Structure and Strength of Acid-Base in Aqueous Medium Aritsune KAJI* and Masaru NAKAHARA* * Department of Chemistry, Faculty of Science, Kyoto Univers

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1 Structure and Strength of Acid-Base in Aqueous Medium Aritsune KAJI* and Masaru NAKAHARA* * Department of Chemistry, Faculty of Science, Kyoto University

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11 1) J. Hayami, N. Ono, A. Kaji, Tetrahedron Lett ) N. Ono, Bull. Chem. Soc. Japan (1971) 4) W.T. Miller Jr., J.H. Fried, H. Goldwhite, J. Amer. Chem. Soc (1960) 5) E.J. King, "Acid-Base Equilibria" p. 8, Pergamon Prees (1965) 8) A.H. Narten, H.A. Levy, Ref. (6), Chap. 8 9) D. Eisenberg, W. Kauzmann, "The Structure and Properties of Water" Oxford (1969) 10) "Water", Vols. 1-3, ed. F. Franks, Plenum (1972, 1973) 11) E. Wicke, M. Eigen, Th. Ackermann, Z. Phys. Chem., N.F (1954) 12) H.L. Friedman, C.V. Krishnan, Ref. (10), Vol. 3, p ) R. Zana, E. Yeager, J. Phys. Chem (1966) ; , 4241 (1967) 14) L.G. Hepler, Ref. (10), Vol. 3, p ) S.D. Hamann, J. Phys. Chem (1963) 16) D.L. Martin, F.J.C. Rossotti, Proc. Chem. Soc ) D.L. Martin, F.J.C. Rossotti, ibid ) R.D. Corsaro, G. Atokinson, J. Chem. Phys (1971) 19) R.A. Robinson, R.H. Stokes, "Electrolyte Solutions" 2 nd Ed., Appendix, Butterworths (1959) 20) I.M. Koithoff, A. Willman, J. Amer. Chem. Soc (1934) 21) H.S. Gutowsky, A. Saika, J. Chem. Phys (1953) 22) O. Redlich, J. Bigeleisen, J. Amer. Chem. Soc (1943) 23) H.S. Harned, B.B. Owen, "The Physical Chemistry of Electrolytic Solutions" Appendix, Reinhold (1958) (1963) : A. Albertm, E.P. Serjeant, "Ionization Constatants of Acids and Bases, A Laboratory Manual" Methuen (1962) Equilibria in Analytical Chemistry" John Wiley & Sons (1963) 26) J.B. Hendrickson, D. J. Cram, G.S. Hammond, "Organic Chemistry" 3 rd Ed., p. 304, Ktigakusha (McGraw-Hill) (1970) 27) D.D. Perrin, "Dissociation Constants of Organic Bases in Aqueous Solution" Butterworths (1965, 1972) 28) Ref. (5), Chap. 9 29) Ref. (19), Chap ) M. Nakahara, Rev. Phys. Chem. Japan (1974) 31) Ref. (23), Chap ) Ref. (5), Chap. 8 33) Ref. (5), Chaps ) Ref. (5), Chap. 7 35) T.L. Hill, "Introduction to Statististical Thermodynamics" Chaps , Addison-Wesley (1960) 36) D.H. Aue, H.M. Webb, M.T. Bowers, J. Amer. Chem. Soc (1972) 37) L.P. Hammett, "Physical Organic Chemistry" 2 nd Ed., Chap. 11, McGraw-Hill (1970) 38) J.E. Leffler, E. Grunwald, "Rates and Equilibria of Organic Reactions" Chaps. 6,-8, John Wiley & Sons (1963) 39) "Advances in Linear Free Energy Relationships", eds. N.B. Chapman, J. Shorter, Plenum (1972) 41) H.H. Jaffe, Chem. Rev (1953)

12 42) D.H. McDaniel, H.C. Brown, J. Org. Chem (1958) 43) P.R. Wells, Chem. Rev (1963) Pauling, "The Nature of the Chemical Bond" 3rd Ed., Cornell University Press (1960) 45) D.A. Maclnnes, J. Amer. Chem. Soc (1928) 46) J.P. Greenstein, ibid (1936) 47) H.K. Hall, Jr., ibid (1957) 48) W.M.A. Henderson, Jr., C.A. Streuli, ibid (1960) 49) J.P. Briggs, R. Yamdagni, P. Kebarle, ibid (1972) 50) W.J. Hehre, J.A. Pople, Tetrahedron Lett ) Ref. (40), Chap. 9 52) G.S. Hammond, "Steric Effect in Organic Chemistry" ed. M.S. Newman, Chap. 9, Chapman & Hall (1956) 53) A. Ishizawa, Bull. Chem. Soc. Japan (1975)

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