研究成果報告書(基金分)

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(DMS) 1 3 DMS 2 4 DMS II-VI CdTe ZnTe 2 4 DMS 2 4 DMS II-VI 2 3d 4 3d (MBE) II-VI ZnTe CdTe 3d Mn, Cr, Fe 2 4 DMS MBE X (XRD)X (XAFS) II (SQUID) (a) 4 DMS (Cd,Mn,Cr)Te 4 DMS II-VI CdTe 2 Mn, Cr (Cd,Mn,Cr)Te Mn 20%Cr 0~7% MBE XRD XAFS Mn, Cr Cd 1 2K (M-H )Cr 3 (Cd,Mn)Te M-H Cr Cr Cr 2 (ZFC) (M-T ) 1: Cd 1-x-y Mn x Cr y Te (x ~ 0.2, y = 0 ~ 0.046) 2K M-H 2Cd 1-x-y Mn x Cr y Te (x ~ 0.2)3 ( T B, P, 2K H C )Cr y

3Zn 1-x-y Cr x Fe y Te (x ~ 0.06, y = 0 ~ 0.02) 2K M-H T B M-T Curie-Weiss P 2K H C P Cr ( P = -20K) Cr y=0.0046 ( P = 25K)Cr y Mn 3 (Cd,Mn)Te Cr Cr y P, T B, H C Mn Cr Mn Cr Mn Cr Cr Cr + Mn 2+ Mn Cr (b) 4 DMS (Zn,Cr,Fe)Te 4 DMS II-VI ZnTe 2 Cr, Fe (Zn,Cr,Fe)Te 4 DMS Cr Fe 100% (Zn,Cr,Fe)Te Cr 6% Fe 0~2% MBE XRD XAFS Cr, FeZn 3 2K M-H H C Fe Fe Fe M S Cr Fe H C Fe Cr Fe X (XMCD) Cr Fe Cr Fe 1. K. Zhang, R. Akiyama, K. Kanazawa, S. Kuroda, H. Ofuchi, "Effect of acceptor co-doping on magnetism and electronic states in ferromagnetic semiconductor (Zn,Cr)Te", Physica Status Solidi (c), in press. DOI: 10.1002/pssc.201300755 2. S. Ishitsuka, T. Domon, R. Akiyama, K. Kanazawa, S. Kuroda, "Structural and magnetic characterization of (Zn,Fe)Te thin films grown by MBE", Physica Status Solidi (c), in press. DOI: 10.1002/pssc.201300649 3. R. Akiyama, H. Oikawa, K. Yamawaki, S. Kuroda, "Electric-field modulation of ferromagnetism in hexagonal chromium telluride thin film", Physica Status Solidi (c), in press. DOI: 10.1002/pssc.201300751 4. H. Kobayashi, K. Yamawaki, Y. Nishio, K. Kanazawa, S. Kuroda, M. Mitome, Y. Bando, Structural analysis of Cr aggregation in ferromagnetic semiconductor (Zn,Cr)Te, Physics of Semiconductors, Proceedings of the 31th International Conference on the Physics of Semiconductors, AIP Conference Proceedings vol. 1566, 341-342 (2013). DOI: 10.1063/1.4848425 5. K.Kanazawa, S. Yoshida, H. Shigekawa, S. Kuroda, "Cross-sectional STM study of impurity states in diluted magnetic semiconductor (Zn,Cr)Te", Physics of Semiconductors, Proceedings of the 31th International Conference on the Physics of Semiconductors, AIP Conference Proceedings vol. 1566, 331-332 (2013). DOI: 10.1063/1.4848420

6. H. Kobayashi, Y. Nishio, K. Kanazawa, S. Kuroda, M. Mitome, Y. Bando, Structural analysis of the phase separation in magnetic semiconductor (Zn,Cr)Te, Physica B 407, 2947-2949 (2012). DOI: 10.1016/j.physb.2011.08.023 7. K. Ishikawa, S. Kuroda, MBE growth and magnetic properties of quaternary magnetic semiconductor (Cd,Mn,Cr)Te, Physics of Semiconductors, 30th International Conference on the Physics of Semiconductors, AIP Conference Proceedings vol. 1399, 705-706 (2012). DOI: 10.1063/1.3666572 1. S. Kuroda, "Quaternary magnetic semiconductors containing two kinds of transition metal elements (invited)", International Workshop of Computational Nano-Materials Design on Green Energy (1-3 June 2014, Osaka Univ., 2. S. Kuroda, "Realization of ferromagnetism in diluted magnetic semiconductors based on II-VI compounds --- Quaternary DMS containing two kinds of TM elements: Ferromagnetism due to interaction between different TM elements (invited)", Energy Materials and Nanotechnology Meeting (EMN 2013 Fall) (7-10 December 2013, Orlando, Florida, USA). 3. K. Yamawaki, N. Sekita, K. Kanazawa and S. Kuroda, "Strutural and Magnetic Properties of Ternary Transition-metal Chalcogenide CrFeTe Grown by MBE", International Conference on Solid State Devices and Materials (SSDM 2013) (24-27 September 2013, Fukuoka, 4. H. Oikawa, R. Akiyama, S. Kuroda, "Effect of an Electric Field on Magnetism of Ferromagnetic Semiconductor (Zn,Cr)Te", The 16th International Conference on II-VI 5. R. Akiyama, H. Oikawa, K. Yamawaki, S. Kuroda, "Modulation of Ferromagnetism by Applied Electric Fields in the Hexagonal CrTe Thin Film" The 16th International Conference on II-VI Compounds and Related Materials (II-VI 2013) (9-13 September 2013, Nagahama, 6. S. Ishitsuka, T. Domon, R. Akiyama, K. Kanazawa, S. Kuroda, M. Mitome, Y. Bando, H. Ofuchi, "MBE Growth and Magnetic Properties of Diluted Magnetic Semiconductor (Zn,Fe)Te" The 16th International Conference on II-VI 7. K. Zhang, R. Akiyama, K. Kanazawa, S. Kuroda, H. Ofuchi, "Effect of Acceptor Co-doping on Magnetism and Electronic States in Ferromagnetic Semiconductor (Zn,Cr)Te" The 16th International Conference on II-VI Compounds and Related Materials (II-VI 2013) (9-13 September 2013, Nagahama, 8. T. Nishimura, K. Kanazawa, S. Yoshida, H. Shigekawa, S. Kuroda, "STM/STS Study of Cr Impurity States in (Zn,Cr)Te" The 16th International Conference on II-VI 9. K. Zhang, K. Kanazawa, R. Akiyama, S, Kuroda, H. Ofuchi, "Suppression of ferromagnetism due to acceptor co-doping in magnetic semiconductor (Zn,Cr)Te", 7th International School and Conference on Spintronics and Quantum Information Technology (SPINTECH7) (29 July - 2 August 2013, Chicago, USA). 10. K. Kanazawa, T. Nishimura, S. Yoshida, H. Shigekawa, S. Kuroda, "Atomic-scale observation of Cr impurity states in (Zn,Cr)Te by STM", 7th International School and Conference on Spintronics and Quantum Information Technology (SPINTECH7) (29 July - 2 August 2013, Chicago, USA). 11. K. Kanazawa, S.Yoshida, H. Shigekawa, S. Kuroda, "Spatial Distribution of Impurity States of Cr Atoms in (Zn,Cr)Te Studied by STM", International Conference on Solid State Devices and Materials (SSDM 2013) (25-27 Septermber 2012, Kyoto, 12. N. Sekita, K. Yamawaki, K. Kanazawa, S. Kuroda, M. Mitome, Y. Bando, "Structural and Magnetic Properties of Binary Compound CrTe Grown by MBE", International Conference on Solid State Devices and Materials (SSDM 2013) (25-27 Septermber 2012, Kyoto, 13. K. Kanazawa, S. Yoshida, H. Shigekawa, S. Kuroda, "STM/STS study of electronic states in (Zn,Cr)Te", The 7th International Conference on the Physics and Applications of Spin Related Phenomena in Semiconductors (PASPS-VII) (5-8 August 2012, Eindhoven, Netherlands). 14. K. Kanazawa, S. Yoshida, H. Shigekawa, S. Kuroda, "Local Electronic States of Cr atom in Diluted Magnetic Semiconductor (Zn,Cr)Te Studied by STM and STS", 31st International Conference on the Physics of

Semiconductors (ICPS 2012) (29 July - 3 August, 2012, Zurich, Switzerland). 15. H. Kobayashi, Y. Nishio, K. Kanazawa, S. Kuroda, M. Mitome, Y. Bando, "Cr Aggregation and Magnetic Properties in Ferromagnetic Semiconductor (Zn,Cr)Te", 31st International Conference on the Physics of Semiconductors (ICPS 2012) (29 July - 3 August, 2012, Zurich, Switzerland). 16. (Zn,Cr)Te Cr STM 61 (2014 3 17 3 20 ) 17. MBE (Zn,Cr,Fe)Te 61 (2014 3 17 3 20 ) 18. (Zn,Cr)Te 61 (2014 3 17 3 20 ) 19. (Zn,Cr)Te Cr STM 18 (PASPS-18) (2013 12 910 ) 20. CdTe(111)A MBE CrFeTe 18 (PASPS-18) (2013 12 910 ) 21. (Zn,Cr,Fe)Te MBE 18 (PASPS-18) (2013 12 910 ) 22. (Zn,Co)O n 18 (PASPS-18) (2013 12 910 ) 23. MBE CrFeTe 74 (2013 9 16 20 ) 24. (Zn,Cr)Te Cr STM/STS 74 (2013 9 1620 ) 25.,,,,,, MBE (Zn,Fe)Te 17 (PASPS-17) (2012 12 1920 ) 26.,,, (Zn,Cr)Te Cr STM 17 (PASPS-17) (2012 12 1920 ) 27. CrTe MBE 73 (2012 9 1114 ) 28. STM (Zn,Cr)Te 73 (2012 9 1114 ) 29. (Zn,Fe)Te MBE 73 (2012 9 1114 ) 30. MBE (ZnFe)Te 60 (2013 3 2730 ) 31. MBE (Cd,Mn)Te 60 (2013 3 2730 ) KURODA Shinji 40221949