Hideki MATSUOKA: An Introduction to Small-angle Scattering Fundamental aspects of small-angle scattering technique are duly explained from the very ba

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Transcription:

Hideki MATSUOKA: An Introduction to Small-angle Scattering Fundamental aspects of small-angle scattering technique are duly explained from the very basic points for the beginners and newcommers of this useful technique to study the strucuture of g Vernachlasisgten Dimensionen h.

(Dimension studied by scattering techniques.) from small, large and anisotropic particles.)

(Three scattering regions and information obtained.) small-angle scattering from isolated particle.)

(Calculation of scattering from core-shell sphere.) small-angle scattering from multi-particle system.)

(Radius of gyration (Rg) of particles.)

(Maximum position for scattering from sphere with radius R.) from polydisperse sphere.)

(Schematic representation of internal and external contrast variation techniques.)

1) O. Kratly, O. Glatter, ed.: gsmall-angle X-ray Scattering h, Academic (1982). 3) A. Guinier and G. Fournet: gsmall-angle Scattering of X-rays h, Wiely (1955). 4) A. Guinier: gx-ray Diffraction in Crystals, Imperfect Crystals, and Amorphous Bodies h, Freeman 1963, Dover Edition (1994). 5) H. Brumberger ed.: gsmall-angle X-ray Scattering h, Gordon & Breach (1967). 6) P. Lindner and Th. Zemb: gneutron, X-ray and Light Scattering: An Introduction to an investigative tool for colloidal and polymeric systems. hnorth Holland (1991). 7) J. S. Higgins and H. G. Benoit: gpolymers and Neutron Scattering h, Oxford (1994). 13) J. B. Hayter, J. Penfold: Coll. Polym. Sci. 26 1022 (1983). 14) I. Fankuchen et al.: Ind. Eng. Chem. 37 158 (1945). 15) T. Hashimoto, M. Fujimura, and H. Kawai: Macromolecules 13 1660 (1980). 16) P. Mittelbach: Acta Physica Austriaca 19 53 (1964). 18) P. W. Schmidt: gthe fractal approach to Heterogeneous Chemistry, Surface, Colloids, Polymers h, Ed. D. Avnir, Chap. 2, Weily (1989). 19) D. W. Schaefer and K. D. Keefer et al.: in gscience of Ceramic Chemical Processing h, LL. Hench, D. R. Ulrich eds., Weily, (1986). 21) K. Nakanishi et al.: J. Amer. Ceram. Soc. 75 971 (1992). 22) P. Debye: Phys. Z. 28 135 (1927), ibid 31 348 (1930). 23) G. Fournet: Handbuch der Physik XXXII Springer (1957). 25) F. Zernike and J. A. Prins: Z. Physik 41 184 (1927). 26) P. Debye and H. Menke: Phys. Z. 31 297 (1930). 27) J. P. Hansen and J. B. Hayter: Mol. Phys. 46 651 (1982). 28) R. Hosemann and S. N. Baguchi: gdirect Analysis of Diffraction by Matter h, North Holland (1966).

29) H. Matsuoka et al.: PhYs. Rev. B. 41 3854 (1990). 30) P. Debye and A. M. Bueche: J. Appl. Ctvst. 20 518 (1949). 31) L. S. Ornstein and F. Zernike: Physik. Z. 19 134 (1918). 32) L. S. Ornstein and F. Zernike: Physik. Z. 27 761 (1926). 34) G. Porod: Kollid-Z. 124 83 (1951). 35) T. Hashimoto et al.: Macromolecules 13 1660 (1980). 36) M. Nakano, H. Matsuoka, H. Yamaoka, A. Poppe, and D. Richter: Macromolecules 32 697 (1999). 37) M. Nierlich et al.: J. Physique 46 649 (1985). 38) K. Sumaru, H. Matsuoka, H. Yamaoka, and G. D. Wignall: Phys. Rev. E 57 1744 (1996). Department of Polymer Chemistry, Kyoto University, Kyoto 606-8501, Japan TEL. 075-753-5611 FAX. 075-753-5609