1... 2 2...2 (1)... 2... 3... 3... 3 (2)... 4... 4 (3)... 6 3... 8... 9... 10... 11... 14 4... 15 5... 16... 19 1
1 2 (1) Fig. http://www.aandt.co.jp/ Fig.1 T F Loge C Eo R n 2
1 3
vs. S.H.EStandard Hydrogen Electrode (2) V 2 ref 2 ref / - / 0 ref 0 = 0 ref 0 Fig.3 4
V ref V ref V ref Fig.5 1-3 mol/l 3 mm (3-5 mmol/l) 0.3 mmol/l 3 mol/l 0.010.1 mol/l Fig.5 W 5
(3) 1-3.3 mol/l Fig.6 Fig.6 Fig.7 Fig.7 6
Fig.8 Fig.9 W 7
3 V ref Fig.10 K- Ag/AgCl V ref Fig.11 Fig.10 W W Ag/AgCl CWISECoated Wire Ion-Selective Electrode 8
Ag/AgCl / - Fig.12 THF Fig.12 Cl 0.1-0.2 mm Cl B Cl K + Cl Fig.13 9
N 2 10001100 Fig.14 o- 56 1 o- Fig.15 * N H L D N H D L 3 * Fig.15 10
1111 0.0001 1 -- Fig.16 ( ) C.J.Pedersen Fig.17 11
12 Pedersen 1 Fig.18 21 Fig.18 Fig.19
Table 1 R a) Selectivity coefficient logkk,na -2.0-2.7-3.2-3.5 a) R N 140 mmol/l 4 mmol/l 10-13
Table 2 310 Table 2 R a) logkk,na N N - 2.8-3.0 N N - 3.0-3.5 a) R 8 mmol/l 14
C 12 H 25 C 8 H 17 N N Fig.20 0.01100 4 Ag/AgCl Fig.21 Ag/AgCl U 15
V Ag/AgCl ref Fig.22 5 Fig.22 L-STD 1 mol/l M ref ref / M / ref 0 ref 0 L-STD L-STD A&T L ref / L / ref W 0 ref 0 L-STD 16
L-M L-M/ L / M / W S ref L-M W L S ref M H-STD( L-STD L-STD H-STD H-M W H S ref M H-L H-M L-M W H S ref M W L S ref M W H W L wlog H L H-STD L-STD H-M L-M w Log H L H-M L-M H L w 25 59 mv 17
(mmol/l) Fig.23 H-STD L-STD H-M L-M 96.1-40.0 mv 96.1 mv 10 9.61 mv, -4 mv 10 1/10 1/5 mv 18
[ ] [LW ] H L H-M L-M wlog H L w H-M L-MLog H L 9.61+4 mv mv H-STD L-STD H-STD S-M H-M L-M wlog H L L-M CL Cs H-M S-M wlog H S Cs 19