16 Dissolution Rate of Alumina into Molten CaO-SiO2--Al2O3-MgO Slags Shoichirou TAIRA, Kunihiko NAKASHIMA and Katsumi MORI Synopsis : Dissolution rate

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1 16 Dissolution Rate of Alumina into Molten CaO-SiO2--Al2O3-MgO Slags Shoichirou TAIRA, Kunihiko NAKASHIMA and Katsumi MORI Synopsis : Dissolution rates of sintered alumina into molten CaO-SiO2-9mass%Al2O3-10mass%MgO slags were measured by rotating specimen method. Experiments were conducted at various revolution speeds,temperatures, and CaO/SiO2 ratioes, and the microstructures of specimens after experiments were examined by EPMA. Based on these results, the dissolution mechanism was discussed. The dissolution rate of alumina increased with increasing revolution speed and rising temperature. These results suggested that the dissolution rate was controlled by mass transport in the boundary layer of molten slags. The dissolution rate of alumina decreased rapidly as increasing CaO/SiO2 from 0.64 to 0.80, and then increased rapidly as increasing CaO/SiO2 from 0.80 to According to the EPMA analysis, a compact deposition of MgO E Al2O, spinel particles in slag and a formation of CaO E 6Al2O3 compounds in alumina were confirmed in the specimen immersed into the slag of CaO/SiO2 = It was estimated that these reaction proudcts suppressed the flow of slag components to decrease the dissolution rate. However, MgO EAl2O3 spinel particles observed in the specimen immersed into other slags were scattered, and might not disturb the flow of slag component, so that the dissolution rate was not retarded. Key words : refractory ; slag ; dissolution rate ; dissolution mechanism ; alumina ; CaO-SiO2-Al2O3-MgO system ; MgO E Al2O3 spinel. 16

2 17 Table 1. Chemical composition of slags(mass%). (1 ) Fig. 1. Relationship between periphery velocity and dissolution rate of alumina into CSAM and CSA slags. (2 ) (3 ) 17

3 18 (4 ) (5 ) Fig. 2. Arrhenius plots of the mass transfer coefficient for CSAM and CSA slags. Table 3. Activation energies Eā, ED for CSAM and CSA slags. (7 ) (6 ) Table 2. Estimated values of saturation contents of Al2O3 in CSAM slags.

4 19 Fig. 3. Effect of CaO/SiO2 on the dissolution rate of alumina into CSAM and CSA slags. Fig. 4. Variation of slag viscosity (Č), (%Al203 ) and mass transfer coefficient (k) with Ca0 / Si02 for CSAM slags. 19

5 20 鉄 と 鋼Vol.81 (1995) No. 1 (A) Fig. 5. EPMA analysis (B) of the specimen after 常 に 小 さ い た め,ア ル ミ ナ の 拡 散 が 抑 制 さ れ ず,こ 0.80<CaO/SiO2<1.00でkが (C) immersion の 結 果, at 1823K and for 60min. 転 数 の増 加 に よ る ス ラグB中 へ の ア ル ミナ の 溶 解 速 度 の 変 化 に つ い て は, 合 に つ い て,温 度1823Kで,試 料 回 転 数 を400rpmと せ た 場 合 に つ い て 同 様 にEPMA観 に はMgO Al2O3ス 場 測 定 し て お ら ず 不 明 で あ る た め,今 増 加 さ 察 を 行 っ た と こ ろ,界 場 合 と同 様 にCaO 6Al2O3の 面 同 様 の ス ラグ 系 へ の 多結 晶サ フ ァ イ アの 溶 解 現 象 を考 察 して い るSandhageら5) 7)は,本 針 状 組 織 が確 認 さ ピ ネ ル は,200rpmの の ス ラ グ の 場 合,1723Kに 場 合の Al203ス 一方 示 し た よ う な 密 な 集 合 体 は 形 成 し て お ら ず,む し ろFig.5(A)に 示 した ス ラ グAの 場 合 の よ うな 粗 な 分 布 形 態 が 観 察 さ れ た ま た,CaO 6Al2O3は,非 常 に 小 さ く しか も部 分 的 に しか 認 め ら れ ず,Fig.5(B)の よ う に試 料 を保 護 後検 討 す る必 要 が あ る もの と考 え ら れ る ピ ネ ル の 分 布 が 観 察 さ れ,一 部 の 界 面 で れ た し か し,MgO Al2O3ス 研 究 と同 じMgO;10 mass ピ ネ ル の 緻 密 な連 続 層 が 確 認 さ れ た と報 告 して い る,1823Kに MgO Al203ス お い て は ア ル ミナ が 侵 食 さ れ や す い た め に, ピ ネ ル の 連 続 層 が 形 成 さ れ に く くな る と も報 告 し て い る 回 転 数 の 増 加 に よ りMgO Al2O3ス ピネ ル の 連 続 層 が 形 成 さ れ る 現 象 は 本 研 究 結 果と異 な る が,彼 す る よ う な 生 成 形 態 は 観 察 さ れ な か っ た こ の よ う に, 回 転 数 の 増 加 に よ り界 面 で 生 成 し たMgO Al203ス 前 述 し た よ う に 温 度 も1723Kと ピネルや 減 少 す る傾 向 を示 し た こ とか ら,こ れ らの 化 比 較 的 高AI203濃 らの 用 度 で あ り, 低 い こ とか ら,こ の 差 は主 に 実 験 条 件 の 差 に よ る も の で あ る と考 え られ る ま た,本 20 % お い て 回 転 数 の 増 加 に 伴 いMgO いた ス ラグ はAl203=20mass%と CaO 6Al,03が 200rpm, へ 分 離 して い く もの と推 定 さ れ る しか し,回 急 激 に 増 加 し た もの と推 定 さ ま た,特 に 界 面 で 生 成 し て い た 化 合 物 が 密 な ス ラ グBの Fig.5(B)に slags 合 物 は 試 料 の 回 転 数 の 増 加 に よ り表 面 か らバ ル ク ス ラ グ 中 れ る は200rpmの into 系

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