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- さなえ そや
- 9 years ago
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1 Fe(3+) ) 21) 57) ppm 18), 24) 18) (1) : ; 1) 24) (2) : ; ) ; ; ppm30 (3) : ( ) ; ; (4) : 12 (5) : (7) * : 1 * : ( ) 1 ;
2 2 ; ; 23) *: *: * 11618) : : ) 1 27) (1) A. B. C. D. E. (2) A. : 100% 18) B. C. D. E. : 1 :1mg 5 : :0.5-1mg 5 2mg(0.04mg/kg) 0.5mg :0.02mg/kg 5 1mg 0.1mg F. : ; 1) / : 14) G. : X 1624)
3 3 (3) A ) (Hb)2 3 (Met-Hb) 3 18) [ ] 24) 1) 1 1 (0.25mL) ) 1 1 (0.25mL) 25) 100% 30 / ) ) 2) ( ) 3% 10mL 20 ( 1520 ) 10mL ) mLkg10mL ( 1520 ) 24) ) : B. (HBO) HBO HBO 10 * 12 (1) ( ) 15 (2) * 1
4 4 (1) (2) A. : (1) : (2) : 7) B. : ( ) [ ]Sulfurated hydrogen Hydrosulfuric acid Hydrogen sulfuric acid Sulfur hydride Stink DAMP 519) CAS No ) : 99.9% 417) ) 5) [ ]H2S [ ]34.08 [ ]1.188( =1)(251 )20)
5 5 [ ]0.96 [ ]1.384(nD) []-85.5 []-60.4 [ ] [ ]20mmHg(25.5) [ ]260 [ ]100.5 [ ]8.9 [ ]4.346% [ ](1g/242mL 20) (1g/94.3mL,20) 45) [ ] 20) ( ) (DMSO ) ( ), ( ) ( ) 4517) : 2 ( ) :2 ;17 ; 1 ( ) 3 (2 )417) 18 2 MSDS 36) 18) 500ppm ppm 1,, 24) :0.0047ppm :0.05ppm [ ], 24) 0.05ppm :
![3mL,20) 45) [ ] 20) ( ) (DMSO ) ( ), ( ) ( ) 4517) : 2 ( ) :2 ;17 ; 1 ( )](/docs-images/42/22973676/images/page_5.jpg "3 (2 )417) 18 2 MSDS 36) 18) 500ppm 3060 8001000ppm 1,, 24) :0.0047ppm :0.")
6 0.1 ppm : 50150ppm 250ppm ppm >500ppm : : : : ppm: 6%24) ppm 24) 24) 10ppm67 26) 250ppm 3 26) 24) 4100ppm 50500ppm 250ppm ppm 600ppm ppm 1000ppm 12 [ ] 500ppm ) ppm 24) % 24) ;LCLo:800ppm5 19) ;LCLo:600ppm ) ;LCLo:5700g/kg 1619) / mg/L 24) 6100ppm 24) 0.92mg/L 1.06mg/kg 0.38mg/kg 0.34mg/kg ppm 24) 0.45g/mL g/ml (0.014mmol/mL) (0.143mmol/mL) 2.72g/mL 5.04g/mL 6
7 7 (0.085mmol/mL) (0.045mmol/mL) 0.42g/mL 9.30g/mL (0.013mmol/mL) (0.083mmol/mL) 0.16g/mL (0.005mmol/mL) [ ( )] ;LC50:444ppm 19) ;LC50:634ppm1 19) ;LC:1.12mg/L(800ppm)1030 5) ;LC:1.5mg/L(1000ppm)15 5) ;LC:1.5mg/L(1000ppm)2 5) ;LC:1.4mg/L(900ppm) 5 5) ;LC:0.7mg/L(500ppm) 1 5) ;LC100:60ppm1 5) ;LC100:100ppm1 5) [ ] : : : [ ] ACGIH:TLV-TWA ;10ppm 4520) ACGIH: TLV-STEEL;15ppm 520) IDLH( ):300ppm Fe(3+) ) ( )1622) 21) 57)
8 8 2122) (H2S)HS(-)S(2-) ; 6100ppm 0.92mg/L1.06mg/L0.38mg/L0.34mg/L ppm 24) 0.45g/mL g/ml (0.014mmol/mL) (0.143mmol/mL) 2.72g/mL 5.04g/mL (0.085mmol/mL) (0.045mmol/mL) 0.42g/mL 9.30g/mL (0.013mmol/mL) (0.083mmol/mL) 0.16g/mL (0.005mmol/mL) 0.05mg/L 24) (1 LD 85% ) 521) 24) 1821) ppm 18), 24) 18) (1) : ; 1) 24) ;50400ppm
9 (2) : ; 1, 16, 18) ; ppm 24) ppm30 ; ppm48 600ppm30 18)250ppm ppm 24) 416% ) 24) 63 24) (3) : () 24) ; ; 50150ppm 250ppm 3 26) 500ppm30 24) >500ppm: ) ppm 24) ppm ( ) ; 20 CT mg/L 0.05mg/L 20 24) ( ) ( ) 222) (CT )13) 24) (4) : 12 ( ) 9
10 (5) : (7) * : 1 * : ( ) 1 1 ; ; ; 23) * : ; ppm67 26) 5060ppm 24) ppm; colored halos( gas eyes ) ( gas eyes ) 1, 5, 16, 18, 24) 1 *: ) 100ppm ) *: 24) * : ) * : 2000Hz 27) 3 27) 10 HSDB32) positive pressure self-contained breathing apparatus:scba 34)
11 11 HSDB)32) ) X 24) 24) (HBO)24) * 11618) : : ) 68 27) 1 27) (1) A. B. C. D. E. (2) A. : 100% 18) B. C. : 1 (1 ) (2 ) 1) 200mg 400mg mL 5% g/mL : 25g/kg/ 510g/kg/ : 2) 4mL(4mg)5% 1000mL 4g/mL : ;23mL(812g)/
12 12 ;0.10.2g/kg/ :0.51mL(24g)/ D. : 2472 ( ) : : ( ) : : 18) E. : 1 :1mg 5 : :0.51mg 5 2mg(0.04mg/kg) 0.5mg :0.02mg/kg 5 1mg 0.1mg F. : ; 1) 14) : G. : X, 24) 24) 24) 2 24) (3) A ) [ ] (Hb)2 3 (Met-Hb) 3
13 ) 18) [ ] CN(-) HS(-) ) 18) 1 24) 2 24) [ ] 24) 24) (1) 1 1 (0.25mL) ) 1 1 (0.25mL) 25) 100% 30 / ) ) 25) (2) ( ) 3% 20mL 0.6g 30) 3 10mL 20 ( 1520 ) 3 10mL 50100mL 24 29) 10mL )
14 mLkg10mL 20 ( 1520 ) 24) ( ) 2429) (g/dl) 3% 8g 0.22mL/kg 10g 0.27mL/kg 12g( ) 0.33mL/kg 14g 0.39mL/kg 129) : ( ) (Smith 1950) Na2S2O3 + CN(-) SCN(-) + Na2SO3 ( ) 8) [ ] ) 40% 9 12mg/kg(1%) 5mg/kg 3) : 80mmHg 7) ( ) 1) B. (HBO) HBO HBO 10) HBO : 2 100% HBO 1 : :75 2 :
![39mL/kg 129) : ( ) (Smith 1950) Na2S2O3 + CN(-) SCN(-) + Na2SO3 ( ) 8) [ ]](/docs-images/42/22973676/images/page_14.jpg "2025 26 200325) 40% 9 12mg/kg(1%) 5mg/kg 3) : 80mmHg 7) ( ) 1) B.")
15 15 (3 / 1 / 6 12 )10) HBO : - 10) 1012) 12) 10) * 12 (1) ( ) 15 (2) A. : B. : * 1 (1) (2) A. : (1) : 42C 4042C 1530 ( ) 1 2 (2) : 7) B. : * 5 5)
16 16 1) 3 30,48, (A) 48 (B) (C)30 46 B (-) Respirator 100 (C) (+) (-)Anisocolie(+) (+) Respirator 21% 60ppm24ppm 30ppm 0 800ppm A, B, C, 28) 2) ) 3) 1 44 (A)50 (B)58 (C) B AC C A CB A C DOA B %,,,5 12 X,CT ) 4)
17 % 2, %( 0.5% ) 1 5) ) ) ( )20) : 21,24) GC/MS 24) 1) (HSDB)32) m(330660feet) ( ) 60m(200feet) 0.2km (0.1miles) 0.5km(0.3miles) 125m(400feet) 0.3km (0.2miles) 1.4km(0.9miles) (HAZARDTEXT)33) 30m(100feet) 0.2km(0.1miles) 0.3km(0.2miles) 215m(700feet) 1.4km(0.9miles) 4.3km(2.7miles) 200L 200L 11km(7miles)
18 18 30 (HSDB)32) 1600m(1miles) 1600m(1miles) 2) (HSDB)32) 1) 2) 3) 4) (HSDB)32) 3) 34)
19 19 1.POISOINDEX ;53rd Edition 2.Clinical Toxicology of Commercial Products;5th Edition, ;< > ;, ;, ;, ;, FM Audeau etal;industrrial MEDICINE,Hydrogen sulphide poisoning; associated with pelt processing. New Zealand Med J 1985;13; Roger P.Smith;Hydrogen Sulfide Poisoning.Journal of Occup Med 1979;21; (DREISBACH;handbook of POISONING);, 1984 ", " 10.Martin J. Smilkstein et al;hyperbaric oxygen therapy for severe hydrogensulfide poisoning. The Journal of Emergency Medicine 1985;3; Jerry B.Vannatta;Hydrogen Sulfide poisoning. Report of Four Cases and Brief Review of the Literature. OSMA JOURNAL 1982; 75; Daniel D.Whitcraft;Hydrogen sulfide poisoning treated with hyperbaric oxygen. The Jounal of Emergency Medicine 1985;3; Fumisuke Matsuo;Neurological Sequelae of Massive Hydrogen Sulfide Inhalation. Arch Neurol 1979;36; Adriano G Ravizza.et al;the TREATMENT OF HYDROGEN SULFIDE INTOXI- CATION;OXYGEN VERSUS NITRITES. SCIENTIFIC REPORTS POISINDEX:HYDROGEN SULFIDE,VOL.96, ,, :,, NIOSH:Registry Toxic Effects of Chemical Substance,VOL.36, :,, Matthew J.E.& Donald G.B.:Medical Toxicology,2nd edition, Elsevier, Goldfrank,L.R. et al:toxicologic Emergencies,5th edition, Appleton-Century-Crofts, : ,40(3), , Rumack BH & Spoerke DG(eds): HYDROGEN SULFIDE,POISINDEX(R) Information System.MICROMEDEX,Inc., Colorado, VOL.115, pp pp pp
20 (1) Rumack BH & Spoerke DG(eds): CYANIDE POISINDEX(R) Information System.MICROMEDEX,Inc., Colorado, VOL.115, (10): Goldfrank,L.R. et al:toxicologic Emergencies,6th edition, Appleton-Century-Crofts, Hazardous Substance Data Bank:HYDROGEN SULFIDE,VOL.55, HAZARDTEXT(R):Hazard management:hydrogen SULFIDE,VOL.55, ,.,,1996,pp ,,:DOA ;8(4),pp ,,2002.pp ID O
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1 982 2207 CAS 67630 2- H 3 C H 3 C CH OH C 3 H 8 O 60.10 1 99.9 % n- 1. 2-88.5 3 82.5 3 11.7c.c. 455 4 212 d 20 4 0.78505 3 2.1 = 1 4 4.4 kpa 33 mmhg20 4 log Pow0.05 0.07 5 m/z45, 1.0 43 0.19 27 0.17
,977 t 157,977 t mg l mg l BOD 9398 % OH = cm 3 / sec 11 = cm 3 / sec OH = /
1 9625 2219 CAS 75569 1, 2-1, 2- H 2 C CH CH 3 C 3 H 6 O 58.08 1 99 % 1. 2 2, 3-112.13 2, 3 34.23-37 449 2.8-37 % 2 d 0 4 0.859 4 d 20 0.8304 2 2, 4 2.00 = 1 53.33 kpa 400 mmhg18 59.33 kpa 445 mmhg20 5
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1 20019 1527 CAS 1317368 1230 PbO 223.20 1 99 1. 2 888 2 9.53 0.017 g/l 20 3 3 2 2. 10 29,309 t 22,069 t 7,240 t 4 1 3. 1 2 3.5 6 1 µg/l 9.1-24 2 µg/l < 43 6 27,431-70,000 4.5-1,300 13.4-17 31.7 0.48-3,459
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3, 3-1 200019 4800 CAS 91941 1138 3, 3-4, 4 - -3, 3 - H 2 N Cl Cl NH 2 C 12 H 10 C l2 N 2 253.13 1 95 1. 2 3, 4 132-133 402 5 >200 5 700kg/m 3 5 8.73 = 1 5.610-8 kpa 4.210-7 mmhg20 4 6 log Pow3.51 3.57
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N,N- N,N-Dimethylacetamide Acethyldimethylamine CAS 127-19-5 C 4 H 9 NO 87.12 ~ 87.14 87.68413 163-165 C 1) - 18.59 C 2) 1 mg/l 25 C 3) 3.3 hpa 2 C 4) log P ow -.77 2).9429 2/4 C 1) 3.1 4) 1.31E - 8 atm-m
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3--2-3-Iodo-2-propynyl butylcarbamate (IPBC) Carbamic acid, butyl-, 3-iodo-2-propynyl ester Iodocarb CAS 55406-53-6 C 8 H 12 NO 2 I C (g/cm 3 ) (mmhg) log P ow 281.09 (280.9910) 64 68 1.51 1.57 (20 C)
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