(a) (b) X Ag + + X AgX F < Cl < Br < I Li + + X LiX F > Cl > Br > I (a) (b) (c)

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1 ( 13 : : 00 )

2 (a) (b) X Ag + + X AgX F < Cl < Br < I Li + + X LiX F > Cl > Br > I (a) (b) (c)

3 (a) CH 3 -Br (b) (c),2,4- (d) CH 3 O-CH=CH-CH 2 (a) NH 2 CH 3 H 3 C NH 2 H CH 3 CH 3 NH 2 H 3 C CH 3 NH (b)

4 (a), (b) (a) 2H 2 (g) + O 2 (g) = 2H 2 O(l) H 298 K 1 atm O 2 1 mol 572 kj (g)(l) O 2 1 mol U R = 8.31 JK 1 mol 1 1 atm = Pa (b) T 1 mol V 1 V 2 R (a) (b) S (c) 20% 10 log 10 2 = (a) (b)

5 l C (a) I 0 I (b) l (a) (i) (ii) l (a) mol dm 3 1 dm 3 AgCl mol 2 dm 6 AgI mol 2 dm 6 Cl 35 Ag 108 I 127 (a) 1.0 mmol (b) (a) Ag + (c) AgCl AgI Ag +

6 +Ze e m e Ĥ = 2 Ze 4πε r 0 r ε 0 n, l, m r, θ, φ r θ φ r θ φ 2 2 Z e E1 = 8πε 0a0 2 4πε 0h a0 = 2 m e e 5 n E n = l n l

7 (a) -D- 20 C (b) 20 C (c)

8 ( 9 : : 30 ) 3

9 (a) H 3 PO 4 > H 2 PO 4 > HPO 2 4 (b) H 2 Se > H 2 S > H 2 O (c) HClO 4 > H 2 SO 4 > H 3 PO 4 > H 4 SiO 4 (a) fac-[co(gly) 3 ]gly = [Ni(CO) 4 ] [PtCl 3 (C 2 H 4 )] C 2 H 4 = [Fe(C 5 H 5 ) 2 ] C 5 H 5 = [Co(CN) 5 ] 3 (b) (1) (III) (2) [Co(NH 3 ) 6 ] 2+ [Co(NH 3 ) 6 ] 3+ (3) [MnO 4 ] Mn O Re 2 Cl 2 8 Re Cl Cl Cl Re Cl Cl Re Cl Cl 871 Cl

10 (a) (b) (a) CH 3 + Cl 2 hν CH 3 (b) + HI (c) + H 2 C CH 2 H 2 SO 4 (d) CH 3 CH 2 CH 2 CH 3 Cl + H 2 O (e) CH 3 2 CH 3 CO 2 C 2 H 5 NaOC 2 H 5 C 2 H 5 OH H 3 O +

11 P G (a) G P+ P P solid O D liquid gas A B (b) A, B C (c) (b) T P AB Tm T b T b+ T (d) (c) OA, OC, OD O dp/dt (e) P + P G (f) (Tm)(T b) Tm T b

12 i P i S k S = k p i ln p i i U i E i < E i > (a) U p i (b) <( E i U ) 2 > < E i 2 > U 2 (c) E W i p i S (d) V T N i E i Q Q ( T, V, N) = exp( E i kt ) i i p i U Q S A Q

13 Ag + + e = Ag Nernst E = E Ag Ag + ( 2.303RT F)log(1 a Ag+ ) a Ag+ E Ag/Ag+ F, T, R Faraday (a) NHE E Ag/Ag V 298K 0.799V (b) NHE( mol dm 3 )( mol dm 3 ) 298K 298K 2.303RT /F 0.060V (c) (d) E AgCl/Ag a Cl - ph = dc B / dph C B K a HA C a C b CB [H + ] CC = C a + C b K a K w

14 [OH ] + [A ] = C = C a + C b = K a = [A ] = K w = [H + ] C B C B = [H + ] dc B / d [H+] = dc B /dph = 2.3{K w / [H + ] + [H + ] K a C [H + ] / ([H + ] + K a ) 2 } (a)(e) (a) (b) (c) (d) (e)

15 m V(x)a, b V 0 x b 0 b < x < a V(x) = V 0 a x a 0 a < x < b x b (a) E V 0 0 < E < V 0 φ (x) k E, V 0, m h h ( = ) A, B, C, D 2π φ (x) = A exp(ikx) + B exp( ikx) (k > 0) φ (x) = C exp(kx) + D exp( kx) (k > 0) φ (x) = 0 (b) A, B, C, D E (c)

16 (a) Hückel MO MO (b) MO MO MO MO MO MO (c) MO (b) (d) Hückel MO E 1 = 2E 2,3 = E 4 = 2 MO

17 cm M ph = 4.61 M = 1 mol dm 3 ph = cm 3 4 M ph (a) ph 4.8 (b) (c) - H-Arg-Glu-Thr-Ile-Glu-Ser-Leu-Ser-Ser-Ser M - (d) - HPLC 8,5009,300 HPLC Edman 212

18 (e) H-Tyr-Pro-Phe(or Trp)-Phe-NH 2

19

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