) SVOC 1 Fluoranthene-d10 ( : C16D10 : 212.3 : 99.3%) 2. SVOC 1.2 1.5 m WHO 5.0 L/min 24 SVOC 50-100 240-260 (Volatile Organic Compounds: VOC)240-260 380-400 (Semi Volatile Organic Compounds: SVOC) VOC SVOC 3. SVOC / (GC/MS) SVOC 1 21 35 ( ) 3 1. 14 73 SVOC (Type 2500 QAT-UP) 3M Empore (High Performance Extraction Disks, 2215FF, C18) mg/ml 2 ( ) PropetamphosMGK-264Resmethrin EMO-47 MP-500 Hydramethylnon 5.0 mg/ml 400 4Thiabendazole2.0 mg/ml Empore 10 ml 10 5 SVOC 123g/ml Fluoranthene-d10 Acetone 5,000 ( PCB 10.0 100g/ml
Di(2-ethylhexyl) adipate 103-23-1 C22H42O4 370.6 100.6 Dimethyl phthalate 131-11-3 C10H10O4 194.2 99.9 Diethyl phthalate 84-66-2 C12H14O4 222.2 99.7 Di-n-propyl phthalate 131-16-8 C14H18O4 250.3 99.9 Di-iso-butyl phthalate 84-69-5 C16H22O4 278.3 99.4 Di-n-butyl phthalate 84-74-2 C16H22O4 278.3 99.6 Di-n-pentyl phthalate 131-18-0 C18H26O4 306.4 99.5 Di-n-hexyl phthalate 84-75-3 C20H30O4 334.5 99.6 Benzylbutyl phthlate 85-68-7 C19H20O4 312.4 99.8 Di-n-heptyl phthalate 3648-21-3 C22H34O4 362.5 97.0 Dicyclohexyl phthalate 84-61-7 C20H26O4 330.4 100.0 Di(2-ethylhexyl)phthalate 117-81-7 C24H38O4 390.6 99.6 Triethyl phosphate 78-40-0 C6H15O4P 182.2 99.9 Tripropyl phosphate 513-08-6 C9H21O4P 224.2 Pfaltz&Bauer 97.0 Tributyl phosphate 126-73-8 C12H27O4P 266.3 99.9 Tris(2-chloroethyl) phosphate 115-96-8 C6H12Cl3O4P 285.5 100.0 Tris(1,3-dichloro-2-propyl) phosphate 13674-87-8 C9H15Cl6O4P 430.9 95.6 Triphenyl phosphate 115-86-6 C18H15O4P 326.3 99.9 Tris(2-butoxyethyl) phosphate 78-51-3 C18H39O7P 398.5 Aldrich 94.0 Tris(2-ethylhexyl) phosphate 78-42-2 C24H51O4P 434.6 99.5 Tricresyl phosphate 1330-78-5 C21H21O4P 368.4 99.7# Dichlorvos 62-73-7 C4H7Cl2O4P 221.0 98.2 Diazinon 333-41-5 C12H21N2O3PS 304.3 99.8 Dichlofenthion 97-17-6 C10H13Cl2O3PS 315.2 98.4 Chlorpyrifosmethyl 5598-13-0 C7H7Cl3NO3PS 322.5 Dr. Ehrenstorfer GmbH 99.5 Fenitrothion 122-14-5 C9H12NO5PS 277.2 99.9 Malathion 121-75-5 C10H19O6PS2 330.4 99.8 Fenthion 55-38-9 C10H15O3PS2 278.3 Dr. Ehrenstorfer GmbH 95.5 Chlorpyrifos 2921-88-2 C9H11Cl3NO3PS 350.6 99.9 Tetrachlorvinphos 22248-79-9 C10H9Cl4O4P 366.0 99.5 Pyridaphenthion 119-12-0 C14H17N2O4PS 340.3 100.0 Propetamphos 31218-83-4 C10H20NO4PS 281.3 AccuStandard 97.8 Fenobucarb 3766-81-2 C12H17NO2 207.3 99.8 Carbaryl 63-25-2 C12H11NO2 201.2 99.9 Propoxur 114-26-1 C11H15NO3 209.2 99.6 Allethrin 584-79-2 C19H26O3 302.4 99.2 Tetramethrin 7696-12-0 C19H25NO4 331.4 Dr. Ehrenstorfer GmbH 99.1 Phenothrin 26002-80-2 C23H26O3 350.5 Dr. Ehrenstorfer GmbH 94.5 Permethrin 52645-53-1 C21H20Cl2O3 391.3 Dr. Ehrenstorfer GmbH 97.5 Cyfluthrin 68359-37-5 C22H18Cl2FNO3 434.3 Dr. Ehrenstorfer GmbH 98.5 Deltamethrin 52918-63-5 C22H19Br2NO3 505.2 Dr. Ehrenstorfer GmbH 99.0 Empenthrin 54406-48-3 C18H26O2 274.4 95.0 Furamethrin 23031-38-1 C18H22O3 286.4 91.8 Prallethrin 23031-36-9 C19H24O3 300.4 92.5 Imiprothrin 72963-72-5 C17H22O4N2 318.4 50.0 Resmethrin 10453-86-8 C22H26O3 338.4 94.0 Bifenthrin 82657-04-3 C23H22ClF3O2 422.9 99.6 Cyphenothrin 39515-40-7 C24H25NO3 375.5 Riedel-de Haen 96.5 Ethofenprox 80844-07-1 C25H28O3 376.5 99.9 Silafluofen 105024-66-6 C25H29FO2Si 408.6 96.7 Metoxadiazone 60589-06-2 C10H10N2O4 222.2 97.2 Fenoxycarb 79127-80-3 C17H19NO4 301.3 99.6 Methoprene 40596-69-8 C19H34O3 310.5 Dr. Ehrenstorfer GmbH 98.0 Pyriproxyfen 95737-68-1 C20H19NO3 321.4 100.0 Tripropyl isocyanurate 4015-16-1 C12H21N3O3 255.3 96.3 Hydramethylnon 67485-29-4 C25H24F6N4 494.5 AccuStandard 99.4 2,3,3,3,2',3',3',3'-Octachlorodipropylether (S-421) 127-90-2 C6H6Cl8O 377.7 Riedel-de Haen 99.0 Piperonyl butoxide 51-03-6 C19H30O5 338.4 94.3 MGK 264 113-48-4 C17H25NO2 275.4 AccuStandard 97.4 1-Chloronaphthalene 90-13-1 C10H7Cl 162.6 89.9 Chlorothalonil 1897-45-6 C8Cl4N2 265.9 99.7 Dichlofluanid 1085-98-9 C9H11Cl2FN2O2S2 333.2 100.0 Thiabendazole 148-79-8 C10H7N3S 201.3 99.6 2-(Thiocyanomethylthio)benzothiazole (TCMTB) 21564-17-0 C9H6N2S3 238.3 Supelco 99.5 3-Iodo-2-propynyl-N-butylcarbamate (IPBC) 55406-53-6 C8H12INO2 281.1 Aldrich 97.0 1-Bromo-3-ethoxycarbonyloxy-1,2-diiodo-1-propene () 77352-88-6 C6H7O3BrI2 460.8 99.1 p-chlorophenyl-3-iodopropargyl formal (IF-1000S) 29772-02-9 C10H8O2ClI 322.5 97.0 Thiuram 137-26-8 C6H12N2S4 240.4 99.9 Cyproconazole 94361-06-5 C15H18ClN3O 291.8 100.0 Furmecyclox 60568-05-0 C14H21NO3 251.3 Riedel-de Haen 98.2 Difolatan 2425-06-1 C10H9Cl4NO2S 349.1 98.7 Pentachlorophenol 87-86-5 C6HCl5O 266.3 99.5 N,N-Diethyl-m-toluamide (DEET) 134-62-3 C12H17NO 191.3 96.0
MS EI 70eV 60A 200 50 min SIM SVOC 0 0.12 0.23 0.47 0.94 1.88 (Selective Ion Monitoring) 3.757.5015.0 30.0g/ml 1.08 kv 0.2 sec (34.7 Auto Injector 20i 40.6 min 0.31 sec) 8 0.3ml (7.0 min19.019.023.423.426.7 3.0l 26.728.128.130.330.334.734.7 40.640.650.0 min) Empore 2 10ml 8 ml 10 SVOC SVOC 10 (2000 rpm10) SVOC (g/ml) / 5 ml (g/ml)(x) SVOC 3.0l / (y) SD905 ( 150 ml/min/ 30) 0.3 SVOC(ng) ml Auto Injector 20i SVOC(ng) {(SVOC GC/MS ) } (g/ml) GC/MS Auto 0.3(8/5)1000 Injector 20i GCMS-QP2010 Gas Chromatograph Mass Spectrometer SVOC SVOC (ng/m 3 ) GC J&W DB-1 ( 30 m SVOC (ng/m 3 ) 0.25 mm 0.25m) = { ( SVOC(ng) 68.4 kpa SVOC(ng))1000} 20.0 ml/min 1.14 (L/min) (h) ml/min 300 60 ( 2.0) 60-5/min-300(10 ) 300 1.0l
1. 73 SVOC (15.0 Tetramethrin g/ml) (TIC) 1 SVOC 50 Imiprothrin Tricresyl phosphate Deltamethrin Hydramethylnon TIC SVOC (1 No. 4192333 37526682 84) SVOC (EmpenthrinFuramethrinAllethrin Prallethrin Imiprothrin Resmethrin PhenothrinCyphenothrin PermethrinCyfluthrinDeltamethrin) Tricresyl phosphate
MGK-264 1-Chloronaphthalene Imiprothrin 90%50% SVOC 2. SVOC 3 adipate Tris (2-chloroethyl) phosphate SVOC030.0g/ml 6 02.0g/m 3 Thiuram IPBC EmpenthrinPentachlorophenol Chlorothalonil IF-1000S CarbarylFuramethrinFenitrothion SVOC DichlofluanidThiabendazoleAllethrin SVOC TCMTBPrallethrinCyproconazol ImiprothrinPiperonyl butoxidetris (2-butoxyethyl) phosphate SVOC PyridaphenthionFenoxycarbTris (2-ethylhexyl) phosphatepyriproxyfen Tricresyl phosphatecyphenothrin PermethrinCyfluthrinEthofenprox Deltamethrin 2 4. 3. Empore ( ) SVOC 120l ( 2058 ng/m 3 ) 4 (Control) 4 SVOC 5.0 L/min24 Empore 1 24 10 ml Empore 2 SVOC ( Empore 4 Diethyl phthalate Di-iso-butyl phthalate Di-n-butyl phthalatedi (2-ethylhexyl) phthalate 2(Sample 1) Di (2-ethylhexyl) SVOC 8 Empore 3) 3 Empore (Sample 2) 4
24 Empore 1 (Blank) SVOC 6 5 (Sample) 6 (Control) 60l SVOC (%) ( 1029 ng/m 3 ) = { (Sample 1 SVOC8 ml * Blank SVOC 6 *) Control SVOC * }100 6 8 ml Blank Blank SVOC (%) SVOC = { Sample 2 SVOC * (Sample 1 SVOC *Blank SV OC *)}100 SVOC () Sample SVOC * * SVOC Control SVOC * 4Blank SVOC * 1-ChloronaphthaleneThiuram Blank SVOC * 100 Empenthrin Furmecyclox Furamethrin FenthionMGK-264 Allethrin Prallethrin * SVOC 6 MethopreneImiprothrinDifolatan ResmethrinTetramethrinPhenothrin 6.0l Cyphenothrin Hydramethylnon( 103 ng/m 3 ) 10% 6 SVOC Propetemphos 70% 100% SVOC Thiabendazole 18 5677% 55 80% 24 1% 6. 5.0 L/min24 18 55 SVOC 2g/m 3 5. SVOC 5 SVOC
3 SVOC 0.12g/ml10 24 SVOC 7 Diethyl phthalate Di-iso-butyl phthalatedi-n-butyl phthalatedi (2-ethylhexyl) phthalate Di (2-ethylhexyl) adipate Tris (2-chloroethyl) phosphate6 4 Diethyl phthalatedi-n-butyl phthalate Di (2-ethylhexyl) phthalate 3 SVOC 0.1 2.0 ng/m 3 SVOC0.5 ng/m 3 Di-n-butyl phthalate Di (2-ethylhexyl) phthalate SVOC IPBC PentachlorophenolChlorothalonil IF-1000S Carbaryl Fenitrothion DichlofluanidThiabendazoleTCMTB CyproconazolPiperonyl butoxidetris (2-butoxyethyl) phosphate PyridaphenthionFenoxycarbTris (2-ethylhexyl) phosphatepyriproxyfen Tricresyl phosphatepermethrin CyfluthrinEthofenprox Deltamethrin 2 7. 5 ( ) SVOC 60l ( 1029 ng/m 3 )
5.0 L/min24 Sample 3 Control Sample SVOC SVOC (ng/m 3 ) { (Sample SVOC(ng) Control SVOC(ng) *)1000} ( (L/min) (h) 60) *3 (n=5) 5.0L ( 86 ng/m 3 ) 8 60l 5.0l Cyfluthrin Deltamethrin SVOC 10% 2 SVOC 60l Pentachlorophenol Chlorothalonil Dichlofluanid ThiabendazoleDeltamethrin SVOC 10% 73 SVOC SVOC (Empenthrin 5.0l FuramethrinAllethrinPrallethrin SVOC 10% ImiprothrinResmethrinTetramethrin 13% PhenothrinCyphenothrin) SVOC 1-ChloronaphthaleneThiuram 2 FurmecycloxFenthionMGK-264 MethopreneDifolatanHydramethylnon Propetamphos18
Empore Thiabendazole 2 SVOC 33 1 2g/m 3 IPBCPentachlorophenolChlorothalonil IF-1000SCarbaryl FenitrothionDichlofluanidTCMTB CyproconazolPiperonyl butoxidetris (2-butoxyethyl) phosphate PyridaphenthionFenoxycarbTris (2-ethylhexyl) phosphatepyriproxyfen Tricresyl phosphatepermethrin CyfluthrinEthofenprox Deltamethrin 2 SVOC 5.0 L/min24 SVOC