English Version Guidelines for Surveying Controlled Chemical Substance Content in Products SEG Green Purchasing Standard for Production Materials Ver. 2.0 Established : January15, 2003 Revised : August 15, 2003 Enacted : September 1, 2003 Seiko Epson Corporation CS/Quality Assurance and Environment Department
Table of Contents 1. Purpose 2. Scope 3. Survey Response Method 4. SEG Survey Response Tool Overview 5. Using the SEG Survey Response Tool 6. Survey Response Procedure 7. Notes on Chemical Substance Survey 8. Additional Clause Appendix 1: Chemical Substance Group List Appendix 2: List of Breakdown Substances Appendix 3: Certain Amines (Formed Through Cleavage of One or More Azo Bonds) Appendix 4: CSV Format for Survey Responses Appendix 5: Survey Response Format Creation Manual 1
1Purpose Based on the "SEG Green Purchasing Standard for Production Material," these guidelines describe how to use the software tool to respond to the controlled chemical substance content survey. These guidelines are intended to provide the information you will need to complete and submit the survey. Note As a member of the Japanese Green Procurement Survey Standardization Initiative (JGPSSI) workgroup, Seiko Epson Corporation has adopted the JGPSSI's standard survey tool for gathering information about the controlled-substance content of supplier products used in Seiko Epson Group (SEG) products. Although based on the JGPSSI's standard survey, the "SEG Survey Response Tool" also contains SEG-specific items. Ref.) The Japanese Green Procurement Survey Standardization Initiative (JGPSSI), a consortium made up of 50 Japanese electronic equipment manufacturers, is working jointly with the EICTA (European Information and Communications Technology Association) and the EIA (US Electronics Industries Alliance) to develop global standards for green purchasing surveys. 2Scope Falling within the scope of the survey are all production materials that make up a product of the SEG. Note Vendors will also be asked to respond retroactively for existing production materials that the SEG has already decided to use and that vendors are supplying. Packing materials used for transport and storage do not fall within the scope of this survey. 3Survey Response Method Please use the SEG survey response tool to report the controlled-substance content of new and existing production materials delivered to the SEG. The controlled substances are set forth in "SEG Green Purchasing Standard for Production Material." The only thing you, the vendor or supplier, are required to provide is a.csv file created using the SEG survey response tool. In this survey, you are asked to provide content information down to the chemical substance group. Where possible, however, the SEG would like you to provide information down to the breakdown substance. However, for SEG additional controlled chemical substance group, enter only the chemical substance group. Note Here, "content" and "include" mean the intentional addition of a chemical substance to provide the product with functionality or features deemed necessary for the product design or manufacture. Naturally occurring impurities and residual solvents, unreacted monomers, and other residual substances from a common industrial precision manufacturing process are not considered to be intentionally added. "Content information" refers generally to information indicating the presence or absence of a substance, the amount contained, parts where substance is included, and purpose of inclusion. Production materials are classified as either "new" or "existing." Production materials delivered on or before February 28, 2003, are considered to be "existing production materials." Production materials accepted after February 28, 2003, are considered to be "new production materials." For information on the SEG survey response tool, see "4. SEG Survey Response Tool Overview." For information on entry items, see "5. Using the SEG Survey Response Tool." For information on creating.csv files, see "Appendix 5: Survey Response Format Creation Manual." 4 SEG Survey Response Tool Overview The SEG survey response tool consists of the three parts listed below. A maximum of 100 production material items can be entered per file. Basic Information Survey: General survey to provide information about SEG, the vendor, production materials, and chemical substances included in materials. Chemical Substance Survey (1): Information on the inclusion of chemical substance groups Chemical Substance Survey (2): Information on the inclusion of breakdown substances Note When providing information on chemical substance groups, information can be entered directly into the Chemical Substance Survey (1) file. Data provided for breakdown substances in Chemical Substance Survey (2) breakdown substances is automatically tabulated and displayed in Chemical Substance Survey (1). Chemical substances are listed in "Appendix 1: Chemical Substances Group List." Breakdown substances are listed in "Appendix 2: List of Breakdown Substances." 2
5Using the SEG Survey Response Tool (1) Basic Information Survey New production materials (a) Reference number: not needed (b) Date of data entry: not needed (c) Surveying company: not needed (d) Surveyed company: Enter company information Ex.) Company name: A Corporation Address: 0123 A Street, New York, New York Division name: A Division, B Department, C Section Contact name: Gary Green Telephone number: 12-3456-7890 Fax number: 12-3456-7899 Email address: a@bc.co.jp Column 4 (date of data entry by vendor): 2003/03/01 Column 5 (vendor code): 012345 (6-digit vendor code specified by SEG) Column 6: (leave blank) (e) Part number, Part name, Surveying company columns 1 3 Please enter the part No. and part name specified by the SEG. The SEG may ask vendors to fill in Surveying Company Columns 1-3. Ex.) Part number: 0123456 (7-digit code assigned by SEG) Part name: Upper Case A (part name assigned by SEG) Surveyor item 1 comment : (space for vendor comments) Surveyor item 2 : (Enter only if requested by SEG) Surveyor item 3 : (Enter only if requested by SEG) (f) Manufacturer's name, Part number, and Surveyed company column 1-3 Please enter the name of the manufacturer and the part number used by the manufacturer. SEG may ask vendors to fill out Surveyed Company Columns 1-3. Ex.) Manufacturer: Widgets Inc. Part number: B5789 (Manufacturer model No.) Surveyed company column 1: (Enter only if requested by SEG) Surveyed company column 2: (Enter only if requested by SEG) Surveyed company column 3: (Enter only if requested by SEG) (g) Unit Select the unit from the pull-down menu. Choose the most appropriate unit from among the following choices: pcs, cm2, m2, m3, m, liter, g. Note Please DO NOT select kg. If applicable, use the unit specified by SEG. For raw materials, select "g". (h) Part Mass Enter in grams the total mass per unit selected in the "Units" column. Note For raw materials, enter "1" for the part mass. 3
(i) Use of ozone-depleting substances Leave this area blank. Instead of asking vendors to respond to this item, the SEG asks each vendor to submit a "Certification that Substances Banned from Manufacturing are Not Used." (j) List A Substances Contained If the production material contains a chemical substance listed in "Appendix 1: Chemical Substance Group List," enter "1". Then, click the Input button under the "List A Substances" column. If the production material contains none of the chemical substances, enter "0". The survey is complete. Existing Production Materials (a) Reference number: Used by the SEG as a number for controlling the file. (SEG will enter the number.) Ex.) Reference number: EPSON-HQ02-0001 (EPSON - division code & fiscal year - serial number) (b) Date of data entry: SEG will enter the date that the survey was requested. Ex.) Date of data entry: 2003/03/01 (c) Surveying Company: Information about the SEG. Columns 1-3 are used based on SEG's settings. Note This portion of the form is strictly for SEG use. Please DO NOT make any entries. Ex.) Division name: (leave blank) Contact name: (leave blank) Telephone number: 0266-52-8782 Fax number: 0266-52-8409 Email address: green-purchasing@exc.epson.co.jp Column 1: (leave blank) Column 2: (leave blank) Column 3: (leave blank) (d) Surveyed company: Information about the vendor Note The SEG will fill out the Company name cell and Column 5 (vendor code). Vendors are asked to fill out all other items in this section of the form. Ex.) Company name: A Corporation Address: 0123 A Street, New York, New York Division name: A Division, B Department, C Section Contact name: Gary Green Telephone number: 12-3456-7890 Fax number: 12-3456-7899 Email address: a@bc.co.jp Column 4 (date of data entry by vendor): 2003/03/01 Column 5 (vendor code): 012345 (6-digit vendor code specified by SEG) Column 6: (leave blank) 4
(e) Part number, Part name, Surveying company columns 1-3 The SEG will enter the part number and part name used by the SEG. The SEG may ask vendors to fill out Surveying company columns 1-3. Ex.) Part number: 0123456 (seven-digit code assigned by SEG) Part name: upper case A (part name specified by SEG) Surveying company column 1 comment: Production discontinued. (space for vendor comments) Surveying company column 2 : (Enter only if requested by SEG) Surveying company column 3 : (Enter only if requested by SEG) (f) Manufacturer's name, Part number, Surveyed company column 1-3: The SEG will fill in the manufacturer's name and part number (used at surveyed company). SEG may ask vendors to fill in Surveyed company columns 1-3. Ex.) Manufacturer: Widgets Inc. Part number: B5789 (manufacturer's part number) Surveyed company column 1: (Enter only if requested by SEG) Surveyed company column 2: (Enter only if requested by SEG) Surveyed company column 3: (Enter only if requested by SEG) (g) Survey unit: Select the counting unit from the pull-down menu. (For the survey, choose the most appropriate unit from among the following choices: pcs, cm2, m2, m3, m, liter, g) Note Please DO NOT select kg. If applicable, use the unit specified by SEG. For raw materials, select "g". (h) Part mass Enter in grams the total mass per unit selected in the "Units" column. Note For raw materials, enter "1" as the part mass. (i) Use of ozone-depleting substances Leave this area blank. Instead of asking vendors to respond to this item, the SEG asks each vendor to submit a "Certification that Substances Banned from Manufacturing are Not Used." (j) List A Substances Contained If the production material contains a chemical substance listed in "Appendix 1: Chemical Substance Group List," enter "1". Then, click the Input button under the "List A Substances" column. If the production material contains none of the chemical substances, enter "0". The survey is complete. (2) Chemical Substance Survey Items that apply to both existing and new production materials The Chemical Substance Surveys are used to obtain information on chemical substances included in production materials. Chemical substances need to be specified at least down to the substance group unit based on "Appendix 1: Chemical Substance Group List." Where possible, however, please provide the breakdown substance based on "Appendix 2: List of Breakdown Substances." 5
(a) Total sum (content on Group Level) Enter in number of milligrams of a chemical substance contained per specified unit (the unit selected in the "Unit" column of the Basic Information Survey) of the production material. Round the figure up or down at the second significant digit (so that the third digit is rounded to the nearest whole number). Ex.) 2549 mg would be rounded to 2500 mg 1.1456 mg would be rounded to 1.1 mg 0.00214 mg would be rounded to 0.0021 mg 0.1 mg would be rounded to 0.10 mg (b) Application Enter the name of the application (part or location) that contains the chemical substance. Use either the generic name of the application or the name your company uses to identify the application. If the same chemical substance is included in multiple applications, enter the name of the main application. Please refer to the following examples. Note An "application" is defined as an item shown in a structural drawing of the part or product in question or listed in the bill of materials for the part or product. Production materials procured by the SEG are categorized as follows. Devices and OEM products (finished products and electric/electronic device products procured on an OEM basis, etc.) Entry ex.) chassis, upper case, cable, board unit, manual, etc. Assembled electronic parts (unit electronic parts, power supply board, interface board, etc.) Entry ex.) stacked ceramic capacitor, electrolytic capacitor, printed circuit board, solder for assembly. Single electronic parts (single parts denoted by the symbols L, C, R, etc. in electronic circuit diagrams) Entry ex.) ceramic material in stacked ceramic capacitor, internal electrode material and external electrode material, lead wire of electrolytic capacitor, electrolytic fluid, sealing material, and electrode foil. Mechanical part (parts such as screws and chassis that are formed by processing a material and that do not have electrical functions) Entry ex.) ABS, PS and other plastic materials; SECC, SPCC and other steel sheet and rod material, etc. Raw materials (raw materials for plastics, steel sheets, rod material, etc.) Entry ex.) Surface, within raw material. Process materials (materials used in manufacturing processes such as solder and marking ink) Entry ex.) Within material. Packing material (wrapping paper, cardboard, plastic, tape, marking label, fastener, cushioning material, desiccant, and other material for transporting and storing device products, electronic components, and so forth) Entry Ex.) Surface, within material, marking ink. (c) Purpose of use: Enter the purpose for which the chemical substance is used. Ex. 1) Stabilizer, plasticizer, colorant, flame retardant, rust prevention, solder component, etc. Ex. 2) Primary component, thermal stability enhancement, electrical property enhancement, mechanical property enhancement, etc. Ex. 3) Impurity (if the content ly exceeds the threshold value), etc. (d) Method of entering SEG additional controlled chemical substance group: If included in your product is a chemical substance listed in Table 1 "SEG additional controlled chemical substance group" (see Appendix 1 Chemical Substance Group List), click the "Input button" on line C99 Other in the Chemical Substance Survey (1), and enter it on Chemical Substance Survey (2). 6
6Survey Response Procedure Procedure for new production materials (1) Download the most recent SEG Survey Response Tool from the Seiko Epson Corp. (2) Enter the required chemical substance content information into the following worksheets in the SEG Survey Response Tool: Basic Information Survey Chemical Substance Survey (3) Send the completed.csv file by e-mail or on a floppy disk or other storage medium to the person in the SEG Group who requested the survey. Use the following file naming convention when submitting your file: "new" + "vendor name" + "date".csv For example, if Widgets Corp. submits a completed new production material survey on March 1, 2003 the filename would be as follows: newwidgets20030301.csv. Note: Trading companies and distributors need to survey the manufacturer. Completed survey files should be submitted using the trading company or distributor name. (4) SEG reviews the data using a data checking tool. * Screen capture of a sample.csv file 7
Procedure for existing production materials (1) SEG fills out the vendor and production material information in the SEG Survey Response Tool. (2) After entering the required information, SEG sends the.csv file created using the SEG Survey Response Tool to the vendor by e-mail or on a storage medium. (3) The vendor enters the required chemical substance content information into the following worksheets in the SEG Survey Response Tool: Basic Information Survey Chemical Substance Survey (4) The vendor returns the completed.csv file to the person in SEG from whom the request was received, by e-mail or on a floppy disk or other storage medium. Note: Do not change the name of the file. Note: Trading companies and distributors are asked to survey manufacturers and to organize.csv files for submission, using the manufacturer's name for the returned file. (5) SEG reviews the data using a data checking tool. * Screen capture of a sample.csv file 8
7Notes on Chemical Substance Survey (1) Content level in responses For intentionally added substances, please provide the exact amount of content level instead of the "threshold value." If the concentration of the following unintentionally included substances is equal to or greater than the level indicated below, please provide the amount: Cadmium: 75 ppm Lead (only in plastics): 100 ppm Lead (excluding in plastics and including solder), mercury, chromium VI: 1000 ppm Chemical substances for which no response is received will be considered to have been unintentionally added. (2) Calculation of content level Content figures may be actual measured values or theoretical values, calculated values, or design values. If the content level has a wide variation according to manufacturing lot, please provide the general maximum value, or the mode or average value. When calculating the content level of a part, include the chemical substances contained in purchased parts and materials that comprise the part, not only the substances included in the manufacturing process. (3) Metals and metal compounds For metal compounds, please provide content values that have been converted to a metal element amount, instead of the amount of included compounds. You can convert values to metal elements by multiplying the molecular weight of the compound by a conversion factor. Representative conversion factors are provided in "Appendix 2: List of Breakdown Substances." In the case of metal alloys, please enter the amount of chemical substance included in the alloy. For chemical substances not listed in "Appendix 2: List of Breakdown Substances," please look up the conversion factor, perform the calculation, and enter the amount. Ex. 1) Ex. 2) The amount of antimony when antimony trichloride (sbcl 3 ) is included is expressed by a value found by multiplying the amount of antimony by the conversion factor 0.534. (antimony trichloride) 100 mg x 0.534 = 53 mg (amount of antimony) In the case of eutectic solder, please provide not the solder amount (mass) but the amount (mass) of lead contained in the solder. Note Nickel compounds and chromium compounds do not include metal nickel or metal chrome. Therefore, metal nickel and metal chrome found within alloys such as stainless steel are exempt from the survey. Exclude oxide layers and so forth that reside on a metal surface in the normal state. (4) Chemical substances used in processes You do not need to include solvents, cleaning agents, foaming materials and so forth that are used in the manufacturing process but that do not remain on products. (5) Precautions The following items often contain the substances that are the focus of this survey, so please check them especially closely. Lubricants such as grease that are used with bearings, levers and in other components having moving parts Flame-retardants in resin materials Polyvinyl chloride, flame retardants and stabilizers in lead wire jackets (cladding) Special metals (alloys) used for electrical lubrication of contacts and so forth Additives in belts, rollers, bushings, tubes, and other rubber parts Paints, varnishes, and other materials used to mark color codes and so forth 9
(6) Chemical substances consisting of multiple chemical substances A chemical substance that is made up of multiple chemical substances is considered to fall under the category of each substance it contains and, hence, requires that you provide information in accordance with the component percentage. For example, if a chemical substance includes lead chromate, the you would enter the amount of lead in the "Lead and its compounds" column and the amount of chromium VI in the "Chromium VI compounds" column. (7) Azo compounds Certain azo dyes and certain azo pigments are subject to control. Specifically controlled are those that give rise to certain cancer-causing amines [listed in "Appendix 3: Certain Amines (Formed Through Cleavage of One or More Azo Bonds)"] in the process of using a product designed such that it is constantly touched by the user. Therefore, assembled electronic and electric components inside a case, for example, are not subject to control, as they are not in constant contact with users. 8Additional Clause (1) Revision and withdrawal This standard shall be revised and/or withdrawn based on the Seiko Epson Group Green Purchasing Standard (No. C3A1-02-1). (2) Revision history Version Establishment Date Revision History Ver. 1.0 January 15, 2003 First version Ver. 2.0*1 August 15, 2003 Added information on SEG additional controlled chemical substance group. *1 Clerical error correction(august 20,2003) 10
Appendix 1: Chemical Substance Group List General Class No. Substances Group A 1 Antimony and its compounds 2 Arsenic and its compounds 3 Beryllium and its compounds 4 Bismuth and its compounds 5 Cadmium and its compounds 6 Chromium compounds *1 7 Chromium VI compounds 8 Cobalt and its compounds 9 Lead and its compounds 10 Mercury and its compounds 11 Nickel compounds *2 12 Organo tin compounds 13 Selenium and its compounds 14 Tellurium and its compounds 15 Thallium and its compounds Group B 16 Chlorinated paraffins 17 Polybrominated biphenyls (PBBs) 18 Polybrominated diphenyl ethers (PBDEs) 19 Halogenated Resin Additives *3 20 PCBs 21 Polychlorinated naphthalenes (with 3 or more chlorine atoms) 22 Polyvinyl chloride (PVC) Group C 23 Asbestos types 24 Azo compounds *4 25 Cyanide compounds 26 Ozone-depleting substances *5 27 Phthalate esters 28 Radioactive substances 29 Others *6 *1: Chromium compounds excluding chromium VI and chromium metal *2: Nickel compounds excluding metallic nickel *3: Halogenated resin additives excluding chlorinated paraffin, PBB, and PBDE *4: Azo compounds that form certain amines. ("Certain amines" refers to amine compounds cited in the 19th amendment of EU Directive 76/769/EEC.) *5: Substances cited by the Montreal Protocol *6: SEG additional controlled chemical substance group (See Table 1 below.) Table 1: SEG additional controlled chemical substance group No. Substances Other 1 Nickel Other 2 Copper and Copper compounds Other 3 Gold and Gold compounds Other 4 Palladium and Palladium compounds Other 5 Silver and Silver compounds Other 6 Magnesium Other 7 Inorganic phosphorus compounds Other 8 Organic phosphorus compounds Other 9 Aromatic hydrocarbons Other 10 Halogenated hydrocarbons Other 11 Ethers Other 12 Ketons Other 13 Nitrogen compounds Other 14 Fluoroacetates Other 15 Dioxins 11
Appendix 2: List of Breakdown Substances Note: Every effort has been made to ensure the accuracy of the CAS No., Chemical Formulas, and Heavy Conversion Factor to Metal Mass. However, accuracy is not guaranteed. General Class Group A Substance Classification No. Substance Group Breakdown Substance Classification No. Breakdown Substances Chemical Formula Conversion Factor to Metal Mass CAS No. A01 Antimony and A01001 Antimony Sb 1.000 7440-36-0 its compounds A01002 Antimony trichloride SbCl 3 0.534 10025-91-9 A01003 Antimony trioxide Sb 2O 3 0.835 1309-64-4 A01004 Antimony pentoxide Sb 2O 5 0.753 1314-60-9 A01005 Sodium antimonate Na 3O 4Sb 0.632 15432-85-6 A01997-9 Other antimony compounds - - - A02 Arsenic and its A02001 Arsenic As 1.000 7440-38-2 compounds A02002 Gallium arsenide GaAs 0.518 1303-00-0 A02003 Arsenic pentoxide As 2O 5 0.652 1303-28-2 A02004 Arsenic trioxide As 2O 3 0.757 1327-53-3 A02997-9 Other arsenic compounds - - - A03 Beryllium and A03001 Beryllium Be 1.000 7440-41-7 its compounds A03002 Beryllium oxide BeO 0.360 1304-56-9 A03997-9 Other beryllium compounds - - - A04 Bismuth and its A04001 Bismuth Bi 1.000 7440-69-9 compounds A04997-9 Other bismuth compounds - - - A05 Cadmium and A05001 Cadmium Cd 1.000 7440-43-9 its compounds A05002 Cadmium oxide CdO 0.875 1306-19-0 A05003 Cadmium sulfide CdS 0.778 1306-23-6 A05004 Cadmium chloride CdCl 2 0.613 10108-64-2 A05005 Cadmium sulfate CdSO 4 0.539 10124-36-4 A05997-9 Other cadmium compounds - - - A06 Chromium A06001 Chromium (III) oxide Cr 2O 3 0.684 1308-38-9 compounds *1 A06002 Neochromium Cr(OH)SO 4 0.315 64093-79-4 A06997-9 Other chromium compounds - - - A07 A07001 Sodium dichromate Na 2Cr 2O 7 0.397 10588-01-9 Chromium VI A07002 Chromium (VI) oxide CrO 3 0.520 1333-82-0 compounds A07003 Calcium chromate CaCrO 4 0.333 13765-19-0 A07004 Lead (II) chromate PbCrO 4 0.161 7758-97-6 A07005 Potassium dichromate K 2Cr 2O 7 0.353 7778-50-9 A07006 Potassium chromate K 2CrO 4 0.268 7789-00-6 A07997-9 Other hexavalent chromium compounds - - - A08 Cobalt and its A08001 Cobalt Co 1.000 7440-48-4 compounds A08002 Cobalt (II) oxide CoO 0.786 1307-96-6 A08003 Cobalt oxide (II,III) Co 3O 4 0.734 1308-06-1 A08997-9 Other cobalt compounds - - - A09 Lead and its A09001 Lead Pb 1.000 7439-92-1 compounds A09002 Lead (II) carbonate PbCO 3 0.775 598-63-0 A09003 Lead (IV) oxide PbO 2 0.866 1309-60-0 A09004 Lead (II,IV) oxide Pb 3O 4 0.907 1314-41-6 A09005 Lead (II) sulfide PbS 0.866 1314-87-0 A09006 Lead (II) oxide PbO 0.928 1317-36-8 A09007 Lead (II) carbonate basic 2PbCO 3.Pb(OH) 2 0.801 1319-46-6 A09008 Lead hydroxidcarbonate 2PbCO 3.Pb(OH) 2 0.801 1344-36-1 A09009 Lead (II) sulfate PbSO 4 0.683 7446-14-2 A09010 Lead (II) phosphate Pb 3(PO 4) 2 0.766 7446-27-7 A09011 Lead (II) chromate PbCrO 4 0.641 7758-97-6 A09012 Lead (II) titanate PbTiO 3 0.686 12060-00-3 A09013 Lead sulfate,sulphuric acid, lead salt Pb XSO 4 1.000 15739-80-7 A09997-9 Other lead compounds - - - 12
A10 Mercury and its A10001 Mercury Hg 1.000 7439-97-6 compounds A10002 Mercury (II) chloride HgCl 2 0.739 7487-94-7 A10003 Mercury (II) oxide HgO 0.926 21908-53-2 A10997-9 Other mercury compounds - - - A11 Nickel A11001 Nickel (II) oxide NiO 0.786 1313-99-1 compounds*2 A11002 Nickel (II) carbonate NiCO 3 0.494 3333-67-3 A11003 Nickel (II) Sulfate NiSO 4 0.379 7786-81-4 A11997-9 Other nickel compounds - - - A12 Organic tin A12001 Bis(tri-n-butyltin) oxide C 24H 54OSn 2 0.398 56-35-9 compounds A12002 Dibutyltin maleate C 12H 20O 4Sn 0.342 78-04-6 A12003 di(n-octyl)tin maleate C 20H 36O 4Sn 0.258 16091-18-2 A12997-9 Other organic tin compounds - - - A13 Selenium and its A13001 Selenium Se 1.000 7782-49-2 compounds A13002 Selenous acid H 2SeO 3 0.612 7783-00-8 A13997-9 Other selenium compounds - - - A14 Tellurium and A14001 Tellurium Te 1.000 13494-80-9 its compounds A14997-9 Other tellurium compounds - - - A15 Thallium and its A15001 Thallium Tl 1.000 7440-28-0 compounds A15002 Thallium (I) oxide Tl 2O 0.962 1314-12-1 A15003 Thallium (I) sulfate Tl 2SO 4 0.810 7446-18-6 A15004 Thallium nitrate TlNO 3 0.767 10102-45-1 Group B 01 Chlorinated Paraffin waxes and Hydrocarbon 01001 Unspecified paraffin waxes, chloro - 63449-39-8 B01002 Chlorinated Paraffins (C12,60% Unspecified Chlorine) - 108171-26-2 B01003 Chlorinated Paraffins (C23,43% Unspecified Chlorine) 108171-27-3 01004 Alkanes, chloro Unspecified - 61788-76-9 B01997-9 Other chlorinated paraffins - - - B02 PBBs 02001 polybrominated biphenyls C 12H xbr (10-x) - - B03 PBDEs 03001 polybrominated diphenyl ethers C 12H xbr (10-x)O - - B04 Halogenated B04001 1,1,2,2-Tetrabromoethane C 2H 2Br 4-79-27-6 resin additive *3 B04002 Tetrabromobisphenol A C 15H 12Br 4O 2-79-94-7 B04003 Hexabromobenzene C 6Br 6-87-82-1 B04004 Tris(2-chloroethyl) phosphate C 6H1 2Cl 3PO 4-115-96-8 B04005 1,2,5,6,9,10-hexabromocyclodecane C 12H 18Br 6-3194-55-6 B04006 Polytetrafluoroethylene (C 2F 4) n - 9002-84-0 B04007 1,1'-(isopropylidene)bis[3,5-dibromo C 21H 20O 2Br 8-21850-44-2 -4-(2,3-dibromopropoxy)benzene] B04997-9 Other halogenated resin additives - - - B05 PCBs/PCTs B05001 Polychlorinated biphenyls Unspecified - 1336-36-3 B05002 Polychlorinated terphenyls Unspecified - 61788-33-8 B05997-9 Other PCBs/PCTs - - - B06 Polychlorinated B06001 Polychlorinated Naphthalenes Unspecified - 70776-03-3 Naphthalenes (with more than B06007-9 (with more than 3 chlorine atoms) Other polychlorinated Naphthalenes - - - 3 chlorine atoms) (with more than 3 chlorine atoms) B07 Polyvinyl B07001 Polyvinyl chloride (PVC) (CH 2CHCl) n - 9002-86-2 chloride Group C C01 Asbestos types C01001 Actinolite Unspecified - 77536-66-4 C01002 Amosite Unspecified - 12172-73-5 C01003 Anthophyllite Unspecified - 77536-67-5 C01004 Chrysotile Unspecified - 12001-29-5 C01005 Crocidolite Unspecified - 12001-28-4 C01006 Tremolite Unspecified - 77536-68-6 C01997-9 Other asbestos - - - C02 Azo compounds C02001 - - - - *4 C03 Cyan C03001 Acrylonitrile C 3H 3N - 107-13-1 compounds C03002 Sodium cyanide NaCN - 143-33-9 C03997-9 Other cyanides - - - C04 Ozone-depleting C04001 CFC-11 CFCl 3 - - substances *5 (incl. isomers) C04002 CFC-12 CF 2Cl 2 - - 13
C04003 CFC-113 C 2F 3Cl 3 - - C04004 CFC-114 C 2F 4Cl 2 - - C04005 CFC-115 C 2F 5Cl - - C04006 Halon 1211 CF 2BrCl - - C04007 Halon 1301 CF 3Br - - C04008 Halon 2402 C 2F 4Br 2 - - C04009 CFC-13 CF 3Cl - - C04010 CFC-111 C 2FCl 5 - - C04011 CFC-112 C 2F 2Cl 4 - - C04012 CFC-211 C 3FCl 7 - - C04013 CFC-212 C 3F 2Cl 6 - - C04014 CFC-213 C 3F 3Cl 5 - - C04015 CFC-214 C 3F 4Cl 4 - - C04016 CFC-215 C 3F 5Cl 3 - - C04017 CFC-216 C 3F 6Cl 2 - - C04018 CFC-217 C 3F 7Cl - - C04019 Carbon tetrachloride CCl 4 - - C04020 1,1,1-Trichloroethane C 2H 3Cl 3 - - C04021 HCFC-21 CHFCl 2 - - C04022 HCFC-22 CHF 2Cl - - C04023 HCFC-31 CH 2FCl - - C04024 HCFC-121 C 2HFCl 4 - - C04025 HCFC-122 C 2HF 2Cl 3 - - C04026 HCFC-123 C 2HF 3Cl 2 - - C04027 HCFC-123*6 CHCl 2CF 3 - - C04028 HCFC-124 C 2HF 4Cl - - C04029 HCFC-124*6 CHFClCF 3 - - C04030 HCFC-131 C 2H 2FCl 3 - - C04031 HCFC-132 C 2H 2F 2Cl 2 - - C04032 HCFC-133 C 2H 2F 3Cl - - C04033 HCFC-141 C 2H 3FCl 2 - - C04034 HCFC-141b*6 CH 3CFCl 2 - - C04035 HCFC-142 C 2H 3F 2Cl - - C04036 HCFC-142b*6 CH 3CF 2Cl - - C04037 HCFC-151 C 2H 4FCl - - C04038 HCFC-221 C 3HFCl 6 - - C04039 HCFC-222 C 3HF 2Cl 5 - - C04040 HCFC-223 C 3HF 3Cl 4 - - C04041 HCFC-224 C 2HF 4Cl 3 - - C04042 HCFC-225 C 3HF 5Cl 2 - - C04043 HCFC-225c *6 CF 3CF 2CHCl 2 - - C04044 HCFC-225cb*6 CF 2ClCF 2CHClF - - C04045 HCFC-226 C 3HF 6Cl - - C04046 HCFC-231 C 3H 2FCl 5 - - C04047 HCFC-232 C 3H 2F 2Cl 4 - - C04048 HCFC-233 C 3H 2F 3Cl 3 - - C04049 HCFC-234 C 3H 2F 4Cl 2 - - C04050 HCFC-235 C 3H 2F 5Cl - - C04051 HCFC-241 C 3H 3FCl 4 - - C04052 HCFC-242 C 3H 3F 2Cl 3 - - C04053 HCFC-243 C 3H 3F 3Cl 2 - - C04054 HCFC-244 C 3H 3F 4Cl - - C04055 HCFC-251 C 3H 4FCl 3 - - C04056 HCFC-252 C 3H 4F 2Cl 2 - - C04057 HCFC-253 C 3H 4F 3Cl - - C04058 HCFC-261 C 3H 5FCl 2 - - C04059 HCFC-262 C 3H 5F 2Cl - - C04060 HCFC-271 C 3H 6FCl - - C04061 Dibromofluoromethane CHFBr 2 - - C04062 Bromodifluoromethane CHF 2Br - - C04063 Bromofluoromethane CH 2FBr - - C04064 Tetrabromofluoroethane C 2HFBr 4 - - C04065 Tribromodifluoroethane C 2HF 2Br 3 - - C04066 Dibromotrifluoroethane C 2HF 3Br 2 - - C04067 Bromotetrafluoroethane C 2HF 4Br - - C04068 Tribromofluoroethane C 2H 2FBr 3 - - C04069 Dibromodifluoroethane C 2H 2F 2Br 2 - - C04070 Bromotrifluoroethane C 2H 2F 3Br - - C04071 Dibromofluoroethane C 2H 3FBr 2 - - C04072 Bromodifluoroethane C 2H 3F 2Br - - C04073 Bromofluoroethane C 2H 4FBr - - C04074 Hexabromofluoropropane C 3HFBr 6 - - C04075 Pentabromodifluoropropane C 3HF 2Br 5 - - 14
C04076 Tetrabromotrifluoropropane C 3HF 3Br 4 - - C04077 Tribromotetrafluoropropane C 3HF 4Br 3 - - C04078 Dibromopentafluoropropane C 3HF 5Br 2 - - C04079 Bromohexafluoropropane C 3HF 6Br - - C04080 Pentabromofluoropropane C 3H 2FBr 5 - - C04081 Tetrabromodifluoropropane C 3H 2F 2Br 4 - - C04082 Tribromotrifluoropropane C 3H 2F 3Br 3 - - C04083 Dibromotetrafluoropropane C 3H 2F 4Br 2 - - C04084 Bromopentafluoropropane C 3H 2F 5Br - - C04085 Tetrabromofluoropropane C 3H 3FBr 4 - - C04086 Tribromodifluoropropane C 3H 3F 2Br 3 - - C04087 Dibromotrifluoropropane C 3H 3F 3Br 2 - - C04088 Bromotetrafluoropropane C 3H 3F 4Br - - C04089 Tribromofluoropropane C 3H 4FBr 3 - - C04090 Dibromodifluoropropane C 3H 4F 2Br 2 - - C04091 Bromotrifluoropropane C 3H 4F 3Br - - C04092 Dibromofluoropropane C 3H 5FBr 2 - - C04093 Bromodifluoropropane C 3H 5F 2Br - - C04094 Bromofluoropropane C 3H 6FBr - - C04095 Chlorobromomethane CH 2BrCl - - C04096 Methyl bromide CH 3Br - - C05 Phthalate ester C05001 Dibutyl phthalate C 16H 22O 4-84-74-2 C05002 Dioctyl phthalate C 24H 38O 4-117-81-7 C05997-9 Other phtalate - - - C06 Radioactive C06001 Uranium U - - substances C06002 Plutonium Pu - - C06003 Radon Rn - - C06004 Americium Am - - C06005 Thorium Th - - C06997-9 Other radioactive substances C99 Other *8 Other 1 Nickel - - - Other 2 Copper and Copper compounds - - - Other 3 Gold and Gold compounds - - - Other 4 Palladium and Palladium compounds - - - Other 5 Silver and Silver compounds - - - Other 6 Magnesium - - - Other 7 Inoganic phosphorus compounds - - - Other 8 Organic phosphorus compounds - - - Other 9 Aromatic hydrocarbons - - - Other 10 Halogenated hydrocarbons - - - Other 11 Ethers - - - Other 12 Ketons - - - Other 13 Nitrogen compounds - - - Other 14 Fluoroacetates - - - Other 15 Dioxins - - - *1: Chromium compounds excluding chromium VI and chromium metal *2: Nickel compounds excluding metallic nickel *3: Halogenated resin additives excluding chlorinated paraffin, PBB, and PBDE *4: Azo compounds that form certain amines. "Certain amines" refers to amine compounds cited in the 19th amendment of EU Directive 76/769/EEC. *5: Substances cited by the Montreal Protocol *6: These substances have the highest potentials to be used commercially. *7: For chemical substances that the metal conversion factors cannot be specified, it is settled as "1" *8: SEG additional controlled chemical substance group 15
Appendix 3: Certain Amines (Formed Through Cleavage of One or More Azo Bonds) Substance Chemical Formula CAS o-anisidine C 7 H 9 NO 90-04-0 2-naphthylamine C 10 H 9 N 91-59-8 3,3'-dichlorobenzidine C 12 H 10 Cl 2 N 2 91-94-1 Biphenyl-4-ylamine C 12 H 11 N 92-67-1 Benzidine C 12 H 12 N 2 92-87-5 o-toluidine C 7 H 9 N 95-53-4 4-chloro-o-toluidine C 7 H 8 ClN 95-69-2 2,4-toluenediamine C 7 H 10 N 2 95-80-7 o-aminoazotoluene C 14 H 15 N 3 97-56-3 5-nitro-o-toluidine C 7 H 8 N 2 O 2 99-55-8 3,3'-dichloro-4,4'-diaminodiphenylmethane C 13 H 12 Cl 2 N 2 101-14-4 4,4'-methylenedianiline C 13 H 14 N 2 101-77-9 4,4'-diaminodiphenylether C 12 H 12 N 2 O 101-80-4 p-chloroaniline C 6 H 6 ClN 106-47-8 o-dianisidine C 14 H 16 N 2 O 2 119-90-4 3,3'-dimethylbenzidine C 14 H 16 N 2 119-93-7 2-methoxy-5-methylaniline C 8 H 11 NO 120-71-8 2,4,5-trimethylaniline C 9 H 13 N 137-17-7 4,4'-thiodianiline C 12 H 12 N 2 S 139-65-1 4-methoxy-m-phenylenediamine C 7 H 10 N 2 O 615-05-4 4,4'-methylenedi-o-toluidine C 15 H 18 N 2 838-88-0 4-Aminoazobenzene C12H11N3 60-09-3 16
Appendix 4: CSV Format for Survey Responses 17
Appendix 5: All 12 pages in survey response format creation manual Survey Response Format Creation Manual, Ver. 1.2
Survey / Response Tool & Data Checking Tool Implementation * For new production materials, please download from the SEC web site the latest revision of the survey response tool. (A) Survey / Response Tool Used to perform and answer surveys. Enter data and output/enter.csv file. (B) Data Checking Tool A tool used by SEG to display only data, enabling SEG to check received.csv files. < Seiko Epson > (1) Survey request Enter survey part info (A) Survey / Response Tool Enter info on purchased parts. Entries can be made for up to 100 production materials. (4)Response check (B) Data Checking Tool SEG database CSV (A) Survey / Response Tool Assumes file is sent by e- mail or storage CSV file < Vendors > (2)Response entry (A) Survey / Response Tool (3) Response data output CSV Response entry Response data? i) Vendor (A) Survey / Response Tool < Co. targeted for secondary survey > media Survey response Secondary survey response complilation
Survey / Response Tool (Chemical Substances) Screens This chart shows the sheets that are invoked from the Basic Information Survey (Chemical Substances). Details regarding each of the sheets can be found of following pages. (1) Basic Information Survey (Chemical Substances) LOAD CSV (2) Chemical Substances Survey (1) input (4) File selection screen (LOAD) (5) File selection screen (SAVE) SAVE CSV (6) Item Setting Item setting (3) Chemical Substances Survey (2) input The sheet differs depending on the substance classification No. selected in Chemical Substance Survey (1). Representative substance classification Nos. A01, B01, C01and C99 are explained on the following pages: A01 => (3)-1 B01 => (3)-2 C01 => (3)-3 C99 => (3)-4
(1) Basic Information Survey (Chemical Substances) Click to load the CSV file. From the file selection screen that appears, select the CSV file to load. If data is already present, it is replaced with newly loaded data. Click to save data in a CSV file. From the file selection screen that appears, select the CSV file to save. If you select an existing file, the data in it will be overwritten if you elect to do so on the confirmation screen that appears. Click to set items. Clicking invokes the Item Setting sheet. Enter the date of data entry. The unit is the gram. input input input input input input input input input input input input input input input input input input Select the input appropriate unit from input input the drop-down list: input Enter production material info at the surveying company Enter production material info at the surveying company A maximum of 100 production materials can be entered Pcs. Kg* cm2 m2 m3 m liter g * Do not select Kg. Click to invoke the Chemical Substance Survey (1) sheet and to enter lower-level data for the part in this row. Click to erase the lowerlevel data for the part in this row from the Chemical Substance Surveys (1) & (2). The data on this sheet cannot be erased. Click to the lower-level data for the part in this row from the Chemical Substance Surveys (1) & (2) to the rows for other parts. This sheet's data cannot be input Specify the row number of the destination. n: to row n n-m: to row n through row m n-: to row n through row 100 -m: Copy m rows, from row 1
(2) Chemical Substances Survey (1) Chemical Substance Survey (1) Data entered on the Basic Information Survey sheet appears here. *1 Class ificati on No. A01 A02 A03 A04 A05 A06 A07 A08 A09 A10 A11 A12 A13 A14 A15 C01 C02 C03 C04 C05 C06 C99 input Click to invoke the Chemical Substance Survey (2) sheet and enter information down to the breakdown level. The unit is mg. The total sum of the content amounts entered in the breakdown level appears.*1 input Click to invoke the Chemical Substance Survey (2) sheet and enter information down to the breakdown level. For metal compounds (AXX) enter the amount of heavy metal included. For halogenated organic compounds (BXX) and others (CXX), enter the amount OK CANCEL Click to accept the data that you entered and to return to return to the Basic Information Survey sheet. Click to cancel the data entered and return to the Basic Information Survey sheet. *2, *3 *1. Data cannot be entered directly on this sheet. *2. The data displayed when this sheet was first invoked from the Basic Information Survey sheet is restored. *3. Breakdown substance information is also restored to that displayed when this sheet was first invoked from the Basic Information Survey sheet.
(3)-1 Chemical Substance Survey (2) The unit is mg. Chemical Substance Survey (2) Data entered on the Basic Information Survey sheet appears Sb SbCl 3 Sb 2 O 3 Sb 2 O 5 NaSbO 2 OK When you use rows for other substances, you can enter the CAS No. Enter the amount of compound included. Heavy metal content is calculated using a metal conversion factor and cannot be entered manually. For other compounds, however, figures have to be entered manually, Click to accept the data that you entered and to return to return to the Chemical Substance Survey (1) h t *1. Data cannot be entered directly on this sheet.
(3)-2 Chemical Substance Survey (2) The unit is mg. Chemical Substance Survey (2) Data entered on the Basic Information Survey sheet appears here. *1 Unspecified Unspecified Unspecified Unspecified OK Enter the amount included. When you use rows for other substances, you can enter the CAS No. Click to accept the data that you entered and to return to return to the Chemical Substance Survey (1) sheet. *1. Data cannot be entered directly on this sheet.
(3)-3 Chemical Substance Survey (2) The unit is mg. Chemical Substance Survey (2) Data entered on the Basic Information Survey sheet appears here. *1 Unspecified Unspecified Unspecified Unspecified Unspecified Unspecified When you use rows for other substances, you can enter the CAS No. Enter the amount included. Click to accept the data that you entered and to return to return to the Chemical Substance Survey (1) sheet. *1. Data cannot be entered directly on this sheet.
(3)-4 Chemical Substance Survey (2) The unit is mg. Chemical Substance Survey (2) Data entered on the Basic Information Survey sheet appears here. *1 OK Enter the amount included. *1. Data cannot be entered directly on this sheet. Click to accept the data that you entered and to return to return to the Chemical Substance Survey (1) h t
(4) File Selection Screen (LOAD) Enter the filename. (5) File Selection Screen (SAVE) Enter the filename. Select the file to be loaded. Click to load the file that was selected or entered and close the file selection screen. Click to cancel the selected file and close the file selection. Select the file to be saved. Click to save the file that was selected or entered and close the file selection scren. If you specify an existing file, a confirmation dialog box appears and asks you whether it is OK to overwrite the existing data. Click to cancel the selected file and close the file selection screen.
(6) Item Setting (Changes by the vendor are prohibited) Enter the data from the Basic Information Survey sheet. C99 of Chemical Substance Survey (2). Enter the English substance names from other sheets Click to accept the data that you entered and to return to return to the Basic Information Survey (1) sheet. Click to cancel the data entered and return to the Basic Information Survey sheet. (The data that existed at the time this sheet was invoked will be restored.) C99 of Chemical Substance Survey (2). Enter the Japanese substance names from other sheets.
(7) Data Checking Tool (for use by SEG to check responses) Click to load the CSV file. From the file selection screen that appears, select the CSV file to load. If data is already present, it is replaced with newly loaded data. Click to invoke the Item Setting sheet and set items. LOAD CSV The item set in the Item Setting sheet appears. *1 The item set in the Item Setting sheet appears. *1 The item set in the Item Setting sheet appears. *1 The item set in the Item Setting sheet appears. *1 Up to 100 different production materials can be entered *1. Data cannot be entered directly on this sheet.