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1 Physical Chemistry I (Basic Chemical Thermodynamics) [I] [II] [III] [IV] Introduction Energy(The First Law of Thermodynamics) Work Heat Capacity C p and C v Adiabatic Change Exact(=Perfect) Differential

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固体物理の基礎 サンプルページ この本の定価 判型などは, 以下の URL からご覧いただけます. http://www.morikita.co.jp/books/mid/066581 このサンプルページの内容は, 初版 1 刷発行当時のものです. http://www.morikita.co.jp/support ( 03 3817 5670 FAX03 3815 8199) i 1 2 5 6

nm (T = K, p = kP a (1atm( )), 1bar = 10 5 P a = atm) 1 ( ) m / m

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1 9 v.0.1 c (2016/10/07) Minoru Suzuki T µ 1 (7.108) f(e ) = 1 e β(e µ) 1 E 1 f(e ) (Bose-Einstein distribution function) *1 (8.1) (9.1)

1 9 v..1 c (216/1/7) Minoru Suzuki 1 1 9.1 9.1.1 T µ 1 (7.18) f(e ) = 1 e β(e µ) 1 E 1 f(e ) (Bose-Einstein distribution function) *1 (8.1) (9.1) E E µ = E f(e ) E µ (9.1) µ (9.2) µ 1 e β(e µ) 1 f(e )

master.dvi

4 Maxwell- Boltzmann N 1 4.1 T R R 5 R (Heat Reservor) S E R 20 E 4.2 E E R E t = E + E R E R Ω R (E R ) S R (E R ) Ω R (E R ) = exp[s R (E R )/k] E, E E, E E t E E t E exps R (E t E) exp S R (E t E )

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December 28, 2018

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128 3 II S 1, S 2 Φ 1, Φ 2 Φ 1 = { B( r) n( r)}ds S 1 Φ 2 = { B( r) n( r)}ds (3.3) S 2 S S 1 +S 2 { B( r) n( r)}ds = 0 (3.4) S 1, S 2 { B( r) n( r)}ds

127 3 II 3.1 3.1.1 Φ(t) ϕ em = dφ dt (3.1) B( r) Φ = { B( r) n( r)}ds (3.2) S S n( r) Φ 128 3 II S 1, S 2 Φ 1, Φ 2 Φ 1 = { B( r) n( r)}ds S 1 Φ 2 = { B( r) n( r)}ds (3.3) S 2 S S 1 +S 2 { B( r) n( r)}ds

No δs δs = r + δr r = δr (3) δs δs = r r = δr + u(r + δr, t) u(r, t) (4) δr = (δx, δy, δz) u i (r + δr, t) u i (r, t) = u i x j δx j (5) δs 2

No.2 1 2 2 δs δs = r + δr r = δr (3) δs δs = r r = δr + u(r + δr, t) u(r, t) (4) δr = (δx, δy, δz) u i (r + δr, t) u i (r, t) = u i δx j (5) δs 2 = δx i δx i + 2 u i δx i δx j = δs 2 + 2s ij δx i δx j