Matsusiro Hamasumi and Goro Ohira : - The System Fe-Cu-Fe3C The equilibrium diagram of Fe-Cu-Fe3C presented by Ishihara, Ishigaki and Yonekura in 1932

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1 Matsusiro Hamasumi and Goro Ohira : - The System --3C The equilibrium diagram of --3C presented by Ishihara, Ishigaki and Yonekura in 1932 is revised in the present investigation, The research was carried out by thermal and dilatometric. analysis and by microscopic examination, using electrolytic iron, electrolytic copper and pure white cast iron as raw materials. The following three points are of special value. to mention. (1) The monoteetic reaction suspected by many authors do not exist on the - side. The region consisting of two liquid layers extends from the -3C side so closely to the - side and the critical point lies at 1435 and at the composition containing 40o of, 60 of and 0.1 of C. (2) The ternary eutectoid of, and 3C lies at 702 and it contains 6.5 of and 085 of C. The structure consists of alternate layers of,ferrite and cementite, and the fine globules of copper in ferite. (3) The equilibrium state of copper corner is precisely investigated and a peritecto-eutectic point was found of 1092, which contains 2.70 of and 0008 of C. The whole results obtained are represented in the diagram of Fig. 36. (Received April 8, 1941) (1) K. Daeves : Stahl u. Eisen, 46 (1926), (2) R. Schenck, T, Dingmann, P. H. Kirscht, H. Wesselko ck: Z. anorg. allg. Chem., 182 (1929), 97. H.Kirscht : Stahl u. Eisen, 52 (1932), W. Storey : Trans. Amer. Electrochem. Soc., 89 (1921), 175. (3) H. B, Kinnear: lion Age, 128(1931), 696. H. Buchholz, W. Koster : Stahl u. Eisen, 50(1930), 687. C. S. Smith, B. W. Palmer : Trans. Amer. Min. Met. Eng., 105 (1933),133. (4) A. F. Stogoa, W. S. Messkin : Arch. Eisenhiittenwes., 2 (1928), 321, (5) D. Hanson, J. W. Ford ; J. Inst, Metals, 32 (1924), 335. (8) W. Lipin : Stahl u. Eisen, 20 (1900), 27 (1907). (9) F. H. Wingham. Metallurgie, 3 (1906). (10) W. Miller : Stahl u. Eisen, 26 (1906). (11) J. E. Stead : J. Iron Steel Inst, 60 (1901). (12) R. Sahmen : Z. anorg. allg. Chem., 57 (1908), 9. (13) R.Ruer : rrum, 14 (1917), 49. (14) F. Ostermann : Z. Metallk., 17 (1925), 278. (15) Muller: Mitt, K,-W.-Inst. Eisenforscli., 9(1927),173,

2 (16) 0. Reuleaux : Metal u. Erz, 24 (1927), 99, 129. (17) C. Benedicks : Z. Phys. Chem., 131 (1928), 285. (18) Vogel, Dannohl : Arch. Eisenhuttenwes., 8 (1934/5), 39. (19) J. La Gregg, B. N. Daniloff : "Alloys of Iron and Copper (Alloys. of Iron monograph)" (1934), 33. (20) M. Hansen : "Aufbau der Zveistofflegierungen" (1936),560. (22) W. R. Haddocks, G. E. Clausen : The first report of the Alloy Steel research comittee (Iron & Steel Inst Special report No ). (23) Sir Harold Carpenter, J. M. Robertson : "Metals" 2(1939). (24) John T. Norton : Trans. A. I. M. E, 116 (1935), 386.(25) G. Tarnmann, W. Oelsen : Z. anor5. allg. Chem.,186 (1930), 257, (26) Guertler : Z. anorg. Chem., 51 (1906), 397. (27) Mathiessen, Holzmann : Pogg Ann., (1860), 110, 222.(28 ) W, Hempel : Z. angew. Chem., 17 (1904), 321. (29) W. Guertler : "Metallographie"Berlin (1913) 1 part 2645,

3 Fig. 3 3C- diagram proposed by Ishihara. Fig. 4 3C- diagram proposed by the authors. Fig. 5 The Qualitative diagram of the ternary system --3C

4

5 (30) T. Ishihara : Science report of Tohoku Imp. Univ., 14 (1925), 377. (31) L. Reed : Trans. Amer. Soc. Steel Treat., 20 (1932), 115. (32) R. Ruer, R. Klesper : Perrum, 11 (1014), 257.

6

7 Fig. 9 The sectional diagram at 0. Fig. 10 The sectional diagram at 1. Fig. 11 The sectional diagram at 2. Fig. 12 The sectional diagram at 3. Fig. 13 The sectional diagram at 5. Fig. 14 The sectional diagram at 7. Fig. 15 The sectional diagram at 10. Fig. 16 Tho sectinn al diagram at 12. Fig. 17 Primary Crystallization surfaces and Isothermal curves of the --3C-system.

8

9 Fig. 21 Primary crystallisation ranges and isothermal curves of the copper corner.

10

11 Fig. 24 Determination of ternary eutectoid by microscopic observation. Fig. 25 Crystallization surface of a- and isothermal curves.

12 Fig. 27 Ternary eutectoid plane of the corner. Fig. 28 The sectional diagram at 0 5. Fig. 30 The sectional diagram at 4. Fig. 29 The sectional diagram at 2. Fig. 31 The sectional diagram at 5e. Fig. 32 The sectional diagram at 0.15C. Fig. 34 The sectional diagram at 0.55 C. Fig. 33 The sectional diagram at 0.25C. Fig. 35 The sectional diagram at 0.77 C.

13 Fig. 36 The equilibrium diagram of the --3C system.

14 258 研 1 C rest ~250 Primary 2, boundary CO rest ~250 Primary. 究, boundary. 5 rest CO-3 Separated into phase'upper 50 charged. ~ layer: C 0.02 rest. 9 cooled 10 hrs Etched two layer: at rest, , Primary 5 separated as mass mass 7 rest. globules, 50 4 of, dendrite of with 10 solid solid solu ground tion. C rest ~250 Primary dendrite mass solution. Etched Primary ground solution. ~250, solid C O-005 (NH4)2S203 ~250 Homogeneous. tion. dendrite mass of, (solid solu Slow annealed Picral. 10 b cooled from 10hrs at Etched ~ Lower 780. with C 0.33 rest ~250 ground CO-62 from liquid 6 CO-01 rest ~250 ground 第5巻 ground with rest. Etched Separated ctoide-phase 5 Picral. 8-phase mass 13 Slow annealed - CO-73 Slow cooled with 5 X1500 of, 11 rest CO-36 Slow cooled 4.95 from 1050 Etched with 5Picral. ~ and - from C eu tectoid. Slow Etched Picral. ~1500 ternary cooled with ground CO net mass from Picral. ~1500 work ternary 12 of 3C, eutectoid. C 0.76 rest.slow with Boundary und Boundary eute- Etched eutectoid. grohule,proeute and 780 Boundary eutectoid , mass 7.06 cooled from 5 Picral. ~1500 E-phase ternary of 1050., eutectoid. gro

9) H. SCHMCLZRIED: Z. Elektrochem. 66 (l%1) p ) W. D. KINGERY et al.: J. Am. Chem. Soc., 42 (1959), p ) F. HUND: Z. Phys. Chem., 199 (195

9) H. SCHMCLZRIED: Z. Elektrochem. 66 (l%1) p ) W. D. KINGERY et al.: J. Am. Chem. Soc., 42 (1959), p ) F. HUND: Z. Phys. Chem., 199 (195 9) H. SCHMCLZRIED: Z. Elektrochem. 66 (l%1) p. 572 10) W. D. KINGERY et al.: J. Am. Chem. Soc., 42 (1959), p.394 11) F. HUND: Z. Phys. Chem., 199 (1952), p. 142 12) J. F. ELLIOTT and M. GLEISER: " Thermochemistry

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