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ありかつすえたけ
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1 Bull. Nagoya Univ. Museum No. 20, 79 91, 2004 Quantitative chemical analysis of rocks with X-ray fluorescence analyzer XRF-1800 NAKAZAKI Mineko TSUBOI Motohiro KANAGAWA Kazuyo KATO Takenori SUZUKI Kazuhiro Center for Chronological Research, Nagoya University, Chikusa, Nagoya , Japan Graduate School of Enviromental Studies, Nagoya University, Chikusa, Nagoya , Japan Abstract This paper describes analytical procedures to determine 10 major and 15 trace elements in silicate rocks, using an X-ray fluorescence analyzer (Shimadzu SXF 1800) with a Rh target at the Center for Chronological Research, Nagoya University. Analyses are carried out on glass bead prepared through fusion of sample and flux (Li 2 B 4 O 7 ) mixture in the proportion of 0.7g : 6.0g for major elements (Si, Ti, Al, Fe, Mn, Mg, Ca, Na, K, P ) and 2g : 3g for trace elements (V, Cr, Co, Ni, Cu, Zn, As, Rb, Sr, Y, Zr, Nb, Ba, Pb, Th). Calibration curves for the major elements cover a wide compositional range of igneous, metamorphic and sedimentary silicate rocks. Calibration curves for the trace elements are corrected for spectral line-overlap and matrix effect, and carry out reliable analyses at concentration above 2-10ppm. 79

2 θ θ α α α α α 80

3 αα αα α α θ αα α αα α 81

4 JB-1a JB-2 JB-3 JG-1a JG-2 JG-3 JGb-1 JA-1 JA-2 SiO TiO Al 2 O Fe 2 O 3 * MnO MgO CaO Na 2 O K 2 O P 2 O H 2 O (+) H 2 O ( ) Total JA-3 JR-1 Ol-neph CO01 CO02 CO C 2401D 2401F SiO TiO Al 2 O Fe 2 O 3 * MnO MgO CaO Na 2 O K 2 O P 2 O H 2 O (+) H 2 O ( ) Total

5 JA-1 JA-2 JA-3 JB-1a JB-2 JB-3 JF-1 JF-2 JG-1a V Cr Co Ni Cu Zn Rb Sr Y Zr Nb Ba Pb Th As JG-2 JG-3 JGb-1 JP-1 JR-1 JR-2 Ol-neph 9G3 9B1a V Cr Co Ni Cu Zn Rb Sr Y Zr Nb Ba Pb Th As R2 13F1 14G1a 14B3 15B1a JB2As1 JB2As2 JB2As3 JB2Pb V Cr Co Ni Cu Zn Rb Sr Y Zr Nb Ba Pb Th As

6 84

7 α αα α αα α αα α SiO TiO Al 2 O Fe 2 O MnO MgO CaO Na 2 O K 2 O P 2 O Total

8 θ α α α α α α α α α α θ α β β α α α α α β α α α α α α α α α α α α α α α α θ αααα 86

9 θ α αααα α θ θ α β α β α β α β α β α α α ββ α β I VKα = I VKα * k I TiKα 87

10 α θ θ θ α β θ θ α β α β α β α β α β α α α I VKα = I* VKα I TiKα I CrKα = I* CrKα I VKα I CrKα = I* CrKα (I* VKα I TiKα ) 88

11 I YKα = I* YKα IRbKα I NbKα = I* NbKα I YKα I NbKα = I* NbKα (I* YKα IRbKα ) I Zr Kα = I* Zr Kα I SrKα I BaLα = I* BaLα I TiKα β α Wi = ( a I 2 + b I + c ) (1 + Σdj Wj ) σ = I Peak +IBackground 2IBackground ; I peak I background c= 3 2IBackground /( A t)t σ α β α α β β α α β 89

12 90

13 Imai, N., Terashima, S., Itoh, S. and Ando, A. (1995) 1994 compilation values for GSJ reference samples, Igneous rock series. Geochemical J., 29, Suzuki, K. (1986) Enrichment of incompatible elements at grain-boundaries of olivine in an olivinenephelinite. Geochemical J., 20,

X線分析の進歩36 別刷

X線分析の進歩36 別刷 X X X-Ray Fluorescence Analysis on Environmental Standard Reference Materials with a Dry Battery X-Ray Generator Hideshi ISHII, Hiroya MIYAUCHI, Tadashi HIOKI and Jun KAWAI Copyright The Discussion Group