橡遺棄化学兵器の廃棄本文
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- さわ いそみ
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32 / / / / Munster mm mm Defense Evaluation & Research Agency Chemical & Biological Defense Establishment Salisbury Porton Down
33 Ieper Poelkapalle Poelkapalle Antwerpen
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36 Keystone Center Modena Bunnett Mikolajczyk 3) RSCH2CH2Cl 4) (CH2=CH2)2S 5) C-S C-SC-N C-S
37 6) bioremediation 7) 2) Na2CO3 As O H2O2 CAs H2O2 ) )
38 1) 2) 3) J.F.Bunnett, M.Mikolajzyk, ed., Arsenic and Old Mustard, Chemical Problems in the Destruction of Old Arsenical and Mustard Munitions, NATO ASI Series, Kluwer Academic Pub., Dordrecht 1998
39 4),, ) S.Bales, J. Chem. Soc., 123, 2486 (1923) 6) H.Wariishi, Fungal Metabolism of Environmentally Persistent Compounds. Substrate Recognition and Metabolic Response Biotechnol. Bioprocess Eng. 5, 422 (2000) 7), (B)(2) (2001) 8),,,,, 52 (1999) 9) K.Tani, S.-I.Hanabusa, S.Kato, S.-Y.Mutoh: S.-I.Suzuki, M.Ishida, J. Chem. Soc.,Dalton, 518 (2001)
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87 ,,,,, 1997,,,, 1999, 2000 D. H. Ellison,Handbook of Chemical and Biological Warfare Agents,CRC Press, Boca Raton, Florida 2000 J. F. Bunnett, M. Mikolajczyk ed., Arsenic and Old Mustard: Chemical Problems in the Destruction of Old Arsenical and Mustard Munitions, NATO ASI Series, Disarmament Technologies, Vol.19, Kluwer Academic Pub, Dordrecht (1998) Recommendations for the Disposal of Chemical Agents and Munitions, National Research Council, Washington, D.C. (1994) Review and Evaluation of Alternative Technologies for Demilitarization of Assembled Chemical Weapons, National Research Council, Washington, D.C. (1999) Assembled Chemical Weapons Assessment Program,Supplemental Report to Congress, Program Evaluation Team (1999) Abstracts of Papers and Posters, Symposium, Munster, Germany (2000) 2 nd International CW Destruction Proceedings of the International CW Destruction Symposium, Munster, Germany (1998),
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3, ,104 t mg/l 30 mg/l BOD mg 14 C 8, /kg 11 8, 1 11 OH = cm 3 / sec 11 OH /cm ppm
3, 3-1 200019 4800 CAS 91941 1138 3, 3-4, 4 - -3, 3 - H 2 N Cl Cl NH 2 C 12 H 10 C l2 N 2 253.13 1 95 1. 2 3, 4 132-133 402 5 >200 5 700kg/m 3 5 8.73 = 1 5.610-8 kpa 4.210-7 mmhg20 4 6 log Pow3.51 3.57
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橡フタル酸ブチルベンジル.PDF
1 97 7 3 1312 CAS 85 68 7 O BBP 1, 2- C 19 H 20 O 4 312.4 C C O O O (CH 2 ) 3 1 99.9 % 1. 2-35 3 2, 3 370 3, 4 199 d 25 4 1.117 2 10.8 = 1 5 1.15 10-3 Pa 8.6 10-6 mmhg 20 5 253 Pa 1.9 mmhg 200 5 log Pow
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Series No. 60Jan. 2004 CONTENTS 2 RAD-AR News Vol.14, No.5 (Jan. 2004) 3 4 RAD-AR News Vol.14, No.5 (Jan. 2004) 5 RAD-AR News Vol.14, No.5 (Jan. 2004) 6 7 RAD-AR News Vol.14, No.5 (Jan. 2004) 8 9 1100
CAS H 3 C C CH 2 C 9 H tert d = hpa
1 200140 35 CAS 98839 1335-2- H 3 C C CH 2 C 9 H 10 118.18 1 99 4-tert- 1. 2-23.2 2 163164 2 54 574 3 0.96.6 20 d 4 0.9082 2 4.07 = 1 2.5 hpa 1.9 mmhg20 2 4 log Pow3.48 3.44 m/z 118, 1.0 103 0.58 91 0.21
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橡96-07.PDF
1 967 2482 CAS 50000 CH 2 O 30.03 2952% 12.5 % 1. 2) -92 2) -19.5 2) 5085 3) 424 3) 7.073.0% 4) 20 d 4 0.815 5) 1.03 ( = 1) 5) 1.33 kpa (10 mmhg) (-88.0) 2) log Pow0.35 ( ) 6) 0.35 ( ) 7) 1) m/z 29 ( 1.0
,977 t 157,977 t mg l mg l BOD 9398 % OH = cm 3 / sec 11 = cm 3 / sec OH = /
1 9625 2219 CAS 75569 1, 2-1, 2- H 2 C CH CH 3 C 3 H 6 O 58.08 1 99 % 1. 2 2, 3-112.13 2, 3 34.23-37 449 2.8-37 % 2 d 0 4 0.859 4 d 20 0.8304 2 2, 4 2.00 = 1 53.33 kpa 400 mmhg18 59.33 kpa 445 mmhg20 5
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b 0 1PPm 10PPm 100PPm 1000PPm 10000PPm 0.0001% 0.001% 0.01% 0.1% 1% 10% 1PPm 10PPm 100PPm 1000PPm 10000PPm 0.0001% 0.001% 0.01% 0.1% 1% 10% 1PPm 10PPm 100PPm 1000PPm 10000PPm 0.0001% 0.001% 0.01%
CAS NC(CH 2 ) 4 CN 1,4- C 6 H 8 N c.c d = Pa
1 200117 21512 CAS 111693 110 NC(CH 2 ) 4 CN 1,4- C 6 H 8 N 2 108.14 1 99 2-1. 2 1 295 159 c.c. 550 3 1.7-4.9 20 d 0.965 4 3.73 = 1 0.3 Pa 0.002 mmhg20 2 log Pow-0.32 m/z 41, 1.0 68 0.54 54 0.43 4 Koc9-16
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1 9924 2260 CAS 107186 H 2 C CH CH 2 OH 2- -1- C 3 H 6 O 58.08 1 99 1. 2, 3 3, 4, 5-129 96-97 2 21c.c. 24o.c. 2 6, 7 378 6, 7 2.5-18 d 20 4 0.8540 2, 5 2.00 = 1 2.7 kpa 20 mmhg204.3 kpa 32 mmhg30 4 log
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2-1 200169 2740 CAS 110-49-6 1103 2- O H 3 C C O CH 2 CH 2 O CH 3 C 5 H 10 O 3 118.13 200168 2-1 99 2-1. 2 2, 3-65 2, 3 144145 45 o.c. 3 392 3 1.512.3 d19 1.009 2 4.07 = 1 30 Pa 0.23 mmhg20 2 4 log Pow0.10
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