apple ｦ0 09 apple ｦ apple0309apple076 56ｦ fl 0603apple6ｦ

Transcription

1 1305ｨｬ ｨｦ00ｨｦ07ｨ ｨｹ ｨ ｨｦ00ｨｦ07ｨ ｨｹ, 2009, 6ｧ8 6, 06. 1ｨC18 ｨｬ /21; ｨ 05ｨｺｨｦ0700ｨｦ07ｨ 02ｨ ｨｹ ｨｪ00ｨｺ020200ｨｲ ｨ 05ｨｪｨｦｨｮ04ｨ 01ｨｦ05 05ｨｬ ｨｬｨｪ04ｨｦ050501ｨ 09 ( ｨｹ ｨｮ02ｨｪ0102) apple ｦ0 1, ｦ06 5apple , 00. ｨｨ ｦ0 3, ｦ ｨ ｦ ｨｦ ｨｺ0204, apple0601, ｨ ｦ ｨｦ ｨｺ0204, ｨｨ0003apple07086ｦ ｦ0030ｹ06ｦ , ｨ apple6ｦ ｨｦ ｨｺ0204, apple0601, ｨｨ ｦ0 6 5 apple00 6ｦ0010ｷ3090ｸ ｨｨapple ｸ8 apple ｦ0030ｸ apple ｹ ｦ00009fl 0300apple036ｦ ｸ ｹ ｦ0006ｦ ｨｦ08apple , 0ｹ00307 apple6ｦ apple0ｸ fl0ｸ apple076 50ｸ ｸ8 0300apple036ｦ ｸ ｸ76ｦ ｦ ｸ903 6ｦ ｦ ｸ ｦ apple apple6ｦ ｹ ｹ , ｸ90ｹ06ｦ0fl apple ｸ800 (ｨｺｨ ｨｴ) ｦ ｸ8 (ｨｴｨｨ07). ｨ 006ｦ00ｹ ｸ ｦ0apple096ｦ00ｷ ｦ001apple apple ｦ apple6ｦ apple076 5 apple6ｦ ｹ0-000ｸ ｹ ｦ0090ｸ86 56ｦ00ｸ ｦ0 apple6ｦ009000ｸ ｸ apple0309apple076 56ｦ00009fl 09 03apple6ｦ apple036ｦ apple ｹ apple076 56ｦ ｦ0096ｦ00007, 0ｹ ｦ000000ｸ apple036ｦ ｸ ｸ apple0309apple076 56ｦ fl 08apple ｨB ｦ0apple6ｦ0036ｦ apple0ｸ apple000ｸ ｦ0006ｦ ｸ apple090ｹ fl ｦ000000ｸ ｸ ｸ ｷ apple6ｦ00ｷ ｦ0006ｦ0, 6 56ｦ0006ｦ0 09fl, 03apple07036ｦ0, fl, ｦ ｦ0, ｨｺｨ ｨｴ, ｨｴｨｨ ｸ ｹ ｹ apple030ｸ8 006ｦ fl 0ｹ apple6ｦ apple6ｦ003 (6 7026ｦ ｸ apple6ｦ , ｸ800 6ｦ ｦ ｸ8) apple6ｦ ｦ0fl 06apple00 6ｦ ｸ ｸ ｹ ｸ803 0ｹ ｨ ｷ apple09apple076 56ｦ apple apple ｸ fl03 036ｦ apple07fl ｨ apple ｹ apple036ｦ ｸ ｹ , apple6ｦ0096 7apple04086ｦ00ｸ90ｸ fl 006ｦ ｦ apple6ｦ00300apple6ｦ003 6ｦ ｸ ｦ , 096ｦ fl ｷ applefl 6ｦ0 0ｹ ｹ ｸ ｦ apple076 5, ｸ90ｸ ｦ0 036ｦ ｦ003090ｹ ｸ909 0ｸ8, fl0ｸ90ｸ fl 0703 apple6ｦ ｦ0-6 56ｦ apple070ｷ ｦ apple00000ｷ3096ｦ00ｷ30909 ( ) apple ｸ ｦ ｦ003090ｹ apple6ｦ ｦ000090ｹ apple apple6 5040ｸ9 070ｹ000apple00 00, 006ｦ apple086ｦ ｹ ｹ , 6ｦ0 036ｦ ｹ ｦ0apple6ｦ apple , ｦ00ｸ90ｸ apple apple036ｦ ｸ803 apple6ｦ apple fl apple6ｦ009 6ｦ fl ｸ909 6ｦ0 6 7apple ｸ80309 (6 56ｦ ｸ80309) ｦ00309, ｸ909 / apple000ｸ ｸ8. ｨｴ ｦ fl ｸ apple ｦ apple ｹ apple ｹ ｦ apple ｦ00000, 6ｦ0 036ｦ apple apple000ｸ apple6ｦ00ｷ ｸ ｦ ｦ008000ｸ ｦ apple apple- 0309apple076 56ｦ00009fl ｦ000090ｹ apple03 fl6 502fl000306fl ｦ ｸ76ｦ00ｸ90ｸ ｦ ｸ ｸ7, apple0ｸ ｷ309apple apple040ｸ903. ｨｨapple09 0ｹ ｦ ｹ apple07-0ｷ ｦ0 0ｹ apple6ｦ0010ｷ ｹ ｹ ｸ76ｦ0-0ｸ90ｸ apple ｦ fl 0300apple036ｦ ｸ80309 apple6ｦ apple6ｦ00309, ｸ90ｸ ｦ ｸ ｸ apple- 000ｸ [30]. ｨｨ07fl fl ｦ ｹ apple6ｦ00304apple fl ｦ000000ｸ apple apple apple070ｹ ｷ ｹ ｦ ｷ3096ｦ00ｷ309fl apple036ｦ ｸ ｦ003 6ｦ ｸ ｦ [2, 29, 30, apple.] fl0ｸ ｹ ｷ ｸ ｹ ｹ , apple0ｸ ｦ00ｸ apple6ｦ ｹ0-000ｸ803 0ｹ ｹ ｸ ｹ , 0207apple0309apple04fl ｹ0000ｸ apple ｸ800 apple6ｦ apple0ｸ apple ｹ ｦ000000ｸ apple ｦ ｹ apple076 56ｦ00009fl 0207apple03 006ｦ fl 0ｹ apple6ｦ apple6ｦ003 02fl apple006ｦ ｸ fl apple apple fl 08apple ｦ apple ｦ apple070300apple036ｦ ｸ ｨB ｦ0, 6ｦ0 036ｦ fl apple070ｷ ｸ8 08apple fl0ｸ apple070ｷ apple6ｦ00ｷ ｸ9-09 6ｦ0, 006ｦ00ｹ009006ｦ0fl ｦ fl ｦ ｦ003090ｹ apple6ｦ ｦ06 56ｦ fl fl 006ｦ apple ｨｺ6ｦ apple0ｸ8 applefl 6ｦ0 6 76ｦ apple070300apple036ｦ ｸ ｹ ｦ0006ｦ ｹ ｦ ｹ ｹ06ｦ00ｸ90306fl ｦ0006ｦ ｹ0000ｸ apple030708apple07fl ｦ0 apple ｸ803 6ｦ ｸ ｦ0006ｦ apple6ｦ0, ｦ fl0ｸ apple0003fl 08apple fl0306fl apple ｹ ｦ00009fl [3]. ｨｴ ｦ fl ｸ8036ｦ fl ｦ apple apple ｸ ｹ ｦ ｹ ｹ apple070300apple036ｦ ｦ0006ｦ ｹ ｷ ｸ apple00 026ｦ06 76ｦ ｦ apple fl0306fl 09 6ｦ0006ｦ apple040ｸ90306fl 6ｦ000000ｸ apple apple036ｦ ｸ803 apple6ｦ apple ｦ0006ｦ , 6ｦ0 006ｦ ｦ apple ｦ003090ｹ apple076 56ｦ00009fl 00026ｦ fl 08apple ｨｦ ｨｪ ｨ ｨｦ050204ｨ ｦ ｦ ｦ ｸ ｦ ｦ0030ｹ06ｦ apple ｦ0, ｸ90ｸ76ｦ0fl 036ｦ ｦ ｸ9 6 50ｸ ｦ0 04apple applefl, ｹ000030ｸ8apple ｸ803, 1

2 apple ｦ0 09 apple ｦ apple0309apple076 56ｦ fl 0603apple6ｦ apple ｸ ｦ apple6ｦ ｹ000apple apple09-016ｦ apple000ｸ apple fl0309, 6ｦ ｦ ｹ ｸ ｦ ｹ0000ｸ apple [25]. ｨ 09040ｹ ｦ ｦ0006ｦ apple ｦ0090ｸ86 56ｦ00003, 0ｹ apple ｦ0 090ｸ9 apple ｦ0 000ｸ ｷ ｷ fl ｦ0- apple6ｦ apple006ｦ0 0ｹ ｦ0fl 00fl apple ｦ0apple6ｦ apple6ｦ apple ｦ0 6ｦ ｦ0 0ｸ apple (08apple ｸ apple006ｦ003090ｹ ) apple fl ｦ06 50ｸ apple090ｹ apple0003fl 006ｦ0applefl apple006ｦ003090ｹ apple apple fl ｸ ｸ ｦ00300apple096ｦ0026ｦ0 6ｦ0096ｦ ｦ06 56ｦ0. 026ｦ00300apple096ｦ apple , 006ｦ00ｹ009006ｦ0fl , 0ｸ802 apple000904apple ｸ803, 0ｹ ｦ fl apple ｨC1929, 1960ｨC1961, [4, 7, 12, 18] ｦ003070ｹ apple0703fl ｸ apple6 56ｦ apple , ｸ apple0907 0ｸ ｦ0096ｦ ｦ ｦ00ｷ ｦ00ｹ06ｦ , ｦ ｦ fl ｦ ｦ0apple apple070300apple- 036ｦ fl ｸ80ｹ06ｦ ｸ ｹ10000apple ｹ ｦ0apple6ｦ apple6ｦ00309: 1800ｨC , 0ｹ ｦ ｷ309apple fl applefl ｦ ｦ001 ｰ086ｦ apple ｱ [18, 22]. 05 0ｹ apple0907 0ｸ8 ｰ096ｦ fl ｱ 6ｦ ｦ0006ｦ0 apple006ｦ fl 0ｹ000apple apple00040ｸ apple030708apple07fl ｦ ｸ803 01apple6ｦ00300apple6ｦ ｦ ｦ ｦ0006ｦ , 02fl apple6ｦ00300apple ｸ fl ｦ0-020ｸ9 6ｦ00ｸ90306fl 6 50ｸ apple6ｦ00304apple000ｸ ｦ0apple07020ｸ apple , 06apple apple6ｦ00304apple000ｸ ｦ0apple076 76ｦ ｸ ｸ ｸ apple036ｦ ｸ800 08apple07fl fl apple ｹ (0505) 01apple6ｦ00300apple6ｦ ｦ0006ｦ0 [3, 11, 26, apple] ｦ0fl 6 507apple ｦ0 08apple ｦ06 502fl apple0ｸ apple6ｦ00300apple, ｦ ｹ1036ｦ fl ｦ0006ｦ0 (apple ). 05apple0003fl 07 apple6ｦ ｦ00009fl 0ｹ apple6ｦ00300apple6ｦ0 6ｦ00309apple fl apple6ｦ ｨC [25] ｦ fl0ｸ apple0003fl 6 5 0ｹ apple6ｦ00300apple apple ｹ000000ｸ8 006ｦ ｸ7000ｸ ｸ apple6ｦ00304apple000ｸ ｦ0apple076 76ｦ ｸ800 ( ｦ0apple ｸ800) 6 50ｸ ｸ ｦ0006ｦ , apple ｦ ｦ ｦ0fl 036ｦ006060ｹ10000apple ｹ ｦ0fl apple6ｦ0096 7apple ｦ ｦ0006ｦ0. ｨｨ07 6ｦ000000ｸ ｨｨ0702fl016ｦ0 [22] ｨｪ6ｦ0apple6ｦ0006ｦ ｦ00309 [27] ｦ0fl 6 507apple ｦ ｦ06 502fl / SO ｹ10000apple apple ｹ apple6ｦ00300apple6ｦ0 036ｦ0apple6ｦ apple fl 006ｦ002090ｹ apple ｸ apple ｦ apple070300apple036ｦ ｸ ｸ : ｸ ｹ06ｦ ｦ ｦ0apple : apple apple6ｦ00304apple6ｦ 縺05, 6ｦ0 036ｦ apple6ｦ0096 7apple ｦ0 0500apple ｦ0apple apple6ｦ00304apple6ｦ ｸ 縺05. ｨ ｦ0 6 50ｸ ｹ ｦ apple6ｦ ｹ apple00apple0ｸ ｦ009036ｦ003090ｹ ｦ000090ｹ apple07086ｦ00009fl 6 5 apple6ｦ apple ｦ0006ｦ0 [16], 006ｦ ｦ0 020ｸ9 6ｦ fl ｸ ｦ0apple apple036ｦ ｸ ｹ ｨｨ , ｹ apple090ｹ ｦ ｦ00ｸ903 6ｦ ｦ ｸ ｦ ｹ , ｦ apple0ｸ fl fl apple ｦ ｦ06 56ｦ0 006ｦ0 01apple ｹ ｦ ｦ003090ｹ ｸ ｸ apple ｷ36ｦ000030ｸ ｸ apple ｦ ｦ ｦ06 76ｦ00ｸ90306fl 6ｦ0006ｦ ｹ ｦ000000ｸ ｦ ｹ ｦ0006ｦ apple ｦ0030ｸ ｹ apple076 56ｦ00009fl 0207apple03 006ｦ fl 0ｹ apple6ｦ apple6ｦ003, 0ｹ fl apple fl ｦ000090ｸ ｦ apple ｦ ｦ ｸ ｸ ｦ0006ｦ ｨｪｨｦ0501 ｨ ｨ ｨｬｨｮ0004ｨ ｨｹ ｨC ｦ ｦ apple ｦ0000ｸ ｹ , ｸ8, 6 7applefl ｸ ｸ fl, ｸ8 006ｦ apple (0205) ｸ apple6ｦ apple6ｦ00300apple apple066ｦ ｦ0, apple apple6ｦ ｦ apple fl ｦ0apple applefl (apple ) ｦ : ｨC fl0ｸ ｸ apple0709apple6ｦ00ｹ apple0709apple6ｦ00ｹ ; ｨC fl0ｹ ｸ8, 07 apple6ｦ009040ｸ90ｸ fl, ｦ ｸ apple6ｦ , 096ｦ0 060ｹ ｦ00009fl , 036ｦ , ｹ apple ｦ0, ｦ apple0ｸ apple6ｦ ｦ apple0ｸ ｷ ; ｨC fl0ｸ applefl ｸ ｸ8, 0ｷ apple0ｸ ｦ0apple0009apple ｦ ｹ000apple apple09 apple ｹ06ｦ apple6ｦ apple6ｦ00300apple apple066ｦ ｦ0 ( ), ｦ ｸ ｦ0 020ｸ9 6ｦ0026ｦ ｦ ｦ0fl ｦ0fl 6 76ｦ apple070300apple036ｦ ｦ0fl 00fl , 6 50ｸ8apple6ｦ0086ｦ ｦ0fl06fl 006ｦ apple apple ｷ ｸ ｦ ｦ apple ｹ ｦ ｦ000090ｹ ｦ ｦ apple016ｦ0 006ｦ apple apple ｸ ｰ ｱ, 07 apple6ｦ009040ｸ90ｸ fl 096ｦ0 060ｹ ｦ apple000ｸ ｦ , 09060ｹ ｦ00ｸ90ｸ ｸ ｨｨapple07 0ｸ apple6ｦ apple ｦ ｸ803 08apple apple , 020ｸ9 0ｸ ｦ001030ｸ ｦ002026ｦ ｸ ｸ90ｹ000000ｸ8. ｨｨapple apple ｦ ｸ803 apple6ｦ apple ｦ ｦ00300applefl apple04, Eh, ｨｪ 縺 apple ｦ ｦ00009fl fl 026ｦ0 07apple6ｦ00307apple ｦ0006ｦ ｦ apple070ｷ apple6ｦ0 08apple07 0ｸ ｸ apple076 56ｦ ｹ000apple apple6ｦ000000ｸ apple0ｸ8 ( 096ｦ apple 0807apple m). ｨｨapple09 03apple6ｦ apple0309apple apple6ｦ000000ｸ800 apple6ｦ apple0ｸ8 03apple6ｦ ｦ ｸ apple6ｦ ｨｦ0307 apple6ｦ0000ｸ8 036ｦ apple07 0ｸ8 6 7apple ｦ ｦ ( ) 006ｦ0 0300apple036ｦ ｸ ｸ76ｦ0 016ｦ ｦ fl ｦ apple076 50ｸ : ｨC ｦ ｸ apple070300apple036ｦ ｸ ｸ76ｦ00ｸ90ｸ apple07 006ｦ0 0300apple036ｦ ｸ ｸ76ｦ0 016ｦ apple ｹ06ｦ fl; ｨC ｸ ｦ apple ;

3 ｨ 05ｨｺｨｦ0700ｨｦ07ｨ 02ｨ ｨｹ ｨｪ00ｨｺ020200ｨｲ ｨ 05ｨｪｨｦｨｮ04ｨ 01ｨｦ05 05ｨｬ (a) apple ｦ ｦ0apple apple6ｦ00300apple 056ｦ ｦ ｦ000006ｦ0fl 05apple ｦ0 05ｨｨ ｨｦ fl 6 7applefl ｦ apple6ｦ00300apple 0109apple066ｦ ｦ ｨｺ ｦ0 0708apple ｦ00009fl 6ｦ ｸ803 01apple6ｦ00300apple ｦ0 ｨC 016ｦ0apple036ｦ ｦ0 6ｦ ｸ803 01apple6ｦ00300apple (016ｦ0apple- 036ｦ ｦ0 6 50ｸ ｦ ｦ ); ｨC 00036ｦ ｸ ｸ8 0708apple ｦ00009fl 6 5 6ｦ ｸ803 01apple6ｦ00300apple6ｦ : 006ｦ (05ｨｨ) apple ｹ apple6ｦ00300apple6ｦ apple (0205) ( apple ｦ0 apple ｦ0). ｨｮ00apple000ｸ ｹ0016ｦ ｦ0-096ｦ0000ｸ ｦ apple6ｦ0 08apple07. ｨC 066ｦ00307apple07 006ｦ0fl 0600apple6ｦ apple ｹ06ｦ ｦ0- apple ｸ apple ( ｦ0apple apple ｹ06ｦ fl). ｨｨapple07 0ｸ8 06apple6ｦ ｸ76ｦ ｦ ｸ apple ｹ0000ｸ ｦ ｸ8, 6ｦ0 096ｦ ｦ0 07apple6ｦ00307apple000ｸ fl apple apple09 6ｦ ｦ ｦ0026ｦ ｦ0fl 026ｦ0096ｦ0. 016ｦ ｸ ｦ apple086ｦ00009fl apple070ｹ apple6ｦ apple6ｦ apple fl ｨ 05ｨｨ-02ｨｴ05 006ｦ0 08apple09 07apple00 IRIS Advantage ｨ ｨｦ ｨｺ0204 ( ｦ0006ｦ , ｨｪapple ｦ0). ｨｦ08apple apple086ｦ00009fl ｨｺｨ ｨｴ, 6ｦ0 036ｦ Rb, Sr, Ba, Pb, Th, U 6 5 6ｦ0006ｦ apple ｸ803 apple6ｦ apple6ｦ ｨ 05ｨｨ ｸ fl apple6ｦ009 6ｦ fl fl ｦ apple6ｦ0 0409apple ｹ000036ｦ apple ｦ000 6ｦ0apple030703, ｦ00ｹ apple ｸ ｸ8 apple6ｦ ｷ apple6ｦ00ｷ ppb. 0502fl 6 7apple6ｦ0 0409apple ｦ00209 apple6ｦ apple0ｸ ｦ000 6ｦ0apple03000ｸ ｹ apple6ｦ0090ｷ apple086ｦ ｹ ｦ apple ｸ8, 6ｦ0 036ｦ Hg, Tl, Bi 070ｷ ｦ ｹ ｸ apple apple

4 ｦ ( ) S-3 S ｨｨ-12 02ｨｬｨｪ ｨｨ ｨｨ /05; 0505ｨｨ ｲ ｨｨ-2/1 0505ｨｨ ｨｨ ｨｨ-9/1 0505ｨｨ ｨｨ ｨｨ ｨｨ , 4/ /6, ｨｮ01-6ｦ0, ｨｮ ｦ , 2, 3, 6/ ｦ ｦ00ｲ ｨｬ ｹ06ｦ ｦ ｦ ｦ ｨｬｨｪ-27 02ｨｬｨｪ-26 02ｨｬｨｪ-28 02ｨｬｨｪ-24 02ｨｬｨｪ-25 02ｨｬｨｪ-23 02ｨｬｨｪ-31 02ｨｬｨｪ-30 02ｨｬｨｪ ｨｨ ｨｺ ｨｨ ｦ000 6ｦ000036ｦ ｲ4 6 50ｸ ｲ ｦ0 036ｦ ｸ ｦ ｲ4 ELEMENT Finnigan Mat ( ｦ0006ｦ ｨ ｦ ｦ0) ｸ ｦ ｲ402060ｲ4 6 5 ｨ ｨｦ ｨｺ0204 (6ｦ0006ｦ ｦ0) ｲ402060ｲ4 07 ｨB ｸ803 6ｦ ｹ ｨｬ ｨｦ00ｨｦ07ｨ ｨｹ ｨ ｨｦ00ｨｦ07ｨ ｨｹ ｧ

5 1307ｨ 05ｨｺｨｦ0700ｨｦ07ｨ 02ｨ ｨｹ ｨｪ00ｨｺ020200ｨｲ ｨ 05ｨｪｨｦｨｮ04ｨ 01ｨｦ05 05ｨｬ Fe 3+ Cl ｨC Fe 3+ Mg 2+ Al 3+ Fe 3+ Cl ｨC Cl ｨC Cl ｨC Fe 3+ Al 3+ Al 3+ Mg 2+ 2ｨC SO 4 Ca Mg ｨC 4 2ｨC SO 4 SO 4 2ｨC SO Al 3+ Ca 2+ Ca 2+ 4 K + Na + Mg 2+ Ca 2+ Na + Na + F ｨC F ｨC Cl ｨC Fe 3+ Fe 3+ Al 3+ 2ｨC Al 3+ Cl ｨC + + NH 4 NH 4 5 SO Cl ｨC 8 Cl ｨC Ca2+ 2+ Mg Mg 2+ Ca 2+ K + Na+SO 4 2ｨC Fe 3+ Al3+ Mg 2+ Ca 2+ SO2ｨC 4 Fe 3+ Al 3+ Mg 2+ Ca 2+ SO 4 2ｨC ｨｺ ｸ apple6ｦ009000ｸ803 apple6ｦ apple6ｦ ｦ0006ｦ ｨC 08apple0709apple6ｦ00ｹ0000ｸ ｸ ｸ8 006ｦ ; 2 ｨC apple0ｸ ｸ8; 3 ｨC070900apple apple6ｦ00300apple apple066ｦ ｦ0; 4 ｨC ｸ apple ; 5 ｨC 0807apple076 50ｸ ｸ apple ; 6 ｨC 6 7applefl ｸ ｸ8 006ｦ ; 7 ｨC 0807apple076 50ｸ ｸ ｦ0apple apple ( ｦ0fl ｦ0apple07026ｦ0 006ｦ ｧ8 S-1); 8 ｨC 0807apple076 50ｸ ｸ ｦ0apple apple (036ｦ ｦ0fl ｦ0apple07026ｦ0 006ｦ ｧ8 S-2). apple07 6ｦ ｦ00209fl ｦ fl [24]. ｨｦ066ｦ apple ｦ0 08apple ｦ apple ｸ apple6ｦ0036ｦ0 0600apple00 apple6ｦ0. ｨｨ apple076 50ｸ8-6 56ｦ00206fl apple07 6ｦ ｸ803 6ｦ ｦ apple ｦ00307apple6ｦ0 ｨC ｦ ｸ ｦ0060ｷ3076 5: Cl ｨC + Ag + AgCl Ag + + CNS ｨC AgCNS ｦ apple ｸ800 08apple07 0ｸ apple086ｦ apple apple07, 07apple6 76ｦ000090ｹ ｸ ｦ0, (II 09 III) 09 6ｦ0020ｸ , apple0ｸ ｦ apple ｸ apple ｦ0. ｨ fl apple6ｦ apple apple ｸ apple07 6ｦ ｦ0apple6 76ｦ0000ｷ ｸ ｦ ｸ90ｸ ｦ ｦ0 09 6ｦ0020ｸ fl. 056ｦ apple07 0ｸ apple076 56ｦ ｦ0006ｦ apple076 56ｦ ｸ ｦ ｦ apple ｸ8 0708apple fl ｷ3096ｦ ｸ ｦ003, apple6ｦ009apple6ｦ ｦ000000ｸ ｦ008apple07 09apple076 56ｦ000000ｸ ｨ ｨｦ ｨｺ fl ｷ ｹ apple apple6ｦ ｦ06 56ｦ0. ｨｨapple09 6ｦ0006ｦ ｦ ｦ0 08apple07-0ｸ8 08apple ｦ0apple ｦ ｦ00ｸ90ｸ ｦ apple ｦ ｹ000apple ｦ ｨｬ-2. ｨ 6ｦ ｦ apple fl0206fl 08applefl030ｸ apple076 56ｦ apple00 00, apple086ｦ0-0ｸ ｦ00ｷ , 06036ｦ000 6ｦ0apple03000ｸ803 apple6ｦ apple ｦ0apple09fl apple ｦ00307apple6ｦ apple07036ｦ ｨｴ ｦ00307apple ｦ ｦ0apple apple00 00 (apple04 = 2.0), 6ｦ06 56ｦ0fl apple6ｦ ｸ9 apple006ｦ0010ｷ3090ｸ9 09 0ｹ apple apple6ｦ apple apple6ｦ apple6ｦ ｸ9 [21] apple apple fl0206fl ｷ apple090ｹ ｸ7000ｸ apple ｹ apple07 6ｦ apple6ｦ0 ｰｨ -130 ｱ ｦ00ｸ90ｸ fl ｦ ｦ0 09 6ｦ0020ｸ fl apple076 56ｦ ｦ ｦ0006ｦ apple ｸ800 08apple07 0ｸ apple ｦ003apple09fl ｷ apple6ｦ00ｷ309fl N, 0.01N N. ｨｺ00ｨ ｨｬ00ｨｲｨｪ02ｨｪ ｦ06 5 apple6ｦ apple ｦ apple070300apple036ｦ ｸ ｹ , , apple6ｦ ｸ apple ｦ ｦ0006ｦ , 070ｹ apple6ｦ apple6ｦ fl0306fl ｸ apple6ｦ ｸ ｦ003 (09006ｦ00ｹ fl apple fl0ｸ90306fl 0703 ｨC ) ｸ ｦ ｸ ｷ3096ｦ , fl0ｸ90ｸ fl apple apple ｦ003: ｸ ｦ apple076 50ｸ803 apple6ｦ apple6ｦ apple036ｦ ｸ ｸ76ｦ ｦ0apple096ｦ00ｷ apple- 086ｦ00009fl03 036ｦ0apple6ｦ apple000ｸ8 016ｦ001 02fl ｸ , 036ｦ fl apple070ｹ ｸ ｦ apple ｦ , ｦ ｸ apple6ｦ , apple ｦ ｦ00309 (036ｦ ; apple ) apple ｸ ｦ0apple ｸ ｦ003 apple0ｸ ( /02), apple00 01apple6ｦ00300apple6ｦ0 0109apple- 066ｦ ｦ0 ( /02), ｦ apple ( /02) 09 apple6ｦ apple6ｦ applefl ｸ ( /02) ｦ0030ｸ ｦ00ｹ009030ｸ ｹ ｦ003 08apple09-

6 apple ｦ0 09 apple. ｨｪ6ｦ ｷ36ｦ ｹ ｦ0apple6ｦ apple0ｸ ｸ ｦ ｦ apple070300apple036ｦ ｸ ｹ fl, 036 7/02 6ｧ8 08apple07 0ｸ8 ｨｪ 縺05 apple04 Eh Cl ｨC * F ｨC * Na + K + Ca 2+ Mg 2+ Fe Al 3+ SO 4 2ｨC PO 4 2ｨC ｨｨapple0709apple6ｦ00ｹ0000ｸ ｸ ｸ8 006ｦ ｦ0apple / / / / / ｨｦ0900apple apple6ｦ00300apple apple066ｦ ｦ / / ｸ apple (01apple6ｦ00300apple00 056ｦ ｦ0) ｨｺ0ｸ ｸ / applefl ｸ ｸ / ｨｨ-2 87 ｨC ｨｨ-2/1 72 ｨC ｨｨ-3 87 ｨC ｨｨ ｨｨ-5 84 ｨC ｨｨ ｨｨ ｨｨ ｨｨ-9 75 ｨC ｨｮ01-6ｦ ｨｮ / ｨｨ07apple076 50ｸ ｸ8 0300apple036ｦ ｸ76ｦ ｨｨ ｨｨ ｨｨ ｨｨ ｨｨ ｨｨ07apple076 50ｸ ｸ8 0600apple000ｸ ｦ0apple0702 S S ｨｨapple ｹ06ｦ *Cl ｨC 2ｨC 09 SO 4 ｨC /02; ｦ : ｰ00.. ｱ ｨC 0ｹ apple fl0206fl, ｰ ｱ ｨC 0ｹ ｦ0apple NH 4 +

7 1307ｨ 05ｨｺｨｦ0700ｨｦ07ｨ 02ｨ ｨｹ ｨｪ00ｨｺ020200ｨｲ ｨ 05ｨｪｨｦｨｮ04ｨ 01ｨｦ05 05ｨｬ ｸ ｦ003 apple6ｦ apple ｦ ｦ ｸ800 2ｨC ｹ ｦ0 PO ｸ8fl ｸ apple076 50ｸ803 apple6ｦ apple6ｦ apple036ｦ ｸ76ｦ apple ｹ06ｦ fl ( /02), ｦ apple086ｦ ｦ / apple6ｦ apple6ｦ003 apple6ｦ apple fl ｦ0apple ｸ ｸ ｸ ｦ00009fl apple ｦ : apple0709apple6ｦ00ｹ0-000ｸ apple0709apple6ｦ00ｹ0000ｸ ｹ ｦ apple086ｦ00009fl apple ｦ apple ｦ ｸ800, 6 5 apple6ｦ apple6ｦ applefl ｸ apple076 50ｸ ｦ apple000ｸ ｦ0apple apple09 0ｸ ｸ apple ｦ0 6ｦ0-0ｸ ｦ ｦ0036ｦ ｦ0fl 0ｹ06ｦ ( 90%) 08apple ｦ ｦ apple ｦ00309 ( / applefl ｸ ｦ / apple6ｦ apple6ｦ apple000ｸ ｦ0apple0702) ｦ ｸ ｦ003 apple6ｦ apple076 5 (apple0ｸ fl, apple00 01apple6ｦ00300apple6ｦ0 0109apple066ｦ ｦ0, apple apple076 50ｸ ｦ ), 006ｦ007 07apple0703, 0702fl ｦ ｸ ｦ ｸ apple086ｦ00009fl ｦ ｦ0apple ｸ8 6 5 apple0ｸ ｨC 036ｦ003, fl SO ｦ06 502fl % (6 5 06apple ｨC /02) ｨ 6 56ｦ [13] ｸ apple036ｦ ｸ ｹ ｦ ｦ apple6ｦ ｦ ｦ apple09 000ｸ800 ( ｦ apple09 000ｸ800) ｨC ｰ ｱ 0207apple0309apple076 56ｦ00009fl ｦ003000ｸ ｸ8 ｰ apple ｱ 0207apple0309apple076 56ｦ00009fl. ｨｴ ｸ apple6ｦ ｦ06 5apple apple apple fl0009fl ｦ0006ｦ ｸ Cl ｨC 2ｨC / SO apple ｦ [6, 7] , ｦ apple apple0309apple076 56ｦ apple- 000ｸ ｦ0apple fl 036ｦ ｦ003090ｹ HCl 06040ｸ ｦ0fl, 0ｹ apple apple0309apple076 56ｦ apple ｹ ｦ ｸ ｦ ｦ000000ｸ803 apple6ｦ apple ｦ ｹ0096 5: ｸ ｹ ｦ ｦ apple , apple00 01apple6ｦ00300apple6ｦ0 0109apple- 066ｦ ｦ0 08apple ｦ0 6ｦ00ｸ90ｸ70903 fl6 502fl000306fl 016ｦ002000ｷ30906 (apple ). 05 apple0ｸ ｦ apple076 50ｸ ｦ ｦ0 0800apple ｸ ( 07 66%), 6ｦ0 6 5 apple6ｦ apple6ｦ applefl ｸ ｨC 6ｦ0020ｸ ｨｦ ｦ ｦ00ｸ apple ｸ800 apple6ｦ apple0ｸ apple000ｸ ｦ0apple ｸ ｦ fl6 502fl000306fl 6ｦ , apple0ｸ ｦ00ｹ apple ｦ0 6ｦ ｦ ｦ ｸ ｦ ｦ00309 ( 80%, /02) ｸ90ｸ apple086ｦ000090ｸ ｹ apple6ｦ apple6ｦ003 fl6 502fl000306fl 6ｦ0020ｸ (11%, /02) fl apple070ｹ (01 0ｹ apple ｸ ｹ ｸ8, apple0ｸ ｦ0086ｦ apple6ｦ00304apple apple ｰtrace elements ｱ) ｸ apple6ｦ ｦ00ｷ30909 apple6ｦ apple ｦ06 502fl fl030ｸ apple07-0ｷ ｦ ｸ ｹ ｦ003, 6 7applefl ｸ ｦ apple076 50ｸ ｦ apple ｨｦ006ｦ ｸ ｦ fl 6 5 apple0ｸ ｦ apple016ｦ apple ( %) apple076 50ｸ803 apple6ｦ apple6ｦ apple036ｦ ｸ ｸ76ｦ apple000ｸ ｦ0apple0702 ( ｦ0036ｦ0apple) 0702fl apple070ｹ ｦ apple6ｦ006036ｦ00003: % ｸ apple6ｦ ｦ00ｷ30909, (036ｦ ) ｦ apple ｦ0 6ｦ00ｸ90ｸ apple070ｹ apple6ｦ ｹ0000ｸ apple0ｸ ｦ apple070ｹ ｸ apple6ｦ ｦ apple apple6ｦ006-08apple070603apple6ｦ : ｸ80309 fl6 502fl0ｸ90306fl Mn, Cu ( ｦ06 502fl0ｸ ｦ ｸ ｸ9 06apple apple070ｹ ｨC % /02), ｸ90ｸ70900 ｨC As 09 Zn ( % ), ｦ0 Cd 09 Sr ｨC %, flfl 6 7apple ｦ apple070ｹ ｨC Cr, Ni, Co, V, 05, apple0ｸ ｦ06 502fl0ｸ ｹ %. ｨｴ ｸ8 Li, Ti, Ba, Be, apple086ｦ00ｸ fl n 036 7/02, apple006 50ｸ8046ｦ0-0ｸ % apple070ｹ ｦ apple6ｦ apple6ｦ00300apple apple066ｦ ｦ0 006ｦ ｸ9 Mn 08apple fl % ｸ apple070ｹ apple6ｦ apple6ｦ apple ( ｦ apple076 50ｸ ｦ003) 006ｦ0 0800apple ｸ : apple086ｦ00009fl ｦ00ｸ ｹ / apple076 50ｸ ｦ003, 6ｦ0 0702fl ｦ06 502fl applefl 016ｦ0 30% ｸ apple086ｦ00009fl ｦ ｸ8 02fl Mn, Sr, As. 046ｦ apple6ｦ ｸ ｦ ｹ ｸ8 0002fl0ｸ90306fl 6 7applefl ｸ ｸ8. ｨ 03 apple6ｦ apple0ｸ ｹ06ｦ00ｸ90306fl ｸ apple036ｦ ｸ803 apple6ｦ apple ｦ000090ｹ apple ｦ ｦ ｸ ｷ apple6ｦ00ｷ309fl0309 Cr, Ti, Ni, V. ｨｦ ｸ ｸ apple ｦ ｹ apple6ｦ apple ｦ06 502fl apple ( /02, 0ｹ %), Cr, Sr, Ti, Mn, Ni, V, Nb apple- 086ｦ00306fl 036ｦ ｦ00ｹ ｸ ｹ ｦ003 (> /02). 026ｦ ｦ apple086ｦ apple07036ｦ0 6 5 apple6ｦ apple6ｦ ｦ0 ｨｦ0301apple0ｸ8030ｸ806 (0505ｨｨｨC2) ｦ /02 [3] (036ｦ ). 05 [29] 0ｸ802 08apple ｦ0006ｦ apple6ｦ apple076 5, ｦ0apple ｸ ｦ ｦ ｦ00007 ( ｦ00007, ｦ0apple ｦ0), apple0ｸ apple086ｦ00009fl 03apple07036ｦ ｹ ｦ (Vasco) 0ｸ /02 ( ｦ ｸ9, fl 0ｹ ｦ0). 01apple , 6 5 apple6ｦ apple6ｦ applefl ｸ ｦ002090ｹ ｦ00ｹ009030ｸ ｷ apple6ｦ00ｷ Ga, Ba, Mo apple076 50ｸ ｦ apple036ｦ ｸ ｸ76ｦ ｸ apple070ｹ ｦ00309 fl6 502fl- 0ｸ90306fl V, B, Ti, Mn, apple086ｦ00009fl apple0ｸ803 08apple006 50ｸ8046ｦ00ｸ /02. ｨｦ0ｹ ｸ ｷ apple6ｦ00ｷ30909 As, Zn, Cu, Cr, Li, Zr, Sr, Ni, Co apple076 50ｸ803 apple6ｦ apple6ｦ apple000ｸ ｦ0- apple apple ｦ0 6ｦ00ｸ90ｸ apple070ｹ fl6 502fl000306fl 07apple: apple086ｦ00009fl 290ｨC /02, 0ｹ ｦ06 502fl % apple070ｹ ｦ apple0ｸ ｦ0-0ｹ ｹ apple6ｦ apple6ｦ As, ｷ apple6ｦ0-0ｷ ｦ00ｸ /02, apple086ｦ00009fl 0604apple00030ｸ ｸ ｸ90ｸ apple6ｦ00608apple070603apple6ｦ ｹ apple6ｦ apple6ｦ ｦ0096ｦ00206fl ｦ000, ｹ apple ｦ ｦ ｸ ｦ0, 016ｦ001 As 09 Sb. 026ｦ0apple6 76ｦ000000ｷ3, 0ｷ , 0ｷ309apple , 6 56ｦ0006ｦ ｦ06 502fl0ｸ apple6 50ｸ / ｦ apple6ｦ ｦ ｦ ｷ3, 03apple0703, ｦ , ｷ apple6ｦ00ｷ apple0ｸ ｦ ｸ apple000ｹ ｸ apple070ｹ ｸ , apple086ｦ apple036ｦ ｸ ｹ ｦ003, ｦ ｦ apple076 50ｸ803 apple6ｦ apple6ｦ apple- 036ｦ ｸ ｸ76ｦ ｦ00ｹ ｸ apple6ｦ ｦ003apple096 56ｦ ｸ800 0ｹ ｸ fl6 502fl0ｸ90306fl 036ｦ0apple6ｦ apple ｸ ｸ apple ｹ ｹ apple ｸ apple6ｦ ｸ ｦ003, 016ｦ001, 006ｦ008apple090300apple, Cr: apple086ｦ00009fl 0ｹ ｹ ｦ apple076 50ｸ ｦ apple fl apple0ｸ ｦ003, apple00 01apple6ｦ00300-

8 apple ｦ0 09 apple. ｨｪ6ｦ ｷ36ｦ apple086ｦ00009fl apple0ｸ ｹ ｹ apple6ｦ apple6ｦ ｦ apple070300apple036ｦ ｸ ｹ ｦ0006ｦ , 036 7/02 6ｧ8 08apple07 0ｸ8 SiO 2 Mn Ba Sr As Zn Cu Ti V Co Cr Ni Be B ｨｨapple0709apple6ｦ00ｹ0000ｸ ｸ ｸ8 006ｦ ｦ0apple / < < <0.003 < / < <0.002 <0.003 <0.003 < / < <0.005 <0.005 <0.002 <0.003 <0.003 < < <0.003 <0.003 <0.001 < / < <0.005 <0.005 <0.002 < < / < <0.005 <0.005 <0.002 <0.003 <0.003 <0.001 <0.003 ｨｦ0900apple apple6ｦ00300apple apple066ｦ ｦ / < < / < ｸ apple (01apple6ｦ00300apple00 056ｦ ｦ0) < <0.003 <0.003 <0.001 < < <0.003 <0.003 <0.001 < < <0.003 <0.003 <0.001 < < <0.003 <0.003 <0.001 < < < <0.003 <0.003 <0.001 <0.003 ｨｨ07apple076 50ｸ ｸ ｦ ｦ apple < <0.001 < < < < < < < ' < < <0.001 < < < < < ｨｺ0ｸ ｸ < <0.005 < < <0.005 < < < / applefl ｸ ｸ / < ｨｨ ｨｨ-2/ < ｨｨ < ｨｨ < ｨｨ ｨｨ < < ｨｨ ｨｨ < ｨｨ < < ｨｮ01-6ｦ < <0.002 <0.003 <0.003 < ｨｮ < < < / < < ｨｨ07apple076 50ｸ ｸ8 0300apple036ｦ ｸ ｸ76ｦ < < ｨｨ ｨｨ ｨｨ ｨｨ ｨｨ < ｨｨ07apple076 50ｸ ｸ8 0600apple000ｸ ｦ0apple0702 S- / S-3/

9 1307ｨ 05ｨｺｨｦ0700ｨｦ07ｨ 02ｨ ｨｹ ｨｪ00ｨｺ020200ｨｲ ｨ 05ｨｪｨｦｨｮ04ｨ 01ｨｦ05 05ｨｬ apple086ｦ apple07 00/ apple09030ｸ8 Cl 10 ｨC apple086ｦ apple07 00/ apple09030ｸ8 Cl 10 ｨC ｨｺ6ｦ apple0ｸ La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu La Ce Pr Nd Sm Eu Gd Tb Dy Ho Er Tm Yb Lu (a) ( ) ｨｨ07apple076 50ｸ800 apple6ｦ apple0ｸ8 0300apple036ｦ ｸ ｸ76ｦ ｨｨ07apple076 50ｸ800 apple6ｦ apple0ｸ ｦ0apple ｸ apple ｨｺ ｨｺ6ｦ00608apple ｨｺｨ ｨｴ 6 5 apple6ｦ apple6ｦ applefl ｸ (6ｦ0), 0807apple076 50ｸ ｦ apple036ｦ ｸ ｸ76ｦ ｦ0apple ｸ apple ( ). 0502fl 02apple6ｦ ｦ0 6ｦ0: 1 ｨC 0505ｨｨ-2; 2 ｨC 0505ｨｨ-2/1; 3 ｨC 0505ｨｨ-3; 4 ｨC 0505ｨｨ-4; 5 ｨC 0505ｨｨ-5; 6 ｨC 0505ｨｨ-7; 7 ｨC 0505ｨｨ fl 02apple6ｦ ｦ0 : 1 ｨC 0505ｨｨ-10; 2 ｨC 0505ｨｨ-11; 3 ｨC 0505ｨｨ-12; 4 ｨC 0505ｨｨ-13; 5 ｨC S-1; 6 ｨC S-3. apple6ｦ0 0109apple066ｦ ｦ ｸ ｦ00ｹ fl n 07 n 036 7/ ｷ apple6ｦ00ｷ30909 Co 09 Ni, 08apple ｸ90ｸ ｹ ｦ003 0.n 036 7/ ｦ00ｸ / apple076 50ｸ803 apple6ｦ apple6ｦ apple086ｦ00009fl 07apple6ｦ apple076 50ｸ ｦ apple apple6ｦ06 500fl0ｸ90306fl /02. ｨｦ ｸ apple ｷ apple6ｦ00ｷ apple6ｦ00608apple apple ｸ803 0ｹ ｸ apple086ｦ00009fl ｨｺｨ ｨｴ ｨC 000ｸ ｦ apple6ｦ apple apple036ｦ ｸ ｸ76ｦ ｨｨ07 06apple6ｦ ｸ apple ｸ ｦ ｦ ｸ ｦ000000ｸ ｸ ｦ003000ｸ apple ｦ003000ｸ ｦ apple070300apple036ｦ ｸ8 [34], apple086ｦ00009fl ｨｺｨ ｨｴ apple036ｦ ｸ803 apple6ｦ apple6ｦ ｦ0006ｦ0 6 50ｸ apple6ｦ009, 6ｦ apple036ｦ ｸ (0505ｨｨ-5) ｨC apple6ｦ ｦ0apple000ｸ apple- 086ｦ00009fl ｨｺｨ ｨｴ ｦ00ｸ / ｦ003, 6ｦ0 6 5 apple6ｦ apple6ｦ apple036ｦ ｸ ｸ76ｦ ｸ90306fl /02 (036ｦ ) apple apple086ｦ ｸ ｦ0apple ｦ0006ｦ0 ｨｴ [2] apple apple ｹ ｦ003, ｦｲｨｺｨ ｨｴ ｦ0026ｦ /02, ｨｦ 006ｦ ｦ ｷ apple6ｦ00ｷ30909 ｨｺｨ ｨｴ 096ｦ ｸ ｨｺ6ｦ00608apple ｨｺｨ ｨｴ 6 5 apple6ｦ apple6ｦ , 096ｦ ｸ90ｹ apple036ｦ ｦ0 0505ｨｨ-7, apple apple096 56ｦ0fl apple6ｦ0 08apple ｦ06 502fl ｸ ｸ9, ｦ0-020ｸ9 6ｦ fl ｨｺｨ ｨｴ 08apple09 096ｦ ｦ00ｸ fl ｸ80309 ｨｺｨ ｨｴ (apple ｦ0). 05 apple6ｦ apple6ｦ apple036ｦ ｸ ｸ76ｦ apple6ｦ00608apple ｨｺｨ ｨｴ apple ｨC 03fl ｦ0fl 0ｹ06ｦ ｸ apple ｦ0-