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- まいか みやくぼ
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1
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5 16
6
7 GWP GWP NEDO
8 GWP
9 GWP
10
11 ( ) ( ) 0111 NEDO
12 1-2
13 1-3
14 1-4
15 1-5
16 1-6
17 1-7
18
19
20 10 - i -
21 ii -
22 CFC HCFC 2020 HFC COP3 HFC GWP GWP GWP GWP 1.2 CFC
23 1995 CFC HCFC HFC CFC 2000 CFC HCFC HFC /- HCFC HCFCHFC HCFC HFC 2020 HCFC HFC HFC 2-2
24 **1990 HCFC-22 CHClF
25 CFC CFC 1974 UNEP 1987 CFC CFC 1995 HCFC 2020 HCFC HCFC HCFC HCFC HCFC-141b HCFC-142b 2010 HCFC
26 (%) HCFC CFCHCFC HFC 1988 UNEP WMO IPCC COP3 2-5
27 HCFC HFC COP5 HFC 2010 HFC 2.2 CFC CFC CFC CFC HCFC 2020 CFC HCFC HFC CFC 2-6
28 HFC HFC CFC-114 HFC CFC-114 OH GWP ( ) TEWILCA OH GWP
29 ODP
30 50 CFC HFC-134a 3-1 (COP)H * * (THEDYNA) Te=30Tc=80 (40) 50 HFC-245fa HFC-365mfc (60) mn/m (J/g) HFC-43-10mee 14.1(25) 130(25) 30mN/m 18.0(45) 44.6(30) 1,1, CFC
31 (p.11) OH GWP 2-10
32
33 p
34
35 2-14
36 (p.16) (NEDO) (RITE) RITE JEMA 2-15
37
38 CFC HCFC HFC, CO CFCHCFCHFC
39 OH GWP GWP 1997 GWP 100 GWPITH= PFC 50, , CVD ASHRAE/ISO 2-18
40 HFE-245mc HFE-143m HFE-245mc 8, COP HFE-245mc COP HFE-245mc kg 10ton100ton HFE-245mc CFC-114 ODP 5 CFC-114 HFC HFC-134a HFE-143m HFC-134a HFC-134a HFC-134a HCFC 2-19
41 CFC-113 HCFCHFC HFE-347pc-f HFC ODP 6 300kg 5,000 /kg HFE-347pc-f HFE-55-10mec-fc HFE HCFC 6.3 HFC-245fa HFC-365mfc HFE-254pc 2-20
42 HFE-254pc
43 CFCHCFC COP3 CFCHCFC HFC CFCHCFC 7.2 CFCHCFC 2-22
44 CFCHCFC GWP 7.5 NEDO RITE RITE 2-23
45 7.6 GWP CFCHCFC
46 2. 3. GWP OH GWP OH GWP
47 2-26
48 p p p , HCFC
49 CFC MeOPr MeOEt MeOMe HFC CFC,HCFC HFC EtOEt MeOC4 MeOC5 225cb 225ca b b a 115 C5F10O C4F9OCF3 C4F8O C2F5OC2F5 CF3OCF2CF2CF3 CF3OCF2OCF3 CF3OCF2CF3 CF3COCF3 C3F6O 407C 22 CF3OCF3 410A CH3OCF2CF3 CH3OCF3 C4F9OCH3 (HFE-7100)
50 8-3 HFE HFC 8-3 ( ) HFE-245mc HFE-143m HFE-254pc HFE-236pc HFE-347pc-f HFE-55-10mec-fc CFC-114 ( ) 63.8 CFC-12HFC-134a HCFC-141bHFC-245fa mw/(mk) HCFC-225 HFC-43-10mee ( ) mnm ,14.2 ZEORORA-H mnm
51 GWP OH OH 8-4p.31 HFE-125 HFE-134p HFC-32 OH OH GWP GWP 2-30
52 8-4 IPCC 3rd Ed.(2001) 2-31
53 (1) HFE-245mc 8,000 HFE-245mc HFE-143m HFC-134a (2) HFE HFE-254pc (3) HFE-347pc-f HFE55-10mec-fc (4) 2-32
54 CFCHCFC (1) CFC HCFC (p.33) CFC-12 HFC-134a CFC-11 HCFC-123 HCFC 2020 HCFC-22 HCFC-22 R-407CR-410A R-502 R-404AR-507A CFC-11 HCFC-123 HFC-134a CFC-114 CO 2001 CO
55 CO2 ( ) CO2 2-34
56 (2) CFC HCFC-141b HCFC HFC HFC-245fa HFC-236ea HFC-245fa HFC-365mfc HCFC-141b HFC
57 (3) 1,1,1- CFC-113 HCFC-225HCFC-141b HCFC HFC-43-10meeCyclic HFC HFE F F F F F F H F H H 2-36
58 WWW (PVT) (VLE) NMR IR HFEHFKHFC World Wide Web 63 (WWW) SP PVT 192 VLE
59
60 3. (1) Neural Network SP Neural Network Monte Carlo 3 Neural Network (8-6) x 1 y x 1 2 x 3 y 2 y j x i z Neural Network 2-39
61 4.THEDYNA THEDYNA( ) THEDYNA THEDYNA THEDYNA THEDYNA MS-DOS (XY ) SI THEDYNA THEDYNA MS-DOS THEDYNA 32bit 2-40
62 g100g 500g kg 10kg (1) RfOR RfOCl 2-41
63 Rf RfOR (2) KOH Cu CF 3 CFIOCF 3 -OCF 3 (3) RfOR KF (4) (5) RfOR RfCOR
64 8-7 (6) HFE-245mc HFE-143m HFE-245mc HFE-347pc-f HFE-254pc HFE-55-10mec-fc
65 2. (1) Antoine () 2-44
66 HFE 28 HFE () 2 ml HFE13 5 Antoine 243 K353 K 0.02% () ( MPa) 278 K323 K 0.2% () ( ) MPa 277 K 5 K 10 K 332K 0.3% () 2-45
67 25 ml ( MPa) K 2% (2) ASOG 35 HFE-143m () 3 2 ( ) () 473 K 10 MPa 100 cm HFC-134a/HFE-143m HFC-125/HFE-143m () HFC-134a/HFE-143m HFC-125/HFE-143m 2 PR () HFC-125/HFE-143m HFC-125/HFE-143m 2-46
68 0.2 % () HFC-134a/HFE-143m 0.3 % HFC-125/HFE-143m 2-47
69 3. (1) CF 3 OCH 3 (HFE-143m) CF 3 CHFOCF 3 (HFE-227me) CF 3 CF 2 OCH 3 (HFE-245mc) CF 3 CF 2 CF 2 OCH 3 (HFE-347mcc) (CF 3 ) 2 CFOCH 3 (HFE-347mmy) HFE-143m HFE-245mc HCFC-22 OH (H) 8-9 CF3OCF HCFC-22 CHClF HFE-125 CF 3 OCHF HFE-116 CF 3 OCF > 150 HCFC-22 R-407AR-410C HFC ( ) PVT ()PVT 2-48
70 () HFE-143mHFE-245mcHFE-347mcc HFE-347mmy HFE-143m HFE-245mc 0.3 % HFE-347mcc HFE-347mmy 0.1 % HFE-143mHFE-245mcHFE-347mcc HFE-347mmy 4 HFE-245mc HFE-143m ( ) () HFE-245mc HFE-143m CFC % () HFE-245mc CFC % HFE-245mc CFC
71 () ( :5 m) HFE-143m CFC % HFE-245mc () HFE-143m HFE-245mc ASHRAE 8-10 HFC-32 HFC-245fa 2-50
72 8-10 ASHRAEStandard (100) (23) ( ) Class vol.% vol.% vol.% vol.% kg / m 3 kj / kg HFE-143m > HFE-245mc HFC HFC-245fa () ASHRAE HFE-143m HFC 4372vol%HFE-245mc 1825vol% HFE-143m HFE-245mc F HFE-143m HFE-245mc
73 ( ) HFE-245mc, 100 C, 5days HFE-245mc, 50 C, 15days HFE-143m, 50 C, 15days
74 (2) CFC-11HCFC-141bHFEHFC-245fa,365mfc ( 3.39%) HFE CFC HCFC HFC HFE G400 > 750ED > 450S > PE315 PE315 G ED 450S 40wt% PE315 60wt% PrOMe EtOEt n- EtOMe PrOMe CHF 2 --CHF- 2-53
75 PE-315 HFE-236pc (CHF 2 CF 2 OCHF 2 ) 8-8 Neural Network wt% 5wt% Neural Network HFE HFE-236pc HFE-236pc PE wt% PE-315 HFE Calculated Solubility in PE-315 [wt%] 8-8 PE-315 Neural Network Observed Solubility in PE-315 [wt%] 8-9 PE-315 ; () ; (+)
76 C-O-C C-C-O-CC-C-C-O-CC-C-O-C-C C-O-C C-C-O-C C-C-C-O-C C-C-O-C-C C-C-C-C-O-C C-C-C-O-C-C mW/mK 40wt% HFE-254pc,HFE-236pc,HFE-347mcc 2-55
77 (3) ,1,1-30 mn/m 64 n- n- n- G-6050 CFC n- 2 HCFC n- G-6050 n- G-6050 HCFC HFE-55-10mec-fcHFE-458mecfHFE-54-11mec-f 2-56
78 HFE-449mec-fHFE-347pc-f HFE-347mcf OH cm 3 molecule -1 s (1) TEWI LCA 15kV 7mm0.15sec 0.3mm 2.0cm DC3648V 20cm 40cm 30 60cm 10 40cm F F 2-57
79 RF RF RF ASHRAE ISO (2) mg/kg, 300 mg/kg, 2,000 mg/kg 3 ( ) mg/l, 2.0 mg/l, 20.0 mg/l Ames ( ) ( 63 ) ( 61 ) 3 HFE 8 HFE ( ) 2-58
80 8-12 RITE Name Ames 28 HFE-245c HFE-347mcc HFE-347mmy HFE-143 HFE-347pc-f HFE-449mec-f HFE-54-11mec-f HFE-55-10mec-fc HFE-245mc HFE-449mec-f H6 H7 H8 H9 H10 H11 H12 H Ames
81 8.2.3 GWP100 GWP GWP OH OH CFC ( ) GWP GWP 8-10 OH ( ) GWP (ph ) ( ) UV 8-10GWP 2-60
82 total OH OH water solid light 1 total 1 OH 1 water 1 solid 1 light 1. (1) OH OH OH 5 OH FP-H 2 O LP-H 2 O LP-CH 4 LP-H 2 O 2 DF OH OH LIF OH K (2) OH 1 m 3 SUS
83 260nm OH OH FTIR GC-FID OH k OH (3) OH RITE k cm 3 molecule -1 s HFE-143m CF3OCH3 1.1 A10 12 E/R cm 3 molecule -1 s -1 K HFE-245mc CF3CF2OCH HFE-245pc CHF2CF2OCCH2F HFE-245qc CH2FCF2OCHF HFE-347pc-f CHF2CF2OCH2CF HFE-449mec-f CF3CHFCF2OCH2CF HFE-55-10mec-fc CF3CHFCF2OCH2CF2CHF HFE-54-11mec-f CF3CHFCF2OCH2CF2CF HFES-123m CF3OC(O)H OH OH 2-62
84 1 2 C-H (1) OH T k(t) kt k( T ) γ ( T ) h Q Q Q = A B E 0 exp kt QA, QB, Q A, B E 0 (A+B) γ Wigner 6-31G** MP2 MP2 MP-SAC
85 8-11 OH MP-SAC2 (logk) k calc 3k calc 1/3k calc (2) HOMO chemical potential hardness C-H bond dissociation enthalpy, BDE D 298K 0 OH
86 8-15 C-H molecule BDE (kcal/mol) k (298 K) (cm 3 molecule -1 s -1 ) k (298 K) (cm 3 molecule-1 s-1) CH3OCH E E-12 CH3OCH2F E-13 CH3OCH2F E E-13 CH3OCHF E-15 CH3OCHF E E E-13 CF3OCH E E-14 CF3OCHF E E-16 CHF2OCHF E E-15 CH3OCF2CHF E-15 CH3OCF2CHF E E E-14 CF3CH2OCHF E-16 CF3CH2OCHF E E-14 CF3CF2OCH E E-14 CF3CF2CF2OCH E E-14 (CF3)2CFOCH E E-14 CH3OCF2CHFCl E-15 CH3OCF2CHFCl E E E-14 a C-H (3) OH HFE-245mc ( OH ) OH (k OH ) 8-16 C-H BDE OH
87 8-16 E act k OH Formate syn anti syn anti Total CF 3 OC(O)H C 2 F 5 OC(O)H C 3 F 7 OC(O)H C 4 F 9 OC(O)H CHF 2 OC(O)H CHF 2 CF 2 OC(O)H CF 3 CHFOC(O)H CHF 2 CF 2 CF 2 OC(O)H CF 3 CHFCF 2 OC(O)H CF 3 CF 2 CHFOC(O)H Eact [kcal/mol]; koh [cm 3 molecule -1 s -1 ]; τoh [year] τ OH 3. OH CO 2 COF 2 COF 2 (1) 0.95 m 1m 3 CH 3 C(O)CF 2 CF 2 CF 2 CF 3 260nm
88 CH 3 C(O)CF(CF 3 ) 2 13 h 100 Torr Φ = 0.1 CH 3 C(O)CF 2 CF 2 CF 2 CF (2) (COF 2 ) OH HFE HFE 2 H khyd CH 3 OC(O)CF 3 C 2 F 5 OC(O)H CH 3 OC(O)CF 3 298K H 1.90 M atom -1 khyd 1.84 s -1 C 2 F 5 OC(O)H RfOMe (3) 2-67
89 HFC ppm (4) OH OH OH HFE OH CO 2 COF 2 C m F 2m+1 C(O)F OH 4. GWP GWP : Global Warming Potential GWP 2-68
90 GWP GWP IPCC (Intergovernmental Panel on Climate Change) U.S. Standard LBLRTM 1/e ( )( )1ppb OH OH OH OH 2-69
91 Plamb and Mahlman (1987) NIRE-CTM 60km SF6 Age spectrum 8-17 OH GWP HOMO OH GWP GWP GWP HFC-134a 8-17 GWP RITE GWP (20) (100) (500) HFE245mc CH3OCF2CF HFE347mcc CH3OCF2CF2CF HFE347mmy CH3OCF(CF3) HFE143m CF3OCH HFE254pc CHF2CF2OCH HFE347mcf CF3CF2CH2OCHF HFE347pc-f CHF2CF2OCH2CF
92 2001 Climate Change 2001, The Scientific Basis 2-71
93 HFE-347mccHFE-347mmy HFE-245mc HFE-245mc HFE-143m (1) HFE-245mc 500 HFC (POE) CFC COP COP HFE-245mc (2)HFE-143m CFC-12 HFC-134a HFE-143m HFC-134a HFC-134a (3) HCFC HFE 2-72
94 HCFC 2. (1) HFEHFCHC HFE-254pc,HFE-236pc,HFE-347mcc (2) PPG ( ) (3) HFE-254pc HFE-254pc 2-73
95 3. (1) 6 6 CFC HCFC (2)HFE (3) HFE HFE 2-74
96 HFE n- NS 100 HFE 4. (1) EIAJ HFE CVD (2) CF 3 CHFOCF 3 (HFE-227me) FM200 HFC
97 HFC HFC COP COP4 HCFC HFC 2010 HCFC ,3 HFE
98 CO 2 CO 2 JEMA GWP THEDYNA MS-DOS MS-Windows 2-77
99
100 (1) HCFC CO 2 NH 3 (2) HCFC (3) HCFC HFE (1) Neural Network Neural Network Neural Network (2) (THEDYNA) THEDYNA MS-DOS MS-Windows H( ) HFE-7100(3M) 2020 (DuPont) HCFC-22 HFC-134a R410A HFC-32/HFC-125 HFC R407C HFC-32/HFC-125/HFC-134a n- / HFC HFC HFC-245fa HFC-365mfc HCFC-225 HFC-43-10mee Cyclic HFC-447cce ( ) HFE-449mccc ( ) Neural Network ( ) HCFC-141 HCFC-142b b2010 ( (GE)
101 ** H7 H8 H9 H10 H11 H12 H13 8(6) 4(2) 1(1) 2 4(1) - 19(10) 1(1) 4(2) (3) 4(2) (2) (1) 6(4) 3(1) 1-12(6) 26(10) 21(8) 13(2) (1) - 78(21) ** (1) * HFE- 245 HCFC HFC (2) 40 HFE HFC CFC HCFC HFE HFC 12 4 (3) ,1,1-2-80
102 (1) ASHRAE ASHRAE/ISO RF = [U / L 1 ] Q / M U: Q: L: M: (2) LD
103 H 2 OO 2 HOx 6-31G** OH 3-2 OH CO 2 OH (3) (4) OH -CH 2 OCHF 2 CH 3 CCl 3 OH1/10 3-3GWP 2-82
104 (1)HFE-245mc (CF 3 CF 2 OCH 3 ) [CFC-114 ] ( ) 500 POE( ) (HPC) ( ) 75 HPC COP HFE-245mc (2)HFE-143m(CF3OCH3) [CFC-12/HFC-134a ] "THEDYNA" HFC-134a 50Vol% HFC HFC-134m (HFC-134a) HFC-134a (3) HCFC-141b/142b HCFC (4) HFE-347mmy((CF 3 ) 2 CFOCH 3 )HFE-347mcc(CF 3 CF 2 CF 2 OCH 3 )HFE-227me(CF 3 CHFOCF 3 )Step (2) ( ) HFE-254pc(CHF2CF2OCH3) HFE-236pcCHF2CF2OCHF2) ( ) 254pc236pc HFE-254pc 4-3 (1)HFE-347pc-f HFE-347pc-f(CHF2CF2OCH2CF3) HFC ) (2)HFE-55-10mec-fc(CF3CHFCF2OCH2CF2CHF2) (3)HFE-347pc-f HFE-356mec 4-4 (1) CVD (2) 2-83
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106 2-85
107 2-86
108 2-87
109 2-88
110 2-89
111 2-90
112 2-91
113 2-92
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118 4-3
119 4-4
120 4-5
121 4-6
122 4-7
123 4-8
124 4-9
125 4-10
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127 1-1
128 / HCFC-141b HCFC-141b HCFC-22 HCFC-141b HCFC-141b HFC-134a HFC-134a 1-2
129 CFC HCFC HFC, PFC, SF6 CO 1-3
130 1-4
131 1-5
132 F F F F F F H F H H 1-6
133 1-7
134 1-8
135 HCFC (ODP0GWP GWP OH 1-9
136 1-10
137 1-11
138 - (COP H) * 50 CFC HFC-134a * (THEDYNA) (40) HFC-245fa HFC-365mfc 15.3(60) (mn/m) (J/g) HFC-43-10mee 14.1(25) 130(25) 18.0(45) 187(30) 30mN/m 1,1, CFC cb 225ca b b a CFC,HCFC HFC HFC CH3OCF2CF3 CF3OCF2CF3 CH3OCF3 407C 410A CF3OCF3 MeOMe MeOEt MeOPr CF3OCF2CF2CF3 C2F5OC2F5 C4F9OCH3 (HFE-7100) C4F9OCF3 CF3OCF2OCF3 C5F10O C4F8O C3F6O CF3COCF3 EtOEt MeOC4 MeOC5 1-12
139 1-13
140 HFE HFE-245mc CF 3 CF 2 OCH COP H HFE-143m CF 3 OCH 3 HFC-134a HFE-254pc CHF 2 CF 2 OCH 3 HFE-347pc 347pc-f HFE mec-fc CHF 2 CF 2 OCH 2 CF 3 CF 3 CHFCF 2 OCH 2 CF2CHF
141 - OH GWP 1-15
142 HCFC HCFC-22 HFC HFC-134a R410A HFC-32/HFC-125 R407C HFC-32/HFC-125/HFC-134a n- / i- CO 2 NH 3 HCFC HCFC-141 HCFC-142b HFC HFC-245fa HFC-365mfc 1-16
143 HCFC HCFC-225ca, cb HFC (HFC-43-10mee) ( ) HFE-7100 HFE (HFE-449mccc, mmyc) 1-17
144 ( ( ) ) RfOR RfOR HFE-143m 1 HFE-245mc 1 HFE-347pc-f 1 HFE-254pc 1 HFE-55-10mec-fc CF 3 OCF(CF 3 )CF 2 OCH 3 Cyclic-OCF 2 CF 2 OCF 2 CHF- 1-18
145 Name GWP years ITH=100y Carbon dioxide CO low 1 non HFC-32 CH 2 F low flammable HFC-125 CF 3 CHF low non Propane CH 3 CH 2 CH low flammable HCFC-22 CHClF low non Ammonia NH flammable CFC-12 CCl 2 F low non HFC-134a CF 3 CH 2 F low non HFE-143m CF 3 OCH low 4.9* 680* flammable iso-butane CH(CH 3 ) flammable CFC-114 CClF 2 CClF low non HFE-245mc CF 3 CF 2 OCH low 4.5* 530* flammable HFC-245fa CF 3 CH 2 CHF flammable CFC-11 CCl 3 F low non HCFC-123 CF 3 CCl 2 H non iso-pentane (CH 3 ) 2 CHCH 2 CH flammable HFE-347mmy (CF 3 ) 2 CFOCH low 4.6* 490* non HFE-347mcc CF 3 CF 2 CF 2 OCH low 3.5* 350* non 1-19
146 PVT ( ) CFC-11 < HCFC-141b < HFE < HFC-245fa, 365mfc < c-c 5 H 10 EtOMe PrOMe CHF 2 - -CHF- 1-20
147 C-O-C C-C-O-C C-C-C-O-C C-C-O-C-C C-C-C-C-O-C C-C-C-O-C-C 1050 < 13.5 mw/m K > 40 wt% HFE-254pc : CHF 2 CF 2 OCH 3 HFE-236pc : CHF 2 CF 2 OCHF 2 HFE-347mcc : CF 3 CF 2 CF 2 OCH
148 RITE name 1 CHF 2 CF 2 CF 2 CF 2 CH 2 OCH CF 3 CHFCF 2 OCH 2 CF 2 CHF <5.0 3 CHF 2 CF 2 CH 2 OCF 2 CHF CF 3 CHFCF 2 CH 2 OCHF CF 3 CHFCF 2 OCH 2 CF 2 CF <6.7 6 CHF 2 CF 2 CH 2 OCHF CF 3 CHFCF 2 OCH 2 CF <6.5 8 CF 3 CF 2 CH 2 OCF 2 CHF CF 3 CH 2 OCH 2 CF CHF 2 CF 2 OCH 2 CF < CF 3 CHFCF 2 OCH CF 3 CF 2 CH 2 OCHF <5.2 HFE 1-22
149 "RF- " RF -No. = ( UFL/ LFL 1) (HOC/M) UFL : LFL : HOC : M : H6 H7 H8 H9 H10 H11 H12 H Ames ( ) 1-23
150 OH OH OH OH 1-24
151 OH F H H C O H HFE C-H BDE F C F F C H F C F OH OH CnF2n+ 1OCH3 CnF2n+ 1OCHO CO2, COF2, Cn 1F2n 1COF OH 1-25
152 GWP GWP RITE GWP ITH= HFE-143m CF 3 OCH HFE-245mc CF 3 CF 2 OCH HFE-347mcc CF 3 CF 2 CF 2 OCH HFE-347mmy (CF 3 ) 2 CFOCH HFE-254pc CHF 2 CF 2 OCH HFE-347mcf CF 3 CF 2 CH 2 OCHF HFE-347pc-f CHF 2 CF 2 OCH 2 CF
153 HFE-245mc CF 3 CF 2 OCH 3 ) / CFC-114 POE( ) , COP HFE-143m CF 3 OCH 3 ) / CFC-12, HFC-134a POE POE HFC-134a HFC-134a HCFC-141b/142b 141b/142b HFE-254pc CHF 2 CF 2 OCH 3 ) 1-27
154 HFE-347pc 347pc-f CHF 2 CF 2 OCH 2 CF 3 ) HFC HFE mec-fc CF 3 CHFCF 2 OCH 2 CF 2 CHF 2 ) CVD 1-28
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資料7-1.PDF
1 - (COP H) * 5.46 50 CFC-114 HFC-134a 30 50 HFC-245fa HFC-365mfc * 4.63 (THEDYNA) 30 80 (40) 14.9 15.3(60) (mn/m) (J/g) HFC-43-10mee 14.1(25) 130(25) 18.0(45) 187(30) 30mN/m 1,1,1-25.6 242 CFC-113 17.5
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.............................. 14 1 GWP GWP NEDO GWP GWP 1994 1995 1996 1997 1998 1999 2000 2001 9511 9806 9403 9611 9907 0106 0101 0204 9806 9607 9511 9707 9610 9708 9912 9905 0103 2 0005 ( ) 0105
平成8年2月28日\(水\)
02-04 14 7 5 ) (CFC ) HCFC( ) HFC( ) (COP3) ( ) 1990 500 ( 13 ) 5,500 2 PIO-NET( ) (HFC) ) (CFC)1 13 8 14 2 13 9 14 4 ( ) 300 ( 14 2 ) 2 2 4 (HFC) 2 (320323 ) 6 1 ( ) ( ) (HFC) (HFC) 95 (() ) (HFC) ( R-600a)
環境BOOK2016.indd
2111 93-8815-1 TEL 7-441-2511 URLhttp://www.rikuden.co.jp/ 2 3 1 4 5 7 2 8 9 1 11 12 13 14 15 1 17 18 3 2 2 3 198121 1891214 1898214 1978 28 ( ) AX128 28.1.7, IPCC 221 48 82 5 Masaaki Nakajima 19 192 194
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NISTEP REPORT No. 80 327 146 181 169 125 37 71 64 139 65 997 6 1 3 2 3 0 2 0 1 2 2 2 1 0 2 15 5 8 3 3 0 0 2 0 3 2 0 9 () 326 73 179 65 7 2 23 8 357 145 41 74 26 2 0 7 5 155
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2004 R404A 12 Microsoft Excel Excel Excel Excel97 No R 22-Ver2.xls HCFC CHClF2 () R 123-Ver2.xls HCFC CHCl2CF3 () 3 R 125-Ver2.xls HFC CHF2CF3 () 4 R
3.1 3.2 3.3EPR 3.4 3.5 3.6 3.7 3.8 P2 P2 P3 P3 P4 P6 P8 P10 P11 P12 P13 P15 P15 P16 P16 A1 A2 A3 Function P17 P17 P19 P29 1 2004 R404A 12 Microsoft Excel Excel Excel Excel97 No R 22-Ver2.xls HCFC CHClF2
Microsoft Word - CTCWEB講座（4章照査）0419.doc
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192 No m 1. 5 m 9 mm t kw 38 m
191 No. 50 WWW http // riodb.ibase.aist.go.jp/riscad/ 1. 2. 3. 6. 1. 2007 3 27 15 00 6. 1 1 1. 2007 3 30 2 05 3. 6. 4 2 620 m 2 21 00 1. 2007 3 30 3 15 3. 6. 9 155 m 2 1 000 m 165 t 5 1. 2007 3 28 17 20
橡平成12年度バイオマス発電等の実態調査（HP版）.PDF
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