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2 Fig. 1 Sampling apparatus for the welding fume Table 1. Parameter of X-ray diffraction Table 2. Parameter of X-ray fluoresce analysis
3 Fig. 2 Located of sampling sites in Mizushima district _??_ Industrial Area
4 Fig. 3 X-ray Diffraction pattern of welding fume and covering materials of welding electrode. Fig. 4 X-ray flourence spectrum of welding fume and covering materials of welding electrode.
5 マ ン ガ ンの生体 影 響 に関 す る研 究 Fig. 5 Electron micrograph of the total suspended particulate matter 331 to welding process. 物 質 の 上 昇 す る 上 方 向 に, 100mg/m3以 上 の高 濃 度域 が 分 布 し,拡 散 は,高 1.0m付 さ約 近 か ら増大 して い る.作 業 者 の 標 準 的 な 呼 吸 域 で あ る 高 さ60cm,中 心部 か ら30cm付 近 で は, 10 30mg/m3で あ る.ま た, こ の 領 域 で のMn濃 度 は, mg/m3で あ る. 2)表-3に,実 験に使 用 し た 溶 接 棒 の 被 覆 剤 と, その 溶接 ヒューム 中 の主 な Fig. 6 X-ray fluorence from 図-8は,各 residential spectram area of the total suspended neighboring particulate matter process. 測 定 点 の 濃 度 を結 ん で 拡 散 状 態 られ た.そ 接 ヒ ュ ー ム は,溶 著 で あ っ た. ス,粒 子状 示 した. い ず れ も, Fe, Mn及 びZn の 含 有 率 が 高 く,被 覆剤 組 成 よ り溶 接 ヒ ュ ー ム の 方 が 高 くな る 傾 向 が 認 め を 図 形 化 モ デ ル と して 表 わ し た も の で あ る.溶 接 点 を 中 心 に,ガ 金 属 組 成(%)を の 傾 向 は 特 に,沸 点 の低 い金属 に顕
6 332 森 Fig. 7 X-ray diffraction culate work. Table matter 田 啓 次 郎 pattern of the total from residential 3 Chemical composition ring materials Type of electrode: Non-lime Type of covering: Lime-titania type suspended parti area neighboring of the welding electrode for the iron fume and cove mild steel (JIS-D4303)) 溶 接 保 護 面 を使 用 しな い 場 合 の 同 じ位 置 に つ い て も捕 集 を 行 っ た. 溶 接 保 護 面 を 使 用 し た 場 合, mg/m3 で 平 均 濃 度 は1.1mg/m3で あ っ た.溶 を し な い 場 合, 10 30mg/m3,平 m3で あ り,溶 接 保 護 面 を 使 用 す る こ とに よ り, 暴 露 濃 度 は 約1/10に ま た,溶 減 少 し た. 接 保 護 面 を 使 用 し,更 の 防 塵 マ ス クを 装 着 し,溶 Fig. 8 Graphic model of dencity distribution of welding fume. (Unit: 0.5m) 3)個 図-1, JIS Z (審 っ た.個 接 ヒュー ム の測定 を 議 会 討 案)に っ た 後,活 に 活性 炭付 き 接 作 業 を3.5時 性 炭 に 吸 着 し たMnとFe量 した 結 果, Mn: 450μg, Fe: 1.43mgの 間行 を分 析 分析 値 が 得 られ た. 人 暴 露 濃 度 と保 護 面 の 効 果 ② に お い て,溶 接 保 護面 均 濃 度23mg/ 準 拠 して行 人 暴 露 濃 度 測 定 の た め の 捕 集 位 置 は, 溶 接 保 護 面 の 内 側 の 溶 接 作 業 者 の 呼 吸 域 と し た. 4.製 のMnそ 鉄 工 場 周 辺 の 居 住 地 域 に お け るTSP中 の 他 の 重 金 属 濃 度 と経 年 変 化 NASN18)(国 設 大 気 測 定 網:倉 A )の 過 去11年 間( 年)の 敷 局,図-2 測 定結
7 Fig. 9 Status of, and trends in the levels of the total suspended particulate matter and heavy metals in the residential area neighboring the iron work. (Kurashiki Site ka l: NASN18))
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11 4. Waldron, H. R.: Metals in the Environment, Academic Press, N. Y., pp , Patty, F. A.: Indsutrial Hygiene and Toxicology, vol. II, Interscience Publishers, N. Y., pp , 1962.
12 26. Beaumout, J. J. and Welss, N. S.: Mortality of welders, shipfitters, and other metal trades workers in boilermakers local No. 104, AFL-CIO. Am, J. Epidemiol. 112, , Polednek, A. P.: Mortality among welders, including a group exposed to nickel oxides. Arch. Environ. Health 36, , Mori, T., Akashi, S. and Nukada, A.: Effects of the inhalation of catalytically active metallic oxide fumes on rabbits. Int. Arch. Occup. Environ. Health 36, 29-39, American Conference of Governmental Industrial Hygienists: TLVs (Threshold Limit Values) for Chemical Substances in Workroom Air Adopted by ACGIH for 1979.
13 Studies on biochemical effects of manganese I; Atomospheric levels and phsicochemical properties of manganese in the enviroment Keijiro MORITA Department of Public Health Okayama Unuversity Medical School (Director: Prof. M. Ogata) In the present study, the author examined the physicochemical properties and the atomospheric levels of manganese and other heavy metals in the suspended particulate matter of a welding workshop and a residential area neighboring an iron works. ƒ -Fe2O3 and Fe3O4 were the main components of the suspended particulate matter collected in the atomosphere around both areas. The total suspended particulate matter of the welding process (welding TSP) also contained MnFe2O4 formed from Fe3O4 by exchange of Fe with Mn, metalic Mn and an alloy from of Mn-Fe. These findings were obtained by X-ray diffractometry. Observation through the electron microscope showed the presence of fin particles ( ƒÊm) in welding TSP, and attention should be given hazards. The concentration of the metals in the welding TSP was about 10 to 30 times higher than that in the covering materials of the welding rods. Exposure levels of manganese in the welding workshop at a breathing zone ranged from 0.4 to 1.0ƒÊg/m3 and the levels were reduced to one tenth by using a welding mask. Levels of manganese have decreased from a maximum median levels of 0.24ƒÊg/m3 in 1971 to 0.15ƒÊg/m3 in The order of content of the metals in the paticulate matter was: Fe, Cu, Zn, Pb, Mn, V, Ni, and Cd.
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