I I Settling Characteristics of Mud Carrying Different Floc Structures TOUCH NARONG Takeshi KOEDA, Hironobu OKAMURA, Narong TOUCH and Tadashi HIBINO I
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1 II Settling Characteristics of Mud Carrying Different Floc Structures TOUCH NARONG Takeshi KOEDA, Hironobu OKAMURA, Narong TOUCH and Tadashi HIBINO In this study, the settling velocity and organic properties of sedimentation-selected mud flocs were experimentally measured to understand the organic properties, settling characteristics, and flocculation mechanisms in the course of settling. It was found that the settling velocity of mud flocs significantly depended on the amount and properties of adsorbed organic matter. Further, the settling velocity of mud flocs is averaged due to the fact that differences of the settling velocities of particles are diminished under the collision and flocculation of particles in the settling process. Finally, the experiment results suggest that the flocculation of particles adsorbed by large amounts of organic matter was electrically difficult to generate; whereas it was facilitated owing to an increasing positive charge surface of particles by elimination of the organic matter. 1. Dietrich, Eisma et al., 1991 Wilkinson et al., 1997 JSPS DC cm 1 2 Case 1 27; 39cm 56cm31cm6800cm Case 7 30psu 6.6 5cm 5cm 20 OPTEX TD-M Case Case 6 1 Case 7
2 Case 2Case 76.6 h C/N IL IL 10000G 5 C/N CHNS CHNS/0 2400II SALD-2000J % D 50 a% ILb C/N SS ALI 6 Case 2 5 Case C/N Case 6 7 C/N Case 1b Case 1 5 Case 2 7 IL C/N Case 721.6% 10µm 21 Case 7 µm
3 I_1018 土木学会論文集B2 海岸工学 Vol. 68 No 付着することが可能であり 有機物が付着することで沈 機泥群である 選別された Case 2 の有機泥群が相対的に 降し難い有機泥が形成されると推定される 沈降の遅い 最も散乱強度が弱いのは粒子が大きく 前節で述べた特 有機泥群には比較的新鮮な有機物が付着しているが 付 性により有機物の影響が小さいためと考えられる Case 着する有機物の粒径は 20µm よりも小さいことが粒度分 3 7 では有機泥群の異なる性状に伴う粒子構造の違いは 布 図-2 からわかる 沈降速度が速く IL の小さい 重量効果を除けばALI に反映されている Case 2 は逆に粒径の大きな粒子で構成されており 相対 的に有機物付着量が少ないために有機物付着の効果が薄 れ 土粒子の持つ沈降速度に近い速度を持っていると推 3 選別された有機泥の沈降特性とフロック構造 図-4 には有機泥群の沈降に伴う粒度分布の経時変化 図-5 には超音波照射前後の粒度分布の変化が示されてい 定できる なお 粒径の大きな粒子には炭素含有量の大 る 図-4 中の Initial は投入直後に測定された粒度分布で きい有機物が付着する傾向にある あり t = 0 は測定器内で流れが安定した後の試験開始時 2 平均光強度 SS 濃度関係と沈降泥の構造 間である 図に Case 7 の結果は示されていないが 沈降 SALD-2000J では平均光強度 ALI により粒子径が換 と超音波照射による変化はなく 沈降も分離も起こって 算されている ALI は後方散乱光を測定することにより おらず 図-2 に示した Case 7 粒度分布から変化していな 求められている ミー散乱では粒子径や粒子構造によっ い 図-4 に示した粒度分布は装置に設置後約 25 分後まで て散乱強度分布が変化するため ALI SS 関係と IL の結果である 完全に沈降速度で選別できていたならば C/N 比等との比較から付着する有機物の状態を検討する 表-1 に示した 5cm 深での沈降時間を参照すれば Case 2 3 ことができる 上野ら 2011 ただし フロック構造 では全ての粒子が沈降 Case 5 6 では全ての粒子が残存 を持たない粒子ではALI 値は小さくなる特性もあるため するはずである しかし 図-4 では Case 2 4 の有機泥 ALI のみでは付着有機泥の特性を知ることはできない 群に残留する粒子が含まれており Case 5 では沈降する 図-3 には沈降選別された有機泥群の ALI SS 関係が示さ 粒子も存在している これは 粒度分布を測定する前の れている SS は ALI に対して一意的に決まっていないの 攪拌によって粒子のフロック構造が破壊され Case 2 と は SS が質量 ALI が体積の示標であること 有機泥に付 3 で沈降しない粒子 Case 4 と 5 で沈降速度の速い粒子が 着する有機物の量と性状により散乱強度が変化するため 出現したためと推定される である ALI SS 関係に大きな差があるのは Case 2 の有 図-4 図-5 b ではCase 2 の粒子群に超音波を照射した結果 選別された有機泥群の沈降に伴う粒度分布の経時変化 Initial 約20 分まで 図-5 超音波照射前後の粒度分布の変化
4 6 a ILb C/N 8 40µm Case ab ~ d 30µm 100µm 30µm 4 b Case 4 6 Case 4 5 Case Case 1 Case 2 Case 4Case 7 b ~ dcase 1 a Case 2 b Case 1 Case 2 Case 7 Case cm/s 1/10 Case 4c 5cm/40min Case 2 Case 140µm 7 acase µm Case µm C/N 40µm 8 Case 141.9µm 10
5 D D 50 Case 1b Case 6 D 50 Case 1 25D 50 Case 1 10 Case 1, 1b Case 6 30µm80µm Case 1 Case 1b Case1b 2 Case 1b 15 D 50 9 Case 6 7 Case 7Case 7IL C/N Case 6 % Case 7 Case 1b 5. a 10µm b c Dietrich, W.E. (1982) : Settling velocity of natural particles, Water Resource Research, Vol.18, pp Eisma, D., P. Bernard, G. C. Cadee, V. Ittekot, J. Kalf, R. Laane, J. M. Martin, W. G. Mook, A.Van Put and T. Schuhmacher (1991) : Suspended-matter particle size in some West-European estuaries, Part 1: particle-size distribution, Netherlands Journal of Sea Research, Vol.28, pp Wilkinson, K.J., J.C. Negre and J. Buffle (1997) : Coagulation of colloidal material in surface waters: the role of natural organic matter, Journal of Contaminant Hydrology, Vol.26, pp Vol.54 pp Vol.B2-67 No.2 pp Vol. 26 No.1 pp Vol. B2-66 No.1 pp TOUCH NARONG 2011 Vol.B2-67 No.2 pp Vol.B2-65 No.1 pp TOUCH NARONG 2009 Vol.B2-65 No.1 pp
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