SAXS Table 1 DSC POM SAXSSAXS PF BL-10C BL-15A Fig. 2 LC12 DSC SAXS 138 C T iso T iso SAXS q=1.4 nm -1 q=(4π/λ)sin(θ/2), λ:, θ: Fig. 3 LC12 T iso Figu

Similar documents

Journal of Textile Engineering, v52, n3, pp

64 3 g=9.85 m/s 2 g=9.791 m/s 2 36, km ( ) 1 () 2 () m/s : : a) b) kg/m kg/m k

2 FIG. 1: : n FIG. 2: : n (Ch h ) N T B Ch h n(z) = (sin ϵ cos ω(z), sin ϵ sin ω(z), cos ϵ), (1) 1968 Meyer [5] 50 N T B Ch h [4] N T B 10 nm Ch h 1 µ

untitled

Degradation Mechanism of Ethylene-propylene-diene Terpolymer by Ozone in Aqueous Solution Satoshi MIWA 1 *, 2, Takako KIKUCHI 1, 2, Yoshito OHTAKE 1 a


Study on Application of the cos a Method to Neutron Stress Measurement Toshihiko SASAKI*3 and Yukio HIROSE Department of Materials Science and Enginee

Optical Lenses CCD Camera Laser Sheet Wind Turbine with med Diffuser Pitot Tube PC Fig.1 Experimental facility. Transparent Diffuser Double Pulsed Nd:

II III I ~ 2 ~

中堅中小企業向け秘密保持マニュアル


ＰＲ映画-1


- 2 -


1 (1) (2)

Microsoft Excelを用いた分子軌道の描画の実習

6 2 2 x y x y t P P = P t P = I P P P ( ) ( ) ,, ( ) ( ) cos θ sin θ cos θ sin θ, sin θ cos θ sin θ cos θ y x θ x θ P

????? 1

J. Jpn. Inst. Light Met. 65(6): (2015)

The Plasma Boundary of Magnetic Fusion Devices

pp * Yw; Mq 1. 1L 20 cc [1] Sonoluminescence: Light emission from acoustic cavitation bubble. Pak-Kon Choi (Departm

X線分析の進歩36 別刷

42 1 Fig. 2. Li 2 B 4 O 7 crystals with 3inches and 4inches in diameter. Fig. 4. Transmission curve of Li 2 B 4 O 7 crystal. Fig. 5. Refractive index

From Evans Application Notes



光学

Netsu Sokutei 19 (4) Thermal Transitions and Stability of Fatty Acid-Containing and Defatted Bovine Serum Albumin (BSA) Michiko Kodama, Shinji

C-2 NiS A, NSRRC B, SL C, D, E, F A, B, Yen-Fa Liao B, Ku-Ding Tsuei B, C, C, D, D, E, F, A NiS 260 K V 2 O 3 MIT [1] MIT MIT NiS MIT NiS Ni 3 S 2 Ni

Surface Morphology for Poly-L-lactide Fibers Subjected to Hydrolysis Suong-Hyu Hyon Institute for Frontier Medical Sciences, Kyoto University 53, Shog

修士論文

Accuracy check of grading of XCT Report Accuracy check of grading and calibration of CT value on the micro-focus XCT system Tetsuro Hirono Masahiro Ni

c 2009 i

16 (16) poly-si mJ/cm 2 ELA poly-si super cooled liquid, SCL [3] a-si poly-si [4] solid phase crystalization, SPC [5] mJ/cm 2 SPC SCL (di

Computer Simulation in Thermoplastic Injection Molding Takaaki Matsuoka Toyota Central Research and Development Laboratories, Inc. 41-1, Yokomichi, Na

Chapter n m A 1, A 2,...A n (A k = [a 1 k, a2 k,..., am k ]) n n m m m 2 3 Z 2 Z = w 1 X 1 + w 2 X 2 (5.1) 1

特-4.indd

The Physics of Atmospheres CAPTER :


(2009) Table 1 van Genuchten θ r θ s α n K s h i θ(h i ) K(h i ) Soil type (cm 3 cm 3 ) (cm 3 cm 3 ) (cm 1 ) ( ) (cm d 1 ) (cm) (cm 3 cm 3 ) (c

<955C8E E696E6464>

a) Extraction of Similarities and Differences in Human Behavior Using Singular Value Decomposition Kenichi MISHIMA, Sayaka KANATA, Hiroaki NAKANISHI a

untitled

X線分析の進歩45

3 3.1 R r r + R R r Rr [ ] ˆn(r) = ˆn(r + R) (3.1) R R = r ˆn(r) = ˆn(0) r 0 R = r C nn (r, r ) = C nn (r + R, r + R) = C nn (r r, 0) (3.2) ( 2.2 ) C

カイラル結晶化ver3pp.dvi

The Phase Behavior of Monooleoylglycerol-Water Systems Mivoshi Oil & Fat Co.. Ltd. Faculty of Science and Technology, Science University of Tokyo Inst

ONLINE_MANUAL

ONLINE_MANUAL

Gmech08.dvi


1

% 1% SEM-EDX - X Si Ca SEM-EDX SIMS ppm % M M T 100 % 100 % Ba 1 % 91 % 9 % 9 % 1 % 87 % 13 % 13 % 1 % 64 % 36 % 36 % 1 % 34 46

2 Part A B C A > B > C (0) 90, 69, 61, 68, 6, 77, 75, 20, 41, 34 (1) 8, 56, 16, 50, 43, 66, 44, 77, 55, 48 (2) 92, 74, 56, 81, 84, 86, 1, 27,

1/2 ( ) 1 * 1 2/3 *2 up charm top -1/3 down strange bottom 6 (ν e, ν µ, ν τ ) -1 (e) (µ) (τ) 6 ( 2 ) 6 6 I II III u d ν e e c s ν µ µ t b ν τ τ (2a) (

1206 Funamura2

最終.indd

Fig. ph Si-O-Na H O Si- Na OH Si-O-Si OH Si-O Si-OH Si-O-Si Si-O Si-O Si-OH Si-OH Si-O-Si H O 6

神奈川県西部山北南高感度地震観測井の掘削および孔内検層，Borehole Drilling and Physical Properties of the Yamakita-minami Seismic Observatory in Western Ka

d (i) (ii) 1 Georges[2] Maier [3] [1] ω = 0 1

5b_08.dvi

Table 1. St-VAc blockcopolymers Table 2. Stability of dispersion of blockcopolymers in unsaturated polyester

Hideki MATSUOKA: An Introduction to Small-angle Scattering Fundamental aspects of small-angle scattering technique are duly explained from the very ba

5. F(, 0) = = 4 = 4 O = 4 =. ( = = 4 ) = 4 ( 4 ), 0 = 4 4 O 4 = 4. () = 8 () = 4

a L = Ψ éiγ c pa qaa mc ù êë ( - )- úû Ψ 1 Ψ 4 γ a a 0, 1,, 3 {γ a, γ b } η ab æi O ö æo ö β, σ = ço I α = è - ø çèσ O ø γ 0 x iβ γ i x iβα i

研究室ガイダンス(H28)福山研.pdf

1) K. J. Laidler, "Reaction Kinetics", Vol. II, Pergamon Press, New York (1963) Chap. 1 ; P. G. Ashmore, "Catalysis and Inhibition of Chemical Reactio



結晶成長学からの提案

15

2357

I II III 28 29

X線分析の進歩 39　別刷

Rate of Oxidation of Liquid Iron by Pure Oxygen Shiro BAN-YA and Jae-Dong SHIM Synopsis: The rate of oxidation of liquid iron by oxygen gas has been s

unknown heat Q known heat Q0 (a) (b) Fig. 3 Schematic drawing of output potential difference vs. time curves from a conduction-type calorimeter. Fig.

4‐E )　キュリー温度を利用した消磁：熱消磁

1 a b cc b * 1 Helioseismology * * r/r r/r a 1.3 FTD 9 11 Ω B ϕ α B p FTD 2 b Ω * 1 r, θ, ϕ ϕ * 2 *

吸収分光.PDF

128 3 II S 1, S 2 Φ 1, Φ 2 Φ 1 = { B( r) n( r)}ds S 1 Φ 2 = { B( r) n( r)}ds (3.3) S 2 S S 1 +S 2 { B( r) n( r)}ds = 0 (3.4) S 1, S 2 { B( r) n( r)}ds

n..

Canon EOS Kiss Digital N 製品カタログ

h1

放射線化学, 92, 39 (2011)

生活設計レジメ

1

44 4 I (1) ( ) (10 15 ) ( 17 ) ( 3 1 ) (2)

( ) sin 1 x, cos 1 x, tan 1 x sin x, cos x, tan x, arcsin x, arccos x, arctan x. π 2 sin 1 x π 2, 0 cos 1 x π, π 2 < tan 1 x < π 2 1 (1) (

研究成果報告書

Microsoft Word - mitomi_v06.doc

地質調査研究報告/Bulletin of the Geological Survey of Japan

all.dvi

1).1-5) - 9 -

: u i = (2) x i Smagorinsky τ ij τ [3] ij u i u j u i u j = 2ν SGS S ij, (3) ν SGS = (C s ) 2 S (4) x i a u i ρ p P T u ν τ ij S c ν SGS S csgs

248 Nippon Shokuhin Kagaku Kogaku Kaishi Vol. /-, No./,,.2,/. (,**0) 12 * * * Microencapsulation of Glutamine with Zein by a Solvent Evaporation Metho

レーザ誘起蛍光法( LIF法) によるピストンの油膜挙動の解析

Undulator.dvi

Transcription:

1 1 1 1,2 1,2 1 2 Correlation between Microphase Separation and Liquid Crystallization in Structure Formation of Liquid Crystalline Block Copolymers Shin-ichi TANIGUCHI 1, Hiroki TAKESHITA 1, Masamitsu MIYA 1, Katsuhiko TAKENAKA 1,2, Tomoo SHIOMI 1,2 1 Department of Materials Science and Technology, Nagaoka University of Technology 2 Center for Green-Tech Development in Asia, Nagaoka University of Technology nm (i) (ii) (iii) [1-5] [6-11] [12,13] 2 Fig. 1 CH 2 11 PLC - T iso (T g ) n- PBAT iso T g (PSt) M n w LC M w /M n Figure 1 Chemical structure of block copolymers and PLC homopolymer. Table 1 Characteristics of block copolymers and PLC homopolymer. sample M n [kg/mol] PSt PBA PLC w LC M w /M n Microphase Morphology of Separation LC12 - - 12.0 1.00 1.11 - S14LC01 14.3-1.4 0.09 1.21 PLC sphere S09LC04 9.1-4.3 0.22 1.20 PLC cylinder S14LC09 14.3-8.8 0.38 1.12 LAM S09LC13 9.1-13.0 0.59 1.21 PSt cylinder B38LC30-37.9 30.0 0.44 1.21 LAM B34LC08-34.0 8.2 0.20 1.04 PLC cylinder B38LC07-37.9 6.9 0.15 1.12 PLC sphere

SAXS Table 1 DSC POM SAXSSAXS PF BL-10C BL-15A Fig. 2 LC12 DSC SAXS 138 C T iso T iso SAXS q=1.4 nm -1 q=(4π/λ)sin(θ/2), λ:, θ: Fig. 3 LC12 T iso Figure 2 Bilayer smectic structure of PLC homopolymer determined by SAXS and DSC. Fig. 2 d=4.5 nm T iso T g DSC POM T iso SAXS Fig. 3 Fig. 4 140 C S14LC01 S09LC04 S14LC09 S09LC13 PLC PLC PSt T iso S14LC09 S09LC13 Fig. 2 SAXS (q 1.4 nm 1 ) S14LC01 S09LC04 SAXS S09LC04 - DSC T iso POM Fig. 3 Figure 3 DSC thermograms and POM photographs for the PSt-PLC block copolymers. The scale bar indicates a distance of 100 µm. Figure 4 SAXS profiles of the PSt-PLC block copolymers at indicated temperatures.

Figure 5 2D-SAXS image and schematic model of the phase structure for S09LC13 in liquid crystalline state. LC S14LC01 DSC POM 2 SAXS BL-15A Fig. 5 S09LC13 q=0.32 nm 1 MS q=1.45 nm 1 LC PSt [9] [9] Figure 6 SAXS profiles and POM photographs for the PBA-PLC block copolymers in liquid crystalline state at 40 C. The scale bar indicates a distance of 200 µm. PBA PSt T g 50 C Fig. 6 B38LC30 B34LC08 B38LC07 40 C <T iso SAXS POM B34LC08 B38LC07 q=1.4 nm 1 B34LC08 POM B38LC07 PSt B38LC30 T iso B38LC30 T iso

Figure 7 Development of Lorentz-corrected SAXS profile and POM photograph for B38LC30. The scale bar indicates a distance of 100 µm. The peaks A C are due to the microphase separation structure, and the peak LC due to Sm layers. SAXS POM Fig. 7 SAXS q=0.17 nm 1 (A) T iso 100 Cq=1.4 nm 1 LC (B) (C) (B) POM SAXS (C) (B) (B) [14,15] SAXS - 20 [1] L. W. Hamley, "The Physics of Block Copolymers", Oxford University Press (1988), Chapter 5. [2] A. J. Müller, V. Balsamo, and M. L. Arnal, Adv. Polym. Sci. 190, 1 (2005). [3],, 53, 259 (2004). [4],, 63, 406 (2007). [5] H. Takeshita, N. Ishii, C. Araki, M. Miya, K. Takanaka, and T. Shiomi, J. Polym. Sci. Part B 42, 4199 (2004). [6] M. Yamada, T. Itoh, R. Nakagawa, A. Hirao, S. Nakahama, and J. Watanabe, Macromolecules 32, 282 (1999). [7] M. H. Li, P. Keller, and P.A. Albouy, Macromolecules 36, 2284 (2003). [8] I. A. Ansari, V. Castelletto, T. Mykhaylyk, I. W. Hamley, Z. B. Lu, T. Itoh, and T. Imrie, Macromolecules 36, 8898 (2003). [9] M. Anthamatten, W. Y. Zheng, and P. T. Hammond, Macromolecules 32, 4838 (1999). [10] I. W. Hamley, V. Castelletto, Z. B. Lu, C. T. Imrie, T. Itoh, and M. Al-Hussein, Macromolecules 37, 4798 (2004). [11] N. Tomikawa, Z. Lu, T. Itoh, C.T. Imrie, M. Adachi and M. Tokita, and J. Watanabe, Jpn. J. Appl. Phys. 44, L771 (2005). [12] H. Takeshita, S. Taniguchi, M. Arimoto, M. Miya, Takenaka, and T. Shiomi, Polymer 50, 271 (2009). [13] S. Taniguchi, H. Takeshita, M. Arimoto, M. Miya, Takenaka, and T. Shiomi, Polymer 49, 4889 (2008). [14] M. Tokita, K. -W. Kim, S. Kang, and J. Watanabe, Macromolecules 39 2021 (2006). [15] K. Kaji, K. Nishida, T. Kanaya, G. Matsuba, T. Konishi, and M. Imai, Adv. Polym. Sci. 191, 187 (2005). 2009 1 15 Shin-ichi TANIGUCHI 3 940-2188 1603-1

TEL: 0258-47-9321 FAX: 0225-47-9300 e-mail: shinichi_taniguchi@mst.nagaokaut.ac.jp Hiroki TAKESHITA 940-2188 1603-1 TEL: 0258-47-9321 FAX: 0225-47-9300 e-mail: takeshita@mst.nagaokaut.ac.jp 1999 2007 Masamitsu MIYA 940-2188 1603-1 TEL: 0258-47-9335 FAX: 0225-47-9300 e-mail: miya@konomi.nagaokaut.ac.jp 1979 2004 Katsuhiko TAKENAKA 940-2188 1603-1 TEL: 0258-47-9305 FAX: 0225-47-9300 e-mail: ktakenak@nagaokaut.ac.jp 1986 1995 2007 1,3- Tomoo SHIOMI 940-2188 1603-1 TEL: 0258-47-9304 FAX: 0225-47-9300 e-mail: shiomi@nagaokaut.ac.jp 1980 1991

2024 © docsplayer.net プライバシー | 利用規約 | フィードバック