SPring8 / SAGA-LS

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1

2

3 - - QOL ADL

4 E E

5 E HO O E

6 E

7

8 E E 0.3~0.5wt% 0.3% E SR-IR

9 SR-IR

10 SR-IR

11 OH 4cm Fig. Comparison of IR absorbance of dl-a-tocopherol and Tocopherol acetate

12 OH Single channel cm Wavenumber cm C:\Documents and Settings\pc-user\My Documents\1127ir\071127\ VE/BaF2 C:\Documents and Settings\pc-user\My Documents\1127ir\071127\ BaF2 blk 2007/11/ /11/28 Fig. Comparison of IR absorbance of dl-a-tocopherol and Tocopherol acetate

13 Absorbance Units % 3% 1% 0%(UHMWPE) 4cm Wavenumber cm Fig. Infrared absorption spectra of vitamin E added UHMWPE of various concentrations C:\Documents and Settings\ir-user\ƒfƒXƒNƒgƒbƒv\ V µ ƒtƒhƒ ƒ_\070515\ C:\Documents and Settings\ir-user\ƒfƒXƒNƒgƒbƒv\ V µ ƒtƒhƒ ƒ_\070515\ C:\Documents and Settings\ir-user\ƒfƒXƒNƒgƒbƒv\ V µ ƒtƒhƒ ƒ_\070515\ C:\Documents and Settings\ir-user\ƒfƒXƒNƒgƒbƒv\ V µ ƒtƒhƒ ƒ_\070515\ /05/ /05/ /05/ /05/15

14 SR-IR E E E SR-IR

15 E E 1262cm -1

16 1% E 0.3% E

17

18 E E

19 E OH 1262cm -1 C- O-C1197cm -1 HO O

20 Y m Y m 4cm X m X m 1262cm cm -1 OH C-O-C

21 SR-IR E SR-IR E OH E E

22

23 80% 3

24 Artificial Joints Bone Fixation Materials

25

26 6-Station Knee Simulator AMTI-Boston ISO

27

28 0.16 GUR1050 Oxidation Index GUR wt GUR wt GUR wt GUR wt GUR wt VitaminE VitaminE VitaminE VitaminE VitaminE Depth( m) E 0.3%

29 Stress (MPa) wt%(Aged) 0.005wt%(Aged) 0.01wt%(Aged) 0.05wt%(Aged) 0.1wt%(Aged) 0.3wt%(Aged) 0wt%(Virgin) 0wt% (Aged) 0.005wt% (Aged) 0.3wt%(Aged) 0.1wt%(Aged) 0.01wt% (Aged) 0.05wt% (Aged) 0wt% (Virgin) Strain

30 VitaminE UHMWPE E 2nm Intensity

31

32 Single channel cm-1 dl-a-tocopherol Tocopherol acetate Wavenumber cm C:\Documents and Settings\pc-user\My Documents\1127ir\071127\ VE/BaF2 2007/11/28 C:\Documents and Settings\pc-user\My Documents\1127ir\071127\ BaF2 blk 2007/11/28 Fig 2. Comparison of IR absorbance of dl-a-tocopherol and Tocopherol acetate

33 Single channel Sample A Sample B Wavenumber cm C:\Documents and Settings\pc-user\My Documents\1127ir\071127\ VE simulator C:\Documents and Settings\pc-user\My Documents\1127ir\071127\ VE control C:\Documents and Settings\pc-user\My Documents\1127ir\071127\ BaF2 blk 2007/11/ /11/ /11/28 Fig 3. Comparison of IR absorbance of accelaration oxidation sample of dl-a-tocopherol added UHMWPE and non-oxidation one Sample A:dl-a-tocopherol added UHMWPE Sample B: accelaration oxidation sample of dl-a-tocopherol added UHMWPE

34 Sample A Sample B Fig 4. Comparison of transmittance spectra of molding atomosphere of dl-a-tocopherol added UHMWPE Sample A:Molding in air Sample B:Molding in vacuum

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