|
|
- ちとら かむら
- 5 years ago
- Views:
Transcription
1 Sn Ag Cu Effect of Addition Elements on Creep Properties of the Sn Ag Cu Lead Free Solder Megumi NAGANO*, Noboru HIDAKA*, Hirohiko WATANABE*, Masayoshi SHIMODA* and Masahiro ONO* * * Production Technology Laboratory of Fuji Electric Advanced Technology Co., Ltd. (1 Fujimachi, Hino-shi, Tokyo, ) 40 C125 C 2 Sn Ag Cu Sn 3.5Ag 0.5Cu Ni Ge Sn 3.0Ag 0.5Cu Sn 3.5Ag 0.5Cu Ni Ge Sn 3.0Ag 0.5Cu 125 C 5MPaSn 3.5Ag 0.5Cu Ni Ge Sn 3.0Ag 0.5Cu 3 TEM Abstract Creep properties of two lead-free solder alloys, Sn 3.5Ag 0.5Cu Ni Ge and Sn 3.0Ag 0.5Cu, were investigated at temperatures between 40 C and 125 C. It is found that the creep strength of Sn 3.5Ag 0.5Cu Ni Ge solder is better than that of Sn 3.0Ag 0.5Cu solder. Especially in the low stress region at 125 C, the creep rupture time of Sn 3.5Ag 0.5Cu Ni Ge solder is about three times longer than that of Sn 3.0Ag 0.5Cu solder. Microstructure characterizations, including TEM analysis, were conducted in order to fully describe the creep properties of the lead-free solders. Key Words: Sn 3.5Ag 0.5Cu Ni Ge Solder, Lead-Free Solder, Creep Property, Microstructure, Dislocation, Stacking Fault EU RoHS Sn Ag Cu Ni, Ge Ge Sn 1),2) Ni Ni 3) Sn Ag Cu (Ni, Ge) 2. NiGe Sn 3.5Ag 0.5Cu 0.07Ni 0.01Ge Sn 3.5Ag 0.5Cu Ni Ge JEITA Sn 3.0Ag 0.5Cu 2 Table C SUS 14 mm 160 mm 30 Fig. 1(a)(b) 15 mm 3mm 60 C 24 Fig. 2 Table 2 3 (40 C, 75 C, 125 C) 2 Vol. 9 No. 3 (2006) 171
2 Table 1. Chemical composition of solder alloys Alloy No. Sn Ag Cu Ni Ge Sn 3.0Ag 0.5Cu Rem Sn 3.5Ag 0.5Cu Ni Ge Rem Fig. 3 Strength strain curve of both solders at 25 C and strain rate of s 1 Fig. 1 Appearance of the test specimen Fig. 4 Strength strain curve of both solders at 125 C and strain rate of s 1 Fig. 2 Miniature creep testing machine Ni X (TEM) Table 2. Creep test conditions 3. Test temp. Load stress (MPa) 40 C 14.7, C 9.8, C 5.0, 9.8 #2400 (0.25 mm)ph Ar (SEM) 3.1 3) 125 C Sn 3.0Ag 0.5Cu Sn 3.5Ag 0.5Cu Ni Ge s 1 Fig. 3Fig. 4 Sn 3.5Ag 0.5Cu Ni Ge Sn 3.0Ag 0.5Cu 3) 125 C 172 Vol. 9 No. 3 (2006)
3 Fig. 5 Creep curves of the Sn 3.5Ag 0.5Cu Ni Ge solder and the Sn 3.0Ag 0.5Cu solder at 40 C Fig. 8 The creep strength of the Sn 3.5Ag 0.5Cu Ni Ge and the Sn 3.0Ag 0.5Cu solders Fig. 6 Fig. 7 Creep curves of the Sn 3.5Ag 0.5Cu Ni Ge solder and the Sn 3.0Ag 0.5Cu solder at 75 C Creep curves of the Sn 3.5Ag 0.5Cu Ni Ge solder and the Sn 3.0Ag 0.5Cu solder at 125 C 4) 3.2 Fig. 5 Fig. 7 Sn 3.0Ag 0.5Cu Sn 3.5Ag 0.5Cu Ni Ge Fig C75 C Sn 3.0Ag 0.5Cu 125 C 9.8 MPa 5MPa Sn 3.0Ag 0.5Cu Sn 3.5Ag 0.5Cu Ni Ge 3 Fig. 9Fig. 10 Norton (1) e ss As n (1) e ss s n A Fig. 11 Fig. 12 Sn 3.5Ag 0.5Cu Ni Ge Sn 3.0Ag 0.5Cu Fig. 9Fig. 10 (1)Fig. 11Fig. 12 n Table 3 n n ),6) Table 3 40 C Sn 3.5Ag 0.5Cu Ni GeSn 3.0Ag 0.5Cu n 11 5)7) 125 C n Sn 3.0Ag 0.5Cu n 5.9 n 5 Vol. 9 No. 3 (2006) 173
4 Fig. 9 Creep rate vs. normalized time for Sn 3.5Ag 0.5Cu Ni Ge solder Fig. 12 Relation between the stress and steady-state creep rate (Sn 3.0Ag 0.5Cu) Fig. 10 Creep rate vs. normalized time for Sn 3.0Ag 0.5Cu solder Fig. 13 Correlation of rupture time with Larson Miller parameter Table 3. The stress exponent of the solder alloys Alloy No. 40 C 75 C 125 C Sn 3.0Ag 0.5Cu Sn 3.5Ag 0.5Cu Ni Ge Fig. 11 Relation between the stress and steady-state creep rate (Sn 3.5Ag 0.5Cu Ni Ge) Larson Miller Fig. 13 C 8) 11 2 Sn 3.0Ag 0.5Cu Sn 3.5Ag 0.5Cu Ni Ge Fig. 14 Arrhenius (2) e As n exp (Q/RT) (2) R Q Fig. 14 Q Q 4950 kj/mol Sn 174 Vol. 9 No. 3 (2006)
5 (102 kj/mol) 1/2 Sn 5),9)12) 3.3 Fig. 15 SEM b-sn Ag 3 Sn/Cu 6 Sn 5 b-sn 13) Sn 3.0Ag 0.5Cu Sn 3.5Ag 0.5Cu Ni Ge b-sn Fig C Fig. 16(a)(c) Sn 3.0Ag 0.5Cu NiGe Sn 3.5Ag 0.5Cu Ni Ge Fig. 16(b)(d) 125 C 200 Fig. 14 Arrhenius plots of strain rate and reciprocal temperature Sn 3.0Ag 0.5Cu 0.5 mm mm Sn 3.5Ag 0.5Cu Ni Ge 0.5 mm 14),15) Sn 3.0Ag 0.5Cu Sn 3.5Ag 0.5Cu Ni Ge Sn 3.5Ag 0.5Cu Ni Ge (125 C)Sn 3.0Ag 0.5Cu b-sn Sn 3.5Ag 0.5Cu Ni Ge Sn 3.5Ag 0.5Cu Ni Ni X Fig. 17 Ni X Ni Cu 6 Sn 5 (110) Ni 0.25% Ni 3 Sn 2 (110) Table 4 Ni 2q (3) Bragg d Fig. 15 Microstructure of the lead-free solders Vol. 9 No. 3 (2006) 175
6 Fig. 16 Microstructures of the Sn 3.0Ag 0.5Cu solder and the Sn 3.5Ag 0.5Cu Ni Ge solder Table 4. The plane intervals (d) calculated by measured diffraction angle (2q) Amount of Ni addition (wt%) 2q ( ) d (Å) Fig. 17 Relation between amount of Ni content, and X- ray diffraction peak near to Sn (220) peak 2d sinqnl (3) l X Cu K a ; l Åd q n Sn Ag Cu Ni Cu 6 Sn 5 (Cu,Ni) 6 Sn 5 16),17) Cu Å Ni Å 18) Cu 6 Sn 5 Cu Ni (TEM) Fig. 18(a)(b)Sn 3.5Ag 0.5Cu Ni Ge TEM Fig. 18(a) b- Sn mm Fig. 18(b) mm 176 Vol. 9 No. 3 (2006)
7 Fig. 18 TEM micrograph of the Sn 3.5Ag 0.5Cu Ni Ge solder Fig. 19 EDX mapping analyses of the Sn 3.5Ag 0.5Cu Ni Ge after creep test at 125 C for 550 h Fig. 19 AgSn CuNiSn 2 Fig. 20 TEM EDX Fig. 21 Ag 3 Sn Cu 6 Sn 5 JCPDS Fig. 21(b)Cu 6 Sn 5 (110) 2.09 Å 0.07%Ni X 4. 2 Sn Ag Cu Sn 3.0Ag 0.5CuSn 3.5Ag 0.5Cu Ni Ge 40 C 125 C 1) 40 C 75 C Sn 3.0Ag 0.5Cu Sn 3.5Ag 0.5Cu Ni Ge 125 C Sn 3.5Ag 0.5Cu Ni Ge 3 2) (125 C) Vol. 9 No. 3 (2006) 177
8 Fig. 20 The point analyses of particles in the Sn 3.5Ag 0.5Cu Ni Ge solder after creep test at 125 C for 550 h Fig. 21 Electronic diffraction pattern of the particles in the Sn 3.5Ag 0.5Cu Ni Ge solder after creep test at 125 C for 550 h 3) TEM 4) Sn Ag Cu Ni Cu Sn X Ni Cu 6 Sn 5 Cu (Cu, Ni) 6 Sn ) 7 pp , ) M. Nagano, N. Hidaka, M. Shimoda and H. Watanabe: Effect of Germanium Content on Oxidation Prevention of Sn Ag Cu Lead-Free Solder, Proc. of PSEA04, pp , ) Sn Ag Cu Ni Ge Vol. 8, No.6, pp , ) 9 pp , ) Vol. 8, No. 2, pp , ) Sn 3.5Ag xbi Sn 3.5Ag xcu 6 pp , ) p. 318, ) Sn Ag Bi In Pb 3 pp , Vol. 9 No. 3 (2006)
9 9) R. J. Mccabe and M. E. Fine: Creep of Tin, Sb-Solution- Strengthened Tin, and SbSn Precipitate-Strengthened Tin, Metallurgical and Materials Transactions A, p. 1531, ) S. H. Suh, J. B. Cohen and J. Weertman: Metall. Trans. A, Vol. 14A, p. 117, ) F. A. Mohamed, K. L. Murty and J. W. Morris: Metall. Trans., Vol. 4, p. 935, ) 10 pp , ) 9 pp , ) N. Hidaka, M. Nagano, M. Shimoda, H. Watanabe and M. Ono: Creep Properties and Micro-structure of the Sn Ag Cu Ni Ge Lead-Free Solder Alloy, ASME, IPACK ) Sn Ag Cu 11 pp , ) S. Terashima, Y. Kariya and M. Tanaka: Improvement on Thermal Fatigue Properties of Sn 1.2Ag 0.5Cu Flip Chip Interconnects by Nickel Addition, Materials Transactions, Vol. 45, No. 3, pp , ) C. B. Lee, S. J. Suh, Y. E. Shin, C. C. Shur and S. B. Jung: The Growth Kinetics of Inter-metallic Compound Layer at the Interface between Sn 3.5Ag Base Solder and (Cu, Electroless Ni- P/Cu, Immersion Au/Ni-P/Cu) Substrate, 8th Symposium on Microjoining and Assembly Technology in Electronics, pp , ) p. 37, 2004 Vol. 9 No. 3 (2006) 179
CuおよびCu‐Sn系化合物のSn‐Pbはんだ濡れ性解析
61 Wettability of Cu and Cu-Sn Intermetallic Compound by Sn-Pb Solder Alloy Hisaaki Takao, Nobuyuki Yamamoto, Hideo Hasegawa CuCu-Sn Cu 150 C 2h55nmCu 2 O Cu Cu-Sn 5nm Cu-Sn Cu SnCu-Sn Wettability of Cu
More information第1章 溶接法および機器
670 ) ) ) ) 2.1 ) 42 671 Sn T m K. T m. T m. T m 2.2 JIS BAl BPd Al-Si Al-Mn KAlF -K AlF H O Ni 43 672 Sn-In Zn EU RoHS ) Pb Cd Hg JIS Z ( ) ) ) 3.1 44 673. MO HX MX H O M X (d) Young sf lf cos sl sf lf
More information特-7.indd
Mechanical Properties and Weldability of Turbine Impeller Materials for High Temperature Exhaust Gas Turbocharger 1 000 1 050 246 IN100 The increase in environmental awareness in recent years has led to
More information環境負荷低減に向けた低温接合技術
Low-Temperature Soldering Technology for Environmental Burden Reduction あらまし Sn - Bi Sb.5 mass Sn-Sb Sn-Bi Sn-Bi4 4 PC Sn - Ag - Cu 4518 3 Sn-Bi-Sb Abstract Fujitsu has successfully developed a new lead-free
More information電子部品はんだ接合部の熱疲労寿命解析
43 Evaluation for Thermal Fatigue Life of Solder Joints in Electronic Components Haruhiko Yamada, Kazuyoshi Ogawa 2 63Sn- 37Pb 95Pb-5Sn Si Cu Si 63Sn-37Pb Since automotive electronic components are used
More information渡辺(2309)_渡辺(2309)
[ 29 p. 241-247 (2011)] ** *** ** ** Development of a nickel-based filler metal containing a small amount of silicon by WATANABE Takehiko, WAKATSUKI Ken, YANAGISAWA Atsusi and SASAKI Tomohiro Authors tried
More informationFig. 1 Sampling positions from the ingot. Table 2 Chemical compositions of base metal (%) Fig. 2 (unit: mm) Shape and size of fatigue test specimen. T
Friction welding of ADC 12 aluminum alloy diecastings Kazuyoshi KATO* and Hiroshi TOKISUE* Both squeeze and gravity castings of ADC 12 aluminum alloy were friction-welded, using a brake type welding machine.
More informationMikio Yamamoto: Dynamical Measurement of the E-effect in Iron-Cobalt Alloys. The AE-effect (change in Young's modulus of elasticity with magnetization
Mikio Yamamoto: Dynamical Measurement of the E-effect in Iron-Cobalt Alloys. The AE-effect (change in Young's modulus of elasticity with magnetization) in the annealed state of iron-cobalt alloys has been
More informationFig. 4. Configuration of fatigue test specimen. Table I. Mechanical property of test materials. Table II. Full scale fatigue test conditions and test
(J. Soc. Mat. Sci., Japan), Vol. 52, No. 11, pp. 1351-1356, Nov. 2003 Fatigue Life Prediction of Coiled Tubing by Takanori KATO*, Miyuki YAMAMOTO*, Isao SAWAGUCHI** and Tetsuo YONEZAWA*** Coiled tubings,
More informationAl-Si系粉末合金の超塑性
Superplasticity of Al-Si P/M Alloys Satoru Ishihara, Mikio Kondoh, Kazuhiko Itoh Al-17Si-4.5Cu-0.5Mg-(06)Fe-(02)Mm ( Mm : ) (i) (ii) Si(iii) Fe (iv) Mm Al-17Si-4.5Cu-0.5Mg500 10 2 s 1 520 110 1 s 1 Si
More informationJ. Jpn. Inst. Light Met. 65(6): 224-228 (2015)
65 62015 224 228 ** Journal of The Japan Institute of Light Metals, Vol. 65, No. 6 (2015), 224 228 2015 The Japan Institute of Light Metals Investigation of heat flow behavior on die-casting core pin with
More informationCorrosion Wear of Alloy Tool Steel (SKD 11) Coated with VC and Precipitation Hardening Stainless Steel (SUS 630) in Sodium Chloride Aqueous Solution T
Corrosion Wear of Alloy Tool Steel (SKD 11) Coated with VC and Precipitation Hardening Stainless Steel (SUS 630) in Sodium Chloride Aqueous Solution Toshiyuki TANAKI*, Makoto YUASA** and Isao SEKINE***
More informationThe Effect of the Circumferential Temperature Change on the Change in the Strain Energy of Carbon Steel during the Rotatory Bending Fatigue Test by Ch
The Effect of the Circumferential Temperature Change on the Change in the Strain Energy of Carbon Steel during the Rotatory Bending Fatigue Test by Chikara MINAMISAWA, Nozomu AOKI (Department of Mechanical
More informationFig. 1. Relation between fatigue crack propagation rate and stress intensity factor range. Fig. 2. Effect of stress ratio on fatigue crack opening rat
Fatigue Crack Propagation and Fracture Surface in Polyvinyl Chloride by Tetsuro SHIRAISHI The fatigue crack propagation behavior and the fracture surface appearance under several load conditions in polyvinyl
More information錫-亜鉛-アルミニウム系鉛フリーはんだの実用化
- Practical Use of Lead-Free Tin-Zinc-Aluminum (Sn-Zn-Al) Solder - - - - - Abstract Fujitsu has implemented a company-wide effort to progressively reduce the use of lead and eventually eliminate this environmental
More informationX X 1. 1 X 2 X 195 3, 4 Ungár modified Williamson-Hall/Warren-Averbach 5-7 modified modified Rietveld Convolutional Multiple Whole Profile CMWP 8 CMWP
X X a a b b c Characterization of dislocation evolution during work hardening of stainless steels by using XRD line-profile analysis Tomoaki KATO a, Shigeo SATO a, Yoichi SAITO b, Hidekazu TODOROKI b and
More informationThe Phase Behavior of Monooleoylglycerol-Water Systems Mivoshi Oil & Fat Co.. Ltd. Faculty of Science and Technology, Science University of Tokyo Inst
The Phase Behavior of Monooleoylglycerol-Water Systems Mivoshi Oil & Fat Co.. Ltd. Faculty of Science and Technology, Science University of Tokyo Institute of Colloid and Interface Science, Science University
More informationUDC : ' : '24' : '24'26' : : A Study of Condition of Pits Formation and Their Fe
UDC 620.193: 669.15'26-194.3: 669.15'24'26-194.3: 669.15'24'26'28-194.3: 669.141.24: 621.385.833.2 A Study of Condition of Pits Formation and Their Features in Chloride Solution Norio FUKASAKO, Hirokazu
More informationTable 1. Shape and smelting properties of chrome ores as delivered. Table 2. Chemical composition of chrome ores (%). Table 3. Chemical composition of
UDC 669.263.1: 669.046.462 The Reduction Process and Reducibility of Chromite with Carbon Hiroshi G. KATAYAMA and Akihiko TANAKA Synopsis: In the present work, various chrome ores and relatively pure chromites
More informationFig. 1. Schematic drawing of testing system. 71 ( 1 )
1850 UDC 669.162.283 : 669.162.263.24/. 25 Testing Method of High Temperature Properties of Blast Furnace Burdens Yojiro YAMAOKA, Hirohisa HOTTA, and Shuji KAJIKAWA Synopsis : Regarding the reduction under
More informationInfluence of Material and Thickness of the Specimen to Stress Separation of an Infrared Stress Image Kenji MACHIDA The thickness dependency of the temperature image obtained by an infrared thermography
More informationThe Evaluation of LBB Behavior and Crack Opening Displacement on Statically Indeterminate Piping System Subjected to Monotonic Load The plastic collap
The Evaluation of LBB Behavior and Crack Opening Displacement on Statically Indeterminate Piping System Subjected to Monotonic Load The plastic collapse and LBB behavior of statically indeterminate piping
More informationPlasticity-Induced Martensitic Transformation in Austenitic Stainless Steels SUS 304 and SUS 316 L at Room and Liquid Nitrogen Temperatures (Quantitat
Plasticity-Induced Martensitic Transformation in Austenitic Stainless Steels SUS 304 and SUS 316 L at Room and Liquid Nitrogen Temperatures (Quantitative Measurement using X-ray Diffraction Method) Yoshifumi
More information資源と素材
(Shigen to Sozai) Vol.116 p. 285 290 (2000) 共存硫酸塩を含む強酸性 MnSO 4 溶液中のオゾン酸化によって生成した沈殿の X 線回折および放電特性 * 西村忠久 1 梅津良昭 2 X-ray Diffraction and Discharge Behavior of Precipitates Produced by Ozone Oxidation in
More informationS-5.indd
Development and pplication of Ultrasonic Noise B-scan nalysis ( I-CLT ) Creep Damage ssessment for Fossil-Fuel Boiler Piping precise creep damage assessment method has been required for boiler plants using
More informationVol. 19, No. 3 (2012) 207 Fig. 2 Procedures for minute wiring onto polyimide substrate. Fig. 3 Ink - jet printing apparatus as part of laser sintering
206 : 316-8511 4-12 - 1 Laser Sintering Characteristics of Silver Nanoparticle Paste for Electronics Packaging YAMASAKI Kazuhiko, MAEKAWA Katsuhiro (Received January 10, 2012) Ibaraki University, Faculty
More informationContinuous Cooling Transformation Diagrams for Welding of Mn-Si Type 2H Steels. Harujiro Sekiguchi and Michio Inagaki Synopsis: The authors performed
Continuous Cooling Transformation Diagrams for Welding of Mn-Si Type 2H Steels. Harujiro Sekiguchi and Michio Inagaki Synopsis: The authors performed a series of researches on continuous cooling transformation
More informationSize Effect of Biomass on Carbonization Rate Treated in Superheated Steam Combined with Far Infrared Heating Akiko ISA Yoshio HAGURA and Kanichi Kit Graduate School of Biosphere Science, Hiroshima University,
More informationFig.1 A location map for the continental ultradeep scientific drilling operations.
Application of a Synthetic Smectite to the Ultradeep Scientific Drilling Operations Makoto KOGA Nitchitsu Co., Ltd. Resources Development Devision, Powder Technological Laboratory 351-1 Kamitano, Arakawa-mura,
More informationVol. 21, No. 2 (2014) W 3 mm SUS304 Ni 650 HV 810 HV Ni Ni Table1 Ni Ni μm SUS mm w 50 mm l 3 mm t 2.2 Fig. 1 XY Fig. 3 Sch
110 : 565-0871 2-1 567-0871 11-1 660-0811 1-9 - 1 tanigawa@jwri.osaka - u.ac.jp Influence of Laser Beam Profile on Cladding Layer TANIGAWA Daichi, ABE Nobuyuki, TSUKAMOTO Masahiro, HAYASHI Yoshihiko, YAMAZAKI
More informationUDC '24'26'-192: Strengthening of Ultra-low Carbon Ni-Cr Steel by Precipitation Hardening Isao KIMURA, Hiroshi YADA, and Mitsuo HONDA
UDC 669.15'24'26'-192: 621.785.78 Strengthening of Ultra-low Carbon Ni-Cr Steel by Precipitation Hardening Isao KIMURA, Hiroshi YADA, and Mitsuo HONDA Synopsis: In order to obtain a new age-hardening steel,
More informationInstability of Aerostatic Journal Bearings with Porous Floating Bush at High Speeds Masaaki MIYATAKE *4, Shigeka YOSHIMOTO, Tomoaki CHIBA and Akira CH
Instability of Aerostatic Journal Bearings with Porous Floating Bush at High Speeds Masaaki MIYATAKE *4, Shigeka YOSHIMOTO, Tomoaki CHIBA and Akira CHIBA Department of Mechanical Engineering, Tokyo University
More information(Shigen to Sozai) Vol.116 p (2000) 石炭灰フライアッシュからのゼオライトのアルカリ水熱合成と生成物の陽イオン交換特性 * 1 1 村山憲弘山川洋亮 2 3 小川和男芝田隼次 Alkali Hydrothermal Synthesis of Zeol
石炭灰フライアッシュからのゼオライトのアルカリ水 Title 熱合成と生成物の陽イオン交換特性 Author(s) 村山, 憲弘, 山川, 洋亮, 小川, 和男, 芝田, 隼次 Citation 資源と素材 : 資源 素材学会誌, 116(4): 279-284 Issue Date 2000 URL http://hdl.handle.net/10112/5454 資源 素材学会 (http://www.jstage.jst.go.
More informationTable 2 C, Al and Nb contents of samples (%) Table 3 C, Al and Nb contents of samples (%) Table 4 C, Al and Nb contents of samples (%) 6
Study on the Weldability of Ni Base Superalloy (Part 7) Improvement of Hot Crack Sensitivity of Inconel 713C and its Mechanical Properties by Hiroshi Ikawa, Shigeo Shin, Yoshikuni Nakao, Haruo Yawata and
More informationStudy on Throw Accuracy for Baseball Pitching Machine with Roller (Study of Seam of Ball and Roller) Shinobu SAKAI*5, Juhachi ODA, Kengo KAWATA and Yu
Study on Throw Accuracy for Baseball Pitching Machine with Roller (Study of Seam of Ball and Roller) Shinobu SAKAI*5, Juhachi ODA, Kengo KAWATA and Yuichiro KITAGAWA Department of Human and Mechanical
More informationRate of Oxidation of Liquid Iron by Pure Oxygen Shiro BAN-YA and Jae-Dong SHIM Synopsis: The rate of oxidation of liquid iron by oxygen gas has been s
Rate of Oxidation of Liquid Iron by Pure Oxygen Shiro BAN-YA and Jae-Dong SHIM Synopsis: The rate of oxidation of liquid iron by oxygen gas has been studied using a volume constant technique. The process
More information磁気測定によるオーステンパ ダクタイル鋳鉄の残留オーステナイト定量
33 Non-destructive Measurement of Retained Austenite Content in Austempered Ductile Iron Yoshio Kato, Sen-ichi Yamada, Takayuki Kato, Takeshi Uno Austempered Ductile Iron (ADI) 100kg/mm 2 10 ADI 10 X ADI
More information42 1 Fig. 2. Li 2 B 4 O 7 crystals with 3inches and 4inches in diameter. Fig. 4. Transmission curve of Li 2 B 4 O 7 crystal. Fig. 5. Refractive index
MEMOIRS OF SHONAN INSTITUTE OF TECHNOLOGY Vol. 42, No. 1, 2008 Li 2 B 4 O 7 (LBO) *, ** * ** ** Optical Scatterer and Crystal Growth Technology of LBO Single Crystal For Development with Optical Application
More informationFig. la PL spectra of PSL prepared on Si specimen (p = 1 k Q m) with electrochemical etching in HF solution (26wt %) under galvanostatic conditions of
Vol.47,No.11,1996 Influence of Electrochemical Etching Current Density on Porous Si Luminescence Properties and Microstructure Kazuhiro SHIGYO *, Masahiro SEO *, Kazuhlsa AZUMI * and Hideaki TAKAHASHI
More information特-4.indd
1 000 Ni-Cr Tribological Characteristics of Ni-Cr Alloy at 1 000 C in Air R&D 1 000 Ni-Cr 1 000 Ni-Cr alloy sliding tests in atmosphere at 1 000 C were carried out and the process in which a glazed oxide
More informationA2, Vol. 69, No. 2 Vol. 16, I_237-I_246, Analytical Investigation of Shear Force Distribution of Perfobond Strip with Plural Perforations * ** *
A2, Vol. 69, No. 2 Vol. 16, I_237-I_246, 213. Analytical Investigation of Shear Force Distribution of Perfobond Strip with Plural Perforations * ** *** **** ***** Noriyuki KUBO, Takeshi SAKAI, Shinji OHGUCHI,
More informationThe Evaluation on Impact Strength of Structural Elements by Means of Drop Weight Test Elastic Response and Elastic Limit by Hiroshi Maenaka, Member Sh
The Evaluation on Impact Strength of Structural Elements by Means of Drop Weight Test Elastic Response and Elastic Limit by Hiroshi Maenaka, Member Shigeru Kitamura, Member Masaaki Sakuma Genya Aoki, Member
More informationステンレス鋼用高性能冷間鍛造油の開発
Development of High Performance Cold Forging Oil for Stainless Steel Toshihide Ohmori, Kazuhiko Kitamura ClP ( ) Cl P-Zn ( P ) ClP-Zn High performance cold forging oil for stainless steel has been developed
More information第62巻 第1号 平成24年4月/石こうを用いた木材ペレット
Bulletin of Japan Association for Fire Science and Engineering Vol. 62. No. 1 (2012) Development of Two-Dimensional Simple Simulation Model and Evaluation of Discharge Ability for Water Discharge of Firefighting
More informationSafety Performance of Steel Deck Plate (Flat Decks) Used for Concrete Slab Moulding CONTENTS 1. Introduction ---------------------------------------------------------------- (2) 2. Flat Decks ------------------------------------------------------------------
More informationn-jas09.dvi
Vol. 9 (2009 12 ), No. 03-091211 JASCOME CREEP ANALYSIS DISCONTINUOUS ROCK MASS AROUND UNDERGROUND CAVERN 1) 2) 3) Takakuni TATSUMI, Hidenori YOSHIDA and Masumi FUJIWARA 1) ( 761-0396 2217-20, E-mail:
More informationStudy on Application of the cos a Method to Neutron Stress Measurement Toshihiko SASAKI*3 and Yukio HIROSE Department of Materials Science and Enginee
Study on Application of the cos a Method to Neutron Stress Measurement Toshihiko SASAKI*3 and Yukio HIROSE Department of Materials Science and Engineering, Kanazawa University, Kakuma-machi, Kanazawa-shi,
More informationFundamental Study on the SOX Gas Sensor Utilizing Beta-Alumina with Sputtered Praseodymium Oxide Thin Films by Shinya YAO1*, Kenji MIYAGAWA1, Shigeru
Fundamental Study on the SOX Gas Sensor Utilizing Beta-Alumina with Sputtered Praseodymium Oxide Thin Films by Shinya YAO1*, Kenji MIYAGAWA1, Shigeru IIJIMA2 and Zensaku KOZUKA1 1. Faculty of Engineering,
More informationEffect of Autofrettage on Fatigue Crack Growth Rate for High Pressure Reactors For high pressure reactor vessels such as for polyethylene production,
Effect of Autofrettage on Fatigue Crack Growth Rate for High Pressure Reactors For high pressure reactor vessels such as for polyethylene production, autof rettage is used extensively to have the fatigue
More informationLNG Tank-Its Structure, the Materials and Welding Techniques Yasunosuke OGAWA, Mitsuhiro SAKAMOTO, Kiyoaki TOYOMASU, Mitsuo OHYAMA, Munemitsu FUKAGAWA, and Yoshinori SAIGA Table 2. Material list for various
More informationX線分析の進歩36 別刷
X X X-Ray Fluorescence Analysis on Environmental Standard Reference Materials with a Dry Battery X-Ray Generator Hideshi ISHII, Hiroya MIYAUCHI, Tadashi HIOKI and Jun KAWAI Copyright The Discussion Group
More informationTable 1 Experimental conditions Fig. 1 Belt sanded surface model Table 2 Factor loadings of final varimax criterion 5 6
JSPE-54-04 Factor Analysis of Relationhsip between One's Visual Estimation and Three Dimensional Surface Roughness Properties on Belt Sanded Surface Motoyoshi HASEGAWA and Masatoshi SHIRAYAMA This paper
More information橡
Mein Grad. Eng Univ. Fri'kill, Vol. 61 March 20 I 3) Effects of Saline-Water Volume on Production Performance of Tubular Solar Still Hiroaki TERASAKI*, Takahiro YAMAJI" and Teruyuki FUKUHARA. (Received
More information無電解めっきとレーザー照射による有機樹脂板上へのCuマイクロパターン形成
Title 無電解めっきとレーザー照射による有機樹脂板上への Cu マイクロパターン形成 Author(s) 菊地, 竜也 ; 和智, 悠太 ; 坂入, 正敏 ; 高橋, 英明 ; 飯野, 潔 ; 片山, 直樹 Citation 表面技術, 59(8): 555-561 Issue Date 2008-08 Doc URL http://hdl.handle.net/2115/36647 Type
More information1. Precise Determination of BaAl2O4 Cell and Certification of the Formation of Iron Bearing Solid Solution. By Hiroshi UCHIKAWA and Koichi TSUKIYAMA (
1. Precise Determination of BaAl2O4 Cell and Certification of the Formation of Iron Bearing Solid Solution. By Hiroshi UCHIKAWA and Koichi TSUKIYAMA (Central Research Laboratory, Onoda Cement Co., Ltd.,
More information走査型プローブ顕微鏡によるラテックス/デンプンブレンドフィルムの相分離状態の観察
紙パ技協誌, 53(3): 107-113(1999) * 1 Observation of Separated Domains in SB-latex/Starch blend film by Scanning Probe Microscope Toshiharu Enomae and Fumihiko Onabe Graduate School of Agricultural and Life
More information鉛フリー無電解Niめっき皮膜中の共析物がはんだ実装信頼性に及ぼす影響
Title: 鉛フリー無電解 Ni めっき皮膜中の共析物がはんだ実装信頼性に及ぼす影響 Authors: 土田徹勇起, 大久保利一, 狩野貴宏, 荘司郁夫 Issue Date:2013 年 1 月 20 日 Publisher: 一般社団法人エレクトロニクス実装学会 Citation: エレクトロニクス実装学会誌 Vol.16 No.6(2013)484-491 次ページより本文を掲載致します 論文1.
More information** Department of Materials Science and Engineering, University of California, Los Angeles, CA 90025, USA) Preparation of Magnetopulmbite Type Ferrite
** Department of Materials Science and Engineering, University of California, Los Angeles, CA 90025, USA) Preparation of Magnetopulmbite Type Ferrite Thin Films by Dip-Coating Method and Magnetic Properties
More information研究成果報告書
., SUS34 Inconel6, Cr,.,, Cr,. Cr Cr,., Cr,,,.,,,,.,.,,,.,,.,,., SUS34, Inconel6,. (). CoZrNb, -2 m.,., 9. Cu, 2 m. SUS34, Inconel6 SUS34, Inconel6, 5mm mmmm.,,,. (2) (HP8752A).,. - MHz, -2 dbm.,. (3)
More information卒業論文
Cu-Ru ...7 1.1....7 1.2....7 1.3....8...9 2.1....9 2.1.1....9 2.1.2....10 2.2.... 11 2.2.1.... 11 2.2.2. ()...12 2.2.3. ()...13 2.2....15...18 3.1. Cu z ...18 3.1.1....18 3.1.2....19 3.1.3....29 3.2.
More informationCHEMOTHERAPY APR Fig. 1 Chemical structure of cefotetan (CTT, YM09330)
CHEMOTHERAPY APR. 1982 Fig. 1 Chemical structure of cefotetan (CTT, YM09330) VOL.30 S-1 CHEMOTHERAPY Fig. 2 Comparison of standard curves of CTT on various test organisms by cylinder plate method Column
More information第七回道路橋床版シンポジウム論文報告集 Experimental Study on Fatigue Resistance of RC Slab with UFC Panel for Wheel Running Fatique Test * ** ** *** **** Kazuhiko Minaku
第七回道路橋床版シンポジウム論文報告集 Experimental Study on Fatigue Resistance of RC Slab with UFC Panel for Wheel Running Fatique Test ************ Kazuhiko Minakuchi, Tadashi Abe, Tetsukazu Kida, Satoshi Tanaka and Yuuki
More information九州大学学術情報リポジトリ Kyushu University Institutional Repository 看護師の勤務体制による睡眠実態についての調査 岩下, 智香九州大学医学部保健学科看護学専攻 出版情報 : 九州大学医学部保健学
九州大学学術情報リポジトリ Kyushu University Institutional Repository 看護師の勤務体制による睡眠実態についての調査 岩下, 智香九州大学医学部保健学科看護学専攻 https://doi.org/10.15017/4055 出版情報 : 九州大学医学部保健学科紀要. 8, pp.59-68, 2007-03-12. 九州大学医学部保健学科バージョン : 権利関係
More informationEvaluation of the Microstructures of CSP Microjoints with Sn-Ag Lead-Free Solders Ikuo SHOHJI *, Fuminari MORI * *, Shinichi FUJIUCHI * * and Masaru Y
Evaluation of the Microstructures of CSP Microjoints with Sn-Ag Lead-Free Solders Ikuo SHOHJI *, Fuminari MORI * *, Shinichi FUJIUCHI * * and Masaru YAMASHITA * * * *Card Engineering, Yasu, IBM Japan,
More informationperature was about 2.5 Ž higher than that of the control irrespective of wind speed. With increasing wind speeds of more than 1m/s, the leaf temperatu
Studies on the Row Covering Methods of Vinylon Cheesecloth to Prevent Cold Injury in Cabbage Daizou IGARASHI*, Masumi OKADA** and Keiichl NAKAYAMA*** *Miura Branch, Kanagawa Horticultural Experiment Station,
More informationJournal of Japan Institute of Light Metals, Vol. 58, No. 2 (2008), pp
58 00847 53 * ** ** Journal of Japan Institute of Light Metals, Vol. 58, No. 008, pp. 47 53 Production of aluminum tall container with flange by hydraulic bulging with compression of surrounding material
More informationTime Variation of Earthquake Volume and Energy-Density with Special Reference to Tohnankai and Mikawa Earthquake Akira IKAMi and Kumizi IIDA Departmen
Time Variation of Earthquake Volume and Energy-Density with Special Reference to Tohnankai and Mikawa Earthquake Akira IKAMi and Kumizi IIDA Department of Earth Sciences, Nagoya University (Received January
More information_14.indd
Thermal Characteristics of Japanese Clothing and Western Clothing Yukari Yogi and Isako Nomiyama Key Words : 13 12 4 5 6 13 10 C 50% 10% 1 1 A A B B A B 1 2 A B 2 A 2 A - 1 + + A - 2 A - 1 A - 3 A - 2
More informationFig. 2 Signal plane divided into cell of DWT Fig. 1 Schematic diagram for the monitoring system
Study of Health Monitoring of Vehicle Structure by Using Feature Extraction based on Discrete Wavelet Transform Akihisa TABATA *4, Yoshio AOKI, Kazutaka ANDO and Masataka KATO Department of Precision Machinery
More informationTitle インジウムを添加した Ag-Au-Cu-Pd 系合金の物性 Author(s) 時崎, 照彦 ; 服部, 雅之 ; 小田, 豊 Journal 歯科材料 器械, 26(5-6): URL Right Post
Title インジウムを添加した Ag-Au-Cu-Pd 系合金の物性 Author(s) 時崎, 照彦 ; 服部, 雅之 ; 小田, 豊 Journal 歯科材料 器械, 26(5-6): 367-374 URL http://hdl.handle.net/10130/420 Right Posted at the Institutional Resources for Unique Colle
More informationFig. ph Si-O-Na H O Si- Na OH Si-O-Si OH Si-O Si-OH Si-O-Si Si-O Si-O Si-OH Si-OH Si-O-Si H O 6
NMR ESR NMR 5 Fig. ph Si-O-Na H O Si- Na OH Si-O-Si OH Si-O Si-OH Si-O-Si Si-O Si-O Si-OH Si-OH Si-O-Si H O 6 Fig. (a) Na O-B -Si Na O-B Si Fig. (b) Na O-CaO-SiO Na O-CaO-B -Si. Na O-. CaO-. Si -. Al O
More informationMikio Yamamoto : Young's Modulus of Elasticity and Its Variation with Magnetization in Ferromagnetic Nickel-Copper Alloys. Young's modulus of elastici
Mikio Yamamoto : Young's Modulus of Elasticity and Its Variation with Magnetization in Ferromagnetic Nickel-Copper Alloys. Young's modulus of elasticity and its change with magnetization, that is, the
More informationEffect of Cooking Water ph on Commercial Sterility in the Production of Cooked Rice Packed under Semi-aseptic Condition Kinya SAKUMAl, Haruhiko KATODA1, Tetsuya FUKAYA2, Toshio JOH3, Akira IT03 and Atsuo
More information0801297,繊維学会ファイバ11月号/報文-01-青山
Faculty of Life Environment, Kinjogakuin University, Moriyama-ku, Nagoya 463-8521, Japan Faculty of Home Economics, Japan Women s University, Bunkyo-ku, Tokyo 112-8681, Japan AStudy on Easing by a Variable
More information技術研究所 研究所報 No.80
Calculating Temperatures in Concrete Elements Exposed to Fire by Hideto Saito and Takeshi Morita Abstract Six concrete-filled steel tube column specimens without fire protection measures were subjected
More informationViscosity of Ternary CaO-SiO2-Mx (F, O)y and CaO-Al2O3-Fe2O3 Melts Toshikazu YASUKOUCHI, Kunihiko NAKASHIMA and Katsumi MORI Synopsis : Effects of add
Viscosity of Ternary CaO-SiO2-Mx (F, O)y and CaO-Al2O3-Fe2O3 Melts Toshikazu YASUKOUCHI, Kunihiko NAKASHIMA and Katsumi MORI Synopsis : Effects of additives (Li2O, Na2O, K2O, MgO, BaO, Al2O3, Fe2O3, TiO2,
More information16 Dissolution Rate of Alumina into Molten CaO-SiO2--Al2O3-MgO Slags Shoichirou TAIRA, Kunihiko NAKASHIMA and Katsumi MORI Synopsis : Dissolution rate
16 Dissolution Rate of Alumina into Molten CaO-SiO2--Al2O3-MgO Slags Shoichirou TAIRA, Kunihiko NAKASHIMA and Katsumi MORI Synopsis : Dissolution rates of sintered alumina into molten CaO-SiO2-9mass%Al2O3-10mass%MgO
More informationAuthors' Abstract It in known that the method of feeding powder into split cell affects the adhesion forces of powder beds, especially in fine particle powders. But the effect of the agglomeration phenomenon
More informationEvaluation of Anisotropy and Preferred Orientation of Carbon and Graphite Materials Yoshihiro Hishiyama Fig.1 Diffraction condition in Fourier space.
Evaluation of Anisotropy and Preferred Orientation of Carbon and Graphite Materials Yoshihiro Hishiyama Fig.1 Diffraction condition in Fourier space. Corresponding Author, E-mail: yhishiya@eng.musashi-tech.ac.jp
More information9) H. SCHMCLZRIED: Z. Elektrochem. 66 (l%1) p ) W. D. KINGERY et al.: J. Am. Chem. Soc., 42 (1959), p ) F. HUND: Z. Phys. Chem., 199 (195
9) H. SCHMCLZRIED: Z. Elektrochem. 66 (l%1) p. 572 10) W. D. KINGERY et al.: J. Am. Chem. Soc., 42 (1959), p.394 11) F. HUND: Z. Phys. Chem., 199 (1952), p. 142 12) J. F. ELLIOTT and M. GLEISER: " Thermochemistry
More informationLaser Ablation Dynamics of Amorphous Film of a Cu-Phthalocyanine Derivative Masahiro HOSODA*,**, Hiroshi FURUTANI*,**. Hiroshi FUKUMURA*,** Hiroshi MASUHARA*, Masanobu NISHII*** Nobuyuki ICHINOSE**,***,
More informationClustering in Time and Periodicity of Strong Earthquakes in Tokyo Masami OKADA Kobe Marine Observatory (Received on March 30, 1977) The clustering in time and periodicity of earthquake occurrence are investigated
More information三校永谷.indd
(J. Agric. Meteorol.) 64 (4): 281 288, 2008 * * * ** *** **** * ** *** **** Analysis of Movement of Cooled Air in Shinjuku Gyoen Yui NAGATANI*, Kiyoshi UMEKI*, Tsuyoshi HONJO*, Hirofumi SUGAWARA**, Kenichi
More informationuntitled
2M5-24 SM311 SM332 3 4 e30mm 5 e30mm [2M5-24] 0-5 -10-15 -20-150-125-100-75-50 -25 0 25 50 75 100 125 150 0-5 -10-15 -20-150-125-100-75-50 -25 0 25 50 75 100 125 150 0-5 -10-15 -20-150-125-100-75-50 -25
More informationRefurbishment of Creep Damage Using Re-Heat Process for Ni-Based Superalloy under Bending Load
(Journal of the Society of Materials Science, Japan), Vol. 60, No. 3, pp. 202-209, Mar. 2011 Ni Refurbishment of Creep Damage Using Re-Heat Process for Ni-Based Superalloy under Bending Load by Masaru
More information248 Nippon Shokuhin Kagaku Kogaku Kaishi Vol. /-, No./,,.2,/. (,**0) 12 * * * Microencapsulation of Glutamine with Zein by a Solvent Evaporation Metho
248 Nippon Shokuhin Kagaku Kogaku Kaishi Vol. /-, No./,,.2,/. (,**0) 12 * * * Microencapsulation of Glutamine with Zein by a Solvent Evaporation Method in Reverse Multiple Emulsion Masato Tanaka*, Yoshinari
More informationJFE(和文)No.4-12_下版Gのコピー
JFE No. 4 245 p. 6358 Electrical Steels for Advanced Automobiles Core Materials for Motors, Generators, and High-frequency Reactors SENDA Kunihiro JFE NAMIKAWA JFEMisao HAYAKAWA JFEYasuyuki JNE JNEH JGE
More information土木学会構造工学論文集(2009.3)
Vol. A (9 3 Slip resistance and fatigue strength of friction type of high strength bolted connections with laser cutting holes Eiji Iwasaki, Tatsuya Yamano, Takeshi Mori ( 94-2188 163-1 ( 649-111 137-1
More information(43) Vol.33, No.6(1977) T-239 MUTUAL DIFFUSION AND CHANGE OF THE FINE STRUCTURE OF WET SPUN ANTI-PILLING ACRYLIC FIBER DURING COAGULATION, DRAWING AND
(43) Vol.33, No.6(1977) T-239 MUTUAL DIFFUSION AND CHANGE OF THE FINE STRUCTURE OF WET SPUN ANTI-PILLING ACRYLIC FIBER DURING COAGULATION, DRAWING AND DRYING PROCESSES* By Hiroshi Aotani, Katsumi Yamazaki
More informationレーザ誘起蛍光法( LIF法) によるピストンの油膜挙動の解析
Analysis of Piston Oil Film Behavior by Using Laser Induced Fluorescence Method Shuzou Sanda, Akinori Saito ( Laser Induced Fluorescence Method LIF ) LIF Scanning -LIF Abstract Analysis of the oil film
More informationYuzo Nakamura, Kagoshima Univ., Dept Mech Engr. perfect crystal imperfect crystal point defect vacancy self-interstitial atom substitutional impurity
perfect crystal imperfect crystal point defect vacancy self-interstitial atom substitutional impurity atom interstitial impurity atom line defect dislocation planar defect surface grain boundary interface
More information5b_08.dvi
, Circularly Polarized Patch Antennas Combining Different Shaped Linealy Polarized Elements Takanori NORO,, Yasuhiro KAZAMA, Masaharu TAKAHASHI, and Koichi ITO 1. GPS LAN 10% [1] Graduate School of Science
More informationA Study on Throw Simulation for Baseball Pitching Machine with Rollers and Its Optimization Shinobu SAKAI*5, Yuichiro KITAGAWA, Ryo KANAI and Juhachi
A Study on Throw Simulation for Baseball Pitching Machine with Rollers and Its Optimization Shinobu SAKAI*5, Yuichiro KITAGAWA, Ryo KANAI and Juhachi ODA Department of Human and Mechanical Systems Engineering,
More informationFig. 3 Flow diagram of image processing. Black rectangle in the photo indicates the processing area (128 x 32 pixels).
Fig. 1 The scheme of glottal area as a function of time Fig. 3 Flow diagram of image processing. Black rectangle in the photo indicates the processing area (128 x 32 pixels). Fig, 4 Parametric representation
More informationalternating current component and two transient components. Both transient components are direct currents at starting of the motor and are sinusoidal
Inrush Current of Induction Motor on Applying Electric Power by Takao Itoi Abstract The transient currents flow into the windings of the induction motors when electric sources are suddenly applied to the
More information橡
CO2 Laser Treatment of Tinea Pedis Masahiro UEDA:,' Kiyotaka KITAMURA** and Yukihiro GOKOH*** Table I Specifications 1. Kind of Laser 2. Wavelength of Lasers. Power of Laser. Radiation Mode. Pulse Duration.
More informationuntitled
20 * Re-Evaluation of Isoseismal Maps and Magnitudes from Two Big Earthquakes along the Subduction Zone of Kyushu and Ryukyu Islands Early in the 20th Century Masayuki TAKEMURA, Katsuhisa KANDA Kobori
More informationStress Singularity Analysis at an Interfacial Corner Between Anisotropic Bimaterials Under Thermal Stress Yoshiaki NOMURA, Toru IKEDA*4 and Noriyuki M
Stress Singularity Analysis at an Interfacial Corner Between Anisotropic Bimaterials Under Thermal Stress Yoshiaki NOMURA, Toru IKEDA*4 and Noriyuki MIYAZAKI Department of Mechanical Engineering and Science,
More information