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1 Photochemical Primary Processes of the Exciplex Tadashi OKADA Department of Chemistry, Faculty of Engineering Science, Osaka University, Machikaneyama, Toyonaka 560 (Received July 3, 1984)

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11 1 ) J. B. Birks:Photophysics of Aromatic Molecules (Wiley, London, 1970). 2 ) N. Mataga and T. Kubota:Molecular Interac tions and Electronic Spectra (Marcel-Dekker, New York, 1970). 3 ) R. S. Davidson:Molecular Association, Vol. 1, ed. R. Foster (Academic Press, London, 1975) p ) S. Nagakura:Excited States, Vol. 2, ed. E. C. Lim (Academic Press, New York, 1975) p ) N. Mataga and M. Ottolenghi:Molecular As sociation, Vol. 2, ed. R. Foster (Academic Press, London, 1979) p ) N. Mataga:Molecular Interactions, Vol. 2, ed. H. Ratajczak and W. J. Orville-Thomas (Wiley, London, 1981) p ) S. Masaki, T. Okada, N. Mataga, Y. Sakata, and S. Misumi:Bull. Chem. Soc. Jpn. 49, 1277 (1976). 10 ) T. Okada, T. Fujita, and N. Mataga:Z. Phys. Chem. N. F. 101, 75 (1976). 11 ) T. Okada, M. Kawai, T. Ikemachi, N. Mataga, Y. Sakata, S. Misumi, and S. Shionoya:J. Phys. Chem. 88, 1976 (1984). 13 ) S. K. Garg and C. P. Smyth:J. Phys. Chem. 69, 1294 (1965). 14 ) R. A. Marcus:J. Chem. Phys. 24, 966 (1956); ibid. 26, 867 (1957); Annu. Rev. Phys. Chem. 15, 155 (1964). 15 ) J. J. Hopfield:Proc. Natl. Acad. Sci. U. S. A. 71, 3640 (1974). 16 ) J. Jortner:J. Chem. Phys. 64, 4860 (1976). 17 ) S. Efrima and M. Bixon:J. Chem. Phys. 70, 3531 (1979). 18 ) D. Rehm and A. Weller:Ber. Bunsenges. Phys. Chem. 73, 834 (1969). 19 ) D. Rehm and A. Weller:Israel J. Chem. 8, 259 (1970). 20 ) J.V. Beitz and J. R. Miller:J. Chem. Phys. 71, 4579 (1979); J. R. Miller and J.V. Beitz:J. Chem. Phys. 74, 6746 (1981). 21 ) Y. Nosaka, A. Kira, and M. Imamura:J. Phys. Chem. 83, 2273 (1979); A. Kira:J. Phys. Chem. 85, 3047 (1981). 22 ) J. R. Miller, J. A. Peeples, M. J. Schmitt, and G. L. Closs:J. Am. Chem. Soc. 104, 6488 (1982); J. R. Miller, K.W. Hartman, and S. Abrash:J. Am. Chem. Soc. 104, 4296 (1982). 23 ) A. Namiki, N. Nakashima, and K. Yoshihara: J. Chem. Phys. 71, 925 (1979); S. Strauch, G. McLendon, M. McGuire, and T. Guarr:J. Phys. Chem. 87, 3579 (1983). 24 ) L.T. Calcaterra, G. L. Closs, and J. R. Miller:J. Am. Chem. Soc. 105, 670 (1983); J. R. Miller, L.T. Calcaterra, and G. L. Closs:J. Am. Chem. Soc. 106, 3047 (1984). 25 ) C. Creutz, P. Kroger, T. Matsubara, T. L. Netzel, and N. Sutin:J. Am. Chem. Soc. 101, 5442 (1979). 29 ) T. Hino, H. Akazawa, H. Masuhara, and N. Mataga:J. Phys. Chem. 80, 33 (1976); T. Hino, H. Masuhara, and N. Mataga:Bull. Chem. Soc. Jpn. 49, 394 (1976); H. Masuhara and N. Mataga Acc. Chem. Res. 14, 312 (1981). 30 ) Y. Hirata, Y. Kanda, and N. Mataga:J. Phys. Chem. 87, 1659 (1983). 32 ) K. Schulten, H. Staerk, A. Weller, H.-J. Werner, and B. Nickel:Z. Phys. N. F. 101, 371 (1976); H.-J. Werner, H. Staerk, and A. Weller:J. Chem. Phys. 68, 2419 (1978). 33 ) H.-J. Werner, Z. Schulten, and K. Schulten:J. Chem. Phys. 67, 646 (1977). 34 ) A. Weller:Z. Phys. Chem. N. F. 130, 129 (1982); Pure Appl. Chem. 54, 1885 (1982). 35 ) Y. Hirata and N. Mataga:J. Phys. Chem. 87, 3190 (1983). 36 ) Y. Hirata, N. Mataga, Y. Sakata, and S. Misumi:J. Phys. Chem. 86, 1508 (1982); 87, 1493 (1983); Y. Hirata, M. Takimoto, N. Mataga, Y. Sakata, and S. Misumi:Chem. Phys. Lett. 92, 76 (1982). 38 ) Y. Hirata and N. Mataga:J. Phys. Chem. 87, 1680 (1983).

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