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14 1 P. W. Anderson, Science , A. Kobayashi et al., J. Mater. Chem H. Fukuyama, J. Phys. Soc. Jpn

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21 eg t2g x 2 y 2 3z 2 r 2 yz zx xy

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25 1 S. Kimura et al., Chem. Commun., (2004); S. Kimura et al., J. Am. Chem. Soc., 128, (2006); H. Mori, J. Phys. Soc. Jpn., 75, (2006). 2 F. Sawano, et. al., Nature (2005).

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43 1, com/products/pdf/japanese.pdf 2 Hashizume, M.; Kunitake, T.: Preparation of selfsupporting ultrathin films of titania by spin coating, Langmuir, 19, Fujikawa S.; Muto E.; Kunitake T. : Manuscripts in preparation 4 Li, Y.; Kunitake, T.: Fabrication of large, free-standing nanofilms of platinum and platinum-palladium alloy, Manuscripts submitted 5 Vendamme, R., Onoue, S., Nakao, A. and Kunitake, T. Robust free-standing nanomenbranes of organic/inorganic interpenetration networks, Nature Materials, Vol. 5,

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59 B. C. Stipe, M. A. Razaei and W. Ho, Science W. Ho, J. Chem. Phys M. Kawai et al., Phil. Trans. Roy. Soc. Lond. A 362, Y. Sainoo, Y. Kim, T. Okawa, T. Komeda, H. Shigekawa, and M. Kawai, Phys. Rev. Lett. 95, M. Ohara, Y. Kim, S. Yanagisawa, Y. Morikawa and M. Kawai, to be submitted. Y. Kim, T. Komeda and M. Kawai, Phys. Rev. Lett. 89, T. Komeda, Y. Kim, M. Kawai, B.N.J. Persson, and H. Ueba, Science 295, Molecule Substrate Vibrational modes reported ethynyl C2H C2D Cu 100 a CH stretch acetylene C2H2 C2D2 C2HD Cu 100 b Ni 100 c Ni 110 d CH stretch propyne CH3CCH CH3CCD Ni 110 e CH stretch trans 2 butene CH3CHCHCH3 Pd 110 f CH stretch cis 2 butene CH3CHCHCH3 Pd 110 g CH stretch Pd C stretch 1 3 butadiene CH2CHCHCH2 Pd 110 h ND 1-butene CH2CHCH2CH3 Pd 110 i CH stretch butyne Pd 110 j CH stretch benzene C6H6 C6D6 Cu 100 k ND fullerene C60 Ag 110 l Hg w2 pyridine C2H5N, C2D5N Cu 100 m Ag 110 n pyrrolidine C4H8NH Cu 100 o Ag 100 p CH and NH stretch ring deform. CH2 bend N methylpyrrolidine C4H8NCH3 Cu 100 q tetrahydorothiophene C4H8S Cu 100 r Cu 2 etioporphyrin 1 Cu 100 s formate HCOO Ni 110 t CH stretch carbone monoxide CO Cu 110 u Cu 100 v CO strech hindered rotation hindered translation oxygen O2 Ag 110 w O O stretch O Ag asym. Stretch a ; Lauhon, L. J., Ho, W, Phys. Rev. Lett. 84, b ; Stipe, B. C., Rezaei, M. A., Ho, W. Science Stipe, B. C.; Rezaei, M. A., Ho, W., Phys. Rev. Lett c ; Stipe, B. C., Rezaei, M. A., Ho, W., Phys. Rev. Lett d ; Gaudioso, J., Lee, H. J., Ho, W., J. of Ame. Chem. Soc e ; Ho, W., J. of Chem. Phys f ; Kim, Y., Komeda, T., Kawai, M., Phys. Rev. Lett g ; Sainoo, Y., Kim, Y., Okawa, T., Komeda, T., Shigekawa, H., Kawai, M., Phys. Rev. Lett h ; Kim, Y. Komeda, T., Kawai, M., Phys. Rev. Lett i, j ; Komeda, T., Kim, Y., Kawai, M. unpublished data. k ; Lauhon, L. J., Ho, W., J. Phys. Chem. A Pascual, J. I., Jackiw, J. J., Song, Z., Weiss, P. S., Conrad, H., Rust, H.-P., Phys. Rev. Lett l ; Pascual, J. I., Gomez-Herrero, J., Sanchez-Portal, D., Rust, H.-P., J. Chem. Phys m; Lauhon, L. J., Ho, W., J. of Phys. Chem. A n ; Ho, W., J.Chem. Phys o ; Gaudioso, J., Lauhon, L. J., Ho, W., Phys. Rev. Lett p ; Gaudioso, J., Ho, W., J. Amer. Chem. Soc q ; Gaudioso, J., Ho, W., Ang. Chem. Intern. Ed. Eng r ; Gaudioso, J., Ho, W., J. Amer. Chem. Soc s ; Wallis, T. M., Chen, X., Ho, W., J. Chem. Phys t ; Katano, S., Kim, Y., Kawai, M., to be submitted u ; Lauhon, L. J.; Ho, W. Phys. Rev. B R8525, Heinrich, A. J., Lutz, C. P., Gupta, J. A., Eigler, D. M., Science v ; Lauhon, L. J.; Ho, W. Phys. Rev. B R8525. w ; Hahn, J. R., Lee, H. J., Ho, W., Phys. Rev. Lett

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68 1 M. Kawasaki et.al., Science, 266, 1540 (1994) A. Tsukazaki et. al., Nature Materials, 4, 42 (2005). 4 Y. Matsumoto et. al., Science, 291, 854 (2001) 5 H. Tyosaki et. al., Nature Materials, 3, 221 (2004). 6, 59, 559 (2006).

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4) H. Takayama et al.: J. Med. Chem., 45, 1949 (2002). 5) H. Takayama et al.: J. Am. Chem. Soc., 112, 8635 (2000). 6) H. Takayama et al.: Tetrahedron Lett., 42, 2995 (2001). 9) M. Kitajima et al: Chem.

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