,977 t 157,977 t mg l mg l BOD 9398 % OH = cm 3 / sec 11 = cm 3 / sec OH = /
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1 CAS , 2-1, 2- H 2 C CH CH 3 C 3 H 6 O % , , % 2 d d , = kpa 400 mmhg kpa 445 mmhg20 5 log Pow , 2-5 m/z Koc = 30 Pow 40.5 % w/w ppm = 2.41 mg/m 3, 20 1 mg/m 3 = ppm O
2 ,977 t 157,977 t mg l mg l BOD 9398 % OH = cm 3 / sec 11 = cm 3 / sec OH = /cm = l / secoh = /cm ,2- ph ph % NaCl ph ph % % Pow 13 log Pow = 0.18 log Pow = log Pow = log Pow =
3 ppb ppb ppm B/A B/A B/A B/A 55 0 / / B/A 4. LC 50 mg l EC 50 mg l OECD : Selenastrum capricornutum 15, h : 16 15, 16 Daphnia magna Lepomis macrochirus 4, 11, 12, 15, 16 Gambusia 4, 11, 12, 15 affinis Mugil 11, 12, 15, 16 ceohalus Salmo mykiss 15 Bacillus subtillus 15 Dacus dorsalis h h h h h h : 3, m harmful OECD OECD OECD
4 , 16, 17 1 LD ,140 mg/kg 630 mg/kg mg/kg LC 50 4,000 ppm 4-h 1,740 ppm 4-h LD 50 7,168 mg/kg 1,244-1,500 mg/kg , mg/kg/day 5 / mg/kg/day mg/kg/day 2 6 / 5 / ppm 600 ppm 1500 ppm 6 / 5 / ppm 7 / 5 / ppm7 / 5 / 6 11, 16, 17 5 In vitro TA1535/pSK1002 umu HGPRT CHO In vivo mg/kg CD mg/kg SD 298 ppm 7 / 5 CD mg/kg ppm 7 / 5 / 1-9
5 5 11, 16, 17, 18, 19, 20, 21 6 EPA 1994 EU 1994 B2 2 NTP 1994 IARC B ACGIH 1996 A B SD 1560 mg/kg/week NTP B6C3F ppm 6 / 5 / ppm 400 ppm 400 ppm 1/ ppm 2/50 NTP F ppm 6 / 5 / ppm 3 NMRI mg/ 1 / mg/ ppm ppm 6 / ppm 7 / ppm ppm 7 / ppm 7 / 5 / 2
6 6 11, 16, 17, 20, ,500 ppm mg/m mg/m mg/m , ACGIH ppm 48 mg/m In vitro ,2-1,2- in vitro DNA
7 7 8. OECD harmful 9. 1 in vitro in vivo OH OECD harmful
8 ,, ,, Handbook of Environmental Data on Organic Chemicals, 2nd Ed., Van Nostrand Reinhold Co ,, C Log P,. 7 NIST Library of 54K Compounds. 8 Lyman, W. J., et al., Handbook of Chemical Property Estimation Method, pp ,. 10,,, IPCS, Environmental Health Criteria Hazardous Substance Data Bank HSDB, National Library of Medicine, Mackay, D., Environ. Sci. Technol. 16, , IUCLID International Uniform Chemical Information Data Base, EU. 16 BUA Report IARC, Monographs on the Evaluation of Carcinogenic Risks of Chemicals to Humans, 36, JETOC,,, IARC, Monographs on the Evaluation of Carcinogenic Risks of Chemicals to Humans, List of IARC Evaluations ACGIH, Threshold Limit Values and Biological Exposure Indices , 38,
9 9 mg/ l 10,000 1, h h h h h h LC 50 EC Handbook of Environmental Data on Organic Chemicals, 2nd Ed., Van Nostrand Reinhold Co IPCS, Environmental Health Criteria Hazardous Substance Data Bank HSDB, U.S. National Library of Medicine IUCLID International Uniform Chemical Information Data Base, EU. 5 BUA Report
10 10 B6C3F ppm 6 / 5/ ppm /50 0/50 5/50 0/50 0/50 3/50 0/50 0/50 5/50 0/50 0/50 2/50 1/50 1/50 2/50 F ppm / 5/ ppm /50 0/50 2/50 0/50 0/50 3/50 SD 1560 mg/kg/week 1,2 112 mg/kg/week /50 2/50 19/50 NMRI mg/mouse :1/ 95 mg/mouse /200 3/100 2/100 12/100 15/ IARC, Monographs on the Evaluation of Carcinogenic Risks of Chemicals to Humans, IPCS, Environmental Health Criteria BUA Report
11 11 ppm 6h/d5d/w13w 6h/d5d/w103w 6h/d5d/w103w 2y 7h/d3w+6-10d 1,
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1 97 7 3 1312 CAS 85 68 7 O BBP 1, 2- C 19 H 20 O 4 312.4 C C O O O (CH 2 ) 3 1 99.9 % 1. 2-35 3 2, 3 370 3, 4 199 d 25 4 1.117 2 10.8 = 1 5 1.15 10-3 Pa 8.6 10-6 mmhg 20 5 253 Pa 1.9 mmhg 200 5 log Pow
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