What is Hytrel*? Hytrel* is a high performance engineering elastomer. Hytrel* is the DuPont registered trade mark for its engineering thermoplastic po

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1 polyester elastomer DU PONT- TORAY CO., LTD. HYTREL MARKETING AND SALES DEPT. Tokyo Office 1-1, Nihonbashi Honcho 1-chome, Chuo-ku, Tokyo, TEL(03) Nagoya Office 24-, Meieki Minami 1-chome, Nakamura-ku, Nagoya TEL(052) Hytrel Technical Center , Aza kita, Motohoshizaki-cho, Minato-ku, Nagoya, TEL(052) FAX(03) FAX(052) FAX(052) Product and Application Guide

2 What is Hytrel*? Hytrel* is a high performance engineering elastomer. Hytrel* is the DuPont registered trade mark for its engineering thermoplastic polyetherester elastomer. ln Japan, Hytrel* is manufactured and sold by DuPont -Toray. Hytrel* offers many of the desirable characteristics and processing capability of engineering thermoplastics together with rubber elasticity. lt exhibits superior performance and reliability among thermoplastic elastomers. THE HYTREL* USED IN THIS BULLETIN REFERS TO THE HYTREL* FAMILY MADE BY DU PONT-TORAY CO.,LTD. UNDER THE LICENSE OF E.I. DU PONT DE NEMOURS & CO.INC.. THE HYTREL* PRODUCT LINE OF E.I. DU PONT AND THAT FROM DU PONT-TORAY IS SIMILAR BUT DIFFERENT. IN ORDER TO AVOID ANY CONFUSION, THIS BULLETIN SHOULD BE USED TOGETHER WITH THOSE FROM E.I. DU PONT, WHICH INCLUDEPRODUCT AND PROPERTIES GUIDE-HYTREL*. 2

3 Comparison of Hytrel* with rubbers and plastics. Flexibility: Rubber Hytrel* Plastics Feature of elasticity Rubber Hytrel* Plastics b. Hytrel*, an elastomeric plastics, is excellent as compared to engineering plastics in: * noise abatement impact resistance resilience low temperature properties * flex fatigue resistancewide service temperature range * Durometer A Durometer D Rockwell R Comparison of Hytrel* with other thermoplastic elastomers and engineering plastics. 4 POM Nylon6 Performance: a. Hytrel*, an engineering elastomer, out-performs traditional rubber compounds in: Flexural Modulus 3 2 Olefinics Nylon12 Polyamide elastomer Hytrel* PBT TPU * strength and durability high and low temperature propertieswide service temperature range oil, chemical resistance ozone resistance processing capabilityapplicable in injection, extrusion, blow, rotational and compression molding coloring, painting capability * Styrenics Melting Point 3 4

4 Product line and properties of Hytrel* Basic Grade 5 Physical Properties Thermal Properties Mechanical Properties Property Specific Gravity Water Absorption Melting Point Crystallization Temperature Vicat Softening Point Deflection Temp Under Load Glass Transition Temperature Brittleness Point Flammability Hardness Tensile Yield Strength Yield Elongation Tensile Strength Tensile Elongation 10 Tensile Modulus Tensile Modulus Flexural Strength Flexural Modulus Compression Modulus Resilience Izod Impact(Notched) Tear Strength(2mmt) Taber Abrasion(CS17) Volume Resistivity Mold Shrinkage Melt Index(measurement temperature) Notes 2324H A Method A 5 Test Method UL94 K7215 Durometer K7215 Durometer K C Die C 1kg1000 1kgCycles 2351RH 2,160g D792 1 D570 K76 2 D648 K6261 K K K K K D790 D790 D575 BS903 D256 D256 D624 K74 D257 D1238 Units D D Scale A A Scale J/m J/m Notched J/m J/m Notched KN/m mg cm g/10 g/10 Min ASTM 3 1 ASTM 3 No Break 2 JIS 4 2 JIS 4 Specimens pressed sheet 5 JIS2 5 JIS No.2 tensile test specimen having 2mm thickness is measured at molding direction 2mm For Injection G3548L 4047N N The available grades of Hytrel* are grouped into the categories which include the basic grades and various functional grades to meet diversified requirements for processing and specific performance The data listed here are those obtained under given test conditions representing typical examples of the measurements but not be used to establish specifications limits Equivalent For Extrusion Equivalent Equivalent Equivalent Equivalent

5 efficient molding cycle soft glass reinforced : excellent in mold flow and mold release, for noiseless gears, etc. : rubber-like softness, suitable for grips, etc. : combined flexibility at thin and stiffness at thick cross-sections of the part, for tractor belts, etc. Functional Grade Physical Properties Thermal Properties Mechanical Properties Property Specific Gravity Water Absorption Melting Point Crystallization Temperature Vicat Softening Point Deflection Temp Under Load Glass Transition Temperature Brittleness Point Flammability Hardness Tensile Yield Strength Yield Elongation Tensile Strength Tensile Elongation 10 Tensile Modulus Tensile Modulus Flexural Strength Flexural Modulus Compression Modulus Resilience Izod Impact(Notched) Tear Strength(2mmt) Taber Abrasion(CS17) Volume Resistivity Mold Shrinkage Melt Index(measurement temperature) Notes 2324H A Method A 5 Test Method UL94 K7215 Durometer K7215 Durometer K C Die C 1kg1000 1kgCycles 2351RH 2,160g D792 D570 K76 D648 K6261 K K K K K D790 D790 D575 BS903 D256 D256 D624 K74 D257 D1238 Units D D Scale A A Scale J/m J/m Notched J/m J/m Notched KN/m mg cm g/10 g/10 Min Glass Reinforced 57G G For Blow Molding HTR8341C HTR4275 BK3 BK Efficient Molding Cycle 57M 6347M 7247M SB Equivalent Kg SB Equivalent Soft SB Equivalent SC

6 low-friction : lubricated, for automotive abrasion, friction resistant parts, etc. anti-static, semi-conductive : anti-electrostatic charge, semi-electro-conductivity, for hair care goods, etc. flame retarded : UL94 V-0 rated, for robot cable outer sheath, etc. adhesion and low warpage : enhanced adhesive characteristics and low warpage for over-molding hydrolysis resistant : improved hydrolysis resistance, for hose, tubes, etc. translucent : improved light transmittance, for key pads, etc. In addition, we can offer several specialty grades, such as heat stabilized one and UV stabilized one. Functional Grade Property Notes Test Method Units Anti-static, Semi-conductive Low-friction 4767A 6347E L-01 Flame Retarded F 6037F 7237F Adhesion and scratch resistant Adhesion and Low Warpage 4057N WL Hydrolysis Resistant 77R R-07 Translucent 4001T-X04 Physical Properties Thermal Properties Mechanical Properties Specific Gravity Water Absorption Melting Point Crystallization Temperature Vicat Softening Point Deflection Temp Under Load Glass Transition Temperature Brittleness Point Flammability Hardness Tensile Yield Strength Yield Elongation Tensile Strength Tensile Elongation 10 Tensile Modulus Tensile Modulus Flexural Strength Flexural Modulus Compression Modulus Resilience Izod Impact(Notched) Tear Strength(2mmt) Taber Abrasion(CS17) Volume Resistivity Mold Shrinkage Melt Index(measurement temperature) 2324H A Method A 5 UL94 K7215 Durometer K7215 Durometer K C Die C 1kg1000 1kgCycles 2351RH 2,160g D792 1 D570 K76 2 D648 K6261 K K K K K D790 D790 D575 BS903 D256 D256 D624 K74 D257 D1238 D D Scale A A Scale J/m J/m Notched J/m J/m Notched KN/m mg cm g/10 g/10 Min Equivalent Equivalent Equivalent V V V V Equivalent Equivalent ASTM 3 1 ASTM 3 No Break 2 JIS 4 2 JIS 4 Specimens pressed sheet 5 JIS2 5 JIS No.2 tensile test specimen having 2mm thickness is measured at molding direction 2mm 10

7 Hytrel* applications The combination of superior physical properties of Hytrel*, and its chemical resistance qualify it for a number of demanding applications. Following are the examples which prove its performance and reliability. flex fatigue resistance, dynamic performance: broad service temperature range: mobile phone connector cover automotive CVJ boot air-bag deployment door hair-dryer brush impact resistance, especially in low temperature environments: resilience: oil, grease, chemical resistance: water pump retractable cord hydraulic hose diaphragm creep resistance and load bearing capability: adhesion, over-molding: seals bushings VTR camera grip mop neck-joint 11 12

8 processability for precise-molding, A-class molded surface: coloring capability: noise abatement: printer tractor belt hair brush noiseless gears automotive door lock low-friction, abrasion resistance: soft teeling property,suitable for grips and switches: A/T shift lever cable liner digital camera grip steering switch weather resistanceshould be protected from UV attack: processability for precise-molding, flex fatigue resistance, heat resistance: coloring capability, snap-fitting: bicycle belt fastener grip mandrel bobbin case 13 14

9 Characteristics of Hytrel* Chemical structure of Hytrel* Mechanical properties of Hytrel* Hytrel* is a block copolymer consisting of a hard-segmentpbtand a soft-segment polyether. Hytrel* retains its mechanical strength under broad service temperature range. lzod lmpact V notched chemical structure CO CO O(CH2 ) 4 O CO CO (CH2 n O ) p O q m hard-segment (crystalline) soft-segment (amorphous) Izod Impact Strength DHytrel* exibiting high melting pointrapid crystallization mechanical strength high deformation temperature under load molding processability oil, chemical resistanceaging resistance low glass transition temperature flexibility impact resistance low temperature properties D TPU Ester type D TPU Ester type D Hytrel* Flex Fatigue Resistance D Hytrel* D TPU cycles cycles cycles lmmediate Failure Ross Flex Growth Pierced 15 16

10 Softening Point Half Life of Elongation Acoustic damping chracteristics of Hytrel* High temperature properties and heat aging resistance of Hytrel* Because of its elasticity, Hytrel* is effective for noise abatement compared to engineering plastics. Hytrel* can be applicable in broad temperature range. It contains standard type antioxidants. Acoustic damping chracteristics of Hytrel*VS. POM Hardness and softening point of thermoplastic elastomers Hytrel* Noise (D) (JIS-A) TPS 60 TPO TPU PVC Plastcized PVC Shore D gr Iron Ball t Test Specimens t Steel Board mm Microphone 100mm Noise Meter Heat aging resistance of Hytrel* D 10 2 D 40D * Heat aging resistance can be enhanced by 2 4 using a heat stabilizer package. * It is subject to condition and formulation

11 Adhesive StrengthAdhesive StrengthWarpage Over-molding of Hytrel* Hytrel* shows good adhesion and low warpage with PC,PBT,and ABS resins. 1mm 1mm gate Adhesive Strength Low Warpage 60mm 4057 Primary: Hytrel* 4057 Over-molding mm Secondary: Hytrel* Primary : Hytrel* Secondary : ABS 250 Mold temperature 270 Mold temperature Adhesive Strength N/mm N/mm 100 Primary : Hytrel* Secondary : PC/ABS 250 Mold temperature 270 Mold temperature 0 PC PBT ABS Material Primary Secondary (D) 2533 (60D) 57 (D) Primary : Hytrel* Secondary : ABS 30 cavity 50 cavity 21 (60D) (D) 2533 (60D) Low Warpage 57 (D) 21 (60D) Gate mm Specimens for the Adhesive Strength Test are prepared by the following procedure An injection molded JIS#2 dumbbell specimen of the primary material is cut in half. 2.The cut half of the specimen is replaced into a cavity of the mold. 3.Then, the secondary material is injection molded (D) 2533 (60D) 21 (60D) 57 (D) Hytrel* 57 Hytrel* 2521

12 Opportunities for multifunctional component integration with Hytrel* Oil, fluid and chemical resistance of Hytrel* Hytrel* exibits excellent oil, fluid and chemical resistance, especially towards hydrocarbon type fluids and chemicals among thermoplastic elastomers. Oil, fluid and chemical Resistance The following list should be regarded only as a reference guide. Hence please verify by testing with actual oils and chemicals. Hytrel* is a unique thermoplastic polyetherester elastomer, displays unusual combination of the strength of engineering plastics with the useful elasticity of rubbers. For innovative designers and engineers, this broad portfolio of properties defines a new degree of freedom in component integration. A single part designed with Hytrel* can perform tasks conventionally performed by separate components made from different materials. Used in a thin section, Hytrel* can behave like rubber. In thick or ribbed section, it provides structural functions similar to engineering plastics or metals. Mineral OilsGreases Non-aromatic Hydrocarbons Hardness over 63D The following developmental applications illustrate the principle of multifunctional component integration with Hytrel*. BenzeneToluene Aromatic HydrocarbonsChemicalsSolvents WaterAlcoholsGrycols Room Temperature Over 50 Piston Seal Multipiece Design One-piece Design with Hytrel* AcidsBases Low Concentration High Concentration metal rubber metal rubber metal good fair but depnding on conditions poor Diaphragm Multipiece Design fabric core One-piece Design with Hytrel* O-ring rubber packing rubber sheet fabric core O-ring rubber packing 21 22

13 For any technical services on Hytrel* contact: Technical staff DuPont-Toray can provide customers technical support as requested for productions, processing testing, and technical developments. Hytrel* Technical Center Quality Management The production of sites of Hytrel* have received ISO 9001 and ISO qualifications. Products Liability We accept no responsibility for results obtained by the applications of this information or the safety or suitability of Hytrel*. Users are advised to make their own tests to determine the safety and suitability of each such product. The data listed here are those obtained under given test conditions representing typical examples of the measurements but not be used to establish specifications limits. DuPont-Toray does not warrant that the samples shown in this catalogue do not infringe the patent right or other industrial property rights of a third party. CAUTION: Do not use Hy trel* in medical applications involving permanent implantation in the human body. Hytrel* global product. DuPont-Toray is a joint venture of Toray industries Inc.. and E.I. DuPont de Nemours Co.Inc.. Hytrel* product from DuPont-Toray is produced based on the DuPont technology. Sourcing and technical support is available on a global basis. It's forbidden to reproduce any pictures, graphs and data in this catalogue without notice. * Hytrel* is a Du Pont's registered trademark

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