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12 6 DPPH 13 C-NMR Ethyl protocatechuate quercetin-taxifolin luteolin eriodictyol methyl caffeate methyl hydrocaffeate Catechol: 13 C NMR acetone-d6 125 MHz C C C-3-6Materska 2003Fig. 10-A. Ethyl protocatechuate: 13 C NMR acetone-d6 125 MHz C=O150.7 C C C C C CH CH3 Materska 2003Fig. 10-C. Quercetin: 13 C NMR acetone-d6 125 MHz C C C C-8a148.3 C C C C C C C C C-4a99.2 C C-8Markham 1976Fig. 12-A. -Taxifolin: 13 C NMR acetone-d6 125 MHz C C C C-8a146.6 C C C C C C-4a97.1 C C C C-3Markham 1976Fig. 12-C. Luteolin: 13 C NMR acetone-d6 125 MHz C C C C-8a148.9 C C C C C C C C-4a103.0 C C C-8Materska Eriodictyol: 13 C NMR acetone-d6 125 MHz C C C C-8a145.2 C C C C C C C-4a95.6 C C C C-3Matsuda Fig C NMR analyses acetone-d6 125 MHz to examine the reactivity of catechol and ethyl protocatechuate with DPPH. Acatechol mmol ; Breaction mixture of catechol mmol and DPPH mmol ; C ethyl protocatechuate mmol ; Dreaction mixture of ethyl protocatechuate mmol and DPPH mmol ; EDPPH mmol was added to a mixture of catechol mmol and ethyl protocatechuate mmol. 1 4-dioxane external standard ; 1 1-diphenyl-2-picrylhydrazine; remaining peaks of ethyl protocatechuate.

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