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2 Fig. 1. (a) A log(co/fe)py-log(co/fe)po plot of coexisting pyrite (py) and pyrrhotite (po). An area restricted by a dotted line indicates the data obtained from one specimen represented by the number (see Table 1).A dashed line indicates the distribution of cobalt and iron between pyrite and pyrrhotite at a given temperature ( Ž), which was determined by Bezmen et al.(1975)14 (b) A log(fe/co)pn-log(co/fe)po plot of coexisting cobalt pentlandite (pn) and pyrrhotite (po). Abbreviations for the types of pyrite (Shoji et al.,1980)7: A= aggregate of fine crystals, Bs= brecciated aggregate with smoothly polished plane, D= dispersion aggregate of rounded form.

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4 Fig.2. A diagram showing the formation sequence of various types of pyrite. Fig.3. A log(ni/co)py-1-000/t plot of various kieslager-type copper deposits of Japan. The temperatures are estimated Table 1. Localities and kinds of analyzed ore samples. on the basis of the grade of regional metamorphism. The second term of the left side of equation (2) is neglected, because of the assumption that the Co/Ni ratios of the under-lying igneous rocks are approximately equal to 1. *after Mizuta (1973)6. Table2. List of the cobalt and nickel contents of pyrites * B= Banno (1964)3, H= Hide (1961)27, Is= Isogai (1977)31, It= Itoh (1976)25, KB= Kurata and Banno (1974)33, Km= Kamiyama (1959)29, Kanehira (1970)26, Kn= K1= Kase (1972)4, K2 = Kase (1977)19, K3= Kase (1978)2, MN= Mitsuno et al. (1975)28, Mz= Mizuta (1973)6, NM= Nishiyama Minato (1974)8, SK= Suzuki al. (1972)32, and et SS= Shoji al. (1979)7, T= Takeda (1962)30, W= Watanabe at al. (1970)5. et Z = zeolite **, BS = blueschist, GS = greenschist,ea = epidote-amphibolite, PH= pyroxene-hornfels. A= amphibolite, The values with parentheses represent temperature ( Ž) estimated from the diagram illustrated by Ernst (1976)18, except Shimokawa (this work).

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6 33) Kurata, H. and Banno, S.: J. Petrol., 15 (2), 361 ` 382,(1974) 34) Cambel, B. and Jarkovsky, J.: Freiberger Forsch., 36) Schron, W., Leiger, C. und Kramer, E.: Z. geol. Wiss., 6 k6 l, 767 `778,(1978) 37) Cambel, B. und Jarkovsky, J.: Geochimie der Pyrite einiger Lagerstatten der Tschechoslowakei, Vydavatel'- stvo Slovenskej akademie vied Bratislava, 493p, (1967) 38) Rajamani, V.: Econ. Geol., 71 k5 l, 795 `802,(1976) 39) MacLean, W. H. and Shimazaki, H.: Econ. Geol., 71 15) Nakazawa, H. and Morimoto, N. Mater. Res. Bull., 6, 345 `358,(1971) 16) Scott, S. D. and Kissin, S. A.: Econ. Geol., 68, 475 `479,(1973) 18) Ernst, W. G.: Petrologic Phase Equilibria, W. H. Freeman and Company, San Francisco, 333p,(1976) Geochemistry of Cobalt and Nickel in the Shimokawa Copper Deposit, Hokkaido by Tetsuya SHOJI1 and Nozomi SASAKI2 The Shimokawa deposit is one of the most important kieslager-type are deposits in Japan. The cobalt concentrations of pyrite, monoclinic pyrrhotite and cobalt pentlandite are determined by electron microprobe. The result indicates that pyrite was formed at two stages, and that pyrrhotite and cobalt pentlandite was formed at the second stage. The temperature of the second stage is estimated to have been 250 Ž to 300 Ž, based on the distribution of cobalt between pyrite and pyrrhotite. Compared with the other deposits of the same type, such as Besshi and Hitachi, this deposit is characterized by the ratio of Ni/Co of pyrite increases with the increasing grade of regional metamorphism. This trend coincides with the fact that the most important nickel resources of the world are of the Sudburry-type and the garnierite-type, and that the cobalt resources of the Copperbelt-type and the mesothermal vein-type. From these points, it is expected that the deposits with high cobalt contents occur in Japan. (1. Assoc. Prof., Dr., Faculty of Engineering, the University of Tokyo 2. Hirohata Steel Works, Nippon Steel Corporation)

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