Di(2-ethylhexyl) adipate C22H42O Dimethyl phthalate C10H10O Diethyl phthalate C12H14O D

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1 ) SVOC 1 Fluoranthene-d10 ( : C16D10 : : 99.3%) 2. SVOC m WHO 5.0 L/min 24 SVOC (Volatile Organic Compounds: VOC) (Semi Volatile Organic Compounds: SVOC) VOC SVOC 3. SVOC / (GC/MS) SVOC ( ) SVOC (Type 2500 QAT-UP) 3M Empore (High Performance Extraction Disks, 2215FF, C18) mg/ml 2 ( ) PropetamphosMGK-264Resmethrin EMO-47 MP-500 Hydramethylnon 5.0 mg/ml 400 4Thiabendazole2.0 mg/ml Empore 10 ml 10 5 SVOC 123g/ml Fluoranthene-d10 Acetone 5,000 ( PCB g/ml

2 Di(2-ethylhexyl) adipate C22H42O Dimethyl phthalate C10H10O Diethyl phthalate C12H14O Di-n-propyl phthalate C14H18O Di-iso-butyl phthalate C16H22O Di-n-butyl phthalate C16H22O Di-n-pentyl phthalate C18H26O Di-n-hexyl phthalate C20H30O Benzylbutyl phthlate C19H20O Di-n-heptyl phthalate C22H34O Dicyclohexyl phthalate C20H26O Di(2-ethylhexyl)phthalate C24H38O Triethyl phosphate C6H15O4P Tripropyl phosphate C9H21O4P Pfaltz&Bauer 97.0 Tributyl phosphate C12H27O4P Tris(2-chloroethyl) phosphate C6H12Cl3O4P Tris(1,3-dichloro-2-propyl) phosphate C9H15Cl6O4P Triphenyl phosphate C18H15O4P Tris(2-butoxyethyl) phosphate C18H39O7P Aldrich 94.0 Tris(2-ethylhexyl) phosphate C24H51O4P Tricresyl phosphate C21H21O4P # Dichlorvos C4H7Cl2O4P Diazinon C12H21N2O3PS Dichlofenthion C10H13Cl2O3PS Chlorpyrifosmethyl C7H7Cl3NO3PS Dr. Ehrenstorfer GmbH 99.5 Fenitrothion C9H12NO5PS Malathion C10H19O6PS Fenthion C10H15O3PS Dr. Ehrenstorfer GmbH 95.5 Chlorpyrifos C9H11Cl3NO3PS Tetrachlorvinphos C10H9Cl4O4P Pyridaphenthion C14H17N2O4PS Propetamphos C10H20NO4PS AccuStandard 97.8 Fenobucarb C12H17NO Carbaryl C12H11NO Propoxur C11H15NO Allethrin C19H26O Tetramethrin C19H25NO Dr. Ehrenstorfer GmbH 99.1 Phenothrin C23H26O Dr. Ehrenstorfer GmbH 94.5 Permethrin C21H20Cl2O Dr. Ehrenstorfer GmbH 97.5 Cyfluthrin C22H18Cl2FNO Dr. Ehrenstorfer GmbH 98.5 Deltamethrin C22H19Br2NO Dr. Ehrenstorfer GmbH 99.0 Empenthrin C18H26O Furamethrin C18H22O Prallethrin C19H24O Imiprothrin C17H22O4N Resmethrin C22H26O Bifenthrin C23H22ClF3O Cyphenothrin C24H25NO Riedel-de Haen 96.5 Ethofenprox C25H28O Silafluofen C25H29FO2Si Metoxadiazone C10H10N2O Fenoxycarb C17H19NO Methoprene C19H34O Dr. Ehrenstorfer GmbH 98.0 Pyriproxyfen C20H19NO Tripropyl isocyanurate C12H21N3O Hydramethylnon C25H24F6N AccuStandard ,3,3,3,2',3',3',3'-Octachlorodipropylether (S-421) C6H6Cl8O Riedel-de Haen 99.0 Piperonyl butoxide C19H30O MGK C17H25NO AccuStandard Chloronaphthalene C10H7Cl Chlorothalonil C8Cl4N Dichlofluanid C9H11Cl2FN2O2S Thiabendazole C10H7N3S (Thiocyanomethylthio)benzothiazole (TCMTB) C9H6N2S Supelco Iodo-2-propynyl-N-butylcarbamate (IPBC) C8H12INO Aldrich Bromo-3-ethoxycarbonyloxy-1,2-diiodo-1-propene () C6H7O3BrI p-chlorophenyl-3-iodopropargyl formal (IF-1000S) C10H8O2ClI Thiuram C6H12N2S Cyproconazole C15H18ClN3O Furmecyclox C14H21NO Riedel-de Haen 98.2 Difolatan C10H9Cl4NO2S Pentachlorophenol C6HCl5O N,N-Diethyl-m-toluamide (DEET) C12H17NO

3 MS EI 70eV 60A min SIM SVOC (Selective Ion Monitoring) g/ml 1.08 kv 0.2 sec (34.7 Auto Injector 20i 40.6 min 0.31 sec) 8 0.3ml (7.0 min l min) Empore 2 10ml 8 ml 10 SVOC SVOC 10 (2000 rpm10) SVOC (g/ml) / 5 ml (g/ml)(x) SVOC 3.0l / (y) SD905 ( 150 ml/min/ 30) 0.3 SVOC(ng) ml Auto Injector 20i SVOC(ng) {(SVOC GC/MS ) } (g/ml) GC/MS Auto 0.3(8/5)1000 Injector 20i GCMS-QP2010 Gas Chromatograph Mass Spectrometer SVOC SVOC (ng/m 3 ) GC J&W DB-1 ( 30 m SVOC (ng/m 3 ) 0.25 mm 0.25m) = { ( SVOC(ng) 68.4 kpa SVOC(ng))1000} 20.0 ml/min 1.14 (L/min) (h) ml/min ( 2.0) 60-5/min-300(10 ) l

4 1. 73 SVOC (15.0 Tetramethrin g/ml) (TIC) 1 SVOC 50 Imiprothrin Tricresyl phosphate Deltamethrin Hydramethylnon TIC SVOC (1 No ) SVOC (EmpenthrinFuramethrinAllethrin Prallethrin Imiprothrin Resmethrin PhenothrinCyphenothrin PermethrinCyfluthrinDeltamethrin) Tricresyl phosphate

5

6

7 MGK Chloronaphthalene Imiprothrin 90%50% SVOC 2. SVOC 3 adipate Tris (2-chloroethyl) phosphate SVOC030.0g/ml g/m 3 Thiuram IPBC EmpenthrinPentachlorophenol Chlorothalonil IF-1000S CarbarylFuramethrinFenitrothion SVOC DichlofluanidThiabendazoleAllethrin SVOC TCMTBPrallethrinCyproconazol ImiprothrinPiperonyl butoxidetris (2-butoxyethyl) phosphate SVOC PyridaphenthionFenoxycarbTris (2-ethylhexyl) phosphatepyriproxyfen Tricresyl phosphatecyphenothrin PermethrinCyfluthrinEthofenprox Deltamethrin Empore ( ) SVOC 120l ( 2058 ng/m 3 ) 4 (Control) 4 SVOC 5.0 L/min24 Empore ml Empore 2 SVOC ( Empore 4 Diethyl phthalate Di-iso-butyl phthalate Di-n-butyl phthalatedi (2-ethylhexyl) phthalate 2(Sample 1) Di (2-ethylhexyl) SVOC 8 Empore 3) 3 Empore (Sample 2) 4

8 24 Empore 1 (Blank) SVOC 6 5 (Sample) 6 (Control) 60l SVOC (%) ( 1029 ng/m 3 ) = { (Sample 1 SVOC8 ml * Blank SVOC 6 *) Control SVOC * } ml Blank Blank SVOC (%) SVOC = { Sample 2 SVOC * (Sample 1 SVOC *Blank SV OC *)}100 SVOC () Sample SVOC * * SVOC Control SVOC * 4Blank SVOC * 1-ChloronaphthaleneThiuram Blank SVOC * 100 Empenthrin Furmecyclox Furamethrin FenthionMGK-264 Allethrin Prallethrin * SVOC 6 MethopreneImiprothrinDifolatan ResmethrinTetramethrinPhenothrin 6.0l Cyphenothrin Hydramethylnon( 103 ng/m 3 ) 10% 6 SVOC Propetemphos 70% 100% SVOC Thiabendazole % 55 80% 24 1% L/min SVOC 2g/m 3 5. SVOC 5 SVOC

9

10 3 SVOC 0.12g/ml10 24 SVOC 7 Diethyl phthalate Di-iso-butyl phthalatedi-n-butyl phthalatedi (2-ethylhexyl) phthalate Di (2-ethylhexyl) adipate Tris (2-chloroethyl) phosphate6 4 Diethyl phthalatedi-n-butyl phthalate Di (2-ethylhexyl) phthalate 3 SVOC ng/m 3 SVOC0.5 ng/m 3 Di-n-butyl phthalate Di (2-ethylhexyl) phthalate SVOC IPBC PentachlorophenolChlorothalonil IF-1000S Carbaryl Fenitrothion DichlofluanidThiabendazoleTCMTB CyproconazolPiperonyl butoxidetris (2-butoxyethyl) phosphate PyridaphenthionFenoxycarbTris (2-ethylhexyl) phosphatepyriproxyfen Tricresyl phosphatepermethrin CyfluthrinEthofenprox Deltamethrin ( ) SVOC 60l ( 1029 ng/m 3 )

11 5.0 L/min24 Sample 3 Control Sample SVOC SVOC (ng/m 3 ) { (Sample SVOC(ng) Control SVOC(ng) *)1000} ( (L/min) (h) 60) *3 (n=5) 5.0L ( 86 ng/m 3 ) 8 60l 5.0l Cyfluthrin Deltamethrin SVOC 10% 2 SVOC 60l Pentachlorophenol Chlorothalonil Dichlofluanid ThiabendazoleDeltamethrin SVOC 10% 73 SVOC SVOC (Empenthrin 5.0l FuramethrinAllethrinPrallethrin SVOC 10% ImiprothrinResmethrinTetramethrin 13% PhenothrinCyphenothrin) SVOC 1-ChloronaphthaleneThiuram 2 FurmecycloxFenthionMGK-264 MethopreneDifolatanHydramethylnon Propetamphos18

12

13 Empore Thiabendazole 2 SVOC g/m 3 IPBCPentachlorophenolChlorothalonil IF-1000SCarbaryl FenitrothionDichlofluanidTCMTB CyproconazolPiperonyl butoxidetris (2-butoxyethyl) phosphate PyridaphenthionFenoxycarbTris (2-ethylhexyl) phosphatepyriproxyfen Tricresyl phosphatepermethrin CyfluthrinEthofenprox Deltamethrin 2 SVOC 5.0 L/min24 SVOC

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