化学入門1.ppt
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- うたろう ひろき
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1 ! () ()( )()!!! 1013:Y : Wikipedia
2
3
4
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6 !! αβγ 238 U (238) 206 Pb (206) βγ 18 F (18) 18 O (18) PET
7 P
8 235 U + n 95 Mo La + 2n 238 U Pu 239 Pu
9
10 Jöns : Wikipedia
11 !!!!
12 ,,,,
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15 ,
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17 !!!! (ao 3 ),,,,, aso 4,,
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19 ,
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21 (ZnO 2 ) vs 100
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23 ( 4 ) ( 3-3 )
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26 4 10,,,
27 (Isomers) 7 14! (Structural Isomers) Stereoisomers) 3 (Z)-isomer Achiral 3 (E)-isomer hiral Geometric Isomers) Diastereomers) Enantiomers) (R) 3 3 (R) (S) 3 (S) 3 (R) 3 (S) 3 (S) 3 3 (R) Achiral
28 (Enantiomer) (hiral) (hirality) (Achiral)! O F Br (R)-enantiomer! O Br F Br Br F Br Br O Br F (S)-enantiomer F O Br F O F Br
29 O O (R)-arvone! (S)-arvone! (S)-Limonene! (R)-Limonene!
30 O OMe 2 2 O O β O O
31 R O) R (O)O)
32 ,,
33 O O O O O O O O, ) ()
34 O 2 OO OO 2 OO O OO 2 OO O O OO OO
35 O O O O O,
36
37 a 2+ Mg 2+ l 2
38 2 O OOR 1 2 O OR 1 2 O O + OOR 2 OOR 3 2 O O OR 2 OR O R 1, R 2, R 3 2 2,,, (EPA) (DA), 2 2 O O O OR 1 OR 2 OR NaO 2 2 O O O + R 1 OONa R 2 OONa R 3 OONa
39 DA DA DA DA DA DA DALDL 20ω-6 ω-6 DA ω-3 ω-3ω-6ω-3 : Wikipedia
40
41 nm
42
43 g2000, born in purple)
44 O O O O N O N O,
45
46 ,,,,,
47 , , % vs 95%,,
48
49 -2 190,
50 -, 6,6- OO( 2 ) 4 OO 2 N( 2 ) 6 N 2 (6) (6) OO( 6 4 )OO O( 2 ) 2 O
51
52 -1,,, 1909, O I O II
53 -1,,,
54 - O 2 N N 2 + O
55
56
57 ,,
58 ,,
59 S 2
60 , ,, PET,,
61 3.13),,,
62 50% SBR [],,
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