24 澱 粉科 学 第39巻 Fig. 1. Photomicrographs A, stamp 1.搗 1)餅 Fig,1に (LM)で type ; B, mixer type ; SEM, scanning of various electron Mochi. micrograph ; LM,

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1 23 Physical Characteristics of Mochi Nobuhiro NAGASHIMA Musashigaoka College (111-1, Minamiyoshimi, Yoshimimachi, Hikigun, Saitama, , Japan) The physical characteristics after aging of Mochi prepared by several methods were studied and the following results were obtained:., 1) Mochi prepared by stamping exhibited much of the initial rice grain structure, while that prepared by a power mixer was of a well-mashed paste form rather than rice grain tissue 2) The hardness of each type of Mochi measured by a rheolometer depended on the storage conditions : Mochi prepared by a mixer was softer than by stamping with no storage that prepared by a mixer was harder than by stamping after storing for 3 hr at 5 Ž., while. 3) The creep curves of Mochi measured by a rheoner could be explained by a six-element mechanical model consisting of Hookean body, two pairs of Voigt bodies and a Newtonean body. The shift factor-1/t relationship for Mochi stored at Ž resulted in two straight lines, a refraction point being observed at 50 Ž ; however, no such phenomenon was observed for Mochi stored -20 Ž. 4) The cooking loss of Mochi stored at 5 Ž decreased with increasing storage time that of the Mochi stored at -20 Ž hardly changed. Mochi prepared by stamping showed a small cooking loss after storage at 5 and -20 Ž, respectively., while 5) The crystalline structure of raw glutinous rice could be classified as a type-a pattern although this pattern disappeared upon heating and was transformed into a type-b pattern after, storing at 5 Ž for one week. In the case of Mochi stored at -20 Ž, the crystallinity was never recovered. 6) The viscosity of Mochi measured by a Brabender viscograph after storing at 5 Ž showed a maximum value of 800 to 1000 B. U., while that stored at -20 Ž showed a maximum value of 200 to 300 B. U. The viscosity of the latter reached a peak after storing for 72 hr decreased with a further period of storage., and then

2 24 澱 粉科 学 第39巻 Fig. 1. Photomicrographs A, stamp 1.搗 1)餅 Fig,1に (LM)で type ; B, mixer type ; SEM, scanning of various electron Mochi. micrograph ; LM, light micrograph. な 組 織 細 胞 の 違 い が 物 性 に 大 き く影 響 す る もの と 考 え た. き 方 別 餅 生 地 の 物 理 的 性 質20,23,247 2)餅 生地 の組織構 造 走 査 型 電 子 顕 微 鏡(SEM)お 第1号(1992) 生 地 の テ ク ス チ ャー レオ ロ メ ー タに よ る餅 生 地 の テ ク ス チ ャ ー の 結 果 よび 光 学 顕 微 鏡 観 察 した 搗 き方 別 餅 生 地 の 一 例 を 示 した.餅 生 (Fig.2),硬 た.こ さ と粘 りは 冷蔵 保 存 の 経 過 と と も に増 加 し の うち 硬 さで は 調 製 直 後 は ス タ ンプ 式 が,保 存3 地 の 組 織 は 大 別 す る と糯 米 粒 組 織 の 残 存 部,こ れ ら米 粒 時 間 後 は 逆 に ミキ サ ー式 が 高 い 値 を 示 した.同 様 に 剪 断 細 胞 よ り流 出 した 澱 粉 ペ ー ス トお よび 調 製 時 に混 入 す る 強 度 の 測 定 を した 結 果,テ 気 泡 とか ら構 成 され て い る18).電 動 ス タ ンプ式 餅 生 地 は 傾 向 を示 し た.針 比 較 的 残 存 米 粒 が 多 く,そ の 粒 径 も大 きい こ と,電 動 ミ 搗 き方 別 を 問 わ ず 調 製 直 後 の 餅 生 地 は 針 入 度 が190ュ キ サ ー式 は 糯 米 粒 が 細 か く破 壊 され,残 ニ ッ ト,す な わ ち 生 地 の 厚 み の90%以 存 米粒の粒 径が クス チ ャ ー の 硬 さの 結 果 と同 入度 の 測 定 結 果 をFig.3に 示 した が, 上 の針 入 が あ 小 さ く,し か も米 粒 細 胞 か ら流 出 した 澱 粉 ペ ー ス トや 気 った.こ れ を 冷 蔵 保 存 した24時 間 後の餅生地 の針入度 泡 の 量 が 多 い こ とが 観 察 され た した が っ て,こ の よ う で は,い ず れ の 方 式 で も生 地 の 厚 み の20%以 下 まで激

3 Fig. 2. Texture of various Mochi by rheolometer. Fig. 3. Time course of penetration of Mochi at 20t.

4 Fig. 4. Effect of temperature on the Young's modulus and viscosity of Mochi (stamp type) stored at 5 Ž and-20 Ž.

5 Table 1. Apparent activation energy of Mochi. (kj/mol) Fig. 5. Time course of cooking loss of Mochi. The symbols are the same as those for Fig. 3.

6 Fig. 6, X-ray diffraction patterns of Mochi on storage at various temperatures.

7 Fig. 7. Brabender viscograms of Mochi on storage at various temperatures.

8

9

10 Am. J. Glin. Nutr., 32, (1979). 6) M. MELLIS, R. 3ANDACEK et al.: Am. J. Gun. Nutr., 37, (1983). 7) F. MATTSON, E. HOLLENBACH and C. KUEHL THAU : J. Nutr. 109, (1979). 10) C. A. BERNHARDT : Food Tech. Int. Eur., (1988). 11) D. GARDNER and R. SANDERS : J. Am. Oil Chem. Soc., 67, (1990). 12) Food Chem. News, April 3, (1989). 13) G. P. RIzzI and H. M. TAYLOR : J. Am. Oil Chem Soc., 55, (1978). 14) U. S. Patent, 4, 517, 360 (1985). 15) J. Am. Oil Chem. Sac., 65, (1988). 16) Inform, 2, (1991).

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