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- こごろう けいれい
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1 181121() NPO 1
2 ? CHSO 2 CHS3 CO2CO2 HO2H2O SSO2 2
3 C 1 kmol 12 kg O 2 1 kmol + 32 kg = 22.4m 3 N CO 2 1 kmol 44 kg 22.4 m 3 N MJ/kmol 32/ kg/kg-c 22.4/ m 3 N /kg-c 1(kmol)1(kmol)( )1(kmol)393.5MJ 1kmol12kg()1kmol 32kg(01)22.4m3N 1kmol44kg 22.4m3N m3n 1kg2.67kg 1.867m3N 3
4 H 2 1 kmol 2 kg 22.4m 3 N O 2 1/2 kmol + 32/2 kg 22.4/2 m 3 N = H 2 O 1 kmol 18 kg 22.4m3N MJ/kmol 16/28 kg/kg-h 11.2/25.6 m 3 N /kg-h 1kmol2kg22.4m3N 1kmol1/2kmolH2O1kmol(18kg) 241.8MJ 4
5 S 1 kmol 32 kg O 2 1 Kmol + 32 kg 22.4 m 3 N = 2 SO 2 1 kmol 64 kg 22.4 m 3 N MJ/kmol 32/321 kg/kg-s 22.4/320.7 m 3 N /kg-s 1kmol32kg1kmol SO21kmol(64kg,22.4m3N)296.8MJ 5
6 () 6
7 16.38MJ 0.71MJ CO 1kg m3,H 2 O 0.67m3 N m3 C50%,H6%,O44%() +H 2 O20%() 25 (CO2+H2O+N2) = 5.460m3 1697up -1.67MJ H2O 0.92m = kJ/m3K = 15.42MJ 4.58m 3 N N 2 79%,O 2 21%() 25 31kg ()1kg4.58m3N 1kg1kg0.5kg, 0.06kg,0.44kg 20% 79%N221% m3N,0.92m3N3.61m3N 5.46m3N15.42MJ
8 C 12 H 1 S 32 O 16 N
9 H 2 O H 1 O 16 H 1 = 18 CO 2 C 12 O 16 = 44 O 2 O 16 O 16 = 32 O 16 N 14 = 28 N 2 N 14 SO 2 O 16 S 32 O 16 = 64 H2O 16O1HH2O 18CO2=C(12)+O(16)x2 44O232N228 SO264 9
10 1kmol=1 6.02(1026)() 2.4m 3 N () kg m 3 N =-10 (mol) (6.022x1023)()1(mol)1000 (kmol)1mol ()g() (10)
11 79%21% 76.8%23.2% 11
12 12
13 16.38MJ 0.71MJ CO 1kg m3,H 2 O 0.67m3 N m3 C50%,H6%,O44%() +H 2 O20%() 25 (CO2+H2O+N2) = 5.460m3 1697up -1.67MJ H2O 0.92m = kJ/m3K = 15.42MJ 4.58m 3 N N 2 79%,O 2 21%() 25 13
14 H2O 0.2kg O2 0.44kg H2 0.06kg C0.5kg 1kgA 0 1kg (0.28(db)) x H kg H kg H2O m3n H2O 0.616m3N 0.056m3N x x 0.921m3N O2 11.2/2x0.005 =0.028m3N O2 22.4/12x0.5 =0.933m3N 0.921m3N 0.933m3N 0.961m3N 3.615m3N 5.469m3N N m3N CO2 22.4/12x0.5 =0.933m3N 4.576m3N 1kg 1kg20% 0.5kg0.06kg0.44kg0.2kg 0.055kg 0.005kg 0.028m3N 1kg22.4/2m3N0.06kg 0.06x22.4/2m3N=0.672m3N 20%0.249m3N0.921m3N 0.5kg0.933m3N0.933m3N 0.961m3N21% 0.961m3N0.961/0.21=4.576m3N A m3N 0.921m3N+0.933m3N m3N=4.569m3N20%1kg 14
15 A A=mA 0 A=A 0 m CO,H2,CH4 COH2CH4 A0AA=mA0 A=A0m m 15
16 N 2 (0.79mA 0 ) N 2 (0.79A 0 ) m m=0.21/(0.21-((o 2 )-1/2x(CO))) (O 2 ): (CO): (O 2 )(CO) N2 O2CO m + 16
17 17 1kg1.2 C0.5kg O2 0.44kg H2 0.06kg H2O 0.2kg O2 22.4/12x0.5 =0.933m3N O2 11.2/2x0.005 =0.028m3N H kg H kg x H2O 0.616m3N 0.056m3N x H2O m3n x CO2 22.4/12x0.5 =0.933m3N 0.961m3N N m3N 4.576m3N 1kg (0.28(db)) 3.615m3N 0.933m3N 0.921m3N =6.384m3N 0.915m3N O m3N N m3N O m3N N m3N 1
18 m (CO2+H2O+N2+O2) =7.750m3 1419up -1.67MJ H2O 0.92m MJ 0.71MJ CO 1kg m3,H 2 O 0.67m3 N m3,O m3 C50%,H6%,O44%() +H 2 O20%() = kJ/m3K m= = 15.42MJ 6.87m 3 N N 2 79%,O 2 21%() 25 1kg (CO2+H2O+N2) = 5.460m3 1697up -1.67MJ H2O 0.92m MJ 0.71MJ CO m3,H 2 O 0.67m3 N m3 C50%,H6%,O44%() +H 2 O20%() = kJ/m3K m= = 15.42MJ 4.58m 3 N N 2 79%, O 2 21%() 25 1kg 18
19 0% 30%
20 kg 20
21 ?? 21
22 16.38MJ 0.71MJ CO 1kg m3,H 2 O 0.67m3 N m3 C50%,H6%,O44%() +H 2 O20%() 25 (CO2+H2O+N2) = 5.460m3 1697up -1.67MJ H2O 0.92m = kJ/m3K = 15.42MJ 4.58m 3 N N 2 79%,O 2 21%() 25 1kg 4.58m3N16.38MJ0.71MJ 1.67MJ15.42MJ 22
23 (J)(W) 1021N() 1 m1 J() 1 1W 1Nm=1J() 1 m 1J/s=1W 102g 1 N (J) 1J1N)1m1Nm=1J 1J102g1m( ) 102g1m J/s=1W 11J/3600=1/3600W ()() 23
24 1g1 1cal() 1cal=4.186J() 251(1000cc)45 1,000(45-25)20,000cal=20kcal kJ 1g1 1(cal) 1cal=4.186J 24
25 ():J() 1000J=1kJ () 1000kJ=1 MJ() 1000MJ=1 GJ() 1000GJ=1 TJ() 1000TJ=1 PJ() 1000PJ=1 EJ() kj MJ,GJ,TJ,PJ,EJ 4 25
26 (125) H h H l kcal/mol MJ/kmol MJ/kg kcal/mol MJ/kmol MJ/kg H 2 () C( ) S( ) /p14 (125) 26
27 1kg-f 32.76MJ/kg0.5kg= 16.38MJ/kg-f 141.8MJ/kg0.005kg= 0.709MJ/kg-f 0.5% H 6%=5.5%+0.5% 0.54kg/kg-f C 50% O 44% 0.74kg MJ/kg-f x0.74kg=-1.672mj/kg-f + +20% 0.2kg MJ/kg-f 5.5% kg/kg-f 1kg 16.38MJ 644% 5.5% 0.5%0.709MJ MJ/kg()1.672MJ MJ
28 2 28
29 s n o h c MJ / kg MJ / kg () No.135p62
30 30 kcal/kg MJ/kg kcal/kg MJ/kg a w n o s h c 9, , B 10, , A 10, , , , , , , , , , , , , , Hl Hh ()
31 ??? 31
32 16.38MJ 0.71MJ CO 1kg m3,H 2 O 0.67m3 N m3 C50%,H6%,O44%() +H 2 O20%() 25 (CO2+H2O+N2) = 5.460m3 1697up -1.67MJ H2O 0.92m = kJ/m3K = 15.42MJ 4.58m 3 N N 2 79%,O 2 21%() MJ m3N 32
33 0 1 T th T th = H l /(Gc pm )+T 0 T 0 : H l Gc pm 33
34 :T g =(H l +Q p -Q r )/(Gc pm )+T 0 T0: : Hl: Qp: Qr: G: Cpm: 34
35 1 35
36 p50,51 (:) (:) 36
37 1kg C50%,H6%, O44% +H 2 O20% CO20.93m3,1.73MJ H2O0.92m3,N23.61m3,5.46m MJ,1.685, m 3 N, N79%,O21% CO0.93m3,4.605MJ H2O0.92m3,-0.96MJ N21.805m3,3.65m3 1.41,4.16MJ m 3 N, 200,521kJ 2.29m 3 N 200,521kJ MAWERA () 37
38 38
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I II II 1 dw = pd = 0 1 U = Q (4.10) 1K (heat capacity) (mole heat capacity) ( dq / d ) = ( du d C = / ) (4.11) du = C d U = C d (4.1) 1 1 du = dq + dw dw = pd dq = du + pd (4.13) p dq = d( U + p ) p (4.14)
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10.5月号410～.xls
1 2 3 4 60kg 5 1 ( ) 2 65 3 30 80 31 90 1 31 1 200 9 70 69 (3 ) 56 6 1 8 3 8 10 8 11 7 17 7 30 2 1 2 2 78 1 2 5 7 1 74 1 7 20 6 77 77 72 7 8 1 1 60 7 1 10 100 21 8 PL 26 24 58 25 26 60 2 52 51 1 46 51
(1) θ a = 5(cm) θ c = 4(cm) b = 3(cm) (2) ABC A A BC AD 10cm BC B D C 99 (1) A B 10m O AOB 37 sin 37 = cos 37 = tan 37
4. 98 () θ a = 5(cm) θ c = 4(cm) b = (cm) () D 0cm 0 60 D 99 () 0m O O 7 sin 7 = 0.60 cos 7 = 0.799 tan 7 = 0.754 () xkm km R km 00 () θ cos θ = sin θ = () θ sin θ = 4 tan θ = () 0 < x < 90 tan x = 4 sin
2001 Mg-Zn-Y LPSO(Long Period Stacking Order) Mg,,,. LPSO ( ), Mg, Zn,Y. Mg Zn, Y fcc( ) L1 2. LPSO Mg,., Mg L1 2, Zn,Y,, Y.,, Zn, Y Mg. Zn,Y., 926, 1
Mg-LPSO 2566 2016 3 2001 Mg-Zn-Y LPSO(Long Period Stacking Order) Mg,,,. LPSO ( ), Mg, Zn,Y. Mg Zn, Y fcc( ) L1 2. LPSO Mg,., Mg L1 2, Zn,Y,, Y.,, Zn, Y Mg. Zn,Y., 926, 1 1,.,,., 1 C 8, 2 A 9.., Zn,Y,.
XI 2 (KOMIYAMA, Hirosh) 2004 4 21 1 1.1 1 20 silent spring 1970 1 1.2 1999 2000 2050 2030 2050 2050 1.3 3 20 2 2 20 2.1 20 21 20 20 20 18 60 2000 60 3.5 7.5 1900 7.5 20 20 500 60 20 19 20 3.5 7.5 20 30