0/12 ND(<0.03) g/ 0/12 ND(<0.03) g/ 0/12 ND(<0.03) g/ 0/12 ND(<0.03) g/ 0/12 ND(<0.03) g/ 0/12 ND(<0.03) g/ 0/12 ND(<0.03) g/ 0/12 ND(<0.03) g/ 0/12 N
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1 3(PBB) 0/171 ND(<0.01) g/l ( ) 0/171 ND(<0.01) g/l 0/171 ND(<0.01) g/l 0/171 ND(<0.01) g/l 0/171 ND(<0.01) g/l 0/171 ND(<0.01) g/l 0/171 ND(<0.05) g/l ( ) PBB 0/171 ND 0/48 ND(<2) g/kg 0/48 ND(<2) g/kg 0/48 ND(<2) g/kg 0/48 ND(<2) g/kg 0/48 ND(<2) g/kg 0/48 ND(<2) g/kg 0/48 ND(<10) g/kg PBB 0/48 ND 0/170 ND(<0.01) g/ 0/170 ND(<0.01) g/ 0/170 ND(<0.01) g/ 0/170 ND(<0.01) g/ 0/170 ND(<0.01) g/ 0/170 ND(<0.01) g/ 0/170 ND(<0.05) g/ PBB 0/170 ND 33
2 0/12 ND(<0.03) g/ 0/12 ND(<0.03) g/ 0/12 ND(<0.03) g/ 0/12 ND(<0.03) g/ 0/12 ND(<0.03) g/ 0/12 ND(<0.03) g/ 0/12 ND(<0.03) g/ 0/12 ND(<0.03) g/ 0/12 ND(<0.03) g/ 0/12 ND(<0.03) g/ 0/12 ND(<0.03) g/ 0/12 ND(<0.03) g/ 0/12 ND(<0.03) g/ 0/12 ND(<0.03) g/ 0/11 ND(<5) g/kg 0/11 ND(<5) g/kg 0/11 ND(<5) g/kg 0/11 ND(<5) g/kg 0/11 ND(<5) g/kg 0/11 ND(<5) g/kg 0/11 ND(<5) g/kg 0/11 ND(<5) g/kg 0/11 ND(<5) g/kg 0/11 ND(<5) g/kg 0/11 ND(<5) g/kg 0/11 ND(<5) g/kg 0/11 ND(<5) g/kg 0/11 ND(<5) g/kg 0/48 ND(<2) g/kg 0/48 ND(<2) g/kg 0/48 ND(<2) g/kg 0/48 ND(<2) g/kg 0/48 ND(<2) g/kg 0/48 ND(<2) g/kg 0/48 ND(<10) g/kg PBB 0/48 ND 34
3 0/130 ND(<0.001) g/ 0/130 ND(<0.001) g/ 0/130 ND(<0.001) g/ 0/130 ND(<0.001) g/ 0/130 ND(<0.001) g/ 0/130 ND(<0.01) g/ 0/130 ND(<0.05) g/ PBB 0/130 ND 0/5 ND(<0.03) g/ 0/5 ND(<0.03) g/ 0/5 ND(<0.03) g/ 0/5 ND(<0.03) g/ 0/5 ND(<0.03) g/ 0/5 ND(<0.03) g/ 0/275 ND(<0.001) g/ 0/275 ND(<0.001) g/ 0/275 ND(<0.001) g/ 0/275 ND(<0.001) g/ 0/275 ND(<0.001) g/ 0/275 ND(<0.01) g/ 0/275 ND(<0.05) g/ PBB 0/275 ND 0/5 ND(<0.03) g/ 0/5 ND(<0.03) g/ 0/5 ND(<0.03) g/ 0/5 ND(<0.03) g/ 0/5 ND(<0.03) g/ 0/5 ND(<0.03) g/ 35
4 0/152 ND(<2) g/kg 0/152 ND(<2) g/kg 0/152 ND(<2) g/kg 0/152 ND(<2) g/kg 0/152 ND(<2) g/kg 0/152 ND(<2) g/kg 0/152 ND(<10) g/kg PBB 0/152 ND 0/5 ND(<5) g/kg 0/5 ND(<5) g/kg 0/5 ND(<5) g/kg 0/5 ND(<5) g/kg 0/5 ND(<5) g/kg 0/5 ND(<5) g/kg 0/94 ND(<1) g/kg 0/94 ND(<1) g/kg 0/94 ND(<1) g/kg 0/94 ND(<1) g/kg 0/94 ND(<1) g/kg 0/94 ND(<1) g/kg 0/94 ND(<5) g/kg PBB 0/94 ND 0/141 ND(<2) g/kg 0/141 ND(<2) g/kg 0/141 ND(<2) g/kg 0/141 ND(<2) g/kg 0/141 ND(<2) g/kg 0/141 ND(<2) g/kg 0/141 ND(<10) g/kg PBB 0/141 ND 36
5 PBB 0/27 ND(<0.1-1) g/ HexaBB 0/66 ND(< ) g/ TetraBB 0/66 ND(< ) g/ DecaBB 0/66 ND(< ) g/ PBB 0/27 ND(<5-10) g/kg HexaBB 0/66 ND(<0.9-4,000) g/kg TetraBB 0/66 ND(<0.05-4,000) g/kg DecaBB 0/66 ND(<5-4,000) g/kg HexaBB 0/38 ND(< )ng/m 3 TetraBB 0/38 ND(<0.05-1)ng/m 3 DecaBB 0/38 ND(< )ng/m 3 PBB 0/243 ND(<0.1-1,000) g/kg HexaBB 0/66 ND(<2-1,000) g/kg TetraBB 0/66 ND(<0.1-1,000) g/kg DecaBB 0/66 ND(<2-1,000) g/kg 37
6 4 (HCB) / g/kg 90/ g/kg 43/44 ND(<0.91) 42 g/kg 6/ g/kg 20/ ng/m 3 0/249 ND(<0.05) g/ 0/6 ND(<0.025) g/ 0/19 ND(<0.03) g/ 0/94 ND(<10) g/kg 0/8 ND(<5) g/kg 0/12 ND(<5) g/kg 1/94 ND(<5) 5 g/kg 0/7 ND(<5) g/kg 6/48 ND(<2) 16 g/kg 38
7 0/145 ND(<5) g/kg 0/80 ND(<2-5) g/kg 25/26 ND(<5) 549 g/kg 14/19 ND(<5) 17 g/kg 0/32 ND(<2) g/kg 7/26 ND(<2) 12 g/kg 4/5 ND(<2) 3 g/kg 18/30 ND(<2-50) 65 g/kg 0/30 ND(<2-4) g/kg 0/41 ND(<2-4) g/kg 1/17 ND(<2-5) 6 g/kg 1/14 ND(<2-8) 24 g/kg 2 9/765 ND(< ) g/l 190/792 ND(< ) 480 g/kg 48/63 ND(< ) 3.5ng/m 3 ) 471/1,699 ND(<0.1-5) 28 g/kg ) 87/182 ND(<1-5) 59 g/kg ) 0/461 ND(<1) g/kg 3 ND( ) 0.260ng/ 0.260ng/ ) g/kg 320 g/kg ) ND(<0.1-50) 296 g/kg 296 g/kg 1977 Lake trout(salvelinus namaycush) 3) g/kg 270 g/kg Elbe estuary (Platichthys flesus) 4) 39
8 g/kg g/kg )Stevens,R.J. and M.A.Neilson(1989)Inter-and intralake distributions of trace organic contaminants in surface waters of the Great Lakes. J. Great Lakes Res., Vol.15,No.3, )Oliver,B.G. and K.D.Nicol(1982)Chlorobenzenes in sediments, water, and selected fish from Lakes Superior, Huron, Erie, and Ontario.Environ.Sci.Techno.,Vol.16, )Huestis,S.Y.,M.R.Servos,D.M.Whittle and D.G.Dixon(1996)Temporal and age-related trends in levels of polychlorinated biphenyl congeners and organochlorine contaminants in Lake Ontario lake trout(salvelinus namaycush). J. Great Lakes Res., Vol.22,No.2, )Lucks,B.and U.Harms(1987)Characteristic levels of Chlorinated hydrocarbons and trace metals in fish from coastal waters of North and Baltic Sea. Int.J.Environ.Anal.Chem., Vol.29,
9 5(PCP) (1990 ) 3t(1986 ) (88t) 0.5mg/m /30 ND(< ) 230 g/kg 10/ g/kg 34/44 ND(< ) 61 g/kg 0/249 ND(<0.05) g/ 0/94 ND(<10) g/kg 1/94 ND(<5) 12 g/kg 2/48 ND(<5) 10 g/kg 2 / 2/88 ND(< ) 0.2 g/ 13/83 ND(<2.4-50) 360 g/kg g/ 18 (Salmo gairdneri) 1) 41
10 1)Nagler,J.J.,P.Aysola and S.M.Ruby.(1986)Effect of sublethal pentachlorophenol on early oogenesis in maturing female rainbow trout(salmo gairdneri).arch.environ.contam. Toxicol.,Vol.15,No.5,
11 6 2,4,5- (1975 ) 1t(1975 ) (1t) 1 0/249 ND(<0.05) g/ 0/94 ND(<10) g/kg 0/94 ND(<5) g/kg 0/48 ND(<10) g/kg 2 0/45 ND(<0.01-3) g/ 0/45 ND(< ) g/kg ,000 g/ 11 (Lymnaea stagnalis) 1) 5 6 1)Bluzat,R. and J.Seuge(1983)Chronic intoxication by an herbicide, 2,4,5- trichlorophenoxyacetic acid, in the pond snail, Lymnaea stagnalis L. Environ. Res.,Vol.31,No.2,
12 7 2,4-142t(1999 ) (158t) 14/100 ND(<0.02) 0.26 g/l 0/60 ND(<5) g/kg 0/16 ND(<5) g/kg 0/30 ND(<0.3-34) g/kg 0/10 ND(<13-15) g/kg 0/44 ND(< ) g/kg 37/249 ND(<0.05) 1.56 g/ 11/249 ND(<0.05) 1.15 g/ 6/249 ND(<0.05) 0.42 g/ 0/94 ND(<10) g/kg 0/94 ND(<5) g/kg 0/48 ND(<10) g/kg 0/78 ND(<0.05-1) g/ 0/78 ND(<1-76) g/kg 44
13 50,000 g/ (Chasmagnathus granulata) 1) 1)Rodoriguez,E.M.,M.Schuldt and L.Romano(1994)Chronic histopathological effects of parathion and 2,4-D on female gonads of Chasmagnathus granulata (Decapoda, Brachyura). Food Chem.Toxicol.,Vol.32,No.9,
14 8 (1975 ) 21t(1975 ) (12t) 1 4/249 ND(<0.05) 0.90 g/ 3/249 ND(<0.05) 0.49 g/ 5/249 ND(<0.05) 1.06 g/ 0/94 ND(<10) g/kg 0/94 ND(<5) g/kg 0/48 ND(<10) g/kg 2 0/24 ND(<4) g/ 0/24 ND(<5-20) g/kg
15 9 52t 227t(1999 ) 74t 228t 1 0/30 ND(< ) g/kg 0/10 ND(< ) g/kg 0/44 ND(< ) g/kg 6/249 ND(<0.05) 0.09 g/ 3/249 ND(<0.05) 0.09 g/ 0/249 ND(<0.05) g/ 0/6 ND(<0.05) g/ 0/19 ND(<0.02) g/ 0/94 ND(<10) g/kg 0/8 ND(<5) g/kg 0/12 ND(< ) g/kg 2/94 ND(<1) 20 g/kg 0/7 ND(< ) g/kg 0/48 ND(<2) g/kg 0/145 ND(<1) g/kg 0/80 ND(<2-5) g/kg 0/31 ND(<0.5-2) g/kg 0/30 ND(<1-2.5) g/kg 0/15 ND(<2-50) g/kg 47
16 2 / 0/57 ND(< ) g/ 0/54 ND(<6.8-37) g/kg ,000 g/ 28 (Daphnia pulex) 1) 5 6 1)Schober,U. and W.Lampert(1997)Effects of sublethal concentrations of the herbicide atrazin on growth and reproduction of Daphnia pulex. Bull.Environ.Contam.Toxicol., Vol.17,No.3,
17 10 89t 241t(1999 ) 93t 184t 1 0/249 ND(<0.05) g/ 0/249 ND(<0.05) g/ 1/249 ND(<0.05) 0.38 g/ 0/94 ND(<10) g/kg 0/94 ND(<1) g/kg 0/48 ND(<2) g/kg
Vol.9No.22012
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09030549_001.図書館31-1
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平成１３年度内分泌攪乱化学物質における環境実態調査結果のまとめ
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化学物質の環境リスク初期評価（平成９～１２年度）結果[39物質]
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p,p -DDT 1 p,p -DDT 1,1,1- -2,2- (4- ) CAS 50-29-3 C 14 H 9 Cl 5 354.5 2 109 1) 260 2) 1.5 1) 1.6010-7 mmhg (20 ) 3) 1ppm=14.50 mg/m 3 at 25, n- / 6.366.38 1) 1) 3 4) BOD 0 % ( 2 100 mg/l 30 mg/l) 4) BCF5,10024,400
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N,N- N,N-Dimethylacetamide Acethyldimethylamine CAS 127-19-5 C 4 H 9 NO 87.12 ~ 87.14 87.68413 163-165 C 1) - 18.59 C 2) 1 mg/l 25 C 3) 3.3 hpa 2 C 4) log P ow -.77 2).9429 2/4 C 1) 3.1 4) 1.31E - 8 atm-m
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1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 2 16 17 18 19 20 29 1 21 22 23 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21... 1... 1... 1 PNEC... 2... 2... 3... 4... 4... 5... 6... 6... 6... 6... 6... 7...
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(a) (a) 1010 LC/MS JIS K 04501010 JIS K 04502010 JIS K 04503010 JIS K 04504010 (2) ( JIS K 04505010 JIS K 04506010 JIS K 0128 No 1 PCBPCB 2 αhchβhchγhchδhchp,p DDTp,p DDEp,p DDD I IItranscis transcis HCB
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ORYZA POLYAMINE ORYZA POLYAMINE -P -PC -LC 1. Ver.1.0 MM ver. 1.0MM 1) Roseeuw D.I. et al., Epidermal keratinocytes actively maintain their intracellular polyamine levels. Cell Tissue Kinet. 16, 493-504
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10 1931 10 1050 H21 2,900 45.9% (14%) 253 4.0% 6,321m 3 (100%) 816 12.9% (21%) m 3 2,351 37.2% (41%) 8130 598 1,024m 3 8248% 198m 3 58 7% 1,758m 3 55% 48%+7%=55% 22 519 26 10 4 1 3 Vol53No.4,1998