The faint young Sun paradox Early Mars ( Ga) on Mars wet and warm climate? Valley networks(carr, 1996) The warm climate cannot be sustained (Ka

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Warming of early Mars induced by CO 2 ice clouds Kobe University, the 21st century COE program Microsymposium, Climate and Meteorology on Mars Friday, June 17, 2005 Chihiro Mitsuda (Hokkaido Univ.) Tokuta Yokohata (NIES) Kiyoshi Kuramoto (Hokkaido Univ.)

The faint young Sun paradox Early Mars ( -- 3.8 Ga) on Mars wet and warm climate? Valley networks(carr, 1996) The warm climate cannot be sustained (Kasting, 1991) CO2-H2O atmosphere Solar Luminosity 75 % as present neglect radiation processes of cloud 50 km

Scattering greenhouse effect of CO2 ice cloud cloud reflects IR rafiarion > Solar radiation

Scattering greenhouse effect Previus studies have shown of CO2 ice cloud The strength of greenhouse effect depends on cloud parameters such as particle size and optical depth(e.g. Pierrehumbert and Erlick 1998) Climate can become warm when cloud has optimal parameters(e.g. Mischna et al, 2000) Mechanisms determining these values have not been examined.

mechanisms of cloud parameters change Cloud particle size and optical depth are changed by... particle coalescence by collision particle evaporation as getting out of the cloud particle growth by radiative cooling or evaporation by radiative heating in cloud layer

mechanisms of cloud condition change Cloud particle size and optical depth are changed by... particle combination with collision particle evaporation as getting out of the cloud particle growth by radiative cooling or evaporation by radiative heating in cloud layer This study: Estimation the greenhouse effect of stable CO2 ice cloud

1-D radiation model Solar luminosity: 0.75 times of today (Gouth, 1981) Two-stream approximation (cloud layer: δ-eddington approximation) CO2-H2O Cloud particle: * Mie theory Complex indices of CO2 ice (Warren,1986) Gas ( for IR radiation only): * Line-by-line method absorption line parameters (HITRAN2000) * At cloud layer, Ramdom model band parameter (Houghton, 2002) Albedo: 0.216 (Kieffer et al. 1977) atmosphere

Vertical temperature profile Altitude CO2 Saturate Radiative eq. (thin gray atmosphere) CO2 Moist convective CO2 Dry convective (H 2 O Moist convective) Temperature

1-D radiation model Solar luminosity: 75 % current value (Gouth, 1981) Two-stream approximation (cloud layer: δ-eddington approximation) Cloud particle: * Mie theory Comples indices of CO2 ice (Warren,1986) latent heat of CO2 condensation = net cooling energy in cloud layer regolith Albedo: 0.216 (Kieffer et al. 1977) CO2-H2O atmosphere Gas ( for IR radiation only): * Line-by-line method absorption line parameters (HITRAN2000 * At cloud layer, Ramdom model band parameter (Houghton, 2002)

Latent heat of CO 2 condensation atmospheric pressure: 1 bar ; condensation nucleus: 10 10 m -2 Inverse correlation between particle size and latent heat is important CE equilibrium evaporate By a negative feedback, the particle size change to the CE-equilibrium value if CO2 condensate and evaporate quickly. condense

Estimation of temperature atmospheric pressure: 1 bar ; condensation nucleus: 10 10 m -2 time scale CE equilibrium(hour) << R equilibrium(week) CE equilibrium C Surface temperature change to point C, in which these two equilibriums are archived. A B Radiative equilibrium

Estimation of surface temperature

Estimation of surface temperature NO solution (Particle size is too small)

Estimation of surface temperature Dust (present Mars) ( )

Conclusion We construct simple 1-D radiation model and estimate surface temperature when atmospheric pressure and number of condensation nuclues are fixed. the atmospheric pressure more than about 1 bar is necessary condition of the warm and wet climate on Early Mars. By the negative feedback of changes of the particle size and latent heat of condensation, the clouds may stabilize warm climate on early Mars.

References Gough, D. O.,1981: Solar interior structure and luminosity variations, Sol. Phys., 74, pp.21 34 HITRAN2000, http://www.hitran.com Houghton, J., 2002: The Physics of Atmospheres third edition, Cambridge Univ. Press.,pp320 NASA/JPL Planetary Photojournal, http://photojournal.jpl.nasa.gov/ Kasting, J. F., 1991: CO2 condensation and the climate of early mars, Icarus, 94, pp. 1-13 Pierrehumbert, R. T. and Erlick, C., 1998: On the scattering greenhouse effect of CO2 ice cloud, J. Atmos. Sci., 55, pp.1987-1903 Pollack J. B., Colbirn, D. S., Flasar, F. M., Kahn, R., Carlston, C. E. and Podek, D., 1979: Properties and effect of dust particles suspended in the Marian atmosphere, J. Geophys. Res., 84, B6, pp2929-2945 Mischna, M. A., Kasting, J. F., and Freedman, R., 2000: Influence of carbon dioxide clouds on early Matrian climate, Icarus, 145, pp.546 554 Yokohata, T., Kosugita, K., Matatsugu, O.,and Kuramoto, K., 2002: Radiative absorption by Co2 ice cloud on early mars: Implication on the stability and greenhouse effect of clouds, Proceedings of 35th ISAS Lunar and Planetary Science Conference, pp.13--16 Warren, S. G. 1986: Optical constrants of carbon dioxide ice, Appl. Opt., 95, pp.2650-2674

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2.7 78.1 1.0 1.8-20.9 - - 1.6 0.9 0.01 0.02 95.3 0.035 99.0 98.1 CO2 6x10^-3 10^-4 80 90