平成12年度ものづくり人材支援基盤整備事業
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- あゆみ かくはり
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1 12
2
3
4
5
6
7 1) 1
8 2) 3) 2
9 4) 5) 6) 5) 6) (1) 6) 3
10 (2) (3) ) ) ) ) ) 4
11 ) s. (4) 5
12 6
13 (1) 7) 7) 8)
14 a. b. c. 8
15 (2) (3) 9
16 (4)
17 (1) 6) 1-8 6) 1-8 (2) 9) ( 1-9 ) 11
18 ( 1-10) 1-9 ()
19 2-1-1 (1) 2-1 Single Spring TypeT Type Box Multiple Type 1)
20 (2) (3) 14
21 (4) (5) 15
22 2-1-2 (1) 2-2() 2-2() 2-3() 2-3()
23 (2) 17
24 (3) (4) (5) 1) F.K.Savage: Racks:Design,Construction,Insulation and Maintenance Electroplating Engineering Handbook Edited by A.K.Graham
25 (1) () a. () b. c. d. () (2) (3) (1) b.c.d. (2-2-2 ) (4) (throwing throwing power) ( )
26 2-5 (J.B.Mohler J.B.Mohler) (5) (covering power) a. b (1) 2-6 ()() ()() ph
27 i 1 (1) d2 i 2 d 1 1, ,2 (2) d de 2+K di i 1, i, 2 d de 1+K di k de/di 1 2 ( )( ) ( ) M 1 i1' CEff 1 (3) M 2 i 2 ' CEff 2 (2) (3)(CEff1CEff2) (2) ()( )
28 a. b. c. d. e. f. g ()() (1) ( ) 2-11 () 22
29 2-11 (2) () 2-12 () () 2-12 (3) () () 33 ( 2-3 ) (4) 23
30 ()() () ()()() (5) ( 60 ) ()( ) () ()() ()() (6) () ( 600 ) () 2-13 () WI 2 L S p ( ) () () () 2-13 (D.R.Turner,Plating & SurfFin NII.1976) 24
31 (7) ()() (8) 2-14 () () () () 1 n (9) () ()
32 2-2-4 (1) () () ( ) (2) () () A 0.2A 0.7A 0.3A 0.3A
33 2-3 ( 100) ( ) (99.96) T T T T T6 (2) (99.73) B265-52T grade2 B265-52T grade Metal Finishing Guide Book(1959) () (1) ()
34 (2) ( ) (3) (W0) 0 n n n (1953) 28
35 () I 2 I 2 (a) 2-20 (b) ( ) () 2-22 (a) (b)(c)(d)(f) (e)(f)
36 (1) a b. c (a) 2-26(c) d. 2-26(e) e
37 (2) 2-27 (10 ) 2-27 (3) ()() (de/di)(d d ) (2)()(dE/di) (4) ( ) 31
38 ( 1015) (5) (6)
39 (7)
40 () () 34
41 () () 2-41 M1 M
42 ()
43 (1) ()
44 (2) ( ) (3) () (1) 38
45 (2) () () (A)(B)( ) (3)
46 m ()
47 () () a. b. c () (1) () 41
48
49 (2) (3) () 2-64 ()
50 2-66 (4) (5)
51
52
53 (1) (2) a. b c (3)
54 ()
55 2-7 49
56 2-5-1 () CuNiCr 50
57 () ()
58 (1) (2) (3)
59
60 ()
61 () (VA ) ( ) 2-2-6(1) 2-10 a
62 b. c. d. e. f. g () 2-77 () ()
63 (2-2-6 (3)) () n n ( ) 2-80 (2-2-3 (5)) () 57
64 ( ) CuNiCr 58
65 a. b. c. ph d. e CuNiCr CuNiCr
66 2-84 () 2-85 () ()
67 a. b. c. d
68 B1B2 S P R C
69 ()
70 () () 2-94 (A)(B) (A) (B) 2-94 (A)(B) 64
71 (A)(B) () 65
72 NO.22 NO.23 66
73 NO NO.25 NO () 67
74
75
76 () ()()() () () () () 70
77 () 3-5()
78 () ()
79 m/m
80 mm ( 3-12 ) ( ) () 74
81
82
83 Cu NiCr (m)
84 () 3040 m 3-19 () (ab) 78
85
86 3-1 80
87
88 82
89 83
90 84
91 85
92 86
93 87
94 88
95 89
96 90
97 91
98 92
99 ppm ( ) (CpCpk) () () ppm ppm ppm()parts par million 100 ( ) () 93
100 100ppm ppm (Cp) (Cp)
101 3-30 ()
102 3-4-3 ( ) process capability 96
103
104 (1) 3-36 (2)
105 (3)
106
107
108
109 5 () ()( )
110 () 104
111 () () () () ()
112 ()2-6-2 (2-2-4 ) ) (2-5-2 ) () ( 3-44 )
113
114 3-5-5 ( ) ( 3-10 ) (a) 3-46 b 3-12 ) 3-46 a (b)
115 (A) (B) (C)
116
117 111
118 112
119
120 4-2 () (a) 4-3(a) (b) 4-3(b) (a)
121 4-4 (b) () 115
122
123
124 a a b ab a ba ab N N N
125 () 4-13()
126 2-14 ph () 120
127
128 (1) 122
129 (2) (3) (4) (5) (6) (PVC)MMAPP 3 PVC PP 123
130 PP PP ()
131 Q&A 1 Q A Q2 A
132 4-22 () Q3 A (N () 126
133 Q A Q () 127
134 2A mmmmmmmm 2A 1.5 3A 2.5 5A 4 8A 128
135 PVC PP Q5 A
136
137 4-32 (Whyco Chromium Co.Inc.) (a) (b) 131
138 90 (c) rpm 4-11 ab
139 cm Q6 A (a) 133
140 (b) (c) () 134
141 4-4-4 Q7 A
142 I I IA/ I I A/ 4-37 A/
143 Q8 A
144
145 Q9 A (-) (-) () (-) 139
146
147 H ph ph311 ph H ph H ph 2 Q10 A 141
148 5-1-1 (1) Q1 A
149 5-1 (a)
150 rpm Enyedy (1) () 1 14rpm 50cm 20rpm (b)
151 rpm 20cm 190rpm 25cm 28rpm (c) /41/5 145
152 () (d) () 146
153 (2) Q2 A
154 (H10) 148
155 60 PRTR Q3 A (a) UF (b) 149
156 O/W W/O CaCI (3) Q4 (1)(2) A (a) Q5 A
157 5-2 () ()() () () (a) HLB (b) () (c) (d) n- (b) Q6 A 151
158 H H H (c) Q7 A 152
159 (d) Q8 A PRPeriodic reverse PR 510A/ 0.5A/
160 5-3 ( ) PR PR (1) Q9 A 1950 (a)
161 g/l g/l g/l M (A/) Zn² ² Zn² OH ² Hull Wernlund 7590 Na ZnCN NaOH NaOH ZnCN ² 20ZnOH ² NaOH Na ZnOH Na ZnOH NaCN Na ZnCN M M NaCNg/LZng/L
162 g/ L NaCN g/ L L mm250mm mmmm rpm 5.2L Zn M 5-6 (4) 156
163 - (b) Q10 A NaOHZn L PVA 8090L Zn1013LZaOH120150gLNaOH Zn
164 L 911L 90110gL NaOHZn
165 - Q11 A 5-8 g/l g/l g/l g/l g/l H
166 50mgL H H ppm 2ppm 10ppm 50ppm 250ppm (2) 160
167 - - (2) 161
168 (a) Q12 A 5-12 g/l g/l g/l g/l g/l V CuCN NaCN NaCuCN2 (1) NaCuCN2 NaCN Na CuCN (2) Na CuCN3 NaCN Na CuCN4 ² (3) -
169 40gLCu 28g/L
170 - - g/l Cu 2030 () g/l 3050 ()g/l 1015 H g/l Cu (b) H 164
171 S. E. Craig Jr. H (3) Q13 A ()
172 5-16 (Cl Ni² + ² + ² + ² + Q14 - A - 166
173 (a)throwing Power 267ml 0.5A X Field (a)
174 (b)covering Power mm A 20mm100mm 120cm² 0.1Adm² ² + 168
175 190mm250mm 1mm 2mm 8rpm 5.2L 15mm2mm A 0.6Adm 45 m (a) 5-16 f fa bf 169
176 5-14 (a) 5-15 (b) 5-16 (f) 170
177 gl 68gL gl 12gL ² + () NiSO46H2O 150gL NiCl26H2O 100gL NiSO46H2O 250gL NaCl 30gL gl H H Na (4) (a) 171
178 () () 30 g/l 3 g/l 120 g/l 70 g/l 80 g/l A/dm Q15 A
179 () () ()g/l 14g/l) g/l 2060 g/l Adm 0.53Adm Adm 1 20gL 173
180 L 20L 5-24 () g/l g/l g/l g/l A/dm A/dm A/dm 2 A/dm 2 (b) 19 JIS JIS-H JIS-H
181 Q16 A F. I. Nobel cm6.5cm 10rpm 0.71mm1.3cm K Ni 23.9K Co 175
182 H H H H
183 5-18 ph 0.05 Q17 () A rpm 8rpm11rpm 6 250mm 400mm
184 03 6rpm8rpm11rpm () 2 () 95 (0.05)V(0.05) 95 (0.05) () 178
185 (a) T() T (b) () (c) T et (d) F2/27(0.01)5.49 o F2/27(0.01) o rpm 11rpm F (5) (a) (b) 179
186 (c)
187 5-31 abnormal codeposition(induced codeposition) H
188 / 182
189 5-24 / nb n/n² 0.14b/b² 0.13n-u n/n u/u 0.52V nb nb SnPb ()
190 5-26 Pb n-u u n ⁴ u /n u Na SnO 3H O100g/LCuCN25g/L NaCN50g/L NaCN22g/L NaCN NaOH Sn-Cu 5-27 Sn Cu Sn-Cu NaCN NaOH 5-28 Cu Sn SnCu 5-29 Sn-Cu 5-33 Cu /Sn Cu 184
191 5-29 CuSn 5-33 CuSn (1) 185
192 () (2) Q18 A
193 (a)r-OH-r 5-31(b) Cr-O-r
194 () 5-34 () 188
195 Q19 A ph r (a) r r /L r 35g/L g/l r 10/L n 1g/L r 30/L 15g/L H (b)
196
197 (1) (n) 5-37 (1) 191
198 (a) 1/2 5-39(b) (c) 5-39(d) 192
199 mmmm rpm mmmm L /
200
201 200mm 340mm 3mm 50L 1163/L 96/L 405/L 325 /L PVC PP 6 200mm 250mm3 PVC 1mm 2mm 1mm 2mm PP 0.5mmmm 8rpm 15mm2mm Ni 60/l 1/ L % 40% 1mm PVC
202 5-42 () % 40%
203 5-44 ( d 100) 20L ( 10 ) 10 1 ( 10 ) % () 197
204 PP mm PVC 5-47 PP / / / /
205
206
207 ph 201
208 (1) (a) /
209 5-51 (b) A/
210 (c) Throwing Power H Haring (d) Covering Power (2) (a) 204
211 (b) (IC) HPLCCVS (c) (3) H (a)ph ph ph ph11 ph11 H 1 ph311 H 1 1 H H ph ph H H (b) (c) X X 205
212 ISO mm 1) (1995) 2) (1980) 3)(1988) 4)21 (1986) 5)(1979) 6).11(1988) 7).537(1983) 8).44(1988) 9) 59 (1979) 10) 8 (1979) 11).362(1960) 12) (1959) 13) R.F. Enyedy Handbook of Barrel FinishingReinhold(1955) 206
213 14).245(1979) 15).169(1987) 16) 912 (1992) 17) Vol (1994) 18).17(1980) 19) R.O. Hull & C.J. WernlundTrans. Electrochem. Soc.Vol (1941) 20) G.J. Casey Jr.CEF and R.K. AsherCEFPating and Surface Finishing Vol.8.51(1979) 21)1(1978) 22) Vol.17.93(1966) 23) Lugi, V. BrougnatellAnn. Chem.Vol (1800) 24) F. FraryTrans. Amer. Electrochem. Soc. Vol.23.25(1913) 25) E. C. RinkerU.S. Pat (1950) 26) E. A. ParkerPlatingVol (1953) 27) F. I. NobelB. D. OstrowPlatingSep..1099(1966) 28) Vol (1988) 29) Ch. J. Raub Plating and Surface FinishingVol.63.35(1976) 30) F. B. Koch Plating and Surface FinishingVol.67.52(1980) 31),Vol (1980) 32) A. BrennerElectrodepsition of Alloys Academic Press 33) 34) 35) Vol (1985) 36) 37)(1979) 38) A. K. Graham Electroplating Engineering Handbook Van Nostrand Reinhold(1971) 39) Vol (1962) 40) Eugene G. ChapdelainePlatingVol (1966) 207
214 (1) (2) (3)
215 (4) () 209
216 6-4 ()
217 TEL: FAX: Copyright C 2001 All right reserved.
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