ｨｪ42 ｨｬｨ 994 ｨｪｨｨｨｰ8ｨｨｨｰ-ｨｨ6ｨｪ69, ｨｪｨ ｨｺ6752ｨｪｨｪ42 4ｨ 19ｨ ｨ ｨｰ25ｨｹｨｪ41 ｨｺ686ｨｰｨｺｨｨ1 728ｨｨ61ｨ, ｨｪ2 ｨｨｨｬ26ｨｰ 9ｨｨ9ｨｰ2ｨｬｨ ｨｰｨｨ ﾂ29ｨｺ66 ｨｨ 9ｨｰｨ ｨｰｨｨ9ｨｰｨｨ ﾂ29ｨｺｨｨ 4ｨｪｨ ﾂｨｨｨｬ66 (ｦﾁ =,5) 6ｨｰ5ｨｨ ﾂｨｨ7 6ｨｰ ｨｬｨ 99 ｨｪｨｨｨｰ8ｨｨｨｰ-ｨｨ6ｨｪ69, ｨｪｨ ｨｺ6752ｨｪｨｪ41 4ｨ 966ｨｰ92ｨｰ9ｨｰ9ｨｮ6ｨｴｨｨ2 15ｨｨｨｰ25ｨｹｨｪ42 728ｨｨ614 5ｨｺ9764ｨｨ2ｨｨｨｨ (8ｨｨ9. 3, ｨ ), ｨｰ.2. ｨｬｨ 99ｨ 6ｨｰ6ｨ 8ｨ ｨｪｨｪ6ｨｦ 786ｨ 4 ｨ 45ｨ ｨｨ6ｨｪｨ 5ｨｹｨｪｨ 15ｨｨｨｰ25ｨｹｨｪ69ｨｰｨｨ 786ｨ 66ｨｰｨ 68ｨ. 6ｨ ｨｺｨｨｨｬ 6ｨ 8ｨ 46ｨｬ, 1ｨ ｨｪｨｪ4ｨｦ 2ｨｰ61 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ 157 ｨｨ4ｨｬ282ｨｪｨｨｨｦ 1ｨｨ6ｨｺ9ｨｨ1ｨ ｨ 46ｨｰｨ 9 ｨ ｨｰｨｬ6928ｨｪ6ｨｬ 9641ｨｮ12 761

4 13ｨ 99ｨ ｨｪｨｨｨｰ8ｨｨｨｰ-ｨｨ6ｨｪ ｨ 2, ｨｬｨｺ ｨC ｨ 99ｨ NO2, ｨｬｨｺ, KI 1,2 1,,8,6,4,2, 1,4 1,2 1,,8,6,4, ｨｬ28 ｨｨ4ｨｬ282ｨｪｨｨ7 ｨ 1+1 ｨｪ21 2 ｨｪ21 y = 1,39x R 2 =,98,,,2,4,6,8 1, 1,2 1,4 ｨ 99ｨ NO ｨC 2, ｨｬｨｺ, 668 ｨ 4ｨｨ ｨｮ5ｨｹｨｰｨ ｨｰ4 ｨｬ2ｨｰ61ｨｨ ﾂ29ｨｺｨｨ1 ｨｨ4ｨｬ282ｨｪｨｨｨｦ: ｨ ｨC 622ｨｪｨｺｨ 95ｨｨ7ｨｪｨｨ7 15ｨｨｨｰ25ｨｹｨｪ69ｨｰｨｨ 786ｨ 66ｨｰｨ 68ｨ ｨｪｨ ｨｪｨ ｨｺ6752ｨｪｨｨ2 1ｨｨ6ｨｺ9ｨｨ1ｨ ｨ 46ｨｰｨ 9 786ｨ 2; ｨ ｨC 98ｨ 9ｨｪ2ｨｪｨｨ2 8ｨ 4ｨｪ41 968ｨ 2ｨｪｨｰ69 5ｨｺ9728ｨｨｨｬ2ｨｪｨｰ 76ｨｺｨ 4ｨ 5, ﾂｨｰ6 78ｨｨ 6ｨｰｨ ｨ ｨｨｨｰ25ｨｹｨｪ69ｨｰｨｹ6 6ｨｰ 3 1ｨｪ2ｨｦ 16 4 ｨｪ21 ｨｪ2 786ｨｨ91617ｨｰ ｨｪｨ 94ｨｴ2ｨｪｨｨ2 968ｨ 2ｨｪｨｰｨ ｨｨ5ｨｨ 76ｨｰ287 ﾂｨ 9ｨｰｨｨ ｨｪｨ ｨｺ6752ｨｪｨｪ66 1ｨｨ6ｨｺ9ｨｨ1ｨ ｨ 46ｨｰｨ. 58ｨ 9ｨｪ2ｨｪｨｨ2 968ｨ 2ｨｪｨｰ ｨｴ2ｨｪｨｨ7 1ｨｨ6ｨｺ9ｨｨ1ｨ ｨ 46ｨｰｨ ｨｺｨ ﾂ29ｨｰ92 69ｨｪ69ｨｪ66 968ｨ 2ｨｪｨｰｨ ｨｴ2ｨｪｨｨ7 NO 2 ｨｬ4 ｨｨ9765ｨｹ469ｨ 5ｨｨ 961ｨｪ4ｨｦ 8ｨ 9ｨｰ968 ｨｰ8ｨｨ5ｨｰｨ ｨｪ65ｨ ｨｬｨｨｨｪｨ ｨｪｨｺｨｨ 26 52ｨｺｨｰｨｨ9ｨｪ69ｨｰｨｨ ｨ 45ｨ ｨｪｨ 928ｨｨ7 7ｨ 8ｨ 5525ｨｹｨｪ41 ｨｨ4ｨｬ282ｨｪｨｨｨｦ, 9 ｨｺ6ｨｰ686ｨｦ 6ｨｰｨ ｨ 69ｨｮｨｴ29ｨｰ ｨｰｨ ｨｺ32 9 ｨｨ9765ｨｹ469ｨ ｨｪｨｨ2ｨｬ 8ｨ 9ｨｰ968ｨ ｨｨ61ｨｨ1ｨ ｨｺｨ 5ｨｨ7 (KI), 78ｨｨｨｬ2ｨｪ72ｨｬ ｨｰｨｨ 1ｨｨ186ｨｬ2ｨｰ2695ｨｮ3ｨ ｨｮ5ｨｹｨｰｨ ｨｰ4 ｨｨ4ｨｬ282ｨｪｨｨｨｦ 9 9ｨｨ12 ｨｬｨ 99 ｨｪｨｨｨｰ8ｨｨｨｰ-ｨｨ6ｨｪ69 9 7ｨ 8ｨ 5525ｨｹｨｪ41 786ｨ ｨ ｨｰｨ 952ｨｪ4 ｨｪｨ 1ｨｨｨ 8ｨ ｨｬｨｬ2 8ｨ 9927ｨｪｨｨ7 (8ｨｨ9. 3, ｨ ). 365ｨｮ ﾂ2ｨｪ6, ﾂｨｰ6 78ｨｨ 6ｨｰｨ ｨ 9 ｨｨ9765ｨｹ469ｨ ｨｪｨｨ2ｨｬ 8ｨ 9ｨｰ968ｨ ｨｨ61ｨｨ1ｨ ｨｺｨ 5ｨｨ ｨ 66ｨｰｨ 68ｨｪｨｨｨｺ2 ｨｪｨ ｨｺｨ 75ｨｨ9ｨ 2ｨｰ97 ｨ 65ｨｹ322 ｨｺ65ｨｨ ﾂ29ｨｰ96 ｨｪｨｨｨｰ8ｨｨｨｰ-ｨｨ6ｨｪ69, ﾂ2ｨｬ 78ｨｨ 6ｨｰｨ ｨ 9 8ｨ 9ｨｰ9686ｨｬ ｨ 45ｨｨ ﾂｨｨ ｨｹ 9ｨｰｨ ｨｰｨｨ9ｨｰｨｨ ﾂ29ｨｺｨｨ 4ｨｪｨ ﾂｨｨｨｬ4ｨｬ (ｦﾁ =,5), ｨｪ2ｨｬ, 6ｨｰｨｪ69ｨｨｨｰ25ｨｹｨｪｨ 7 8ｨ 4ｨｪｨｨ2ｨ 969ｨｰｨ 9ｨｨ5ｨ 37%. 1ｨｮ529ｨ 73 ｨｬ6125ｨｹ 67ｨｨ9ｨ ｨｪｨｨ ｨ 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ ｨ ｨ 2ｨｰ, ﾂｨｰ ｨｮｨ ｨｪ4ｨｦ.8., 73ｨｺ2ｨｰ69ｨ :1 56ｨ 6ｨｦ ｨｨ9765ｨｹ4ｨｮ2ｨｬ4ｨｦ 968ｨ 2ｨｪｨｰ 79572ｨｰ97 ｨｨ12ｨ 5ｨｹｨｪ4ｨｬ. 21ｨｪｨ ｨｺ6 765ｨｮ ﾂ2ｨｪｨｪ42 824ｨｮ5ｨｹｨｰｨ ｨｰ4 79ｨｪ6 99ｨｨ12ｨｰ25ｨｹ9ｨｰ9ｨｮ6ｨｰ 6 ｨｰ6ｨｬ, ﾂｨｰ6 8ｨ 4ｨｪ42 968ｨ 2ｨｪｨｰ4 6ｨ 5ｨ 1ｨ 6ｨｰ 8ｨ 45ｨｨ ﾂｨｪ6ｨｦ 97696ｨ ｨｪ69ｨｰｨｹ6 ｨｪｨ ｨｺｨ 75ｨｨ9ｨ ｨｰｨｹ 1ｨｨ6ｨｺ9ｨｨ1 ｨ 46ｨｰｨ. 6ｨｰ6ｨｰ ｨ ｨｺｨｰ ｨｪ26ｨ 161ｨｨｨｬ6 ｨｮ ﾂｨｨｨｰ49ｨ ｨｰｨｹ ｨｮ ﾂ2ｨｪｨｨ7 ｨｺ6882ｨｺｨｰｨｪ41 824ｨｮ5ｨｹｨｰｨ ｨｰ69 ｨｨ4ｨｬ282ｨｪｨｨｨｦ. 58ｨ 9ｨｪ2ｨｪｨｨ2 7ｨ 99ｨｨ9ｨｪ66 786ｨ 66ｨｰｨ 68ｨ 9 ｨｺ6ｨｪｨｰ865ｨｹｨｪ4ｨｬｨｨ ｨｬ2ｨｰ61ｨ ｨｬｨｨ 728ｨｨ ｨｪｨｨ7 ｨｪｨ ｨｰｨｮ8ｨｪ41 ｨｨ4ｨｬ282ｨｪｨｨｨｦ ｨｰ2ｨｬ728ｨ ｨｰｨｮ8ｨ 9641ｨｮ1ｨ 9ｨ 8ｨｹｨｨ869ｨ 5ｨ 9ｨｹ 9 1ｨｨｨ 7ｨ 46ｨｪ2 6ｨｰ ｨC6, ,1 縺5; 6ｨｰｨｪ69ｨｨｨｰ25ｨｹｨｪｨ 7 95ｨ 3ｨｪ69ｨｰｨｹ 9641ｨｮ1ｨ ｨｨ4ｨｬ2ｨｪ75ｨ 9ｨｹ ｨ 1 6ｨｰ %, 78ｨｨ 5ｨｰ6ｨｬ ｨｪｨ ｨ 561ｨ 5ｨｨ9ｨｹ 15ｨｨｨｰ25ｨｹｨｪ42 728ｨｨ614 9 ｨｪｨｨ4ｨｺｨｨｨｬｨｨ (< 5%) 4ｨｪｨ - ﾂ2ｨｪｨｨ7ｨｬｨｨ 95ｨ 3ｨｪ69ｨｰｨｨ. 58ｨ 9ｨｪ2ｨｪｨｨ2 824ｨｮ5ｨｹｨｰｨ ｨｰ69 ｨｨ4ｨｬ282ｨｪｨｨｨｦ, 765ｨｮ ﾂ2ｨｪｨｪ41 ｨｬ2ｨｰ616ｨｬ 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ ｨｨ ｨｺ6ｨｪｨｰ865ｨｹｨｪ4ｨｬｨｨ ｨｬ2ｨｰ61ｨ ｨｬｨｨ, 9 1ｨ ｨｪｨｪ41 ｨｬ2ｨｰ268656ｨｨ- ﾂ29ｨｺｨｨ1 ｨｮ9569ｨｨ ｨｰ6 ﾂ2ｨｺ 6ｨｰｨ 68ｨ 786ｨ ｨｨ ｨｮ1 ｨｨ9765ｨｹ469ｨ ｨｪｨｪ41 ｨｬ2ｨｰ ｨ 9ｨｪ2ｨｪｨｨ7 9479ｨｨ56 9ｨｨ9ｨｰ2ｨｬｨ ｨｰｨｨ ﾂ29ｨｺ62 9ｨｰｨ ｨｰｨｨ9ｨｰｨｨ ﾂ29ｨｺｨｨ 4ｨｪｨ ﾂｨｨｨｬ62 (ｦﾁ =,5) 4ｨ ｨｪｨｨ32ｨｪｨｨ2 4ｨｪｨ ﾂ2ｨｪｨｨｨｦ ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｦ NO 2, 765ｨｮ ﾂ2ｨｪｨｪ ｨｬ6ｨｴｨｹ6 ｨｬ2ｨｰ61ｨ 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ [13]. 5821ｨｪ22 8ｨ 45ｨｨ ﾂｨｨ2 969ｨｰｨ 9ｨｨ56 ｨC46,2 ｨｨ ｨC33% ｨ 2ｨｪｨｰ69 ｨｪｨ 69ｨｪ ｨｨ ｨｨ61ｨｨ1ｨ ｨｺｨ 5ｨｨ7 966ｨｰ92ｨｰ9ｨｰ92ｨｪｨｪ6. 1ｨ ｨｨｨ 65ｨｹ322 8ｨ 45ｨｨ ﾂｨｨ2 ｨｬ231ｨｮ 824ｨｮ5ｨｹｨｰｨ ｨｰｨ ｨｬｨｨ 969ｨｰｨ 9ｨｨ56 ｨC71,3% 78ｨｨ ｨｨ4ｨｬ282ｨｪｨｨ71 9 ｨｨ9765ｨｹ469ｨ ｨｪｨｨ2ｨｬ 8ｨ 9ｨｰ ｨｮ5ｨｹｨｰｨ ｨｰ4 ﾂｨｨ952ｨｪｨｪ41 8ｨ 9 ﾂ2ｨｰ69 ｨｨ ｨｬ2ｨｰ61ｨｨ ﾂ29ｨｺｨｨ1 ｨｨ4ｨｬ282ｨｪｨｨｨｦ 9 ｨｪｨ ｨｰｨｮ8ｨｪ41 ｨｮ9569ｨｨ71 76ｨｺｨ 449ｨ 6ｨｰ, ﾂｨｰ6 ｨｰｨ ｨｺｨｨ2 ｨ ｨｺｨｰ684, ｨｺｨ ｨｺ 26ｨｬ2ｨｰ8ｨｨ7 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺｨ, ｨｺ652ｨ ｨ ｨｪｨｨ2 ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｨ 6ｨｰｨ ｨｨ8ｨ 2ｨｬ66 92ｨｴ29ｨｰ9ｨ, 92ｨｰ28, ｨｪｨ 94ｨｴ2ｨｪｨｨ2 968ｨ 2ｨｪｨｰｨ, ｨｪ2 ｨｬ6ｨｮｨｰ 6ｨ ｨｲ79ｨｪｨｨｨｰｨｹ 765ｨｮ ﾂ2ｨｪｨｪ66 9ｨｨ9ｨｰ2ｨｬｨ ｨｰｨｨ ﾂ29ｨｺ66 8ｨ 45ｨｨ ﾂｨｨ7. ｨｰ ｨｬ7 9ｨｰｨ ｨｰｨｨ9ｨｰｨｨ ﾂ29ｨｺｨｨ 4ｨｪｨ ﾂｨｨｨｬ62 8ｨ 45ｨｨ ﾂｨｨ2 52ｨｺｨｰｨｨ9ｨｪ69ｨｰｨｨ 8ｨ 9ｨｰ96869 ｨｪｨ 69ｨｪ ｨｨ ｨｨ61ｨｨ1ｨ ｨｺｨ 5ｨｨ7 76ｨｺｨ 449ｨ 2ｨｰ ｨｪ26ｨ 161ｨｨｨｬ69ｨｰｨｹ ｨｮ ﾂ2ｨｰｨ 996ｨｦ9ｨｰ9 ｨｨ9765ｨｹ4ｨｮ2ｨｬ41 968ｨ 2ｨｪｨｰ69 ｨｨ 8ｨ 99ｨｬ6ｨｰ82ｨｪｨｨ2 ｨｨ4ｨｨｨｺ6-1ｨｨｨｬｨｨ ﾂ29ｨｺｨｨ1 696ｨ 2ｨｪｨｪ69ｨｰ2ｨｦ ｨ 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ, ﾂｨｰ6 6ｨｰ9ｨｮｨｰ9ｨｰ9ｨｮ2ｨｰ 9 ｨｪｨｮ5296ｨｦ3 ｨｬ6125ｨｨ. 365ｨｮ ﾂ2ｨｪｨｪ42 5ｨｺ9728ｨｨｨｬ2ｨｪｨｰｨ 5ｨｹｨｪ42 1ｨ ｨｪｨｪ42 99ｨｨ12ｨｰ25ｨｹ9ｨｰ9ｨｮ6ｨｰ 6 ｨｰ6ｨｬ, ﾂｨｰ6 ｨｪｨｮ529ｨ 73 ｨｬ6125ｨｹ, ｨｨ9765ｨｹ469ｨ ｨｪｨｪｨ ｨ 8ｨ ｨ 6ｨｰｨｺｨｨ 824ｨｮ5ｨｹｨｰｨ ｨｰ69 ｨｨ4ｨｬ282ｨｪｨｨｨｦ, ｨｪ2 ｨｬ632ｨｰ 9 765ｨｪ6ｨｦ ｨｬ282 67ｨｨ9ｨ ｨｰｨｹ ｨ 99ｨｨ9ｨｪ66 786ｨ 66ｨｰｨ 68ｨ ｨｨ ｨｰ82ｨ ｨｮ2ｨｰ ｨｮｨｰ6 ﾂｨｪ2ｨｪｨｨ7 9 ｨｮ ﾂ2ｨｰ6ｨｬ ｨ ｨｺｨｰ6869, 95ｨｨ76ｨｴｨｨ1 ｨｪｨ 786ｨｰ2ｨｺｨ ｨｪｨｨ ｨ. 6125ｨｨ ｨｨ4ｨｨｨｺ6-1ｨｨｨｬｨｨ ﾂ29ｨｺｨｨ ｨｨ 7ｨ 99ｨｨ9ｨｪ6ｨｬ 6ｨｰｨ ｨ 1ｨｨ6ｨｺ9ｨｨ1ｨ ｨ 46ｨｰｨ 27ｨｨ9ｨ ｨｪｨｪ42 ｨｪｨｨ32 ｨｬ6125ｨｨ ｨｮ ﾂｨｨｨｰ49ｨ 6ｨｰ ｨｰ65ｨｹｨｺ6 ｨ ｨｺｨｰ684, 9974ｨ ｨｪｨｪ42 9 ｨｨ4ｨｨｨｺ6-1ｨｨｨｬｨｨ ﾂ29ｨｺｨｨｨｬｨｨ ｨ ｨｬｨｨ, 786ｨｰ2ｨｺｨ 6ｨｴｨｨｨｬｨｨ 78ｨｨ 7ｨ 99ｨｨ9ｨｪ6ｨｬ 6ｨｰｨ ｨ, ｨｨ ｨ ｨ 6ｨｰ, ﾂｨｰ ｨｬ ｨｪｨｨ7 ｨｨ4ｨｬ282ｨｪｨｨｨｦ 7ｨ 99ｨｨ9ｨｪ4ｨｦ 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺ 4ｨ ｨｴｨｨｨｴ2ｨｪ 6ｨｰ 95ｨｨ7ｨｪｨｨ7 92ｨｰ8ｨ. 6125ｨｹ, ｨｮ ﾂｨｨｨｰ49ｨ 6ｨｴｨ 7 52ｨｺｨｰｨｨ9ｨｪ69ｨｰｨｹ 968ｨ 2ｨｪｨｰ ｨｹ 69ｨｪ69ｨ ｨｪｨ ｨｪｨ ｨｪｨｨｨｨ, ﾂｨｰ6 968ｨ 2ｨｪｨｰ ｨｪ ｨｰ97 1%-ｨｪ6 52ｨｺｨｰｨｨ9ｨｪ4ｨｬ. ｨｺｨ ﾂ29ｨｰ92 1ｨ 8ｨ ｨｺｨｰ28ｨｨ9ｨｰｨｨｨｺｨｨ 968ｨ 2ｨｪｨｰｨ 9961ｨｨｨｰ97 ｨｺ65ｨｨ2ｨｨ2ｨｪｨｰ 5-

5 132ｨｺｨｰｨｨ9ｨｪ69ｨｰｨｨ 968ｨ 2ｨｨｨｨ, ｨｺ6ｨｰ684ｨｦ 8ｨ 92ｨｪ ｨｴ2ｨｪｨｪ41 ｨｬ652ｨｺｨｮ5 6ｨｰ 6ｨ ｨｴ26 ｨｺ65ｨｨ ﾂ29ｨｰ9ｨ ｨｬ652ｨｺｨｮ5, 7ｨ 1ｨ 6ｨｴｨｨ1 ｨｪｨ ｨｪ69ｨｰｨｹ 968ｨ 2ｨｪｨｰｨ. 1ｨ 69ｨｪ692 1ｨ ｨｪｨｪ41 7ｨ 8ｨ 5525ｨｹｨｪ41 ｨｨ4ｨｬ282ｨｪｨｨｨｦ NO 2 ｨｬ2ｨｰ616ｨｬ 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ ｨｨ ｨｺ6ｨｪｨｰ865ｨｹｨｪ4ｨｬｨｨ ｨｬ2ｨｰ61ｨ ｨｬｨｨ ｨ 45ｨｨ ｨｨ4952- ﾂ2ｨｪ4 4ｨｪｨ ﾂ2ｨｪｨｨ7 ｨｺ65ｨｨ2ｨｨ2ｨｪｨｰ69 52ｨｺｨｰｨｨ9ｨｪ69ｨｰｨｨ 968ｨ 2ｨｨｨｨ ｨｨ9765ｨｹ469ｨ ｨｪｨｪ41 968ｨ 2ｨｪｨｰ69. 22ｨｰｨ 5ｨｹｨｪ62 67ｨｨ9ｨ ｨｪｨｨ2 ｨｬ6125ｨｨ 78ｨｨ9212ｨｪ6 9 8ｨ ｨ 6ｨｰ2 [14]. 38ｨｨｨｬ2ｨｪ2ｨｪｨｨ2 ｨｬ6125ｨｨ 78ｨｨ9256 ｨｺ 5ｨｮ ﾂ32ｨｬｨｮ 965ｨ 9ｨｨ6 824ｨｮ5ｨｹｨｰｨ ｨｰ69 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ, ｨｺ6ｨｪｨｰ865ｨｹｨｪ41 ｨｨ4ｨｬ282ｨｪｨｨｨｦ ｨｨ ｨｮ9ｨｰ8ｨ ｨｪ2ｨｪｨｨ6 9ｨｨ9ｨｰ2ｨｬｨ ｨｰｨｨ ﾂ29ｨｺ66 8ｨ 45ｨｨ ﾂｨｨ7 ｨｬ231ｨｮ ｨｪｨｨｨｬｨｨ. 21ｨｪｨ ｨｺ6 8ｨ 99 ﾂｨｨｨｰｨ ｨｪｨｪ42 4ｨｪｨ ﾂ2ｨｪｨｨ7 ｨｺ65ｨｨ2ｨｨ2ｨｪｨｰ69 52ｨｺｨｰｨｨ9ｨｪ69ｨｰｨｨ 968ｨ 2ｨｨｨｨ 969ｨｰｨ 9ｨｨ5ｨｨ 2, ｨC6 ｨｨ 2, ｨC ｨ 2ｨｪｨｰ69 ｨｪｨ 69ｨｪ ｨｨ ｨｨ61ｨｨ1ｨ ｨｺｨ 5ｨｨ7 966ｨｰ92ｨｰ9ｨｰ92ｨｪｨｪ6. 1ｨ ｨｦ12ｨｪｨｪ42 ｨｺ65ｨｨ2ｨｨ2ｨｪｨｰ4 ｨｪ2 965ｨ 9ｨｮ6ｨｰ97 9 ｨｨ4929ｨｰｨｪ4ｨｬｨｨ 78219ｨｰｨ 952ｨｪｨｨ7ｨｬｨｨ 6ｨ ｨｨ9765ｨｹ469ｨ ｨｪｨｪ41 8ｨ 9ｨｰ968ｨ 1 ｨｺｨ ｨｺ 52ｨｺｨｰｨｨ9ｨｪ41 968ｨ 2ｨｪｨｰｨ 1 NO ｨｰ6ｨｬｨｮ 1ｨ ｨｪｨｪｨ 7 ｨｬ6125ｨｹ ｨｪ2 ｨｬ632ｨｰ ｨ 4ｨｰｨｹ ｨｨ9765ｨｹ469ｨ ｨｪｨ 157 6ｨ ｨｲ79ｨｪ2ｨｪｨｨ7 4ｨ ｨｨｨｺ9ｨｨ869ｨ ｨｪｨｪ66 8ｨ 45ｨｨ ﾂｨｨ7 ｨｬ231ｨｮ 824ｨｮ5ｨｹｨｰｨ ｨｰｨ ｨｬｨｨ 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ ｨｨ ｨｺ6ｨｪｨｰ865ｨｹｨｪ41 ｨｨ4ｨｬ282ｨｪｨｨｨｦ. 6125ｨｹ, ｨｮ ﾂｨｨｨｰ49ｨ 6ｨｴｨ 7 696ｨ 2ｨｪｨｪ69ｨｰｨｨ ｨｨ4ｨｨｨｺ6-1ｨｨｨｬｨｨ ﾂ29ｨｺ66 94ｨ ｨｨｨｬ612ｨｦ9ｨｰ9ｨｨ7 1ｨｨ6ｨｺ9ｨｨ1ｨ ｨ 46ｨｰｨ 9 8ｨ 9ｨｰ9686ｨｬ 968ｨ 2ｨｪｨｰｨ ｨｪｨ 9ｨｰ67ｨｴ2ｨｦ 9ｨｰｨ ｨｰｨｹ2 696ｨ 2ｨｪｨｪ69ｨｰｨｨ ｨｨ4ｨｨｨｺ6-1ｨｨｨｬｨｨ- ﾂ29ｨｺ66 94ｨ ｨｨｨｬ612ｨｦ9ｨｰ9ｨｨ7 NO 2 9 8ｨ 9ｨｰ9686ｨｬ 968ｨ 2ｨｪｨｰｨ 8ｨ 99ｨｬ6ｨｰ82ｨｪ ｨｮ ﾂｨ 7 6ｨｰｨ 68ｨ 786ｨ 9 8ｨ 9ｨｰ9686ｨｬ ｨｹ 69ｨｪ6949ｨ 2ｨｰ97 ｨｪｨ ｨｰ6ｨｬ, ﾂｨｰ6 8ｨ 9ｨｰ ｨ 2ｨｪｨｰｨ 7656ｨｴｨ 2ｨｰ ｨｰｨｮ7ｨ 6ｨｴｨｨ2 ｨｬ652ｨｺｨｮ54 ｨ 4ｨ, 61ｨｪｨ ｨｺ6 ｨｺ65ｨｨ2ｨｨ2ｨｪｨｰ ｨ NO 2 9 NO ｨC 2 9ｨ 8ｨｹｨｨ8ｨｮ2ｨｰ97 6ｨｰ ｨｪｨｮ ｨｨｨｪｨｨ24, ｨｨ 26 4ｨｪｨ ﾂ2ｨｪｨｨ2, ｨｰ ｨｰｨｪ69ｨｰｨｹ 6ｨ 8ｨ 469ｨ ｨｪｨｨ7 NO ｨC 2, 4ｨ 9ｨｨ9ｨｨｨｰ 6ｨｰ 9ｨｪ23ｨｪｨｨ1 ｨｮ9569ｨｨｨｦ 786ｨｰ2ｨｺｨ ｨｪｨｨ7 82ｨ ｨｺ2ｨｨｨｨ. 8ｨｪｨ 5ｨｨ4 ｨｨ4929ｨｰｨｪ41 1ｨ ｨｪｨｪ41 6 ｨｨ4ｨｨｨｺ6-1ｨｨｨｬｨｨ ﾂ29ｨｺ6ｨｬ 94ｨ ｨｨｨｬ612ｨｦ9ｨｰ9ｨｨｨｨ NO 2 9 8ｨ 9ｨｰ968ｨ ｨｬｨｨ ｨｺｨ 449ｨ 2ｨｰ, ﾂｨｰ ｨ 8ｨ 469ｨ ｨｪｨｨ7 ｨｪｨｨｨｰ8ｨｨｨｰ-ｨｨ6ｨｪ69 ｨｰ8ｨｨ5ｨｰｨ ｨｪ65ｨ ｨｬｨｨｨｪ 16532ｨｪ ｨｪｨ 161ｨｨｨｰｨｹ97 9 ｨｨ6ｨｪｨｪ6ｨｦ 68ｨｬ2 (ｨｨ18ｨ ｨｰｨｨ869ｨ ｨｪｨｪ6ｨｬ 9ｨｨ12) [9, 15]. 4ｨ 9ｨｨ9ｨｨｨｬ69ｨｰｨｨ 6ｨｰ ｨｺ65ｨｨ ﾂ29ｨｰ9ｨ ｨ 9ｨｰ (9ｨｰ272ｨｪｨｨ ｨｨ18ｨ ｨｰｨｨ869ｨ ｨｪｨｪ69ｨｰｨｨ 668) ｨｬ63ｨｪ ｨｨｨｰｨｹ ｨｰ8ｨｨ ｨｹｨｪ41 95ｨｮ ﾂｨ 7 786ｨｰ2ｨｺｨ ｨｪｨｨ7 1ｨｨｨｬｨｨ ﾂ29ｨｺ6ｨｦ 82ｨ ｨｺ2ｨｨｨｨ 9 8ｨ 45ｨｨ ﾂｨｪ4ｨｬｨｨ ｨｺ65ｨｨ2ｨｨ2ｨｪｨｰｨ ｨｬｨｨ ｨ NO 2 9 NO ｨC ｨｺ6ｨｰ ｨｰｨｨｨｬｨ 5ｨｹｨｪ42 ｨｮ9569ｨｨ7, 6ｨ 2972 ﾂｨｨ9ｨ 6ｨｴｨｨ2 765ｨｪｨｮ6 ｨｨ18ｨ ｨｰｨ 2ｨｨ6 668, ｨC ｨｺ65ｨｨ2ｨｨ2ｨｪｨｰ ｨ NO 2 9 NO ｨC 2 8ｨ 92ｨｪ 21ｨｨｨｪｨｨ22, 82ｨ ｨｺ2ｨｨ7 9 NO 2 786ｨｰ2ｨｺｨ 2ｨｰ 76 ｨｮ8ｨ 9ｨｪ2ｨｪｨｨ6 [7]: 2NO 2 + (HOCH 2 CH 2 ) 3 N + 2OH ｨC 2NO ｨC 2 + O ｨC ｨC N + (CH 2 CH 2 OH) 3 + H 2 O ｨｰｨ ｨｰ6ｨｺ ｨ 9ｨｰ9682 ( ﾂｨ 9ｨｰｨｨ ﾂｨｪｨ 7 ｨｨ18ｨ ｨｰｨ 2ｨｨ7 ｨｰ8ｨｨ5ｨｰｨ ｨｪ65ｨ ｨｬｨｨｨｪｨ ) ｨC ﾂｨ 9ｨｰｨｹ 7656ｨｴｨ 2ｨｬ66 NO 2 82ｨ ｨｨ8ｨｮ2ｨｰ 9 ｨｨ18ｨ ｨｰｨｨ869ｨ ｨｪｨｪ4ｨｬｨｨ ｨｬ652ｨｺｨｮ5ｨ ｨｬｨｨ ｨ 8ｨ 469ｨ ｨｪｨｨ2ｨｬ ｨｪｨｨｨｰ8ｨｨｨｰ-ｨｨ6ｨｪ69, 69ｨｰｨ 93ｨ 797 ﾂｨ 9ｨｰｨｹ 7656ｨｴｨ 2ｨｬ66 NO 2 94ｨ ｨｨｨｬ612ｨｦ9ｨｰ9ｨｮ2ｨｰ 9 ｨｪ2ｨｨ18ｨ ｨｰｨｨ869ｨ ｨｪｨｪ4ｨｬ 668 ｨｨ ｨｨｨｰ 9 18ｨｮｨｨ2 7861ｨｮｨｺｨｰ4 82ｨ ｨｺ2ｨｨｨｨ [16] ｨ 4ｨｰ6ｨｺ ｨ 9ｨｰ9682 ｨC ﾂｨ 9ｨｰｨｹ 769ｨｰｨｮ7ｨ 6ｨｴ26 NO 2 82ｨ ｨｨ8ｨｮ2ｨｰ 9 ｨｨ18ｨ ｨｰｨｨ869ｨ ｨｪｨｪ4ｨｬｨｨ ｨｬ652ｨｺｨｮ5ｨ ｨｬｨｨ ｨ 8ｨ 469ｨ ｨｪｨｨ2ｨｬ NO ｨC 2 (ｨｺ65ｨｨ2ｨｨ2ｨｪｨｰ ｨ 8ｨ 92ｨｪ 21ｨｨｨｪｨｨ22), 69ｨｰｨ 5ｨｹｨｪｨ 7 ﾂｨ 9ｨｰｨｹ NO 2 82ｨ ｨｨ8ｨｮ2ｨｰ 9 ｨｨ4ｨ 4ｨｰ6 ﾂｨｪ4ｨｬｨｨ3 ｨｬ652ｨｺｨｮ5ｨ ｨｬｨｨ ｨ 8ｨ 469ｨ ｨｪｨｨ2ｨｬ ｨｪｨｨｨｰ8ｨｨｨｰ- ｨｨ ｨｪｨｨｨｰ8ｨ ｨｰ-ｨｨ6ｨｪ69 (ｨｺ65ｨｨ2ｨｨ2ｨｪｨｰ ｨ NO 2 9 NO ｨC 2 8ｨ 92ｨｪ,5 [17]). 966ｨｰ92ｨｰ9ｨｰ9ｨｨｨｨ 9 8ｨ 99ｨｬ6ｨｰ82ｨｪｨｪ4ｨｬｨｨ 9432 ｨｮ8ｨ 9ｨｪ2ｨｪｨｨ7ｨｬｨｨ 82ｨ ｨｺ2ｨｨｨｨ 52ｨｺｨｰｨｨ9ｨｪ4ｨｦ ｨｺ65ｨｨ2ｨｨ2ｨｪｨｰ ｨ 1ｨｨ6ｨｺ9ｨｨ1ｨ ｨ 46ｨｰｨ 9 ｨｪｨｨｨｰ8ｨｨｨｰ-ｨｨ6ｨｪ k eff 9 4ｨ 9ｨｨ9ｨｨｨｬ69ｨｰｨｨ 6ｨｰ ｨｺ65ｨｨ ﾂ29ｨｰ9ｨ ｨ 9ｨｰ ｨ 2ｨｪｨｰｨ ｨ ｨｮ12ｨｰ 8ｨ 92ｨｪ 61 ｦﾂ 64, ｦﾂ<ｦﾂ ｨｪ2169ｨｰｨ ｨｰ6ｨｺ 9614; ｦﾂ 64 k eff = 621, ｦﾂ = ｦﾂ ; (2) ｦﾂ , ｦﾂ > ｦﾂ ｨｨ4ｨ 4ｨｰ6ｨｺ 9614, ｦﾂ ｦﾂ = NHO N 2 668ｨC ｨｰ2ｨｺｨｮｨｴ22 ｨｬ65ｨｹｨｪ62 6ｨｰｨｪ632ｨｪｨｨ2 ｨｺ65ｨｨ ﾂ29ｨｰ9ｨ ｨ 9ｨｰ ｨ 2ｨｪｨｰｨ ｨｺ ｨｺ65ｨｨ ﾂ29ｨｰ9ｨｮ 668; ｦﾂ ｨC ｨｬ65ｨｹｨｪ62 6ｨｰｨｪ632ｨｪｨｨ2 ｨｺ65ｨｨ ﾂ29ｨｰ9ｨ 9614 ｨｺ ｨｺ65ｨｨ ﾂ29ｨｰ9ｨｮ 968ｨ 2ｨｪｨｰｨ, 6ｨ 2972 ﾂｨｨ9ｨ 6ｨｴ22 ｨｺ65ｨｨ2ｨｨ2ｨｪｨｰ ｨ NO 2 9 NO ｨC 2, 8ｨ 9ｨｪ4ｨｦ 21ｨｨｨｪｨｨ ｨｺ65ｨｹｨｺｨｮ ｨｰ97 ｨｨ869ｨｺ67ｨｨ ﾂｨｪ4ｨｬ 92ｨｴ29ｨｰ96ｨｬ, 78ｨｨ ｨｪｨｨｨｨ 6ｨｰｨ 68ｨ 786ｨ 9 82ｨ 5ｨｹｨｪ41 ｨｮ9569ｨｨ ｨ ｨｪｨｨ ｨ 9ｨｰ ｨ ｨｮ12ｨｰ 4ｨ 9ｨｨ92ｨｰｨｹ 6ｨｰ 95ｨ 3ｨｪ69ｨｰｨｨ 9641ｨｮ1ｨ ｨｨ 95ｨ 3ｨｪ69ｨｰｨｨ 9641ｨｮ1ｨ ｨｨ ｨ ｨｪｨｨ ｨ 9ｨｰ ｨ 2ｨｪｨｰｨ 9 ｨｬ6125ｨｨ ｨｨ9765ｨｹ469ｨ ｨｪ 4ｨ ｨｺ6ｨｪ 4ｨ ｨｮ57 9 ｨｮ ﾂ2ｨｰ6ｨｬ 5ｨｬ7ｨｨ8ｨｨ ﾂ29ｨｺ6ｨｦ 7678ｨ 9ｨｺｨｨ ｦﾃ [15]. 48ｨ 32ｨｪｨｨ ｨｪｨｺｨｨ ｨｰ2ｨｺｨｮｨｴ26 4ｨｪｨ ﾂ2ｨｪｨｨ7 7ｨ 8ｨ ｨｬ2ｨｰ8ｨ ｦﾂ ｨｨｨｬ22ｨｰ 9ｨｨ1 f ｦﾂ =, (3) (1 ｨC f)ｦﾃ 12 f ｨC ｨｰ2ｨｺｨｮｨｴｨ 7 6ｨｰｨｪ69ｨｨｨｰ25ｨｹｨｪｨ 7 95ｨ 3ｨｪ69ｨｰｨｹ 9641ｨｮ1ｨ, %; ｦﾃ =, ｨｰ92ｨｰ9ｨｰ9ｨｨｨｨ ｨ ｨ 2ｨｬ6ｨｦ ｨｬ6125ｨｹ6 ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨ7 1ｨｨ6ｨｺ9ｨｨ1ｨ ｨ 46ｨｰｨ ｼ9C 622ｨｪｨｨ9ｨ 2ｨｰ ｨｬｨｮ52, 9 ｨｺ6ｨｰ686ｨｦ ｨｨｨｪｨｰ28ｨ 5 ｨ 7786ｨｺ9ｨｨｨｬｨｨ8ｨｮ2ｨｰ97 ｨｺ6ｨｪ2 ﾂｨｪ6ｨｦ 9ｨｮｨｬｨｬ6ｨｦ: ｼ9 ｦ m ｦ m C = ﾖ, (4) ｦ ｦﾓ n S S DT ( ) k ( ) ｦﾓ ﾆDT ( i) keff ( fi) ｦ ｦﾓ eff f d i L ﾒ L 2ｨｰ61 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ 157 ｨｨ4ｨｬ282ｨｪｨｨｨｦ 1ｨｨ6ｨｺ9ｨｨ1ｨ ｨ 46ｨｰｨ 9 ｨ ｨｰｨｬ6928ｨｪ6ｨｬ 9641ｨｮ i = 1 12 D(T) ｨC ｨｺ65ｨｨ2ｨｨ2ｨｪｨｰ 1ｨｨｨｮ4ｨｨｨｨ NO ｨｮ12, 4ｨ 9ｨｨ97ｨｴｨｨｨｦ 6ｨｰ ｨｰ2ｨｬ728ｨ ｨｰｨｮ84, ｨｬ 2 /9 [18]; ｦ ｦﾓ i ｨC 982ｨｬ2ｨｪｨｪ6ｨｦ ｨｨｨｪｨｰ289ｨ 5 9 ｨｨ4929ｨｰｨｪ4ｨｬｨｨ 4ｨｪｨ ﾂ2ｨｪｨｨ7ｨｬｨｨ 6ｨｰｨｪ69ｨｨｨｰ25ｨｹｨｪ6ｨｦ 95ｨ 3ｨｪ69ｨｰｨｨ ｨｨ ｨｰ2ｨｬ728ｨ ｨｰｨｮ84, 9; n ｨC ﾂｨｨ ｨｬ2ｨｪｨｪ41 ｨｨｨｪｨｰ289ｨ ｨｨ4929ｨｰｨｪ4ｨｬｨｨ 4ｨｪｨ ﾂ2ｨｪｨｨ7ｨｬｨｨ 6ｨｰｨｪ69ｨｨｨｰ25ｨｹｨｪ6ｨｦ 95ｨ 3ｨｪ69ｨｰｨｨ ｨｨ ｨｰ2ｨｬ728ｨ ｨｰｨｮ ｨｺｨｨ ｨｺ6882ｨｺｨｰｨｪ69ｨｰｨｨ ｨｪｨｪ6ｨｦ ｨｬ6125ｨｨ ｨ 45ｨ 8232ｨｪｨ 4ｨ 1ｨ ﾂｨ 622ｨｪｨｺｨｨ 4ｨｪｨ ﾂ2ｨｪｨｨ7 ｨｺ65ｨｨ2ｨｨ2ｨｪｨｰｨ ｦﾂ 9 ｨｨ9765ｨｹ469ｨ ｨｪｨｨ2ｨｬ 5ｨｺ9728ｨｨｨｬ2ｨｪｨｰｨ 5ｨｹｨｪ41 1ｨ ｨｪｨｪ41 (ｨｺ6ｨｪｨｰ865ｨｹｨｪ42 ｨｨ4ｨｬ282ｨｪｨｨ7 NO 2, 1ｨ ｨｪｨｪ42 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ NO 2, 4ｨｪｨ ﾂ2ｨｪｨｨ7 95ｨ 3ｨｪ69ｨｰｨｨ 9641ｨｮ1ｨ ) ｨｨ 96769ｨｰｨ 952ｨｪｨｨ2 9 ｨｨ4929ｨｰｨｪ4ｨｬｨｨ 4ｨｪｨ ﾂ2ｨｪｨｨ7ｨｬｨｨ. 1ｨ ｨｨ5ｨｮ ﾂ ｨ 9ｨｨ2 824ｨｮ5ｨｹｨｰｨ ｨｰ69 ｨｺ6ｨｪｨｰ865ｨｹｨｪ41 ｨｨ4ｨｬ282ｨｪｨｨｨｦ ｨｨ 1ｨ ｨｪｨｪ41 7ｨ 99ｨｨ9ｨｪ66 786ｨ 66ｨｰｨ 68ｨ 765ｨｮ ﾂ2ｨｪ6 157 ｦﾂ = 3,9. 1ｨ ｨｦ12ｨｪｨｪ62 4ｨｪｨ ﾂ2ｨｪｨｨ ｨ 9ｨｮ2ｨｰ97 9 ｨｰ2682ｨｰｨｨ ﾂ29ｨｺｨｨｨｬｨｨ 78219ｨｰｨ 952ｨｪｨｨ7ｨｬｨｨ ｨｨ18ｨ ｨｰｨ 2ｨｨｨｨ 668 ｨｨ 5ｨｺ9728ｨｨｨｬ2ｨｪｨｰｨ 5ｨｹｨｪ6 ｨｮ9ｨｰｨ ｨｪ6952ｨｪｨｪ6ｨｦ 925ｨｨ- ﾂｨｨｨｪ6ｨｦ, 8ｨ 9ｨｪ6ｨｦ 3,6 [15]. 5521ｨｮ2ｨｰ 6ｨｰｨｬ2ｨｰｨｨｨｰｨｹ, ﾂｨｰ6 78ｨｨ 95ｨ 3ｨｪ69ｨｰｨｨ 9641ｨｮ1ｨ, 6ｨ 2972 ﾂｨｨ9ｨ 6ｨｴ2ｨｦ 765ｨｪｨｮ6 ｨｨ18ｨ ｨｰｨ 2ｨｨ6 668, ｨｰ.2. k eff = 1, 68ｨｬｨｮ5ｨ (4) 99212ｨｰ97 ｨｺ 68ｨｬｨｮ52 (1) 78ｨｨ ｨｮ9569ｨｨｨｨ, ﾂｨｰ6 ｨｰ2ｨｬ728ｨ ｨｰｨｮ8ｨ 9641ｨｮ1ｨ 769ｨｰ67ｨｪｨｪｨ. 6ｨ ｨｺｨｨｨｬ 6ｨ 8ｨ 46ｨｬ, ｨｪｨｮ529ｨ 73 ｨｬ6125ｨｹ 79572ｨｰ97 ﾂｨ 9ｨｰｨｪ4ｨｬ 95ｨｮ ﾂｨ 2ｨｬ 8ｨ 48ｨ ｨ 6ｨｰｨ ｨｪｨｪ6ｨｦ ｨｨ4ｨｨｨｺ6-1ｨｨｨｬｨｨ- ﾂ29ｨｺ6ｨｦ ｨｬ6125ｨｨ.

6 1386ｨｪ22ｨｪｨｰ8ｨ 2ｨｨ7 NO2, ｨｬｨｺ/ｨｬ 3 86ｨｪ22ｨｪｨｰ8ｨ 2ｨｨ7 NO2, ｨｬｨｺ/ｨｬ ｨC ｨC ｨC ｨC ｨC ｨｪｨｰ865ｨｹ 33/1ｨｮ529ｨ 73 ｨｬ6125ｨｹ ｨ 33/169ｨ 7 ｨｬ6125ｨｹ ｦﾂ = 3,6 29.4ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨC ｨ 29.4ｨC ｨC ｨC ｨC ｨC ｨC ｨｨ61 ｨｨ4ｨｬ282ｨｪｨｨｨｦ ｨC ｨC19.8 4ｨｨ ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｨ NO 2, ｨｨ4ｨｬ282ｨｪｨｪ ｨｬ6ｨｴｨｹ6 ｨｺ6ｨｪｨｰ865ｨｹｨｪ41 ｨｬ2ｨｰ6169 ｨｨ 8ｨ 99 ﾂｨｨｨｰｨ ｨｪｨｪ ｨ ｨｪｨｪ4ｨｬ 7ｨ 99ｨｨ9ｨｪ66 786ｨ 66ｨｰｨ 68ｨ 9 ｨｨ9765ｨｹ469ｨ ｨｪｨｨ2ｨｬ ｨｪｨｮ5296ｨｦ3 ｨｨ 78215ｨ ｨ 2ｨｬ6ｨｦ ｨｬ61252ｨｦ: ｨ ｨC 7ｨｮｨｪｨｺｨｰ ｨｨ4ｨｬ282ｨｪｨｨｨｦ 1, 3ｨｺｨ ｨｰ28ｨｨｨｪｨ ｨｮ8; ｨ ｨC 7ｨｮｨｪｨｺｨｰ ｨｨ4ｨｬ282ｨｪｨｨｨｦ 2, 3ｨｺｨ ｨｰ28ｨｨｨｪｨ ｨｮ8; 9 ｨC 32896ｨｮ8ｨ 5ｨｹ9ｨｺ; ｨC. 343ｨｬｨ 19.6ｨC ｨC ｨC ｨC ｨC ｨｨ61 ｨｨ4ｨｬ282ｨｪｨｨｨｦ 1.1ｨC14.1 1ｨ 8ｨｨ ｨｰｨ 952ｨｪ4 9821ｨｪｨｨ2 19ｨｮ1ｨｪ2125ｨｹｨｪ42 ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｨ NO 2, ｨｨ4ｨｬ282ｨｪｨｪ42 ｨｺ6ｨｪｨｰ865ｨｹｨｪ4ｨｬｨｨ ｨｬ2ｨｰ61ｨ ｨｬｨｨ, ｨｨ ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｨ, 8ｨ 99 ﾂｨｨｨｰｨ ｨｪｨｪ ｨ ｨｪｨｪ4ｨｬ 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ 9 ｨｨ9765ｨｹ469ｨ ｨｪｨｨ2ｨｬ ｨｪｨｮ5296ｨｦ3 ｨｨ 78215ｨ ｨ 2ｨｬ6ｨｦ (ｦﾂ = 3,6) ｨｬ61252ｨｦ 157 8ｨ 45ｨｨ ﾂｨｪ41 728ｨｨ6169 ｨｨ4ｨｬ282ｨｪｨｨｨｦ ｨｨ 7ｨｮｨｪｨｺｨｰ69 6ｨｰｨ 68ｨ 786ｨ. 8ｨ ｨｺ 9ｨｨ1ｨｪ6 ｨｨ4 8ｨ ｨｨｨｺ69, 78ｨｨｨｬ2ｨｪ2ｨｪｨｨ ｨｪｨｪ6ｨｦ ｨｬ6125ｨｨ ｨｨ56 9ｨｮｨｴ29ｨｰ92ｨｪｨｪ6 ｨｮ5ｨｮ ﾂ3ｨｨｨｰｨｹ 965ｨ 9ｨｨ2 824ｨｮ5ｨｹｨｰｨ ｨｰ69 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ 9 1ｨ ｨｪｨｪ4ｨｬｨｨ ｨｺ6ｨｪｨｰ865ｨｹｨｪ41 ｨｨ4ｨｬ282ｨｪｨｨｨｦ 76 98ｨ 9ｨｪ2ｨｪｨｨ6 9 ｨｪｨｮ5296ｨｦ3 ｨｬ6125ｨｹ ｨｹ469ｨ ｨｪｨｨ2 8ｨ 48ｨ ｨ 6ｨｰｨ ｨｪｨｪ6ｨｦ ｨｬ6125ｨｨ 78ｨｨ9256 ｨｺ ｨｮｨｬ2ｨｪｨｹ32ｨｪｨｨ6 9821ｨｪ26 8ｨ 45ｨｨ ﾂｨｨ7 ｨｬ231ｨｮ ｨｺ6ｨｪｨｰ865ｨｹｨｪ4ｨｬｨｨ 824ｨｮ5ｨｹｨｰｨ ｨｰｨ ｨｬｨｨ ｨｨ 824ｨｮ5ｨｹｨｰｨ ｨｰｨ ｨｬｨｨ ｨｨ4ｨｬ282ｨｪｨｨｨｦ, 94765ｨｪ2ｨｪｨｪ ｨｬ6ｨｴｨｹ6 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ, 6ｨｰ ｨC46,2 16 ｨC2,5%. 86ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｨ NO 2, 8ｨ 99 ﾂｨｨｨｰｨ ｨｪｨｪ ｨ ｨｪｨｪ4ｨｬ 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ 9 ｨｨ9765ｨｹ469ｨ ｨｪｨｨ2ｨｬ ｨｪｨｪ6ｨｦ ｨｬ6125ｨｨ, ｨｪ2 ｨｨｨｬ26ｨｰ 9ｨｨ9ｨｰ2ｨｬｨ ｨｰｨｨ ﾂ29ｨｺ66 ｨｨ 9ｨｰｨ ｨｰｨｨ9ｨｰｨｨ ﾂ29ｨｺｨｨ 4ｨｪｨ ﾂｨｨｨｬ66 (ｦﾁ =,5) 6ｨｰ5ｨｨ ﾂｨｨ7 6ｨｰ 4ｨｪｨ ﾂ2ｨｪｨｨｨｦ, ｨｨ4ｨｬ282ｨｪｨｪ41 ｨｺ6ｨｪｨｰ865ｨｹｨｪ4ｨｬｨｨ ｨｬ2ｨｰ61ｨ ｨｬｨｨ. 5ｨ ｨｺ56 ﾂ2ｨｪｨｨ ｨｪｨ 928ｨｨ7 15ｨｨｨｰ25ｨｹｨｪ41 ｨｬ2ｨｰ61ｨｨ ﾂ29ｨｺｨｨ1 ｨｨ4ｨｬ282ｨｪｨｨｨｦ ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｦ 1ｨｨ6ｨｺ9ｨｨ1ｨ ｨ 46ｨｰｨ ｨｬ2ｨｰ616ｨｬ 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ ｨｪｨ ｨｰ288ｨｨｨｰ68ｨｨｨｨ 5821ｨｪ26 78ｨ 5ｨ. 2ｨ ｨｪｨ 8ｨｮ32ｨｪ6, ﾂｨｰ6 ｨｨ9765ｨｹ469ｨ ｨｪｨｨ2 ｨｬ2ｨｰ61ｨ 7ｨ 99ｨｨ9ｨｪ66 786ｨ 66ｨｰｨ 68ｨ 157 ｨｨ4ｨｬ282ｨｪｨｨｨｦ NO 2 9 ｨｬ2ｨｰ268656ｨｨ ﾂ29ｨｺｨｨ1 ｨｮ9569ｨｨ71 1ｨ ｨｪｨｪ66 82ｨｨ6ｨｪｨ 78ｨｨ961ｨｨｨｰ ｨｺ 9ｨｰｨ ｨｰｨｨ9ｨｰｨｨ- ﾂ29ｨｺｨｨ 4ｨｪｨ ﾂｨｨｨｬ6ｨｬｨｮ 4ｨ ｨｪｨｨ32ｨｪｨｨ6 824ｨｮ5ｨｹｨｰｨ ｨｰ ｨ 9ｨｪ2ｨｪｨｨ6 9 ｨｺ6ｨｪｨｰ865ｨｹｨｪ4ｨｬｨｨ 1ｨ ｨｪｨｪ4ｨｬｨｨ. 424ｨｮ5ｨｹｨｰｨ ｨｰ4 ｨｰ2682ｨｰｨｨ ﾂ29ｨｺｨｨ1 ｨｨ 5ｨｺ9728ｨｨｨｬ2ｨｪｨｰｨ 5ｨｹｨｪ41 622ｨｪ6ｨｺ 95ｨｨ76ｨｴｨｨ1 ｨ ｨｺｨｰ ｨｺｨ 4ｨ 5ｨｨ, ﾂｨｰ6 9 ｨ 568ｨｨｨｰｨｬ2 6ｨ 8ｨ ｨ 6ｨｰｨｺｨｨ 1ｨ ｨｪ ｨｮｨ ｨｪ4ｨｦ.8., 73ｨｺ2ｨｰ69ｨ 1.8.

7 13ｨｪ41 7ｨ 99ｨｨ9ｨｪ66 786ｨ 66ｨｰｨ 68ｨ ｨｪ26ｨ 161ｨｨｨｬ6 ｨｮ ﾂｨｨｨｰ49ｨ ｨｰｨｹ 996ｨｦ9ｨｰ9ｨ ｨｨ9765ｨｹ4ｨｮ2ｨｬ41 968ｨ 2ｨｪｨｰ69 ｨｨ 696ｨ 2ｨｪｨｪ69ｨｰｨｨ ｨｨ4ｨｨｨｺ6-1ｨｨｨｬｨｨ ﾂ29ｨｺｨｨ , 786ｨｰ2ｨｺｨ 6ｨｴｨｨ1 78ｨｨ 7ｨ 99ｨｨ9ｨｪ6ｨｬ 6ｨｰｨ ｨ. 4ｨ 48ｨ ｨ 6ｨｰｨ ｨｪｨ ｨｨ4ｨｨｨｺ6-1ｨｨｨｬｨｨ ﾂ29ｨｺｨ 7 ｨｬ6125ｨｹ 7ｨ 99ｨｨ9ｨｪ66 786ｨ 66ｨｰｨ 68ｨ, 69ｨｪ69ｨ ｨｪｨｪｨ 7 ｨｪｨ ｨｨ4929ｨｰｨｪ41 1ｨ ｨｪｨｪ41 6ｨ 696ｨ 2ｨｪｨｪ69ｨｰ71 94ｨ ｨｨｨｬ612ｨｦ9ｨｰ9ｨｨ7 NO 2 9 8ｨ 9ｨｰ968ｨ ｨｬｨｨ ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｨ NO 2, 8ｨ 99 ﾂｨｨｨｰｨ ｨｪｨｪ42 9 ｨｨ9765ｨｹ469ｨ ｨｪｨｨ2ｨｬ ｨｪｨｪ6ｨｦ ｨｬ6125ｨｨ, ｨ 9ｨｮ6ｨｰ ｨｮ5ｨｹｨｰｨ ｨｰｨ ｨｬｨｨ ｨｺ6ｨｪｨｰ865ｨｹｨｪ41 ｨｨ4ｨｬ282ｨｪｨｨｨｦ, ｨｪ2 ｨｨｨｬ26ｨｰ 9ｨｨ9ｨｰ2ｨｬｨ ｨｰｨｨ ﾂ29ｨｺ66 ｨｨ 9ｨｰｨ ｨｰｨｨ9ｨｰｨｨ ﾂ29ｨｺｨｨ 4ｨｪｨ ﾂｨｨｨｬ66 6ｨｰ5ｨｨ ﾂｨｨ7 6ｨｰ ｨｪｨｨ1. 89ｨｰ ｨ 3ｨ 6ｨｰ ｨ 5ｨ 61ｨ 8ｨｪ69ｨｰｨｹ ｨ ｨｪｨｪｨｨｨｺ696ｨｦ ｨｨ ｨｺｨｨ1 ( ｨｺｨｨｨｦ 15-43, 3ｨｺｨ ｨｰ28ｨｨｨｪｨ ｨｮ8), ｨｹｨ 28ｨｮ (112 ｨｨｨｬ ｨｦｨｺ69ｨ, 5ｨ ｨｪｨｺｨｰ-32ｨｰ28ｨ ｨｮ8) 4ｨ ｨｨｨｪｨｰ2829 ｨｨ 9612ｨｦ9ｨｰ9ｨｨ ｨｪｨｨ6 ｨｨ ｨ ｨｪｨｨ7, 9722ｨｨｨ 5ｨｨ9ｨｰｨ ｨｬ ｨｪｨｰ8 5ｨｺ656ｨｨ ﾂ29ｨｺ66 ｨｬ6ｨｪｨｨｨｰ68ｨｨｨｪｨ ｨｨ ｨｺ6ｨｪｨｰ ｨ ｨｰｨ 952ｨｪｨｨ2 824ｨｮ5ｨｹｨｰｨ ｨｰ69 ｨｨ4ｨｬ282ｨｪｨｨｨｦ, 765ｨｮ ﾂ2ｨｪｨｪ41 ｨｪｨ ｨ 9ｨｰ6ｨｬｨ ｨｰｨｨ ﾂ29ｨｺｨｨ1 9ｨｰｨ ｨｪ2ｨｨ71 ｨｬ6ｨｪｨｨｨｰ68ｨｨｨｪｨ. 296ｨ ｨ 7 ｨ 5ｨ 61ｨ 8ｨｪ69ｨｰｨｹ. 428ｨ 6529ｨｮ (2ｨ ｨｲ21ｨｨｨｪ2ｨｪｨｪ4ｨｦ ｨｨ ｨ ｨｰ25ｨｹ9ｨｺｨｨｨｦ 22ｨｪｨｰ8 78ｨｨ ｨｦ9ｨｺ6ｨｦ ｨｺ6ｨｬｨｨ99ｨｨｨｨ, 6ｨｰｨ 5ｨｨ7) 4ｨ ｨｰｨ 952ｨｪｨｨ2 ｨｪｨ ｨ 68ｨ 7ｨ 99ｨｨ9ｨｪ41 786ｨ 66ｨｰｨ 68ｨｪｨｨｨｺ69, ｨ ｨｰｨ ｨｺ32 9ｨｪｨｨｨｬｨ ｨｪｨｨ2 ｨｨ ｨｨｨｪｨｰ2829 ｨｺ ｨｪｨ 32ｨｦ 8ｨ ｨ 6ｨｰ2. 1. Hafkenscheid T., Fromage-Mariette A., Goelen E., Hangarther M., Pfeffer U., PlaisanceH., De Santis F., Saunders K., Swaans W., Tang Y.S., Targa J., Van Hoek C., Gerboles M. Review of the application of diffusive samplers in the European Union for the monitoring of nitrogen dioxide in ambient air. EUR EN. Luxembourg, European Commission, p ｨｺ2ｨｰ69ｨ 1.8., 3611ｨｮｨ ｨｪ4ｨｦ.8. 2ｨｰ61 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ 157 ｨｬ6ｨｪｨｨｨｰ68ｨｨｨｪｨ 1ｨｨｨｬｨｨ ﾂ29ｨｺ66 4ｨ 874ｨｪ2ｨｪｨｨ7 ｨ ｨｰｨｬ6928ｨｪ ｨｮ1ｨ. ﾁｨ 9ｨｰｨｹ 2. 38ｨ ｨｺｨｰｨｨ ﾂ29ｨｺｨｨ2 ｨ 972ｨｺｨｰ4 (6ｨ 468) // 6ｨｺ656ｨｨ ﾂ29ｨｺｨｨ2 9ｨｨ9ｨｰ2ｨｬ4 ｨｨ 78ｨｨｨ ｨC Lee K., Parkhurst W.J., Xue J., Haluk Ozkaynak A., Neuberg D., Spengler J.D. Outdoor/indoor/personal exposures of children in Nashville, Tennessee // J. Air & Waste Manag. Assoc. 24. V. 54. P. 352ｨC De Santis F., Fino A., Tiwari S., Vazzana C., Allegrini I. A performance of the open end tube diffusion sampler (Palmes sampler) for monitoring nitrogen dioxide // Air Pollution VIII / Eds. J.W.S. Longhurst, C.A. Brebbia, H. Power. Boston: WIT Press, 2. P. 419ｨC Plaisance H., Piechocki-Minguy A., Garcia-Fouque S., Galloo J.C. Influence of meteorological factors on the NO 2 measurements by passive diffusion tube // Atmos. Environ. 24. V. 38. P. 573ｨC Gerboles M., Buzica D., Amantini L., Lagler F. Laboratory and field comparison of measurements obtained using available diffusive samplers for ozone and nitrogen dioxide in ambient air // J. Environ. Monit. 26. N 8. P. 112ｨC Glasius M., Carlsen M.F., Hansen T.S., Lohse C. Measurement of nitrogen dioxide on Funen using diffusion tubes // Atmos. Environ V. 33. P. 1177ｨC Heal M.R., Kirby C., Cape J.N. Systematic biases in measurement of urban nitrogen dioxide using passive diffusion samplers // Environ. Monit. & Assess. 2. V. 62. P. 39ｨC Kirby C., Fox M., Waterhouse J., Drye T. Influence of environmental parameters on accuracy of nitrogen dioxide passive diffusion tubes for ambient measurement // J. Environ. Monit. 21. N 3. P. 15ｨC David R. Lide, ed. CRC Handbook of chemistry and physics. 9 th Edition. Boca Raton: Taylor and Francis, p. 11. Diffusion tubes for ambient NO 2 monitoring: practical guidance. Defra, p. URL: gov. uk/documents/821414_no 2 _WG_PracticalGuidance_ Issue1a.pdf (1ｨ ｨｰｨ 6ｨ 8ｨ ｨｴ2ｨｪｨｨ7 14 7ｨｪ9ｨ ) ｨｮｨｺ69619ｨｰ96 76 ｨｺ6ｨｪｨｰ8656 4ｨ 874ｨｪ2ｨｪｨｨ7 ｨ ｨｰｨｬ : 169ｨｺ6ｨｬｨｨ186ｨｬ2ｨｰ, ｨｺ2ｨｰ69ｨ 1.8., 3611ｨｮｨ ｨｪ4ｨｦ.8., ｨ 8ｨｺ ｨｰｨｨ869ｨ ｨｪｨｨ2 ｨｬ2ｨｰ61ｨ 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ 157 ｨｨ4ｨｬ282ｨｪｨｨ7 ｨｺ6ｨｪ22ｨｪｨｰ8ｨ 2ｨｨｨｦ 1ｨｨ6ｨｺ9ｨｨ1ｨ ｨ 46ｨｰｨ 9 ｨ ｨｰｨｬ6928ｨｪ6ｨｬ 9641ｨｮ12 // 6ｨｺ656ｨｨ ﾂ29ｨｺｨ 7 ｨ 2467ｨ 9ｨｪ69ｨｰｨｹ ｨｨ 96982ｨｬ2ｨｪｨｪ42 ｨｰ21ｨｪ656ｨｨｨｨ: ｨ ｨｰ ｨｪｨ ｨｮ ﾂｨｪ6-78ｨ ｨｺｨｰ. ｨｺ6ｨｪ. ｨｨｨ 99, 23ｨC25 12ｨｺｨ ｨ ｨC ｨｺ2ｨｰ69ｨ 1.8., 3611ｨｮｨ ｨｪ4ｨｦ ｨｪｨｺｨ ｨｺ65ｨｨ2ｨｨ2ｨｪｨｰ69 52ｨｺｨｰｨｨ9ｨｪ69ｨｰｨｨ 968ｨ 2ｨｨｨｨ 78ｨｨ 7ｨ 99ｨｨ9ｨｪ6ｨｬ 6ｨｰｨ ｨ 1ｨｨ6ｨｺ9ｨｨ1ｨ ｨ 46ｨｰｨ // 4. 78ｨｨｨｺ5. 1ｨｨｨｬｨｨｨｨ , ｨC Palmes E.D., Johnson E.R. Explanation of pressure effects on a nitrogen dioxide (NO 2 ) sampler // Amer. Ind. Hyg. Assoc. J V. 48, N 1. P. 73ｨC Aoyama T., Yashiro T. Analytical study of low-concentration gases. IV. Investigation of the reaction by trapping nitrogen dioxide in air using the triethanolamine method // J. Chromatogr V P. 69ｨC Wei Y., Oshima M., Simon J., Motomizu S. The application of the chromatomembrane cell for the absorptive sampling of nitrogen dioxide followed by continuous determination of nitrite using a micro-flow injection system // Talanta. 22. V. 57. P. 355ｨC Massman W.J. A review of molecular diffusivities of H 2 O, CO 2, CH 4, CO, SO 2, NH 3, N 2 O, NO and NO 2 in air, O 2 and N 2 near STP // Atmos. Environ V. 32. P. 1111ｨC1127. V.A. Poddubnyi, N.A. Yushketova. Method of passive sampling for measurement of nitrogen dioxide in atmospheric air. Passive sampling is a simple low-cost method for assessment of concentrations of gases in air. In comparison with standard methods, the precision of the results of passive sampling measurements is more influenced by meteorological and methodological factors. Results of theoretical and experimental studies of a number of factors, which influence the precision of the results of passive sampling measurements of ambient NO 2 are presented. Comparison of passive sampling method and reference methods (sorption tubes, chemiluminescent gas analyzer) under moderate continental climate conditions demonstrated systematical statistically significant underestimation of concentrations, measured by passive samplers method. It was shown that the difference observed is accounted for the drawbacks of the model commonly used for treatment of passive sampling data; the model does not take into account particularities of interaction between NO 2 and sorbent solution that are related to the influence of relative humidity. A new NO 2 passive sampling model based on available data on interaction between NO 2 and a sorbent solution was developed. Application of the model allowed us to improve agreement between NO 2 concentrations calculated from passive sampling data and those measured by reference methods, to eliminate systematical and statistically significant difference between the datasets. 2ｨｰ61 7ｨ 99ｨｨ9ｨｪ66 6ｨｰｨ 68ｨ 786ｨ 157 ｨｨ4ｨｬ282ｨｪｨｨｨｦ 1ｨｨ6ｨｺ9ｨｨ1ｨ ｨ 46ｨｰｨ 9 ｨ ｨｰｨｬ6928ｨｪ6ｨｬ 9641ｨｮ ｨｰｨｨｨｺｨ ｨ ｨｰｨｬ69284 ｨｨ 6ｨｺ2ｨ ｨｪｨ, 1 9.