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Organic Nonlinear Optical Materils Osamu Watanabe E P P E P ε 0 E EE EEE ε 0 (n) n n NLO d (2) =2d (1) SI P E E F ζe P p ε 0 αf βff γfff α β γ α β γ π R&D Vol. 27 No. 1 ( 1992. 3 )

NLO effects and the applications. ω ωω ω ω ω ω ω ω ω ω d d d R&D Vol. 27 No. 1 ( 1992. 3 )

d n n π π π γ π P 2ω = 2µ 0 3/2 ε 1/2 0 ω 2 d 2 eff L 2 sin P 2 kl/2 ω P ω An 2ω n ω kl/2 2 ω ω µ ε ω eff ω ω ω ω ω ω ω ω π ω lc ω ω e o ω = ω Theoretical relationships between P 2ω and L. R&D Vol. 27 No. 1 ( 1992. 3 )

Absorption edge and d coefficients of representative crystals. Angle phase matching for positive uniaxial crystal. o n ω : refractive index for ordinary ray of fundamental wave n e ω (θ): refractive index for extraordinary ray of fundamental wave o n 2ω : refractive index for ordinary ray of SHG wave e n 2ω (θ): refractive index for extraordinary ray of SHG wave β β β µ β = ge f 2 2 E g 2 E g hν 2 2 E g 4 hν 2 f µ ν f µge g β R&D Vol. 27 No. 1 ( 1992. 3 )

β β d d d 11 d 11 d 12 d 11 d 11 d Chemical structures and SHG powder efficiency of low molecular weight compounds for second NLO materials. R&D Vol. 27 No. 1 ( 1992. 3 )

d ii d β d d 33 β π d d 11 d 12 µ β R&D Vol. 27 No. 1 ( 1992. 3 )

µ β µ Chemical structures of polymers and low molecular weight compounds for second NLO materials. R&D Vol. 27 No. 1 ( 1992. 3 )

d d d µ Chemical structures of polymers and low molecular weight compounds for second NLO materials. R&D Vol. 27 No. 1 ( 1992. 3 )

β π π β β d d R&D Vol. 27 No. 1 ( 1992. 3 )

ε ε Chemical structures of low molecular weight compounds for third NLO materials. Chemical structures of polymers for third NLO materials. R&D Vol. 27 No. 1 ( 1992. 3 )

α τ α τ π β γ β β α R&D Vol. 27 No. 1 ( 1992. 3 )

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