vol.6 2003.3
1
2 ()
3
4
5
A.Postuma, P.L. Zuidveld, J.E.G. Ploeg 6
7 SRU CLAUSGAS HCU H 2 SWS Ni/V BFW CO 2
8
9 3 SCGP HP
t/d 10 10 6 NM 3 /d Demkolec Buggenum, NL 2000 4.0 1994 Shell Rotterdam, NL 1650 VFCR 4.7 H 2 / 1997 Lanzhou Chem. Lanzhou, PRC 700 VR 2.1 1998 Chemopetrol Litvinov, CZ 1250 VFCR 3.6 /H 2 2001 (R) Lucky Goldstar Naju, Korea 225 VR 0.7 2001 (E) Shuanghuan Chem. Yingcheng, PRC 900 1.3 2004 Sinopec/Shell Dongting, PRC 2000 3.4 2005 AgipPetroli Sannazzaro, It 1200 VFCR 3.4 /H 2 2005 Indian Oil Co. Paradip, India 2300 5.0 /H 2 2005 Sulcis Sardinia, It. 5000 7.0? Liuzhou Chem. Liuzhou, PRC 1200 1.7 2004 Sinopec/Shell Hubei, PRC 2000 3.4 2005 Sinopec/Shell Anqing, PRC 2000 3.4 2006 R E
11
Buggenum AR 5 4.5 30.7 MF 5.7 35.0 (0.5) MF 5.3 16.3 (0.1) MF 0.3 5.2 MF 0.01 0.4 MJ/kg 22.8 33.1 (35.6) AR= MF= 12
Rosa Domenichini, Robert Giglio 13
14 : CCU : PGCC : / SC : GCC : / PC-CFB
15 CO22001 CO22010 2001 2010 CO2 kg/mwh LHV CFB OTU CFB CFB ESP CO2 kg/mwh LHV CO22001 CO22010 2001 2010
CFB CFB PC PC OUTCFB OUTCFB ESP 16 8 % wt 3.0 a.r. M C 15 % RH 60 GE-6FA GE-7FA GT MWe 87.5 197.5 MWe 15 30.5 MWe 72.5 167 ST MWe 250.1 411.3 ST MWe 21 32.8 MWe 229.1 378.5 MWe 337.6 608.8 MWe 35.1 63.3 % 10.4% 10.4% MWe 302.5 545.5 %LHV 44.9 46.8 kcal/k 1915 1837 Wh t/h 47 94 CFBPC t/h 36 51 2000/80/CE CFBPC t/h 18 34 mg/nm Kg/MWh @ mg/nm 3 @ 6% O 2 vol 6% O 2 vol CFB t/h 22 38 t/h 32 56 SO x 96 0.63 200 200 0.47 150 200 CO 0.47 150 Hg 50 1 ppmv 99.995 < 20 30 EPC $/kwe 1200-1400 1100-1300 net NO x t/h 545/571 841/896 bar a 270 270 C bar a 580/600 0.042 580/600 0.042
Me LHV 19 9 36 8 17 18 21 2004 8 2005 2 CFB 2003 6 2006 2 GT 31 4 2006 7 2006 10 2007 6
18 1 CO22CO H2OCOH2 COH2OCO2H2 O2CO2H2O O2COCO2
19
20 250MW 1,700t/ MDEA 1,200 48 % 42 % SOx 8 ppm NOx 5 ppm 4 ppm LHV O2 16
CCP 21
22 CCP 30 70 9
23
24 TIF(145 TIF(145 TIF(145) TIF(145 ) PICF ICFG PICF ICFG TIF TIFG(20 (20 ) TIF TIFG(20 (20 ) PTIF TIFG(3 (3 ) PTIF TIFG(3 (3 ) SDP(38 SDP(38 SDP(38) SDP(38 ) ICFB(2 ICFB(2 ) ICFB(2 ICFB(2 ) PICFB ICFB PICFB ICFB ICFG ICFG
25 TIFG Twin Internally Circulating Fluidized Bed Gasifier EUP Ebara Ube Process TIFG Twin Internally Circulating Fluidized Bed Gasifier EUP Ebara Ube Process EUP Ebara Ube Process
4045 2530 3350 m 3 (NTP)/h DB / (DB) + 99.9 20002200 m 3 (NTP)/h DB 180200kg/h - m 3 (NTP) 26
27 IC FG
28
() 29
30
31
32
33
34
35
36
CaS 37 CaS, ST GT
470MW (%) 85 7580 257MW(1,350) 1060 750 213MW (593/593,16.7Ma) (kcal/m 3 (N),dry) 110 1000 110140 (HHV) 46.0% S (ppm) 8.9% CsS (%) 1 0.20.5 85 (%) 1 0.20.3 1,150kcal/Nm 3 38
39
40
41
42
43
44
45
46
Center for Coal Utilization, Japan