5-U P02-13_6校.indd

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2 製品の特徴 haracteristics of SOLBIN ソルバイン SOLBIN 塩ビと酢ビの特性を活かした共重合樹脂 製品の種類 Product Types ソルバイングレード体系 diagram of SOLBIN opolymer resin with characteristics of vinyl chloride and vinyl acetate ソルバインは塩化ビニルの強靭性 耐薬品性と酢酸ビニルの付着性 可 塑性を活かし さらに他の極性基を付与した接着性 溶解性に優れた変 性樹脂です 乾燥後の塗膜は無味 無臭で耐水性が良く 吸水率が低いなどの優れた 性質をもっており 各種塗料 インキ 接着剤や 磁気テープ 磁気カードな どのバインダー 清涼飲料缶 防湿セロハンなどのコーティング剤として 使用されています SOLBIN is a modified resin that combines the toughness and chemical resistance of vinyl chloride, strong adhesiveness and plasticity of vinyl acetate, and other polar groups that enhance adhesivity and solubility. Due to its many outstanding characteristics, including it's film lack of odor or taste and high resistance to water penetration, SOLBIN has been used as an essential part of various paints, inks, and adhesives. as a binder for magnetic cards and tapes, and as a coating agent for soft drink cans and moisture-proof cellophanes. ソルバインの特徴 haracteristics of SOLBIN SOLBINは 塩化ビニルと酢酸ビニルなどとの共重合樹脂で 次のような特徴があります SOLBIN is a copolymer resin prepared from vinyl chloride and vinyl acetate in addition to other elements, and has the following characteristics: ❶ ケトン エステル等の有機溶剤に溶解します It dissolves in organic solvents such as ketone and ester. ❷ 乾燥後の塗膜は透明性が高く 無味 無臭です It forms an odorless, tasteless, and transparent film. ❸ 酸 アルカリ 塩水に対してすぐれた耐薬品性を示します It is highly resistant to chemicals such as acids, alkalis, and brine. ❹ 特に 耐水性のすぐれた塗膜が得られます It forms a coating film highly resistant to water. ❺ 塗膜は 難燃性で自己消火性を示します Its coating films are fire-retardant and self-extinguishing. ❻ 塗膜は 熱可塑性でヒートシール性を示します Its coating films are thermoplastic and heat-sealable. ❼ ウレタン樹脂 メラミン樹脂とすぐれた相溶性を示します It is highly compatible with urethane and melamine resins. ❽ 親水基をもつグレードは 磁性粉等の無機顔料を良好に分散します Products with hydrophilic groups favorably disperse inorganic pigments such as magnetic powder. ❾ 水酸基をもつグレードは イソシアネート基と反応し架橋します Products with hydroxyl groups react with isocyanate to form cross-links.

3 製品の種類 用途一覧 Product Types pplication list インキ グラビアインキ スクリーンインキ インクジェットインキ 顔料マスターバッチ Gravure printing ink Screen painting ink Ink jet printing ink Pigment preparation L インキ Printing ink 接着剤 dhesive 塗膜は熱可塑性でヒートシール性を有しており 塩 ビ基材を中心に接着剤として使用されます また 酸を付与したMタイプは 金属密着性を有し 金属 プライマーやPTP包装用接着剤に使用されます Strong chemical resistance, water resistance allows SOLBIN to be used in various fields of coating/painting. SOLBIN can also be added into printing media s receiving layer (including Media for Solution-type Ink Jet Ink, and Thermal Sublimation Media). It can help significantly improve the absorption of ink which leads to better color density and resolution. SOLBIN has excellent dispersibility of pigment which help enhances the color of ink. SOLBIN also offers great resolubility which is a crucial character to solve problems such as dirty print or plugging during high speed printing such as Gravure Printing. SOLBIN coating films are thermoplastic and heat-sealable. It can be wildly used as a binder in PV resin based products. The dicarboxylic acid type (SOLBIN M type) also strongly adheres to metals, aluminum, and cellophane. LL インク ジェット用 メディア Ink jet printing media 熱昇華型写真 メディア Thermal sublimation media 木工用塗料 Wood coating 缶塗料 an coating L oating & Paint 船舶用塗料 Marine paint paint その他 Mタイプ PTP包装用 接着剤 -type アルミ用接着剤 dhesive for aluminum 金属用接着剤 dhesive for metal dhesive 塩化ビニル用 接着剤 ヒートシール 接着剤 dhesive for PV Heat seal lacquer L 金属用 プライマー アルミ用 プライマー Primer for metal Primer for aluminum LL H N NL R -type タイプ タイプ -type 接着剤 タイプ タイプ -type Video, audio and data storage tape M-type ビデオテープ オーディオ ストリッパブル テープ 磁気記録塗料 バックアップ用 ペイント Magnetic card Strippable テープ Mタイプ NL M-type NL その他 N Press through package H R LL N H コーティング 塗料 R -type 顔料分散性に優れており インキとしての発色性が 良好です また 印刷時の再溶解性に優れ グラビア 印刷時の目詰まりを起こしにくい為 連続印刷に適 しております タイプ 塗膜は 耐薬品性 耐水性に優れており 幅広いコー ティング 塗料用途で使用されます また 印刷時のイ ンク定着性に優れる為 溶剤系インクジェット受容層 や熱昇華メディア受容層などにも使用されます -type oating & Paint タイプ コーティング 塗料 Printing Ink その他 Mタイプ M-type

4 製品の物性 Properties of SOLBIN 物性表 Properties table 組成 酸価 omposition 塩ビ V 酢ビ その他 Vc 水酸 重合度 K値 基価 cid Hydroxyl value value % by weight mg KOH/g mg KOH/g Degree K-value of 計算値 polymeri- calculated value zation 分子量 Molecular weight Mw Mn ( 0) ( 0) Mw/ Mn ガラス 粘度 粒子径 転移温度 Viscosity Median Glass size transition temperature Tg) mpa s μm 比重 組成 Specific gravity omposition 嵩比重 真比重 bsolute Bulk specific density gravity g/cm 特徴 Features 塩ビ V 酸価 酢ビ その他 Vc cid Hydroxyl value value % by weight g/cm 水酸 重合度 K値 基価 Degree K-value of 計算値 polymeri- calculated value zation mg KOH/g mg KOH/g 分子量 Molecular weight Mw Mn ( 0) ( 0) Mw/ Mn ガラス 粘度 粒子径 転移温度 Viscosity Median Glass size transition temperature Tg) mpa s μm 比重 Specific gravity 嵩比重 真比重 bsolute Bulk specific density gravity g/cm タイプ H * の低粘度タイプ 溶解性良好 * Less viscous than grade * Highly soluble の低粘度タイプ フィルターろ過性良好 * Less viscous than grade * Filterability good の高粘度タイプ 耐熱性 耐候性 透明度良好 * More viscous than * Highly transparent and resistant to heat and weather 高粘度 塗膜強度大 * High viscosity, forms strong coating film Nの低粘度タイプ 溶解性良好 * Less viscous than grade N, highly soluble Mタイプ M-type R 溶解性良好 * Highly soluble.9 の低粘度タイプ * Less viscous than grade 顔料 磁性粉への 分散性良好 酢エチへの溶解性良好 * Favorably disperses pigments and magnetic powders * Highly soluble in ethyl acetate 顔料 磁性粉の 分散性良好.9 顔料 磁性粉への 分散性良好 の熱安定性 改良タイプ.9 低粘度タイプ 金属やアルミ セロファンなどへの. 接着性に優れる NL * ompatible with urethane, alkyd, acrylic, malamine, and urea resins その他 -type N * Gas-tight and highly resistant to water * Highly resistant to chemicals -type LL 86 タイプ L 87 g/cm ウレタン アルキド アクリル メラミン 尿素樹脂との相溶性. 良好 耐水性 ガスバリア性 耐薬品性に優れる 特徴 Features * Favorably disperses pigments and magnetic powders * Favorably disperses pigments and magnetic powders * More thermostable than, *Low viscosity type * Strongly adheres to metals, aluminum, and cellophane 注 この表の値は代表値であり 規格値ではございません Note:The values in the table are representative values, nor standard values. 粘度 樹脂濃度0wt * 0wt 溶剤 MIBK/トルエン=/ B型粘度計にて測定 Viscosity:Resin concentration 0wt * 0wt, Solvent MIBK/toluene=/, Measured by type B viscometer 組成 その他 ビニルアルコール ヒドロキシアルキルアクリレート ジカルボン酸 omposition :,,, vinyl alcohol, Hydroxyalkyl acrylate, dicarboxylic acid 6

5 製品の物性 Properties of SOLBIN 有機溶剤に対する溶解性 L LL H N NL R Solubility in organic solvent グリコールエーテル 測定条件 固形分 0wt%( 0wt% で各溶剤に投入し 0 分撹拌後 時間静置し 0mmセルにてHaze値測定 ブチルエーテル Testing method:feed 0wt% ( 0wt%) resin into each solvents, 0 min of stirring, set for hour at.test Haze in 0mm cell 判定 Score 溶解 Soluble 数値判定 Determing criteria 単独で使用可能 Haze値 0 0 一部溶解 Partially soluble Haze値 0 単独使用可能ですが 判定の溶剤と併用することで更に透明性は良くなります Haze値 00 単独使用は困難ですが 固形分を下げる又は判定4以上の溶剤と併用で使用可能です 不溶解 アルコール Insoluble L LL Difficult to use it by itself. However, by mixing in score or solvents as well as lowering Solbin content can improve its solubility. 単独使用は困難ですが 固形分を下げる又は判定の溶剤と併用で使用可能です Methanol イソプロパノール Isopropanol n-ブタノール n-butanol cetone メチルエチルケトン Methyl ethyl ketone メチルイソブチルケトン Methyl isobutyl ketone シクロヘキサノン yclohexanone イソホロン Isophorone エーテル Tetrahydrofuran ジプロピレングリコール メチルエーテル プロピレングリコール 1モノメチルエーテル メチルエーテル H N NL R Ethylene glycol monoethyl ether 7 トルエン Toluene キシレン Xylene 直鎖状炭化水素 Linear hydrocarbon T-SOL 00 T-SOL 00 エステル Ester 酢酸メチル Methyl acetate 酢酸エチル Ethyl acetate 酢酸プロピル Propyl acetate 酢酸ブチル エチルエテルアセテート Butyl acetate Ethylene glycol monoethyl ether acetate nブチルエテルアセテート Ethylene glycol mono n-butyl ether acetate ジ エチルエーテルアセテート Diethylene glycol monoethyl ether acetate プロピレングリコール メチルエーテルアセテート Propylene glycol methyl ether acetate γーブチロラクトン γ-butyrolactone Diisodecyl phthalate Glycol ether フタル酸ジイソノニル Diisononyl phthalate 塩素化炭化水素 Ethylene glycol monomethyl ether エチルエーテル romatic フタル酸ジイソデシル グリコールエーテル Dipropylene glycol methyl ether 芳香族 Ether テトラヒドロフラン 単独使用不可 判定の溶剤を90%以上使用すれば 溶解可能です annot be used by itself. Must mix in more than 90% of score solvents in order to dissolve. Ketone アセトン Propylene glycol -monomethyl ether lcohol メタノール Diethylene glycol n-butyl ether Difficult to use it by itself. However, by mixing in score solvents as well as lowering Swell Including white turbidity Solbin content can improve its solubility. 不溶解 Insoluble ケトン ジエチレングリコール nブチルエーテル an be used by itself. However, by mixing in score solvents could improve its transparency. 膨潤 白濁も含む 膨潤 Swell onclusion Haze value 0 Haze value 00 Ethylene glycol monobutyl ether an be used by itself. Haze value 0 0 一部溶解 Mostly soluble 判断目安 Glycol ether エチレンクロライド Ethylene chloride hlorinated hydrocarbon 8

6 製品の物性 Properties of SOLBIN SOLBINの溶液粘度 Solution viscosity of SOLBIN MEKの溶液粘度 酢酸エチルの溶液粘度 Solution viscosity with methyl ethyl ketone Solution viscosity with ethyl acetate MIBKの溶液粘度 フィルターろ過速度 Solution viscosity with methyl isobutyl ketone Filter passage speed (Filter: ) 溶解条件 全体量を00wt%として. シクロヘキサノン none 0wt%に樹脂wt%を投入. 0 60分撹拌. プロピレングリコールモノメチルエーテルアセテート PM wt% -n-ブチルエー テルアセテート EB 60wt% 混合し.の溶解液に投入し 分程度撹拌する ondition of dissolution 00wt% as the total amount. Feed wt% resin into the cyclohexanone (none) 0wt%.. gitation it for 60 minutes at 0.. First, blend propylene glycol monomethyl ether acetate (PM) wt% and ethylene glycol monobutyl ether acetate (EB) 60wt%, then mix them together, stir for minutes. 0

7 製品の物性 Properties of SOLBIN 他樹脂との相溶性 ソルバインの使用方法 ompatibility with other resins 投入 FEED 測定条件 0wt%MIBK/TOL 0 分撹拌後 時間静置し 0mmセルにてHaze値測定 芳香族炭化水素系希釈剤 Testing method:0wt%mibk/tol 0 min of stirring, set for hour at, test Haze in 0mm cell 判定 溶解 Soluble 数値判定 Determing criteria 相溶性良好 Haze値 0 0 一部溶解 Mostly soluble Haze値 0 Score romatic hydrocarbon-based diluent onclusion Soluble Haze value 0 Mostly Soluble, but can be slightly cloudy after film formation ケトン系溶剤 相溶性不十分 塗膜に少し曇りあり Difficult to dessolve. May try change solution(s) and proportion Haze value 00 Swell Including white turbidity Difficult to dessolve. May try change solution(s) and proportion 不溶解 Insoluble 不溶解 Difficult to dessolve. May try change solution(s) and proportion UKIDIR EL * 短油アルキド樹脂 UKIDIR EL * メラミン樹脂 Medium to long oil alkyd resin Short oil alkyd resin ブチル化尿素樹脂 MIDIR G-8-60 * ブチル化メラミン樹脂 MIDIR G-8-60 * MIDIR TD-6 * エポキシ樹脂 ビスフェノールA型エポキシ樹脂 ビスフェノールA型エポキシ樹脂 Butylated urea resin Butylated melamine resin ブチル化ベンゾグアナミン樹脂 MIDIR TD-6 * Butylated benzoguanamine resin Epoxy resins JER 88 * JER 88 * Medium viscosity liquid bisphenol /epichlorohydrin epoxy rein JER 00 * JER 00 * Solid bisphenol /epichlorohydrin epoxy resin ウレタン樹脂 溶液型ポリウレタン樹脂 T-0E * T-0E * T-8 * L* Solution type polyurethane resin 溶液型ポリエステルウレタン樹脂 Solution type polyurethane resin 溶液型ポリエステルウレタン樹脂 Solution type polyurethane resin uring agent (TDI and polyfunctional alcohol) 硬化剤 TDIと多官能アルコール アクリル樹脂 cryl resins DEGN P * アクリル酸メチルメタクリル酸ブチルコポリマー DEGN P * ポリメタアクリラート ポリオレフィン ダイヤナールBR-87 *6 ポリメチルメタクリラート Polyacrylate resin based on methylmethacrylate ダイヤナールBR- *6 ポリメチルメタクリラート Polyacrylate resin based on methylmethacrylate Joncryl 89 *7 アクリル共重合樹脂 DEGN P * Polyacrylate resin based on n-buthylmethacrylate and methylmethacrylate DEGN P * Dianal BR-87 *6 Dianal BR- *6 Joncryl 89 *7 撹拌 GITTION 安定剤 投入 FEED 色素 Pigments 添加剤 撹拌 GITTION 可塑剤 製品 PRODUTS Plasticizer ソルバインに使われる代表的な安定剤 Representative stabilizers used in SOLBIN 区分 品 Base Organic dispersion of copolymers based on methacrylacidester and olefines arboxyl acrylic resin * DI株式会社 * 三菱ケミカル株式会社 * 東ソー株式会社 * 日立化成株式会社 DI orporation Mitsubishi hemical orporation Tosoh orporation Hitachi hemical ompany, Ltd. * Evonik Industries G *6 三菱レイヨン株式会社 *7 星光PM株式会社 Evonik Industries G MITSUBISHI RYON O., LTD. SEIKO PM ORPORTION 名 Trade name Urethane resins * NIPPOLN * oronate * dditive resins MIDIR P-8 * min.0, Hr with sufficient agitation dd other resins as needed Melamine resins MIDIR P-8 * 0 で時間 十分に撹拌 Stabilizer 中 短油アルキド樹脂 コロネート 必要に応じてその他樹脂 lkyd resins UKIDIR -EL * T-8 * L LL H N NL R hemical haracterization UKIDIR -EL * ニッポラン SOLBIN Resin 相溶性不十分 溶剤の種類変更 混合比率変更 Insoluble 特徴 アルキド樹脂 ソルバイン 相溶性不十分 溶剤の種類変更 混合比率変更 膨潤 Swell resins Ketone-based solvents 相溶性不十分 溶剤の種類変更 混合比率変更 膨潤 白濁も含む 樹脂 判断目安 Haze value 0 0 Haze値 00 一部溶解 Partially insoluble How to Use SOLBIN TVS 88* TVS 88* TVS 80* TVS 86-SP* アデカスタブ 9* アデカスタブ 6E* アデカスタブ 66* 錫系 Tin TVS 88*, TVS 88*, TVS 80*, TVS 86-SP* dekastab 9*, dekastab 6E*, dekastab 66* エポキシ系 Epoxy * 日東化成 Nitto Kasei o., Ltd. エピコート 88* エピコート 8* アデカサイザー O-OP* アデカサイザー O-8O* Epicoat #88*, Epicoat #8*, dekasizer O-OP*, dekasizer O-80* * DEK DEK ORPORTION * ジャパンエポキシレジン Japan Epoxy Resins o., Ltd.

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9 日信化学工業株式会社 Nissin hemical Industry o.,ltd. ソルバインについてのお問い合わせは For more information about SOLBIN please contact: 営業本部 東京都千代田区内神田 - -( 内神田 TKビル ) TEL.(0)9-9( 代 ) FX.(0)9-99 Sales headquarters Uchikanda TK Building, -- Uchikanda, hiyoda-ku, Tokyo TEL (main) FX 本社 工場 福井県越前市北府 -7- TEL.(0778)-00( 代 ) FX.(0778)-067 Main office and factory -7- Kitago, Echizen, Fukui Prefecture TEL (main) FX 霓信化学 ( 上海 ) 有限公司 関連会社 00 上海市長寧区虹橋路 8 号古北国際財富中心二期 楼 Grand ru 0 号室 TEL FX Nissin hemical Industry Shanghai o.,ltd. 00% owned subsidiary Grand ru Room 0, F GIFⅡ, 8 Hongqiao Road, Shanghai 00 P.R.hina TEL FX Website 注意 WRNING 安全データシート 技術資料の注意事項を守って下さい 本製品は工業用に限り ご使用下さい 当カタログのデータは 規格値ではありません ご使用に際しては 必ず貴社にて事前にテストを行い 使用目的に適合するかどうかご確認下さい なお ここでご紹介する用途はいかなる特許に対しても抵触しないことを保証するものではありません 当カタログの記載内容は 性能向上 仕様変更などのため断りなく変更することがあります 本資料を転載されるときは弊社へご連絡下さい Please follow the instructions on the Safety Data Sheet and Technical Data Sheet. These products are for industrial use only. The data presented in this catalog are representative values. lways perform on-site testing prior to implementation to make sure the product suits your needs. Please be advised that the usages described here may infringe existing patents. Due to our continuous quality improvements and specification upgrades, the information in this catalog are subject to change without notice. Please contact us before reproducing or quoting this catalog. cnissin.08.0.h.o.printed in Japan.

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