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1 Best Practice ph O2 /
2 2 / 3 : 3 : ph 5 : TNK-BP ph 7 ph 9 11 DO % ph Publisher / Production Mettler-Toledo AG Process Analytics Im Hackacker 15 CH-8902 Urdorf Switzerland Images Mettler-Toledo AG Dreamstime.com Subject to technical changes Mettler-Toledo AG 03/2014 2
3 Chemical and Refining Operations 150 Sinopec 2 5 Sabic 2009 Sinopec Sabic Tianjin Petrochemical Plant ph ORP ORP 550mv ph (TDS) ph ORP ph/orp ph InPro 3250 i InPro 3250 i 1 ORP Sinopec Sabic ISM InPro 3250 i (ISM) ISM 3
4 Chemical and Refining Operations ISM InPro 3250 i ph Sinopec Sabic ISM 1 3 UniCond UniCond ISM ph UniCond UniCond 1 InPro 3250 i UniCond Sinopec Sabic ISM M800 M800 imonitor ISM 4
5 Chemical and Refining Operations ph ph ph InPro 4800 i ph ph ph ph 1 2 InPro 4800 i ph InFit 761e M400 ph InPro 4800 i 130 C (266 F) 13 barg (188 psig) PTFE i (ISM) ISM ISM M400 2 InPro 4800 i ph ISM 5
6 Chemical and Refining Operations PC USB isense InPro 4800 i InFit 761e InFit 761e O 1 M400 2 M400 2 ISM M400 2 HART 2 PID 6 InPro 4800 i 2 1 ph 2 1 ISM ph 10 % ph 6
7 Chemical and Refining Operations TNK-BP ph TNK-BP ph TNK-BP 10 BP Alfa, Access / Renova group (AAR) 2003 TNK-BP 50, mboed 100 / TNK-BP ph ph ph ph InPro 4260 InTrac 777 M400 InPro 4260 ph Xerolyt Extra InTrac 777 InPro 4260 ph Xerolyt EXTRA 7
8 Chemical and Refining Operations M M400 2 HART HART ISM TNK-BP TNK-BP 6 8
9 Chemical and Refining Operations ph ~ 1,000 C / ( ) ph 9
10 Chemical and Refining Operations InPro 4800 i ph ph PTFE InPro 4800 i ph ISM 2 M400 HART ISM / EasyClean
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11 DO DO DO EPRI ASME VGB [1,2,3] 2 ppb 2 (AVT-R) AVT-R ppb (AVT-O) (Fe3O4) (FeOOH) AVT-O (OT) 11
12 FeOOH ppb [mg/m 2 ] ph=7 ph= ph= [ppb] 1: ph Power Plant Chemistry [ppb] 1 ph 3 3 μs / cm 1 < 20 ppb > 2,000 ppb ph8~ ( C) 2: ( ) 12
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14 1 2 OptoCap 5 LED OptoCap 2 10 ppb % ( ) 0% 20% 40% 60% 80% 100% 120% 140% 4: 1 4~5 1 OptoCap 1 ph ORP 1 14
15 LED LED O OptoCap ( ) 5: 1. Comprehensive Cycle Chemistry Guidelines for Fossil Plants, , Electric Power Research Institute, Palo Alto, CA (2011). 2. Consensus on Operating Practices for the Control of Feedwater and Boiler Water Chemistry in Modern Industrial Boilers, (1994). Consensus on Operating Practices for Control of Water and Steam Chemistry in Combined Cycle and Cogeneration, (2012). Consensus on Operating Practices for the Sampling and Monitoring of Feedwater and Boiler Water Chemistry in Modern Industrial Boilers (2006). American Society of Mechanical Engineers, New York. 3. VGB-Standard, Feedwater, Boiler Water and Steam Quality for Power Plants / Industrial Plants, VGB-S-010-T-00; EN. 4. Standard Test Method for On-Line Measurement of Low-Level Dissolved Oxygen in Water, ASTM International D , W. Conshohocken, PA. 15
16 1 50 ms/cm 4 RO < 0.06 μs / cm RO 6 RO 1 1 (ISM ) UniCond ISM UniCond (Cycle Chemistry) UniCond UniCond UniCond ASTM NIST 16
17 ISM UniCond ( ) / UniCond( ) 17
18 ph (Cycle Chemistry) ph 2 2 ph ph ph ( ) 50μS / cm ph ph 1 0.5pH phure 1 18
19 phure phure LE phure LE phure ISM ) ASTM D5128 ph 19
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22 1 ppb / ppb 0.2 ppb (NaCl 0.5 ppb) μs / cm ph 2300Na ph ph ph 22
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24 Get in-line with METTLER TOLEDO (ISM) ISM F TEL: FAX:
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4 100g
100g 10 20 30 40 50 60 70 80 4 5 7 9 12 15 19 24 60 100 10 80 100 20 10 5 20 195 20-1- 60 60 15 100 60 100 15 15 15 100 15 15 60 100 10 60 100 100 15 10 10 60 100 15 10 15 10 5-2- 80 80 24 100 80 100 24
インドシナ産業基板基礎調査団報告書
J R 01-08 ABBREVIATlON AOAC APEC APLAC APLMP APMP ASEAN ASTM BIPM BNM BOA BPS BS CBWM CGPM CMS CNLA CNS CSIR CSIRO DOE DOM DOST DSMQC DSN DSS DTI EMC ETL FAO GDP Association of Official Analytical Chemists
CAS O C O * DOP* DEHP 2- C O O * n- C 24 H 38 O CH 2 CH 2 CH 2 CH 3 CH (CH 2 ) % 2- A BHT , 4
2-1 9628 31307 CAS 117817 2- O C O * DOP* DEHP 2- C O O * n- C 24 H 38 O 4 390.56 CH 2 CH 2 CH 2 CH 3 CH (CH 2 ) 3 1 99 % 2- ABHT 1. 2-55 3 3, 4 386 171 350 6 0.1 % d 20 4 0.9861 4 13.48 0.30410-4 Pa 2.2810-7