Liner natomy ライナーの手引き Innovative Chromatography Products www.restek.jp
はじめに ( ) & ( ) Gerstel PTV PTV PTV(PROGRAMMABLE TEMPERATURE VAPORIZATION) LVI(LARGE VOLUME INJECTIONS) PTV LVI PTV LVI ( PETN 100 ( 0.53mm 2-3 ) PTV
ライナー充填物 Restek Restek プレシジョンライナー ウール入り Restek Restek サイクロダブルテーパ ライナー
RESTEK の不活性化処理技術 ( ) Restek Restek TECH TIP: Restek Restek R
ID 容積と内径 Restek Solvent Expansion Calculator (www.restek.com/calculators) Sovent Expansion Calculator ( L) * 4 mm ID Agilent GC Split/Splitless 990 495 2 mm ID Agilent GC Split/Splitless 250 125 5 mm ID Thermo TRACE GC Split/Splitless 2,060 1,030 3.5 mm ID 2010 GC Split/Splitless 914 457 4 mm ID Agilent GC Split/Splitless 900 450 5 mm ID Thermo TRACE GC Split/Splitless 2,000 1,000 3.5 mm ID 2010 GC Split/Splitless 740 370 Agilent GC Split/Splitless 800 400 Agilent GC Split/Splitless 820 410 4 mm ID Agilent GC Split/Splitless 850 425 1.5 mm ID Agilent GC PTV 150 75 * ( ) 0.18mm 0.15mm 0.10mm 1 2 (psi) 15.8 15.8 ( ) 250 250 ( L) 159 1,145 15.8psi 1.5mL/min 0.25mm 30m 40
ライナーメンテナス ( ) (+10 )
形状 ( ) Restek プレシジョンライナー ウール入り Restek シングルテーパ ライナー TECH TIP: EPC GC ( ) Restek ダブルテーパ ライナー Restek シングルテーパ ライナー ウール入り Restek サイクロダブルテーパーライナー ユニライナー下側ホール
www.restek.jp/topaz Topaz GC Topaz GCインレットライナーの革新的技術とその不活性度は次のレベルへ : GC 100 Topaz ライナーは 100% 満足度保証 Topaz Topaz
不活性化 Topaz Restek 1 2 4-DNP 2 1 µg/ml 1. Acenaphthene (IS) 1 2. 2,4-Dinitrophenol (DNP) 1 1. t R (min) (µg/ml) 1. Carbaryl 10.019 0.5 :Rxi-5ms,15m,0.25mmID,0.25µm(Cat.#13420); :Topaz FID liner ; : ; : 1µL (hold 1min); :Topaz4.0mmID, (Cat.#23303); :250 ; :40mL/min; :40 (1min)-18.5 / min-300 (1min); :He, ; :2mL/min; :FID@340 ; :45mL/min :N2;H2 :40mL/min;Air :400mL/min;Data Rate:50Hz; :Agilent 7890AGC 1 2 = Topaz A = Topaz A 7.54 7.56 7.58 7.60 7.62 7.64 7.66 7.68 Time (min) GC_EV1451 9.96 9.98 10.00 10.02 10.04 10.06 10.08 Time (min) GC_EV1452 3 DDT (Topaz EPA 8081 DDT 15% ) 1 Endrin Endrin Breakdown 2 3 DDT DDT Breakdown Topaz (Blue) ( ) 2.1% 1.5% Competitor C C (Red) 17.0% 3.9% ( ) 17.0% 3.9% 4 10.6 10.8 11.0 11.2 11.4 11.6 11.8 12.0 Time (min) GC_EV1453 5 t R (min) (ng/ml) 1. 4,4'-DDE 10.685 * 2. Endrin 10.920 50 3. 4,4'-DDD 11.087 * 4. Endrin aldehyde 11.198 * 5. 4,4'-DDT 11.488 100 6. Endrin ketone 12.005 * * 6 ( ) Topaz Topaz 2,4- DNP DDT GC :Rxi-5ms,15m,0.25mmID,0.25µm(Cat.#13420); :Endrin(50ng/mL) DDT(100ng/mL); :n- ; : 1µL (hold 1.2min); :Topaz4.0mmID, (Cat.#23303); :250 ; :20mL/min; :50 (1.2min)-20 /min-240-6 /min-265 ; :He, ; :1.5mL/min; :ECD@300 ; :60mL/min :N2;Data Rate:20Hz; :Agilent 7890AGC
再現性 Topaz Restek Topaz Restek Topaz 4 (DDT 2 4-DNP ) 5 t R (min) (ng/ml) 1. 4,4 -DDE 10.670 * 2. Endrin 10.902 50 3. 4,4 -DDD 11.067 * 4. Endrin aldehyde 11.177 * 5. 4,4 -DDT 11.464 100 6. Endrin ketone 11.976 * * t R (min) (µg/ml) 1. Acenaphthene (IS) 7.570 1.0 2. 2,4-Dinitrophenol (DNP) 7.668 1.0 3. Carbaryl 10.020 0.5 4. Coumaphos 13.737 0.5 2 Endrin DDT Lot# Endrin DDT Lot # 1 Breakdown 2.1% Breakdown 1.2% 1 2.1% 1.2% 2 2.4% 1.4% 2.4% 1.4% 3 2.1% 1.4% 1 2, 4-DNP Carbaryl Coumaphos Lot# RRF RRF RRF 2, 4-DNP 1 Lot 0.257 # 0.637 0.425 RRF 2 3 10.256 0.257 0.626 20.252 0.256 0.638 0.423 0.438 3 0.252 2 3 4 1 3 4 6 Lot 3 Lot 3 Lot 2 Lot 2 Lot 1 Lot 1 10.6 10.8 11.0 11.2 11.4 11.6 11.8 12.0 Time (min) GC_EV1450 10 Time (min) GC_QA0101 GC_EV1450 :Rxi-5ms,15m,0.25mmID,0.25µm(Cat.#13420); :Endrin(50ng/mL) DDT(100ng/mL); :n- ; : 1µL (hold 1.2min); :Topaz4.0mmID, (Cat.#23303); :250 ; :20mL/min; :50 (1.2min)-20 /min-240-6 /min-265 ; :He, ; :1.5mL/min; :- ECD@300 ; :60mL/min :N2;Data Rate:20Hz; :Agilent 7890AGC GC_QA0101 :Rxi-5ms,15m,0.25mmID,0.25µm(Cat.#13420); :Topaz FID liner ; : ; : 1µL (hold 1min); :Topaz4.0mmID, (Cat.#23303); :250 ; :40mL/min; :40 (1min)-18.5 /min-300 (1min); :He, ; :2mL/min; :- FID@340 ; :45mL/min :N2;H2 :40mL/min;Air :400mL/min;Data Rate:50Hz; :Agilent 7890AGC
生産性 Topaz 5 Endrin 繰り返し測定におけるエンドリン分解率の変化 Breakdown Across Multiple Injections 14.00% 12.00% % Endrin エンドリン分解率 Breakdown 10.00% 8.00% 6.00% 4.00% 2.00% 0.00% 0 10 20 30 40 Injection 注入回数 # Topazライナー Liner Competitor 他社 A A Competitor 他社 B B See Figure 3 for conditions. 3 Topaz Topaz 究極の不活性処理 再現性 生産性 Topaz www. Restek.jp/topaz
さらに詳しくお知りになりたい場合 www.restek.com/liners GC (Webiner) PTV-On Column 1 2 PATENTS & TRADEMARKS Restek patents and trademarks are the property of Restek Corporation. Other trademarks appearing in Restek literature or on its website are the property of their respective owners. The Restek registered trademarks used here are registered in the United States and may also be registered in other countries. Restek RestekJapan@restek.com www.restek.jp Restek patents and trademarks are the property of Restek Corporation. (See www. restek.jp/patents-trademarks for full list.) Other trademarks in Restek literature or on its website are the property of their respective owners. Restek registered trademarks are registered in the U.S. and may also be registered in other countries. 2017 Restek Corporation. All rights reserved. Printed in Japan. Lit.Cat.#GNBR1678-UNV_JP