INTRODUCTION
CONTENTS 2 2 2 3 10 14 16 18 20 1
1 1 1 1 ()3SiO(SiO)n Si()3 SILICONE OIL HOSi O(SiO)nSiOH 2
1 2 40 50 60 ()3SiO(SiO)x (SiO)ySi()3 70 0 5 10 15 20 25 3 ()3SiO(SiO)n Si()3 H 3
1 1 2 1 ()3SiO(SiO)x (SiO)ySi()3 R SILICONE OIL R (dync/cm) 22 26 30 34 () 3SiO(SiO) n Si() 3 R 0 4 8 12 R 2 ()3SiO(SiO)nSi()3 (CH2)2 CF3 4
1 3 POA-R-SiO(SiO)n Si-R-POA ()3SiO(SiO)x (SiO)y Si()3 R POA POA-R- ( SiO- ) Si-POA-R' m n POA 5
1 4 H2NRSiO (SiO)n SiRNH2 ()3SiO(SiO)x (SiO)y Si()3 R NH2 ()3SiO(SiO)x (SiO)y Si()3 R NH ()3SiO(SiO)x (SiO)y Si(SiO)z Si()3 ()3SiO(SiO-) x -(SiO-) y Si()3 R NH2 NH2 R POA POA-R-(SiO-) x -(SiO-) y Si-POA-R' n R NCO R'(EO)n R" H 6
1 5 CH2-CHCH2OR(SiO)nSiROCH2CH-CH2 O O ()3SiO(SiO)x (SiO)y Si()3 ROCH2CH-CH2 O ()3SiO(SiO)x(SiO)ySi()3 R (kgf/mm2) 1500 1400 1300 1200 SH200-3000cs 1.8 1.2 1.8 Blank 0.8 ()3SiO(SiO)x(SiO)y(SiO)ZSi()3 R POA O CH2CH-CH2 O 1000 1100 1200 (kgf/cm2) 7
1 6 HO RSiO(SiO)nSiR OH 7 HOOC-R-SiO(SiO)n Si-R-COOH ()3SiO(SiO)x(SiO)ySi()3 R COOH 8 O O H2C=CCO(CH2)3 SiO (SiO)n Si(CH2)3 OCC=CH2 8
1 9 9
2 SILANE 21 10
2 1000 1500 500 0 50 100 2 2 SILANE 11
2 2 3 SILANE + OMe Si OMe OMe Z-6300 ROOR Heat OMe Si OMe OMe Si MeO MeO MeO MeO Si OMe OMe H2O MeO MeO O Si Si OMe OMe Polyethylene 12
2 80 70 Z-6358BY27-614 60 50 40 30 20 10 0 0 30 60 90 120 150 180 76 74 PE B/Z-6398 72 70 PE C/Z-6398 68 66 64 62 60 0.5 0.6 PE A/Z-6398 0.7 0.8 0.9 1 2 3 13
3 3 1 0-50 SILICONE POWDER -100 0 100 200 300 400 500 600 700 800 900-150 -100-50 0 50 100 150 200 3 2 SILICONE POWDER 0-50 -100 0 100 200 300 400 500 600 700 800 900 40 30 20 10-150 -100-50 0 50 100 150 200 0 n 1 2 3 4 5 6 7 8 9 10 14
3 3 3 CH2=CHSi(OC2H4O)3 CH2=CHSi[OCH()2]3 SILICONE POWDER (C2H5O)3Si(CH2)3-Sx-(CH2)3Si(OC2H5)3 3- x = 3.75 (C2H5O)3Si(CH2)3-Sx-(CH2)3Si(OC2H5)3 3- x = 2.1 15
4 1 2 3 0.6 0.4 0.2 1000cs 0 20 40 60 80 100 PVkg/cm 2 cm/sec1kg/cm 2 4 1 4 2 SILICONE CONCENTRATE SILICONE CONCENTRATE 16
4 0.5 0.4 0.3 0.2 0.1 P2kgf 3wt% APP ABY27-001PP 0 20 40 60 80 100 Vcm/sec B A P V 0.4 PP 0.2 BY27-201PP 0 20 40 60 80 P=1kgf/cm 2 A B V APP BPP PP PVkgf/cm 2 cm/sec 17
5 5 1 Heat Release Rate, kw/m 2 1000 800 600 400 200 Qext=30kW/m 2 100% Polypropylene 75% PP, 25% Mg(OH)2 75% PP, 20% Mg(OH)2 5% DC4-7081 SILICONE POWDER 0 0 200 400 600 800 Time, seconds 18
5 5 2 SILICONE CONCENTRATE 5 3 SILICONE RESIN 19
6 20
6 r r/ R 21
7